Volume 128
Main Index

Issue 01

Nucleobase Orientation and Ordering in Films of Single-Stranded DNA on Gold Dmitri Y. Petrovykh, V. Pérez-Dieste, Aric Opdahl, Hiromi Kimura-Suda, J. M. Sullivan, Michael J. Tarlov, F. J. Himpsel, and Lloyd J. Whitman pp 2–3 DOI: 10.1021/ja052443e Supporting Info

1D Radical Motion in Protein Pocket:  Proton-Coupled Electron Transfer in Human Serum Albumin Yasuhiro Kobori and James R. Norris Jr. pp 4–5 DOI: 10.1021/ja054495+ Supporting Info

Monitoring the Dynamics of Ligand−Receptor Complexes on Model Membranes Suman Lata, Martynas Gavutis, and Jacob Piehler pp 6–7 DOI: 10.1021/ja054700l Supporting Info

Dinuclear Zn-Catalyzed Asymmetric Alkynylation of Unsaturated Aldehydes Barry M. Trost, Andrew H. Weiss, and Axel Jacobi von Wangelin pp 8–9 DOI: 10.1021/ja054871q Supporting Info

A Selective Turn-On Fluorescent Sensor for Imaging Copper in Living Cells Li Zeng, Evan W. Miller, Arnd Pralle, Ehud Y. Isacoff, and Christopher J. Chang pp 10–11 DOI: 10.1021/ja055064u Supporting Info

Synthesis, Structure, and Dynamic Properties of [Ni2Sn17]4- Emren N. Esenturk, James C. Fettinger, and Bryan W. Eichhorn pp 12–13 DOI: 10.1021/ja055379+ Supporting Info

Triplex Formation with α-L-LNA (α-l-Ribo-Configured Locked Nucleic Acid) Niti Kumar, Katrine E. Nielsen, Souvik Maiti, and Michael Petersen pp 14–15 DOI: 10.1021/ja055483r Supporting Info

Generation of Nanopores during Desorption of NH3 from Mg(NH3)6Cl2 Jens S. Hummelshøj, Rasmus Zink Sørensen, Marina Yu. Kustova, Tue Johannessen, Jens K. Nørskov, and Claus Hviid Christensen pp 16–17 DOI: 10.1021/ja0556070 Supporting Info

Rapid Exchange Luminescence:  Nitroxide Quenching and Implications for Sensor Applications Sharon A. Rivera and Bruce S. Hudson pp 18–19 DOI: 10.1021/ja0558490 Supporting Info

Amino Acid Dependent Formation of Phosphate Anhydrides in Water Mediated by Carbonyl Sulfide Luke J. Leman, Leslie E. Orgel, and M. Reza Ghadiri pp 20–21 DOI: 10.1021/ja056036e Supporting Info

Bacillibactin-Mediated Iron Transport in Bacillus subtilis1 Emily A. Dertz, Jide Xu, Alain Stintzi, and Kenneth N. Raymond pp 22–23 DOI: 10.1021/ja055898c Supporting Info

A Dual Parameter FRET Probe for Measuring PKC and PKA Activity in Living Cells Justin Brumbaugh, Andreas Schleifenbaum, Alexander Gasch, Michael Sattler, and Carsten Schultz pp 24–25 DOI: 10.1021/ja0562200 Supporting Info

Energy-Dependent Disassembly of Self-Assembled SNARE Complex:  Observation at Nanometer Resolution Using Atomic Force Microscopy Aleksandar Jeremic, Anthony S. Quinn, Won Jin Cho, Douglas J. Taatjes, and Bhanu P. Jena pp 26–27 DOI: 10.1021/ja056286v Supporting Info

Polarized FTIR Spectroscopy in Conjunction with In Situ H/D Exchange Reveals the Orientation of Protein Internal Carboxylic Acids Florian Garczarek and Klaus Gerwert pp 28–29 DOI: 10.1021/ja056488r

Calorimetric Evidence for a Two-State Unfolding of the β-Hairpin Peptide Trpzip4 Werner W. Streicher and George I. Makhatadze pp 30–31 DOI: 10.1021/ja056392x Supporting Info

Dynamic Transition in tRNA is Solvent Induced Gokhan Caliskan, Robert M. Briber, D. Thirumalai, Victoria Garcia-Sakai, Sarah A. Woodson, and Alexei P. Sokolov pp 32–33 DOI: 10.1021/ja056444i

Two Stable 3D Metal−Organic Frameworks Constructed by Nanoscale Cages via Sharing the Single-Layer Walls Wen-Guan Lu, Cheng-Yong Su, Tong-Bu Lu, Long Jiang, and Jia-Mei Chen pp 34–35 DOI: 10.1021/ja0567337 Supporting Info

Stable Suspension of Layered Double Hydroxide Nanoparticles in Aqueous Solution Zhi Ping Xu, Gregory S. Stevenson, Chao-Qing Lu, Gao Qing (Max) Lu, Perry F. Bartlett, and Peter P. Gray pp 36–37 DOI: 10.1021/ja056652a Supporting Info

A Unimolecular G-Quadruplex that Functions as a Synthetic Transmembrane Na+ Transporter Mark S. Kaucher, William A. Harrell, Jr., and Jeffery T. Davis pp 38–39 DOI: 10.1021/ja056888e Supporting Info

Tris(chloranilato)ferrate(III) Anionic Building Block Containing the (Dihydroxo)oxodiiron(III) Dimer Cation:  Synthesis and Characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5·1.5MeOH·H2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate] Kil Sik Min, Arnold L. Rhinegold, and Joel S. Miller pp 40–41 DOI: 10.1021/ja0566984 Supporting Info

Hydrogel-Encapsulated Lipid Membranes Tae-Joon Jeon, Noah Malmstadt, and Jacob J. Schmidt pp 42–43 DOI: 10.1021/ja056901v

Challenge To Detect 1,4-Zwitterions Spectroscopically in a Ketene−Alkene Reaction Takahisa Machiguchi, Junko Okamoto, Yumiko Morita, and Toshio HasegawaShinichi YamabeTsutomu Minato pp 44–45 DOI: 10.1021/ja054619i Supporting Info

Efficient and Stable Solid-State Light-Emitting Electrochemical Cell Using Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) Hexafluorophosphate Henk J. Bolink, Luca Cappelli, Eugenio Coronado, Michael Grätzel, and Md. K. Nazeeruddin pp 46–47 DOI: 10.1021/ja0565065 Supporting Info

Tris(trimethylsilyl)silyl-Governed Aldehyde Cross-Aldol Cascade Reaction Matthew B. Boxer and Hisashi Yamamoto pp 48–49 DOI: 10.1021/ja054725k Supporting Info

Palladium-Catalyzed Synthesis of 1-Alkylphosphonium Salts from 1-Alkenes Mieko Arisawa and Masahiko Yamaguchi pp 50–51 DOI: 10.1021/ja055775s Supporting Info

Preparation of Alkenyl Cyclopropanes through a Ruthenium-Catalyzed Tandem Enyne Metathesis−Cyclopropanation Sequence Byung Gyu Kim and Marc L. Snapper pp 52–53 DOI: 10.1021/ja055993l Supporting Info

Hydrovinylation of 1,3-Dienes:  A New Protocol, an Asymmetric Variation, and a Potential Solution to the Exocyclic Side Chain Stereochemistry Problem Aibin Zhang and T. V. RajanBabu pp 54–55 DOI: 10.1021/ja0561338 Supporting Info

Catalytic Allylic Alkylation via the Cross-Dehydrogenative-Coupling Reaction between Allylic sp3 C−H and Methylenic sp3 C−H Bonds Zhiping Li and Chao-Jun Li pp 56–57 DOI: 10.1021/ja056541b Supporting Info

Ozonolysis of Phospholipid Double Bonds during Electrospray Ionization:  A New Tool for Structure Determination Michael C. Thomas, Todd W. Mitchell, and Stephen J. Blanksby pp 58–59 DOI: 10.1021/ja056797h Supporting Info

Acid-Triggered Transformation of Diortho Ester Phosphocholine Liposome Zhaohua Huang, Xin Guo, Weijun Li, J. Andrew MacKay, and Francis C. Szoka, Jr. pp 60–61 DOI: 10.1021/ja057024w Supporting Info

A Class of Supported Membranes:  Formation of Fluid Phospholipid Bilayers on Photonic Band Gap Colloidal Crystals Adrian M. Brozell, Michelle A. Muha, Babak Sanii, and Atul N. Parikh pp 62–63 DOI: 10.1021/ja056701j Supporting Info

Nucleotide-Directed Growth of Semiconductor Nanocrystals Sean Hinds, Bradford J. Taft, Larissa Levina, Vlad Sukhovatkin, Chad J. Dooley, Marc D. Roy, Dean D. MacNeil, Edward H. Sargent, and Shana O. Kelley pp 64–65 DOI: 10.1021/ja057002+ Supporting Info

Anion Relay Chemistry:  An Effective Tactic for Diversity Oriented Synthesis Amos B. Smith, III and Ming Xian pp 66–67 DOI: 10.1021/ja057059w Supporting Info

Diastereoselective Proton Transfer:  A Route to Enantiomerically Pure Half-Sandwich Rhenium Complexes Frank Bock, Frank Fischer, and Wolfdieter A. Schenk pp 68–69 DOI: 10.1021/ja057089z Supporting Info

Building Addressable Libraries:  Spatially Isolated, Chip-Based Reductive Amination Reactions Eden Tesfu, Karl Maurer, and Kevin D. Moeller pp 70–71 DOI: 10.1021/ja057155x Supporting Info

High-nuclearity Homoleptic and Heteroleptic Coordination Cages Based on Tetra-Capped Truncated Tetrahedral and Cuboctahedral Metal Frameworks Stephen P. Argent, Harry Adams, Thomas Riis-Johannessen, John C. Jeffery, Lindsay P. Harding, and Michael D. Ward pp 72–73 DOI: 10.1021/ja056993o Supporting Info

Sequential Pd-Catalyzed Asymmetric Allene Diboration/α-Aminoallylation Joshua D. Sieber and James P. Morken pp 74–75 DOI: 10.1021/ja057020r Supporting Info

Determination of the Distance between the Two Neutral Flavin Radicals in Augmenter of Liver Regeneration by Pulsed ELDOR Christopher W. M. Kay, Celine Elsässer, Robert Bittl, Scott R. Farrell, and Colin Thorpe pp 76–77 DOI: 10.1021/ja057308g

Palladium-Catalyzed Alkylation of Aryl C−H Bonds with sp3 Organotin Reagents Using Benzoquinone as a Crucial Promoter Xiao Chen, Jiao-Jie Li, Xue-Shi Hao, Charles E. Goodhue, and Jin-Quan Yu pp 78–79 DOI: 10.1021/ja0570943 Supporting Info

Crystal Structure of the Trigonal Form of Isotactic Polypropylene as an Example of Density-Driven Polymer Structure Claudio De Rosa, Finizia Auriemma, Paolo Corradini, Oreste Tarallo, Stefania Dello Iacono, Eleonora Ciaccia, and Luigi Resconi pp 80–81 DOI: 10.1021/ja0572957 Supporting Info

Stoichiometric Aerobic PtII−Me Bond Cleavage in Aqueous Solutions to Produce Methanol and a PtII(OH) Complex Andrei N. Vedernikov, Seth A. Binfield, Peter Y. Zavalij, and Julia R. Khusnutdinova pp 82–83 DOI: 10.1021/ja0575171 Supporting Info

Enantioselective Organocatalytic Reductive Amination R. Ian Storer, Diane E. Carrera, Yike Ni, and David W. C. MacMillan pp 84–86 DOI: 10.1021/ja057222n Supporting Info

Total Synthesis of Ecteinascidin 743 Jinchun Chen, Xiaochuan Chen, Michèle Bois-Choussy, and Jieping Zhu pp 87–89 DOI: 10.1021/ja0571794 Supporting Info

Dynamics of the Degenerate Rearrangement of Bicyclo[3.1.0]hex-2-ene Charles Doubleday, Christopher P. Suhrada, and K. N. Houk pp 90–94 DOI: 10.1021/ja050722w Supporting Info

Rapidly Functionalized, Water-Dispersed Carbon Nanotubes at High Concentration Yubing Wang, Zafar Iqbal, and Somenath Mitra pp 95–99 DOI: 10.1021/ja053003q

Exploring the Use of Conformationally Locked Aminoglycosides as a New Strategy to Overcome Bacterial Resistance Agatha Bastida, Ana Hidalgo, Jose Luis Chiara, Mario Torrado, Francisco Corzana, Jose Manuel Pérez-Cañadillas, Patrick Groves, Eduardo Garcia-Junceda, Carlos Gonzalez, Jesús Jimenez-Barbero, and Juan Luis Asensio pp 100–116 DOI: 10.1021/ja0543144 Supporting Info

Reagentless, Reusable, Ultrasensitive Electrochemical Molecular Beacon Aptasensor Abd-Elgawad Radi, Josep Lluis Acero Sánchez, Eva Baldrich, and Ciara K. O'Sullivan pp 117–124 DOI: 10.1021/ja053121d

Computer Simulation of the Distribution of Hexane in a Lipid Bilayer:  Spatially Resolved Free Energy, Entropy, and Enthalpy Profiles Justin L. MacCallum and D. Peter Tieleman pp 125–130 DOI: 10.1021/ja0535099

Origin of Bulklike Structure and Bond Length Disorder of Pt37 and Pt6Ru31 Clusters on Carbon:  Comparison of Theory and Experiment Lin-Lin Wang, Sanjay V. Khare, Valeriu Chirita, D. D. Johnson, Angus A. Rockett, Anatoly I. Frenkel, Nathan H. Mack, and Ralph G. Nuzzo pp 131–142 DOI: 10.1021/ja053896m

Hydrophobicity, Shape, and π-Electron Contributions during Translesion DNA Synthesis Xuemei Zhang, Irene Lee, Xiang Zhou, and Anthony J. Berdis pp 143–149 DOI: 10.1021/ja0546830 Supporting Info

Direct-Detected 13C NMR to Investigate the Iron(III) Hemophore HasA Célia Caillet-Saguy, Muriel Delepierre, Anne Lecroisey, Ivano Bertini, Mario Piccioli, and Paola Turano pp 150–158 DOI: 10.1021/ja054902h Supporting Info

Orientation and Conformational Preference of Leucine-Enkephalin at the Surface of a Hydrated Dimyristoylphosphatidylcholine Bilayer:  NMR and MD Simulation Indira Chandrasekhar, Wilfred F. van Gunsteren, Giorgia Zandomeneghi, Philip T. F. Williamson, and Beat H. Meier pp 159–170 DOI: 10.1021/ja054785q Supporting Info

Electron Transfer Kinetics at Polarized Nanoscopic Liquid/Liquid Interfaces Chenxin Cai and Michael V. Mirkin pp 171–179 DOI: 10.1021/ja055091k

Electron Flow in Multicenter Enzymes:  Theory, Applications, and Consequences on the Natural Design of Redox Chains Christophe Léger, Florence Lederer, Bruno Guigliarelli, and Patrick Bertrand pp 180–187 DOI: 10.1021/ja055275z Supporting Info

Selective Protein−Protein Interactions Driven by a Phenylalanine Interface Nicholas C. Yoder and Krishna Kumar pp 188–191 DOI: 10.1021/ja055494k Supporting Info

Visualizing Association of N-Ras in Lipid Microdomains:  Influence of Domain Structure and Interfacial Adsorption Chiara Nicolini, Jörg Baranski, Stefanie Schlummer, José Palomo, Maria Lumbierres-Burgues, Martin Kahms, Jürgen Kuhlmann, Susana Sanchez, Enrico Gratton, Herbert Waldmann, and Roland Winter pp 192–201 DOI: 10.1021/ja055779x

Insertion of Polar and Nonpolar Unsaturated Molecules into Carbon−Rhenium Bonds Generated by C−H Bond Activation:  Synthesis of Phthalimidine and Indene Derivatives Yoichiro Kuninobu, Yukimi Tokunaga, Atsushi Kawata, and Kazuhiko Takai pp 202–209 DOI: 10.1021/ja054216i Supporting Info

Excited-State Potential Energy Surface for the Photophysics of Adenine Lluís Blancafort pp 210–219 DOI: 10.1021/ja054998f Supporting Info

Vacuum Ultraviolet Photoionization of C3 Christophe Nicolas, Jinian Shu, Darcy S. Peterka, Majdi Hochlaf, Lionel Poisson, Stephen R. Leone, and Musahid Ahmed pp 220–226 DOI: 10.1021/ja055430+ Supporting Info

A Mild Pummerer-Like Reaction of Carbohydrate-Based Selenoethers and Thioethers Involving Linear Ozonide Acetates as Putative Intermediates Natacha Veerapen, Stephanie. A. Taylor, Charles. J. Walsby, and B. Mario Pinto pp 227–239 DOI: 10.1021/ja0557029 Supporting Info

Multilayered Polymer Microspheres by Thermal Imprinting during Microsphere Growth Ryu Takekoh, Wen-Hui Li, Nicholas A. D. Burke, and Harald D. H. Stöver pp 240–244 DOI: 10.1021/ja055901s

Potentiation of the Cytotoxicity of the Anticancer Agent Tirapazamine by Benzotriazine N-oxides:  The Role of Redox Equilibria Robert F. Anderson, Sujata S. Shinde, Michael P. Hay, and William A. Denny pp 245–249 DOI: 10.1021/ja0559101 Supporting Info

Intramolecularly Sensitized Precipitons:  A Model System for Application to Metal Sequestration Mark R. Ams and Craig S. Wilcox pp 250–256 DOI: 10.1021/ja0561340 Supporting Info

Synthesis of InAs/CdSe/ZnSe Core/Shell1/Shell2 Structures with Bright and Stable Near-Infrared Fluorescence Assaf Aharoni, Taleb Mokari, Inna Popov, and Uri Banin pp 257–264 DOI: 10.1021/ja056326v

Ethanol-Induced Reorganization of the Liquid-Ordered Phase:  Enhancement of Cholesterol−Phospholipid Association Jianbing Zhang, Honghua Cao, Bingwen Jing, and Steven L. Regen pp 265–269 DOI: 10.1021/ja056918d Supporting Info

Photoinduced Magnetization in Copper Octacyanomolybdate Shin-ichi Ohkoshi, Hiroko Tokoro, Toshiya Hozumi, Yue Zhang, Kazuhito Hashimoto, Corine Mathonière, Isabelle Bord, Guillaume Rombaut, Marc Verelst, Christophe Cartier dit Moulin, and Françoise Villain pp 270–277 DOI: 10.1021/ja0559092 Supporting Info

Mechanism of N2O Reduction by the μ4-S Tetranuclear CuZ Cluster of Nitrous Oxide Reductase Serge I. Gorelsky, Somdatta Ghosh, and Edward I. Solomon pp 278–290 DOI: 10.1021/ja055856o Supporting Info

Crossover Point between Dialkoxy Disulfides (ROSSOR) and Thionosulfites ((RO)2SS):  Prediction, Synthesis, and Structure Eli Zysman-Colman, Neysa Nevins, Nicolas Eghbali, James P. Snyder, and David N. Harpp pp 291–304 DOI: 10.1021/ja0559395 Supporting Info

Models for the Molybdenum Hydroxylases:  Synthesis, Characterization and Reactivity of cis-Oxosulfido-Mo(VI) Complexes Christian J. Doonan, David J. Nielsen, Paul D. Smith, Jonathan M. White, Graham N. George, and Charles G. Young pp 305–316 DOI: 10.1021/ja056109u Supporting Info

Solvent Controlled Self-Assembly at the Liquid-Solid Interface Revealed by STM Wael Mamdouh, Hiroshi Uji-i, Janine S. Ladislaw, Andres E. Dulcey, Virgil Percec, Frans C. De Schryver, and Steven De Feyter pp 317–325 DOI: 10.1021/ja056175w Supporting Info

Gold Nanoclusters Protected by Conformationally Constrained Peptides Laura Fabris, Sabrina Antonello, Lidia Armelao, Robert L. Donkers, Federico Polo, Claudio Toniolo, and Flavio Maran pp 326–336 DOI: 10.1021/ja0560581 Supporting Info

Modulating Protein Structure with Fluorous Amino Acids:  Increased Stability and Native-like Structure Conferred on a 4-Helix Bundle Protein by Hexafluoroleucine Hyang-Yeol Lee, Kyung-Hoon Lee, Hashim M. Al-Hashimi, and E. Neil G. Marsh pp 337–343 DOI: 10.1021/ja0563410 Supporting Info

8-Hydroxyquinoline Derivatives as Fluorescent Sensors for Magnesium in Living Cells Giovanna Farruggia, Stefano Iotti, Luca Prodi, Marco Montalti, Nelsi Zaccheroni, Paul B. Savage, Valentina Trapani, Patrizio Sale, and Federica I. Wolf pp 344–350 DOI: 10.1021/ja056523u

Lewis Acidity of Methyltrioxorhenium(VII) (MTO) Based on the Relative Binding Strengths of N-Donors S. Masoud Nabavizadeh and Mehdi Rashidi pp 351–357 DOI: 10.1021/ja056505c

Hydrogen Oxidation and Production Using Nickel-Based Molecular Catalysts with Positioned Proton Relays Aaron D. Wilson, Rachel H. Newell, Michael J. McNevin, James T. Muckerman, M. Rakowski DuBois, and Daniel L. DuBois pp 358–366 DOI: 10.1021/ja056442y Supporting Info

Encapsulation of Fluorescent Molecules by Functionalized Polymeric Nanocontainers:  Investigation by Confocal Fluorescence Imaging and Fluorescence Correlation Spectroscopy Per Rigler and Wolfgang Meier pp 367–373 DOI: 10.1021/ja056719u Supporting Info

Surface Modification of Confined Microgeometries via Vapor-Deposited Polymer Coatings Hsien-Yeh Chen, Yaseen Elkasabi, and Joerg Lahann pp 374–380 DOI: 10.1021/ja057082h Supporting Info

Issue 02

Structure, Stability, and Hydration of a Polypeptide in AOT Reverse Micelles Stéphane Abel, Marcel Waks, Wladimir Urbach, and Massimo Marchi pp 382–383 DOI: 10.1021/ja053043u Supporting Info

Palladium-Catalyzed [3 + 2] Intramolecular Cycloaddition of Alk-5-enylidenecyclopropanes Moisés Gulías, Rebeca García, Alejandro Delgado, Luis Castedo, and José L. Mascareñas pp 384–385 DOI: 10.1021/ja054487t Supporting Info

Synthesis of an Artificial Cell Surface Receptor that Enables Oligohistidine Affinity Tags to Function as Metal-Dependent Cell-Penetrating Peptides Siwarutt Boonyarattanakalin, Sonalee Athavankar, Qi Sun, and Blake R. Peterson pp 386–387 DOI: 10.1021/ja056126j Supporting Info

The Incorporation of a Photoisomerizable Amino Acid into Proteins in E. coli Mohua Bose, Dan Groff, Jianming Xie, Eric Brustad, and Peter G. Schultz pp 388–389 DOI: 10.1021/ja055467u Supporting Info

Biomolecular Embossing John P. Hulme, Jihye Gwak, and Yuji Miyahara pp 390–391 DOI: 10.1021/ja055805r Supporting Info

A Mild Etch for the Fabrication of Three-Dimensional Nanostructures in Gold Robert E. Ducker and Graham J. Leggett pp 392–393 DOI: 10.1021/ja0555771 Supporting Info

Kinetic Isotope Effect is a Sensitive Probe of Spin State Reactivity in C−H Hydroxylation of N,N-Dimethylaniline by Cytochrome P450 Chunsen Li, Wei Wu, Devesh Kumar, and Sason Shaik pp 394–395 DOI: 10.1021/ja055987p Supporting Info

Enhanced Base Pairing and Replication Efficiency of Thiothymidines, Expanded-size Variants of Thymidine Herman O. Sintim and Eric T. Kool pp 396–397 DOI: 10.1021/ja0562447 Supporting Info

A Ratiometric Fluorescent Viscosity Sensor Mark A. Haidekker, Thomas P. Brady, Darcy Lichlyter, and Emmanuel A. Theodorakis pp 398–399 DOI: 10.1021/ja056370a Supporting Info

A Luminescent Silver−Adenine Metallamacrocyclic Quartet Chandra Shekhar Purohit and Sandeep Verma pp 400–401 DOI: 10.1021/ja056452z Supporting Info

Zinc(II)- and Copper(I)-Mediated Large Two-Photon Absorption Cross Sections in a Bis-cinnamaldiminato Schiff Base Sanjib Das, Amit Nag, Debabrata Goswami, and Parimal K. Bharadwaj pp 402–403 DOI: 10.1021/ja056771q Supporting Info

Direct Observation of Enhanced Translocation of a Homeodomain between DNA Cognate Sites by NMR Exchange Spectroscopy Junji Iwahara and G. Marius Clore pp 404–405 DOI: 10.1021/ja056786o Supporting Info

Self-Trapping of Spatially and Temporally Incoherent White Light in a Photochemical Medium Jihua Zhang, Kailash Kasala, Abhitej Rewari, and Kalaichelvi Saravanamuttu pp 406–407 DOI: 10.1021/ja056838+ Supporting Info

Titanium(II)-Mediated Cyclizations of (Silyloxy)enynes:  A Total Synthesis of (−)-7-Demethylpiericidin A1 Katie A. Keaton and Andrew J. Phillips pp 408–409 DOI: 10.1021/ja057434k Supporting Info

Targeted Cleavage of HIV Rev Response Element RNA by Metallopeptide Complexes Yan Jin and J. A. Cowan pp 410–411 DOI: 10.1021/ja055272m Supporting Info

Accelerated Electrocyclic Ring-Opening of Benzocyclobutenes under the Influence of a β-Silicon Atom Yuji Matsuya, Noriko Ohsawa, and Hideo Nemoto pp 412–413 DOI: 10.1021/ja055505+ Supporting Info

Direct Measure of the Hydration Number of Aqueous Methane Steven F. Dec, Kristin E. Bowler, Laura L. Stadterman, Carolyn A. Koh, and E. Dendy Sloan, Jr. pp 414–415 DOI: 10.1021/ja055283f Supporting Info

Direct Observation of Reactive Trapped Holes in TiO2 Undergoing Photocatalytic Oxidation of Adsorbed Alcohols:  Evaluation of the Reaction Rates and Yields Yoshiaki Tamaki, Akihiro Furube, Miki Murai, Kohjiro Hara, Ryuzi Katoh, and M. Tachiya pp 416–417 DOI: 10.1021/ja055866p Supporting Info

Selective Labeling of Extracellular Proteins Containing Polyhistidine Sequences by a Fluorescein−Nitrilotriacetic Acid Conjugate Christian R. Goldsmith, Jacek Jaworski, Morgan Sheng, and Stephen J. Lippard pp 418–419 DOI: 10.1021/ja0559754 Supporting Info

Facile Synthesis of Tin Oxide Nanoparticles Stabilized by Dendritic Polymers Venkateswarlu Juttukonda, Robert L. Paddock, Jeffery E. Raymond, Dan Denomme, Andrew E. Richardson, Laura E. Slusher, and Bradley D. Fahlman pp 420–421 DOI: 10.1021/ja056902n Supporting Info

A Stable Silaborene:  Synthesis and Characterization Norio Nakata and Akira Sekiguchi pp 422–423 DOI: 10.1021/ja0570741 Supporting Info

A Planar Water Tetramer with Tetrahedrally Coordinated Water Embedded in a Hydrogen Bonding Network of [Tc4(CO)12-(μ3-OH)4·4H2O] Maaz Zuhayra, Willm Uwe Kampen, Eberhard Henze, Zsolt Soti, Laslo Zsolnai, Gottfried Huttner, and Franz Oberdorfer pp 424–425 DOI: 10.1021/ja057142j Supporting Info

Total Synthesis of UCS1025A Tristan H. Lambert and Samuel J. Danishefsky pp 426–427 DOI: 10.1021/ja0574567 Supporting Info

Hydrogen-Substituted Osmium Silylene Complexes:  Effect of Charge Localization on Catalytic Hydrosilation Paul G. Hayes, Chad Beddie, Michael B. Hall, Rory Waterman, and T. Don Tilley pp 428–429 DOI: 10.1021/ja057494q Supporting Info

Self-Assembled Nanodisks with Targetlike Multirings Aggregated at the Air−Water Interface Xiaoheng Liu, Chun Kan, Xin Wang, Xujie Yang, and Lude Lu pp 430–431 DOI: 10.1021/ja057390f Supporting Info

Polyhydroxylated Sapphyrins:  Multisite Non-metallic Catalysts for Activated Phosphodiester Hydrolysis Vladimír Král, Kamil Lang, Jarmila Králová, Michal Dvořák, Pavel Martásek, Aileen O. Chin, Andrei Andrievsky, Vincent Lynch, and Jonathan L. Sessler pp 432–437 DOI: 10.1021/ja0518474 Supporting Info

Changes in Coordination of Sterically Demanding Hybrid Imidazolylphosphine Ligands on Pd(0) and Pd(II) Douglas B. Grotjahn, Yi Gong, Lev Zakharov, James A. Golen, and Arnold L. Rheingold pp 438–453 DOI: 10.1021/ja054779u Supporting Info

Steric Control of Bacteriochlorophyll Ligation Agnieszka Kania and Leszek Fiedor pp 454–458 DOI: 10.1021/ja055537x

Synthesis of Transient and Stable C-Amino Phosphorus Ylides and Their Fragmentation into Transient and Stable Carbenes Yves Canac, Salvador Conejero, Michèle Soleilhavoup, Bruno Donnadieu, and Guy Bertrand pp 459–464 DOI: 10.1021/ja055863c Supporting Info

Organometallic Enantiomeric Scaffolding:  Organometallic Chirons. Total Synthesis of (−)-Bao Gong Teng A by a Molybdenum-Mediated [5+2] Cycloaddition Yongqiang Zhang and Lanny S. Liebeskind pp 465–472 DOI: 10.1021/ja055623x Supporting Info

Gauging the Relative Oxidative Powers of Compound I, Ferric-Hydroperoxide, and the Ferric-Hydrogen Peroxide Species of Cytochrome P450 Toward C−H Hydroxylation of a Radical Clock Substrate Etienne Derat, Devesh Kumar, Hajime Hirao, and Sason Shaik pp 473–484 DOI: 10.1021/ja056328f Supporting Info

Oxygen Independent DNA Interstrand Cross-Link Formation by a Nucleotide Radical In Seok Hong, Hui Ding, and Marc M. Greenberg pp 485–491 DOI: 10.1021/ja0563657 Supporting Info

Specific Ion Pairing and Interfacial Hydration as Controlling Factors in Gemini Micelle Morphology. Chemical Trapping Studies Yan Geng, Laurence S. Romsted, and Fred Menger pp 492–501 DOI: 10.1021/ja056807e Supporting Info

NO-Releasing Zeolites and Their Antithrombotic Properties Paul S. Wheatley, Anthony R. Butler, Michael S. Crane, Sarah Fox, Bo Xiao, Adriano G Rossi, Ian L. Megson, and Russell E. Morris pp 502–509 DOI: 10.1021/ja0503579

Super-Helix Formation Induced by Cyanine J-Aggregates onto Random-Coil Carboxymethyl Amylose as Template Oh-Kil Kim, Jongtae Je, Glenn Jernigan, Leonard Buckley, and David Whitten pp 510–516 DOI: 10.1021/ja0533141 Supporting Info

Infrared Spectroscopy of Phenylalanine Ag(I) and Zn(II) Complexes in the Gas Phase Nick C. Polfer, Jos Oomens, David T. Moore, Gert von Helden, Gerard Meijer, and Robert C. Dunbar pp 517–525 DOI: 10.1021/ja0549291 Supporting Info

Self-organization of Rotaxane Thin Films into Spatially Correlated Nanostructures:  Morphological and Structural Aspects Jean-François Moulin, Jean Crispin Kengne, Rajendra Kshirsagar, Massimilliano Cavallini, Fabio Biscarini, Salvador León, Francesco Zerbetto, Giovanni Bottari, and David A. Leigh pp 526–532 DOI: 10.1021/ja054886o Supporting Info

Sulfur K-Edge XAS and DFT Calculations on Nitrile Hydratase:  Geometric and Electronic Structure of the Non-heme Iron Active Site Abhishek Dey, Marina Chow, Kayoko Taniguchi, Priscilla Lugo-Mas, Steven Davin, Mizuo Maeda, Julie A. Kovacs, Masafumi Odaka, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 533–541 DOI: 10.1021/ja0549695 Supporting Info

Dynamics of Electron Transport by Elastic Bending of Short DNA Duplexes. Experimental Study and Quantitative Modeling of the Cyclic Voltammetric Behavior of 3‘-Ferrocenyl DNA End-Grafted on Gold Agnès Anne and Christophe Demaille pp 542–557 DOI: 10.1021/ja055112a Supporting Info

Anion-Promoted Cation Motion and Conduction in Zeolites Edgar Jordan, Robert G. Bell, Dirk Wilmer, and Hubert Koller pp 558–567 DOI: 10.1021/ja0551887

Magnetic Coupling in Dinuclear Gd Complexes Lindsay E. Roy and Timothy Hughbanks pp 568–575 DOI: 10.1021/ja055035j Supporting Info

Imaging of Ultrafast Molecular Elimination Reactions Wim G. Roeterdink, Anouk M. Rijs, and Maurice H. M. Janssen pp 576–580 DOI: 10.1021/ja055658x

Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides:  Intramolecular Studies Leading to New Intermolecular Reactions Louis-Charles Campeau, Mathieu Parisien, Annie Jean, and Keith Fagnou pp 581–590 DOI: 10.1021/ja055819x Supporting Info

Isotropic−Nematic Phase Transition of Single-Walled Carbon Nanotubes in Strong Acids Pradeep K. Rai, Robert A. Pinnick, A. Nicholas G. Parra-Vasquez, Virginia A. Davis, Howard K. Schmidt, Robert H. Hauge, Richard E. Smalley, and Matteo Pasquali pp 591–595 DOI: 10.1021/ja055847f Supporting Info

On the Role of Tetramethylammonium Cation and Effects of Solvent Dynamics on the Stability of the Cage-like Silicates Si6O156- and Si8O208- in Aqueous Solution. A Molecular Dynamics Study Stavros Caratzoulas, Dionisis G. Vlachos, and Michael Tsapatsis pp 596–606 DOI: 10.1021/ja0561136

Singlet Excited-State Behavior of Uracil and Thymine in Aqueous Solution:  A Combined Experimental and Computational Study of 11 Uracil Derivatives Thomas Gustavsson, Ákos Bányász, Elodie Lazzarotto, Dimitra Markovitsi, Giovanni Scalmani, Michael J. Frisch, Vincenzo Barone, and Roberto Improta pp 607–619 DOI: 10.1021/ja056181s Supporting Info

Arginine- and Lysine-Specific Polymers for Protein Recognition and Immobilization Christian Renner, Jacob Piehler, and Thomas Schrader pp 620–628 DOI: 10.1021/ja0560229 Supporting Info

Structure−Property Correlation of CdSe Clusters Using Experimental Results and First-Principles DFT Calculations Rajan Jose, Nurbosyn U. Zhanpeisov, Hiroshi Fukumura, Yoshinobu Baba, and Mitsuru Ishikawa pp 629–636 DOI: 10.1021/ja0565018 Supporting Info

Host−Guest Complexes between an Aromatic Molecular Tweezer and Symmetric and Unsymmetric Dendrimers with a 4,4‘-Bipyridinium Core Vincenzo Balzani, Heinz Bandmann, Paola Ceroni, Carlo Giansante, Uwe Hahn, Frank-Gerrit Klärner, Ute Müller, Walter M. Müller, Carla Verhaelen, Veronica Vicinelli, and Fritz Vögtle pp 637–648 DOI: 10.1021/ja056615j Supporting Info

Influence of Intermolecular Orientation on the Photoinduced Charge Transfer Kinetics in Self-Assembled Aggregates of Donor−Acceptor Arrays Edwin H. A. Beckers, Stefan C. J. Meskers, Albertus P. H. J. Schenning, Zhijian Chen, Frank Würthner, Philippe Marsal, David Beljonne, Jérôme Cornil, and René A. J. Janssen pp 649–657 DOI: 10.1021/ja0568042 Supporting Info

DNA Hole Transport on an Electrode:  Application to Effective Photoelectrochemical SNP Typing Akimitsu Okamoto, Taku Kamei, and Isao Saito pp 658–662 DOI: 10.1021/ja057040t

Computational De Novo Design and Characterization of a Four-Helix Bundle Protein that Selectively Binds a Nonbiological Cofactor [J. Am. Chem. Soc. 2005, 127, 1346−1347]. Frank V. Cochran, Sophia P. Wu, Wei Wang, Vikas Nanda, Jeffery G. Saven, Michael J. Therien, and William F. DeGrado p 663 DOI: 10.1021/ja059923q Supporting Info

Arthur Suite V. 3.0 Symyx Technologies, Inc., 3100 Central Expressway, Santa Clara, CA 95051. www. symyx.com. See Web site for pricing information. Frank Schoenen and Jeffrey Aubé pp 664–665 DOI: 10.1021/ja0597449

The Chemistry of Cyclobutanes, Parts 1−2 Edited by Zvi Rappoport (The Hebrew University, Jerusalem) and Joel F. Liebman (University of Maryland, Baltimore County). from the Patai Series:  The Chemistry of Functional Groups. Edited by Zvi Rappoport. John Wiley & Sons Ltd.:  Chichester, 2005. xix + 616 pp, xix + 610 pp. $855.00. ISBN 0-470-86400-1. Arthur Greenberg p 666 DOI: 10.1021/ja0597855

LC/MS:  A Practical User's Guide By Marvin C. McMaster (University of Missouri-St. Louis). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xii + 166 pp. $69.95. ISBN 0-471-65531-7. pp 666–667 DOI: 10.1021/ja059829+

Metallopolymer Nanocomposites By Anatoli D. Pomogailo (Russian Academy of Sciences, Moscow Region) and Vladimir N. Kestelman (KVN International, King of Prussia, PA). Springer:  Berlin, Heidelberg, New York. 2005. xx + 564 pp. $199.00. ISBN 0-540-20949-2. Patty Wisian-Neilson p 667 DOI: 10.1021/ja0598107

Theilheimer's Synthetic Methods of Organic Chemistry, Volume 67, 2005 Edited by Alan F. Finch (Cambridge). S. Karger AG and the Thomson Corporation:  Basel, Switzerland. 2005. xxviii + 398 pp. $632.00. ISBN 3-8055-7988-8. p 667 DOI: 10.1021/ja0598210

Annual Review of Materials Research, Volume 35, 2005 Edited by Co-Editors David R. Clarke (University of California, Santa Barbara) and Manfred Rühle (Max-Planck Institute, Stuttgart) and Associate Editor John C. Bravman (Stanford University). Guest Editors include Sir John M. Thomas (The Royal Institute of Great Britain) and Pratibha L. Gai (DuPont and the University of Delaware). Annual Reviews:  Palo Alto, CA. 2005. xii + 662 pp. $208 (print only), $208 (online only), and $250 (print and online). ISBN 0-8243-1735-1. p 667 DOI: 10.1021/ja059828h

Perspectives in Flavor and Fragrance Research Edited by Philip Kraft (Givaudan Schweiz, AG, Dübendorf, Switzerland) and Karl A. D. Swift (Maybridge Ltd., Cornwall, UK). VHCA:  Zürich and Wiley-VCH GmbH & Co. KGaA:  Weinheim. 2005. viii + 242 pp. $170.00. ISBN 3-906390-36-5. pp 667–668 DOI: 10.1021/ja059807n

Annual Review of Biophysics and Biomolecular Structure, Volume 34, 2005 Edited by Douglas C. Rees (California Institute of Technology), Michael P. Sheetz (Columbia University), and James R. Williamson (The Scripps Research Institute). Annual Reviews:  Palo Alto, CA. 2005. xii + 490 pp. $86.00 for individuals print and online. ISBN 0-8243-1834-X. p 668 DOI: 10.1021/ja059808f

Handbook of Condensation Thermoplastic Elastomers Edited by Stoyko Fakirov (University of Sofia, Bulgaria). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xxiv + 620 pp. $330.00. ISBN 3-527-30976-4. p 668 DOI: 10.1021/ja059813j

Issue 03

Dehydration in the Folding of Reduced Cytochrome c Revealed by the Electron-Transfer-Triggered Folding under High Pressure Tetsunari Kimura, Koichi Sakamoto, Isao Morishima, and Koichiro Ishimori pp 670–671 DOI: 10.1021/ja055084w Supporting Info

Folding and Unfolding of Chromophoric Foldamers Show Unusual Colorful Single Molecule Spectral Dynamics Jason J. Han, Wei Wang, and Alexander D. Q. Li pp 672–673 DOI: 10.1021/ja0552287 Supporting Info

Solvent-Tuned Azido-Bridged Co2+ Layers:  Square, Honeycomb, and Kagomé Xin-Yi Wang, Lu Wang, Zhe-Ming Wang, and Song Gao pp 674–675 DOI: 10.1021/ja055725n Supporting Info

Fabrication of Antibody Arrays Using Thermally Responsive Elastin Fusion Proteins Di Gao, Nicole McBean, Jerome S. Schultz, Yushan Yan, Ashok Mulchandani, and Wilfred Chen pp 676–677 DOI: 10.1021/ja056364e Supporting Info

NMR Imino Proton Exchange Experiments on Duplex DNA Primarily Monitor the Opening of Purine Bases U. Deva Priyakumar and Alexander D. MacKerell, Jr. pp 678–679 DOI: 10.1021/ja056445a Supporting Info

Efficient Intramolecular Energy Transfer in Single Endcapped Conjugated Polymer Molecules in the Absence of Appreciable Spectral Overlap Klaus Becker, John M. Lupton, Jochen Feldmann, Sepas Setayesh, Andrew C. Grimsdale, and Klaus Müllen pp 680–681 DOI: 10.1021/ja056469h

Gluing Langmuir−Blodgett Monolayers onto Hydrocarbon Surfaces Junwei Li, Vaclav Janout, and Steven L. Regen pp 682–683 DOI: 10.1021/ja0565469 Supporting Info

Photoresponsive Multilayer Spiral Nanotubes:  Intercalation of Polyfluorinated Cationic Azobenzene Surfactant into Potassium Niobate Zhiwei Tong, Shinsuke Takagi, Tetsuya Shimada, Hiroshi Tachibana, and Haruo Inoue pp 684–685 DOI: 10.1021/ja0564564 Supporting Info

Fractal-like Self-Assembly of Oligo(p-phenylene vinylene) Capped Gold Nanoparticles Jeroen van Herrikhuyzen, René A. J. Janssen, E. W. Meijer, Stefan C. J. Meskers, and Albertus P. H. J. Schenning pp 686–687 DOI: 10.1021/ja056504k Supporting Info

Magnetic Fluorescent Delivery Vehicle Using Uniform Mesoporous Silica Spheres Embedded with Monodisperse Magnetic and Semiconductor Nanocrystals Jaeyun Kim, Ji Eun Lee, Jinwoo Lee, Jung Ho Yu, Byoung Chan Kim, Kwangjin An, Yosun Hwang, Chae-Ho Shin, Je-Geun Park, Jungbae Kim, and Taeghwan Hyeon pp 688–689 DOI: 10.1021/ja0565875 Supporting Info

Intramolecular π-Dimerization in a 1,1‘-Bis(verdazyl)ferrocene Diradical Bryan D. Koivisto, Andrew S. Ichimura, Robert McDonald, Martin T. Lemaire, Laurence K. Thompson, and Robin G. Hicks pp 690–691 DOI: 10.1021/ja0566331 Supporting Info

Electrochemical Evaluation of Alternating Duplex−Triplex Conversion Effect on the Anthraquinone-Photoinjected Hole Transport through DNA Duplex Immobilized on a Gold Electrode Kazuhito Tanabe, Haruka Iida, Ken-ichi Haruna, Taku Kamei, Akimitsu Okamoto, and Sei-ichi Nishimoto pp 692–693 DOI: 10.1021/ja0568244 Supporting Info

Intercepting Palladacycles Derived by C−H Insertion. A Mechanism-Driven Entry to Heterocyclic Tetraphenylenes David Masselot, Jonathan P. H. Charmant, and Timothy Gallagher pp 694–695 DOI: 10.1021/ja056964d Supporting Info

“Click Peptide” Based on the “O-Acyl Isopeptide Method”:  Control of Aβ1−42 Production from a Photo-Triggered Aβ1−42 Analogue Atsuhiko Taniguchi, Youhei Sohma, Maiko Kimura, Takuma Okada, Keisuke Ikeda, Yoshio Hayashi, Tooru Kimura, Shun Hirota, Katsumi Matsuzaki, and Yoshiaki Kiso pp 696–697 DOI: 10.1021/ja057100v Supporting Info

Permeability of a Seemingly Nonporous Crystal Formed by a Discrete Metallocyclic Complex Liliana Dobrzańska, Gareth O. Lloyd, Helgard G. Raubenheimer, and Leonard J. Barbour pp 698–699 DOI: 10.1021/ja057122h Supporting Info

Direct Formation of Micro-/Nanocrystalline 2,5-Dimethyl-N,N‘-dicyanoquinonediimine Complexes on SiO2/Si Substrates and Multiprobe Measurement of Conduction Properties Hiroshi M. Yamamoto, Hiromi Ito, Kunji Shigeto, Kazuhito Tsukagoshi, and Reizo Kato pp 700–701 DOI: 10.1021/ja057176r Supporting Info

Twisted, Z-Shaped Perylene Bisimide Faysal Ilhan, Daniel S. Tyson, Daniel J. Stasko, Kristin Kirschbaum, and Michael A. Meador pp 702–703 DOI: 10.1021/ja056912o Supporting Info

Crystal Structures of the Chiral Lithiosilanes [(Lis)-PhMe2SiLi·THF·(−)-Sparteine] and [Ph2(NEt2)SiLi·(−)-Sparteine] Carsten Strohmann, Christian Däschlein, and Dominik Auer pp 704–705 DOI: 10.1021/ja057348k Supporting Info

BiScO3:  Centrosymmetric BiMnO3-type Oxide Alexei A. Belik, Satoshi Iikubo, Katsuaki Kodama, Naoki Igawa, Shin-ichi Shamoto, Makoto Maie, Takuro Nagai, Yoshio Matsui, Sergey Yu. Stefanovich, Bogdan I. Lazoryak, and Eiji Takayama-Muromachi pp 706–707 DOI: 10.1021/ja057574u Supporting Info

Helix-Sense Controlled Polymerization of a Single Phenyl Isocyanide Enantiomer Leading to Diastereomeric Helical Polyisocyanides with Opposite Helix-Sense and Cholesteric Liquid Crystals with Opposite Twist-Sense Takashi Kajitani, Kento Okoshi, Shin-ichiro Sakurai, Jiro Kumaki, and Eiji Yashima pp 708–709 DOI: 10.1021/ja0576536 Supporting Info

The Square-Planar Cytotoxic [CuII(pyrimol)Cl] Complex Acts as an Efficient DNA Cleaver without Reductant Palanisamy Uma Maheswari, Sudeshna Roy, Hans den Dulk, Sharief Barends, Gilles van Wezel, Bojan Kozlevar, Patrick Gamez, and Jan Reedijk pp 710–711 DOI: 10.1021/ja056970+ Supporting Info

Multi-Electron Transfer from Heme-Functionalized Nanocrystalline TiO2 to Organohalide Pollutants Sherine O. Obare, Tamae Ito, and Gerald J. Meyer pp 712–713 DOI: 10.1021/ja055908+

J-Coupling Nuclear Magnetic Resonance Spectroscopy of Liquids in nT Fields Johannes Bernarding, Gerd Buntkowsky, Sven Macholl, Stefan Hartwig, Martin Burghoff, and Lutz Trahms pp 714–715 DOI: 10.1021/ja055273e

Heterogeneous Hydrogenation Catalyses over Recyclable Pd(0) Nanoparticle Catalysts Stabilized by PAMAM-SBA-15 Organic−Inorganic Hybrid Composites Yijun Jiang and Qiuming Gao pp 716–717 DOI: 10.1021/ja056424g Supporting Info

Highly Enantioselective Direct Reductive Coupling of Conjugated Alkynes and α-Ketoesters via Rhodium-Catalyzed Asymmetric Hydrogenation Jong-Rock Kong, Ming-Yu Ngai, and Michael J. Krische pp 718–719 DOI: 10.1021/ja056474l Supporting Info

Convergent Oxygenation of Arachidonic Acid by 5-Lipoxygenase and Cyclooxygenase-2 Claus Schneider, William E. Boeglin, Huiyong Yin, Donald F. Stec, and Markus Voehler pp 720–721 DOI: 10.1021/ja056517y Supporting Info

A Simple Catalytic Synthesis of Condensed Pyridones from o-Bromoarylcarboxamides Involving ipso Substitution via Palladacycles Raffaella Ferraccioli, Davide Carenzi, Elena Motti, and Marta Catellani pp 722–723 DOI: 10.1021/ja0566127 Supporting Info

Enzymatic Assembly of the Bis-Indole Core of Rebeccamycin Tomoyasu Nishizawa, Sabine Grüschow, Don-Hema E. Jayamaha, Chizuko Nishizawa-Harada, and David H. Sherman pp 724–725 DOI: 10.1021/ja056749x Supporting Info

Significantly Enhanced Hydrogen Storage in Metal−Organic Frameworks via Spillover Yingwei Li and Ralph T. Yang pp 726–727 DOI: 10.1021/ja056831s Supporting Info

Thiocyanate Hydrolase Is a Cobalt-Containing Metalloenzyme with a Cysteine-Sulfinic Acid Ligand Yoko Katayama, Kanako Hashimoto, Hiroshi Nakayama, Hiroyuki Mino, Masaki Nojiri, Taka-aki Ono, Hiroshi Nyunoya, Masafumi Yohda, Koji Takio, and Masafumi Odaka pp 728–729 DOI: 10.1021/ja057010q Supporting Info

Real-Time Sizing of Nanoparticles in Microfluidic Channels Using Confocal Correlation Spectroscopy Christopher L. Kuyper, Kristi L. Budzinski, Robert M. Lorenz, and Daniel T. Chiu pp 730–731 DOI: 10.1021/ja0569252 Supporting Info

Enantioselective Nitroaldol Reaction of α-Ketoesters Catalyzed by Cinchona Alkaloids Hongming Li, Baomin Wang, and Li Deng pp 732–733 DOI: 10.1021/ja057237l Supporting Info

Organocatalytic Direct Asymmetric Aldol Reactions in Water Nobuyuki Mase, Yusuke Nakai, Naoko Ohara, Hidemi Yoda, Kunihiko Takabe, Fujie Tanaka, and Carlos F. Barbas III pp 734–735 DOI: 10.1021/ja0573312 Supporting Info

Deuterium Kinetic Isotope Effects in Gas-Phase SN2 and E2 Reactions:  Comparison of Experiment and Theory Stephanie M. Villano, Shuji Kato, and Veronica M. Bierbaum pp 736–737 DOI: 10.1021/ja057491d

cis-[Rh2(μ-O2CCH3)2(CH3CN)6]2+ as a Photoactivated Cisplatin Analog Daniel A. Lutterman, Patty K.-L. Fu, and Claudia Turro pp 738–739 DOI: 10.1021/ja057620q Supporting Info

Concise Total Syntheses of Palominol, Dolabellatrienone, β-Araneosene, and Isoedunol via an Enantioselective Diels−Alder Macrobicyclization Scott A. Snyder and E. J. Corey pp 740–742 DOI: 10.1021/ja0576379 Supporting Info

Sliding Behavior of Water Droplets on Flat Polymer Surface Naoya Yoshida, Yuu Abe, Hiroaki Shigeta, Akira Nakajima, Hisashi Ohsaki, Kazuhito Hashimoto, and Toshiya Watanabe pp 743–747 DOI: 10.1021/ja050617m Supporting Info

Multiple Wurtzite Twinning in CdTe Nanocrystals Induced by Methylphosphonic Acid Luigi Carbone, Stefan Kudera, Elvio Carlino, Wolfgang J. Parak, Cinzia Giannini, Roberto Cingolani, and Liberato Manna pp 748–755 DOI: 10.1021/ja054893c Supporting Info

Studies of Low-Coordinate Iron Dinitrogen Complexes Jeremy M. Smith, Azwana R. Sadique, Thomas R. Cundari, Kenton R. Rodgers, Gudrun Lukat-Rodgers, Rene J. Lachicotte, Christine J. Flaschenriem, Javier Vela, and Patrick L. Holland pp 756–769 DOI: 10.1021/ja052707x Supporting Info

Carboxylic Acid Chemistry at the Ge(100)-2 × 1 Interface:  Bidentate Bridging Structure Formation on a Semiconductor Surface Michael A. Filler, James A. Van Deventer, Albert J. Keung, and Stacey F. Bent pp 770–779 DOI: 10.1021/ja0549502 Supporting Info

Quenching of Fluorophore-Labeled DNA Oligonucleotides by Divalent Metal Ions:  Implications for Selection, Design, and Applications of Signaling Aptamers and Signaling Deoxyribozymes Nicholas Rupcich, William Chiuman, Razvan Nutiu, Shirley Mei, Kulwinder K. Flora, Yingfu Li, and John D. Brennan pp 780–790 DOI: 10.1021/ja053336n

Crossover from Superexchange to Hopping as the Mechanism for Photoinduced Charge Transfer in DNA Hairpin Conjugates Frederick D. Lewis, Huihe Zhu, Pierre Daublain, Torsten Fiebig, Milen Raytchev, Qiang Wang, and Vladimir Shafirovich pp 791–800 DOI: 10.1021/ja0540831 Supporting Info

Ultrafast Excited-State Dynamics in Vitamin B12 and Related Cob(III)alamins Joseph J. Shiang, Allwyn G. Cole, Roseanne J. Sension, Kun Hang, Yuxiang Weng, Jenna S. Trommel, Luigi G. Marzilli, and Tianquan Lian pp 801–808 DOI: 10.1021/ja054374+

Computational Design of Heterochiral Peptides against a Helical Target Vikas Nanda and William F. DeGrado pp 809–816 DOI: 10.1021/ja054452t Supporting Info

Polyanionic Hydrides from Polar Intermetallics AeE2 (Ae = Ca, Sr, Ba; E = Al, Ga, In) Thomas Björling, Dag Noréus, and Ulrich Häussermann pp 817–824 DOI: 10.1021/ja054456y Supporting Info

Photoregulated Transmembrane Charge Separation by Linked Spiropyran−Anthraquinone Molecules Linyong Zhu, Rafail F. Khairutdinov, Jonathan L. Cape, and James K. Hurst pp 825–835 DOI: 10.1021/ja0545620 Supporting Info

Ab Initio Calculations of the Reaction Mechanisms for Metal−Nitride Deposition from Organo-Metallic Precursors onto Functionalized Self-Assembled Monolayers Mohit Haran, James R. Engstrom, and Paulette Clancy pp 836–847 DOI: 10.1021/ja054685k Supporting Info

Molecular Dynamics Simulations of Surfactant Self-Organization at a Solid−Liquid Interface Goundla Srinivas, Steven O. Nielsen, Preston B. Moore, and Michael L. Klein pp 848–853 DOI: 10.1021/ja054846k Supporting Info

The C2v Structure of Enolic Acetylacetone Walther Caminati and Jens-Uwe Grabow pp 854–857 DOI: 10.1021/ja055333g Supporting Info

Light Stamping Lithography: Microcontact Printing without Inks Kyung S. Park, Eun K. Seo, Young R. Do, Kwan Kim, and Myung M. Sung pp 858–865 DOI: 10.1021/ja055377p

Zwitterionic Metalates of Group 11 Elements and Their Use as Metalloligands for the Assembly of Multizwitterionic Clusters Roberto Pattacini, Lorenzo Barbieri, Alessandro Stercoli, Daniele Cauzzi, Claudia Graiff, Maurizio Lanfranchi, Antonio Tiripicchio, and Lisa Elviri pp 866–876 DOI: 10.1021/ja0554110 Supporting Info

Rapid Access to Unexplored Chemical Space by Ligand Scanning around a Ruthenium Center:  Discovery of Potent and Selective Protein Kinase Inhibitors Howard Bregman, Patrick J. Carroll, and Eric Meggers pp 877–884 DOI: 10.1021/ja055523r Supporting Info

Chemical Synthesis and Molecular Recognition of Phosphatase-Resistant Analogues of Phosphatidylinositol-3-phosphate Yong Xu, Stephanie A. Lee, Tatiana G. Kutateladze, Diego Sbrissa, Assia Shisheva, and Glenn D. Prestwich pp 885–897 DOI: 10.1021/ja0554716 Supporting Info

Synthesis, Structural, and Electron Topographical Analyses of a Dialkylbiaryl Phosphine/Arene-Ligated Palladium(I) Dimer:  Enhanced Reactivity in Suzuki−Miyaura Coupling Reactions Timothy E. Barder pp 898–904 DOI: 10.1021/ja0558995 Supporting Info

Infrared Spectroscopy of Hydrated Amino Acids in the Gas Phase:  Protonated and Lithiated Valine Anthi Kamariotis, Oleg V. Boyarkin, Sébastien R. Mercier, Rainer D. Beck, Matthew F. Bush, Evan R. Williams, and Thomas R. Rizzo pp 905–916 DOI: 10.1021/ja056079v

Support Effect in High Activity Gold Catalysts for CO Oxidation Massimiliano Comotti, Wen-Cui Li, Bernd Spliethoff, and Ferdi Schüth pp 917–924 DOI: 10.1021/ja0561441

Enantioselective TADMAP-Catalyzed Carboxyl Migration Reactions for the Synthesis of Stereogenic Quaternary Carbon Scott A. Shaw, Pedro Aleman, Justin Christy, Jeff W. Kampf, Porino Va, and Edwin Vedejs pp 925–934 DOI: 10.1021/ja056150x Supporting Info

Effect of Functional Group (Fluorine) of Aromatic Thiols on Electron Transfer at the Molecule−Metal Interface Wei Chen, Li Wang, Chun Huang, Ting Ting Lin, Xing Yu Gao, Kian Ping Loh, Zhi Kuan Chen, and Andrew Thye Shen Wee pp 935–939 DOI: 10.1021/ja056324a Supporting Info

A Nitridoniobium(V) Reagent That Effects Acid Chloride to Organic Nitrile Conversion:  Synthesis via Heterodinuclear (Nb/Mo) Dinitrogen Cleavage, Mechanistic Insights, and Recycling Joshua S. Figueroa, Nicholas A. Piro, Christopher R. Clough, and Christopher C. Cummins pp 940–950 DOI: 10.1021/ja056408j Supporting Info

Real-Time Monitoring of Chemical Transformations by Ultrafast 2D NMR Spectroscopy Maayan Gal, Mor Mishkovsky, and Lucio Frydman pp 951–956 DOI: 10.1021/ja0564158

Triplet Diphenylcarbenes Protected by Trifluoromethyl and Bromine Groups. A Triplet Carbene Surviving a Day in Solution at Room Temperature Tetsuji Itoh, Yoshimaru Nakata, Katsuyuki Hirai, and Hideo Tomioka pp 957–967 DOI: 10.1021/ja056575j Supporting Info

Shape and Aggregation Control of Nanoparticles: Not Shaken, Not Stirred Dan Li and Richard B. Kaner pp 968–975 DOI: 10.1021/ja056609n

Coupled Cluster and Density Functional Theory Studies of the Vibrational Contribution to the Optical Rotation of (S)-Propylene Oxide Jacob Kongsted, Thomas Bondo Pedersen, Lasse Jensen, Aage E. Hansen, and Kurt V. Mikkelsen pp 976–982 DOI: 10.1021/ja056611e

Toward Functional π-Conjugated Organophosphorus Materials:  Design of Phosphole-Based Oligomers for Electroluminescent Devices Hai-Ching Su, Omrane Fadhel, Chih-Jen Yang, Ting-Yi Cho, Claire Fave, Muriel Hissler, Chung-Chih Wu, and Régis Réau pp 983–995 DOI: 10.1021/ja0567182 Supporting Info

Room-Temperature High-Spin Organic Single Molecule:  Nanometer-Sized and Hyperbranched Poly[1,2,(4)-phenylenevinyleneanisylaminium] Eiji Fukuzaki and Hiroyuki Nishide pp 996–1001 DOI: 10.1021/ja0569611 Supporting Info

Time-Resolved Thermodynamics:  Heat Capacity Change of Transient Species during Photoreaction of PYP Javaid Shahbaz Khan, Yasushi Imamoto, Mikio Kataoka, Fumio Tokunaga, and Masahide Terazima pp 1002–1008 DOI: 10.1021/ja055584p

Azobenzene-Tethered T7 Promoter for Efficient Photoregulation of Transcription Mingzhe Liu, Hiroyuki Asanuma, and Makoto Komiyama pp 1009–1015 DOI: 10.1021/ja055983k Supporting Info

Total Synthesis of (±)-Jiadifenin and Studies Directed to Understanding Its SAR:  Probing Mechanistic and Stereochemical Issues in Palladium-Mediated Allylation of Enolate-Like Structures David A. Carcache, Young Shin Cho, Zihao Hua, Yuan Tian, Yue-Ming Li, and Samuel J. Danishefsky pp 1016–1022 DOI: 10.1021/ja056980a Supporting Info

Synthesis and Properties of a New Kinetically Stabilized Digermyne:  New Insights for a Germanium Analogue of an Alkyne Yusuke Sugiyama, Takahiro Sasamori, Yoshinobu Hosoi, Yukio Furukawa, Nozomi Takagi, Shigeru Nagase, and Norihiro Tokitoh pp 1023–1031 DOI: 10.1021/ja057205y Supporting Info

Fundamentals of Ion-Irradiated Polymers Edited by Dietmar Fink (HMI Berlin). Springer-Verlag:  Berlin, Heidelberg, New York. 2004. xvi + 404 pp. $139.00. ISBN 3-540-04027-7. J. Kerry Thomas p 1032 DOI: 10.1021/ja041030v

Advances in Chemical Physics, Volume 131 Edited by Stuart Rice (The University of Chicago). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. x + 528 pp. $175.00. ISBN 0471-44526-6. p 1032 DOI: 10.1021/ja059811z

Strategic Applications of Named Reactions in Organic Synthesis; Background and Detailed Mechanisms By László Kürti and Barbara Czakó (University of Pennsylvania). Elsevier Academic Press:  San Diego, CA. 2005. iii + 758 pp. $94.95. ISBN 0-12-429785-4. p 1032 DOI: 10.1021/ja0598199

Issue 04

Selectivity Limitations in the Heterogeneous Epoxidation of Olefins:  Branching Reactions of the Oxametallacycle Intermediate in the Partial Oxidation of Styrene Andreas Klust and Robert J. Madix pp 1034–1035 DOI: 10.1021/ja054845s Supporting Info

C. fumago Chloroperoxidase is also a Dehaloperoxidase:  Oxidative Dehalogenation of Halophenols Robert L. Osborne, Gregory M. Raner, Lowell P. Hager, and John H. Dawson pp 1036–1037 DOI: 10.1021/ja056213b Supporting Info

Lewis Base Activation of Lewis Acids. Vinylogous Aldol Addition Reactions of Conjugated N,O-Silyl Ketene Acetals to Aldehydes Scott E. Denmark and John R. Heemstra, Jr. pp 1038–1039 DOI: 10.1021/ja056747c Supporting Info

Direct Asymmetric anti-Mannich-Type Reactions Catalyzed by a Designed Amino Acid Susumu Mitsumori, Haile Zhang, Paul Ha-Yeon Cheong, K. N. Houk, Fujie Tanaka, and Carlos F. Barbas, III pp 1040–1041 DOI: 10.1021/ja056984f Supporting Info

Enhanced Magnetic Properties of Self-Assembled FePt Nanoparticles with MnO Shell Shishou Kang, G. X. Miao, S. Shi, Z. Jia, David E. Nikles, and J. W. Harrell pp 1042–1043 DOI: 10.1021/ja057343n Supporting Info

An Efficient Catalyst System for the Asymmetric Transfer Hydrogenation of Ketones:  Remarkably Broad Substrate Scope Manfred T. Reetz and Xiaoguang Li pp 1044–1045 DOI: 10.1021/ja057357t Supporting Info

Directed Assembly of Carbon Nanotubes at Liquid−Liquid Interfaces:  Nanoscale Conveyors for Interfacial Biocatalysis Prashanth Asuri, Sandeep S. Karajanagi, Jonathan S. Dordick, and Ravi S. Kane pp 1046–1047 DOI: 10.1021/ja0573965 Supporting Info

Total Synthesis of Garsubellin A Dionicio R. Siegel and Samuel J. Danishefsky pp 1048–1049 DOI: 10.1021/ja057418n Supporting Info

A Stable Neutral Stannaaromatic Compound:  Synthesis, Structure and Complexation of a Kinetically Stabilized 2-Stannanaphthalene Yoshiyuki Mizuhata, Takahiro Sasamori, Nobuhiro Takeda, and Norihiro Tokitoh pp 1050–1051 DOI: 10.1021/ja057531d Supporting Info

Multiwall Carbon Nanotubes Made of Monochirality Graphite Shells Zhi Xu, Xuedong Bai, Zhong Lin Wang, and Enge Wang pp 1052–1053 DOI: 10.1021/ja057303j Supporting Info

Rapid Synthesis of High-Quality InP Nanocrystals Shu Xu, Sandeep Kumar, and Thomas Nann pp 1054–1055 DOI: 10.1021/ja057676k

Ladder Polyether Synthesis via Epoxide-Opening Cascades Using a Disappearing Directing Group Graham L. Simpson, Timothy P. Heffron, Estíbaliz Merino, and Timothy F. Jamison pp 1056–1057 DOI: 10.1021/ja057973p Supporting Info

The Neber Route to Substituted Indoles Douglass F. Taber and Weiwei Tian pp 1058–1059 DOI: 10.1021/ja058026j Supporting Info

C−H Activation as a Strategic Reaction:  Enantioselective Synthesis of 4-Substituted Indoles Huw M. L. Davies and James R. Manning pp 1060–1061 DOI: 10.1021/ja057768+ Supporting Info

Synthesis of Tetrasubstituted and Functionalized Enol Ethers by E-Selective Olefination of Esters with Ynolates Mitsuru Shindo, Taisuke Kita, Toshihiro Kumagai, Kenji Matsumoto, and Kozo Shishido pp 1062–1063 DOI: 10.1021/ja0561082 Supporting Info

Biomimetic Surface Modifications Based on the Cyanobacterial Iron Chelator Anachelin Stefan Zürcher, David Wäckerlin, Yann Bethuel, Barbora Malisova, Marcus Textor, Samuele Tosatti, and Karl Gademann pp 1064–1065 DOI: 10.1021/ja056256s Supporting Info

Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation Domingo García-Cuadrado, Ataualpa A. C. Braga, Feliu Maseras, and Antonio M. Echavarren pp 1066–1067 DOI: 10.1021/ja056165v Supporting Info

Ultrafast Excited-State Electron Transfer at an Organic Liquid/Aqueous Interface Eric A. McArthur and Kenneth B. Eisenthal pp 1068–1069 DOI: 10.1021/ja056518q Supporting Info

Enzyme-Triggered Self-Assembly of Peptide Hydrogels via Reversed Hydrolysis Sophie Toledano, Richard J. Williams, Vineetha Jayawarna, and Rein V. Ulijn pp 1070–1071 DOI: 10.1021/ja056549l

Nonlinear Optical Properties of Alkalides Li+(calix[4]pyrrole)M- (M = Li, Na, and K):  Alkali Anion Atomic Number Dependence Wei Chen, Zhi-Ru Li, Di Wu, Ying Li, Chia-Chung Sun, Feng Long Gu, and Yuriko Aoki pp 1072–1073 DOI: 10.1021/ja056314+ Supporting Info

Thermal and UV Shape Shifting of Surface Topography Zhongqiang Yang, George A. Herd, Stuart M. Clarke, Ali R. Tajbakhsh, Eugene M. Terentjev, and Wilhelm T. S. Huck pp 1074–1075 DOI: 10.1021/ja056866s Supporting Info

Enantiospecific Adsorption of Cysteine at Chiral Kink Sites on Au(110)-(1×2) Angelika Kühnle, Trolle R. Linderoth, and Flemming Besenbacher pp 1076–1077 DOI: 10.1021/ja0568751

Glutathione-Mediated Delivery and Release Using Monolayer Protected Nanoparticle Carriers Rui Hong, Gang Han, Joseph M. Fernández, Byoung-jin Kim, Neil S. Forbes, and Vincent M. Rotello pp 1078–1079 DOI: 10.1021/ja056726i Supporting Info

Tyrosine-Selective Protein Alkylation Using π-Allylpalladium Complexes S. David Tilley and Matthew B. Francis pp 1080–1081 DOI: 10.1021/ja057106k Supporting Info

An Unprecedented Type of Linear Metallocene with an f-Element Jérôme Maynadié, Jean-Claude Berthet, Pierre Thuéry, and Michel Ephritikhine pp 1082–1083 DOI: 10.1021/ja057226s Supporting Info

Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2] Yoshikatsu Umezono, Wataru Fujita, and Kunio Awaga pp 1084–1085 DOI: 10.1021/ja057207i Supporting Info

Catalytic Asymmetric Pictet−Spengler Reaction Jayasree Seayad, Abdul Majeed Seayad, and Benjamin List pp 1086–1087 DOI: 10.1021/ja057444l Supporting Info

Micro-Actuators:  When Artificial Muscles Made of Nematic Liquid Crystal Elastomers Meet Soft Lithography Axel Buguin, Min-Hui Li, Pascal Silberzan, Benoit Ladoux, and Patrick Keller pp 1088–1089 DOI: 10.1021/ja0575070 Supporting Info

Compound I of Heme Oxygenase Cannot Hydroxylate Its Heme meso-Carbon Toshitaka Matsui, Sun Hee Kim, Hiromichi Jin, Brian M. Hoffman, and Masao Ikeda-Saito pp 1090–1091 DOI: 10.1021/ja057578z Supporting Info

A Fluoroacetamidine-Based Inactivator of Protein Arginine Deiminase 4:  Design, Synthesis, and in Vitro and in Vivo Evaluation Yuan Luo, Bryan Knuckley, Young-Ho Lee, Michael R. Stallcup, and Paul R. Thompson pp 1092–1093 DOI: 10.1021/ja0576233 Supporting Info

Total Synthesis of (+)-Cylindramide A Amy C. Hart and Andrew J. Phillips pp 1094–1095 DOI: 10.1021/ja057899a Supporting Info

An Intramolecular G-Quadruplex Structure with Mixed Parallel/Antiparallel G-Strands Formed in the Human BCL-2 Promoter Region in Solution Jixun Dai, Thomas S. Dexheimer, Ding Chen, Megan Carver, Attila Ambrus, Roger A. Jones, and Danzhou Yang pp 1096–1098 DOI: 10.1021/ja055636a Supporting Info

Periodic and High-Temperature Disordered Conformations of Polytetrafluoroethylene Chains:  An ab Initio Modeling Maddalena D'Amore, Giovanni Talarico, and Vincenzo Barone pp 1099–1108 DOI: 10.1021/ja0527929 Supporting Info

Competition between Metal-Amido and Metal-Imido Chemistries in the Alkaline Earth Series:  An Experimental and Theoretical Study of BaNH Alexandra Janczyk, Dennis L. Lichtenberger, and Lucy M. Ziurys pp 1109–1118 DOI: 10.1021/ja053473k

Temperature-Sensitive Micrometer-Thick Layers of Hyaluronan Grafted on Microspheres Derk Joester, E. Klein, Benjamin Geiger, and Lia Addadi pp 1119–1124 DOI: 10.1021/ja0537474 Supporting Info

NMR Analysis of Aromatic Interactions in Designed Peptide β-Hairpins Radhakrishnan Mahalakshmi, Srinivasarao Raghothama, and Padmanabhan Balaram pp 1125–1138 DOI: 10.1021/ja054040k Supporting Info

In Situ Generation of Vinyl Allenes and Its Applications to One-Pot Assembly of Cyclohexene, Cyclooctadiene, 3,7-Nonadienone, and Bicyclo[6.4.0]dodecene Derivatives with Palladium-Catalyzed Multicomponent Reactions Phil Ho Lee, Kooyeon Lee, and Youngjin Kang pp 1139–1146 DOI: 10.1021/ja054144v Supporting Info

Five-Coordinate Aluminum Bromides:  Synthesis, Structure, Cation Formation, and Cleavage of Phosphate Ester Bonds Amitabha Mitra, Lauren J. DePue, Sean Parkin, and David A. Atwood pp 1147–1153 DOI: 10.1021/ja054684s Supporting Info

Computational Design of a Single Amino Acid Sequence that Can Switch between Two Distinct Protein Folds Xavier I. Ambroggio and Brian Kuhlman pp 1154–1161 DOI: 10.1021/ja054718w

Helical Conformational Dynamics and Photoisomerism of Alternating Pyridinedicarboxamide/m-(Phenylazo)azobenzene Oligomers Chenyang Tie, Judith C. Gallucci, and Jon R. Parquette pp 1162–1171 DOI: 10.1021/ja0547228 Supporting Info

Kinetic Solvent Effects on Proton and Hydrogen Atom Transfers from Phenols. Similarities and Differences Merete Folmer Nielsen and K. U. Ingold pp 1172–1182 DOI: 10.1021/ja0548081 Supporting Info

A Combined Experimental and Theoretical Study of Carboxylate Coordination Modes: A Structural Probe Vincent Robert and Gilles Lemercier pp 1183–1187 DOI: 10.1021/ja055121j Supporting Info

Optimization of the Molecular Orbital Energies of Conjugated Polymers for Optical Amplification of Fluorescent Sensors Bin Liu and Guillermo C. Bazan pp 1188–1196 DOI: 10.1021/ja055382t

Effect of Silicon Oxidation on Long-Term Cell Selectivity of Cell-Patterned Au/SiO2 Platforms Mandana Veiseh and Miqin Zhang pp 1197–1203 DOI: 10.1021/ja055473q

A Localized Specific Interaction Alters the Unfolding Pathways of Structural Homologues Guoqiang Xu, Mahesh Narayan, Igor Kurinov, Daniel R. Ripoll, Ervin Welker, Mey Khalili, Steven E. Ealick, and Harold A. Scheraga pp 1204–1213 DOI: 10.1021/ja055313e Supporting Info

Ultrafast Fluorescence Dynamics of Tryptophan in the Proteins Monellin and IIAGlc Jianhua Xu, Dmitri Toptygin, Karen J. Graver, Rebecca A. Albertini, Regina S. Savtchenko, Norman D. Meadow, Saul Roseman, Patrik R. Callis, Ludwig Brand, and Jay R. Knutson pp 1214–1221 DOI: 10.1021/ja055746h

A Structural Investigation of the N−B Interaction in an o-(N,N-Dialkylaminomethyl)arylboronate System Lei Zhu, Shagufta H. Shabbir, Mark Gray, Vincent M. Lynch, Steven Sorey, and Eric V. Anslyn pp 1222–1232 DOI: 10.1021/ja055817c Supporting Info

Combination of a Modified Scoring Function with Two-Dimensional Descriptors for Calculation of Binding Affinities of Bulky, Flexible Ligands to Proteins Csaba Hetényi, Gábor Paragi, Uko Maran, Zoltán Timár, Mati Karelson, and Botond Penke pp 1233–1239 DOI: 10.1021/ja055804z Supporting Info

A Three-State Mechanism for DNA Hairpin Folding Characterized by Multiparameter Fluorescence Fluctuation Spectroscopy Jaemyeong Jung and Alan Van Orden pp 1240–1249 DOI: 10.1021/ja0560736 Supporting Info

Near 0 eV Electrons Attach to Nucleotides Jiande Gu, Yaoming Xie, and Henry F. Schaefer, III pp 1250–1252 DOI: 10.1021/ja055615g Supporting Info

Switchable Surface Properties through the Electrochemical or Biocatalytic Generation of Ag0 Nanoclusters on Monolayer-Functionalized Electrodes Michael Riskin, Bernhard Basnar, Vladimir I. Chegel, Eugenii Katz, Itamar Willner, Feng Shi, and Xi Zhang pp 1253–1260 DOI: 10.1021/ja0561183 Supporting Info

Aminoglycoside-Induced Reduction in Nucleotide Mobility at the Ribosomal RNA A-Site as a Potentially Key Determinant of Antibacterial Activity Malvika Kaul, Christopher M. Barbieri, and Daniel S. Pilch pp 1261–1271 DOI: 10.1021/ja056159z

Catalytic Mechanism and Product Specificity of the Histone Lysine Methyltransferase SET7/9:  An ab Initio QM/MM-FE Study with Multiple Initial Structures Po Hu and Yingkai Zhang pp 1272–1278 DOI: 10.1021/ja056153+ Supporting Info

Monitoring Lipid Membrane Translocation of Sodium Dodecyl Sulfate by Isothermal Titration Calorimetry Sandro Keller, Heiko Heerklotz, and Alfred Blume pp 1279–1286 DOI: 10.1021/ja056389d Supporting Info

Computational Insights into the Mechanism of Radical Generation in B12-Dependent Methylmalonyl-CoA Mutase Renata A. Kwiecien, Ilja V. Khavrutskii, Djamaladdin G. Musaev, Keiji Morokuma, Ruma Banerjee, and Piotr Paneth pp 1287–1292 DOI: 10.1021/ja056333j Supporting Info

Alkaline Phosphatase Mono- and Diesterase Reactions:  Comparative Transition State Analysis Jesse G. Zalatan and Daniel Herschlag pp 1293–1303 DOI: 10.1021/ja056528r Supporting Info

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks Jesse L. C. Rowsell and Omar M. Yaghi pp 1304–1315 DOI: 10.1021/ja056639q Supporting Info

Chemo−Regioselectivity in Heterogeneous Catalysis:  Competitive Routes for CO and CC Hydrogenations from a Theoretical Approach David Loffreda, Françoise Delbecq, Fabienne Vigné, and Philippe Sautet pp 1316–1323 DOI: 10.1021/ja056689v

Guest Exchange Dynamics in an M4L6 Tetrahedral Host Anna V. Davis, Dorothea Fiedler, Georg Seeber, Achim Zahl, Rudi van Eldik, and Kenneth N. Raymond pp 1324–1333 DOI: 10.1021/ja056556+ Supporting Info

Suppressing Aggregation in a Large Polycyclic Aromatic Hydrocarbon Daniel Wasserfallen, Marcel Kastler, Wojciech Pisula, Werner A. Hofer, Yulia Fogel, Zhaohui Wang, and Klaus Müllen pp 1334–1339 DOI: 10.1021/ja056782j Supporting Info

Organization of Acenes with a Cruciform Assembly Motif Qian Miao, Xiaoliu Chi, Shengxiong Xiao, Roswitha Zeis, Michael Lefenfeld, Theo Siegrist, Michael L. Steigerwald, and Colin Nuckolls pp 1340–1345 DOI: 10.1021/ja0570786 Supporting Info

Enantioselective Syntheses of Georgyone, Arborone, and Structural Relatives. Relevance to the Molecular-Level Understanding of Olfaction Sungwoo Hong and E. J. Corey pp 1346–1352 DOI: 10.1021/ja057483x Supporting Info

Growth Kinetics of Heterostructured GaP−GaAs Nanowires Marcel A. Verheijen, George Immink, Thierry de Smet, Magnus T. Borgström, and Erik P. A. M. Bakkers pp 1353–1359 DOI: 10.1021/ja057157h

Bis(allyl)−Ruthenium(IV) Complexes as Highly Efficient Catalysts for the Redox Isomerization of Allylic Alcohols into Carbonyl Compounds in Organic and Aqueous Media:  Scope, Limitations, and Theoretical Analysis of the Mechanism Victorio Cadierno, Sergio E. García-Garrido, José Gimeno, Adrián Varela-Álvarez, and José A. Sordo pp 1360–1370 DOI: 10.1021/ja054827a Supporting Info

An Intramolecular Diels−Alder Approach to the Eunicellins:  Enantioselective Total Syntheses of Ophirin B and Astrogorgin Michael T. Crimmins, Brandon H. Brown, and Hilary R. Plake pp 1371–1378 DOI: 10.1021/ja056334b Supporting Info

Models of the Membrane-Bound Cytochromes:  Mössbauer Spectra of Crystalline Low-Spin Ferriheme Complexes Having Axial Ligand Plane Dihedral Angles Ranging from 0° to 90° Thomas Teschner, Liliya Yatsunyk, Volker Schünemann, Hauke Paulsen, Heiner Winkler, Chuanjiang Hu, W. Robert Scheidt, F. Ann Walker, and Alfred X. Trautwein pp 1379–1389 DOI: 10.1021/ja056343k Supporting Info

Rechargeable Li2O2 Electrode for Lithium Batteries Takeshi Ogasawara, Aurélie Débart, Michael Holzapfel, Petr Novák, and Peter G. Bruce pp 1390–1393 DOI: 10.1021/ja056811q

Cell-Permeable Near-Infrared Fluorogenic Substrates for Imaging β-Lactamase Activity   [J. Am. Chem. Soc. 2005, 127, 4158−4159]. Bengang Xing, Ashot Khanamiryan, and Jianghong Rao p 1394 DOI: 10.1021/ja054676b

Experimental and Theoretical Evidence for the Formation of Zinc Tricarbonyl in Solid Argon [J. Am. Chem. Soc. 2005, 127, 8906−8907]. Ling Jiang and Qiang Xu p 1394 DOI: 10.1021/ja057624v

Organogermanium Reactive Intermediates. The Direct Detection and Characterization of Transient Germylenes and Digermenes in Solution [J. Am. Chem. Soc. 2004, 126, 16105−16116]. William J. Leigh, Cameron R. Harrington, and Ignacio Vargas-Baca p 1394 DOI: 10.1021/ja0582307

Evaluation of Norcarane as a Probe for Radicals in Cytochrome P450- and Soluble Methane Monooxygenase-Catalyzed Hydroxylation Reactions [J. Am. Chem. Soc. 2002, 124, 6879−6886]. Martin Newcomb, Runnan Shen, Yun Lu, Minor J. Coon, Paul F. Hollenberg, Daniel A. Kopp, and Stephen J. Lippard p 1394 DOI: 10.1021/ja0599216

The Science and Technology of Rubber, 3rd Edition Edited by James E. Mark (The University of Cincinnati), Burak Erman (Koc University, Istanbul), and Frederick R. Eirich (Polytechnic University, Brooklyn). Elsevier Academic Press:  San Diego, CA. 2005. xviii + 744 pp. $125.00. ISBN 0-12-464786-3. p 1395 DOI: 10.1021/ja059818g

Resorcinol:  Chemistry, Technology and Applications By Raj B. Durairaj (Indspec Chemical Corporation, Pittsburgh). Springer:  Berlin, Heidelberg, New York. 2005. xxvi + 748 pp. $329.00. ISBN 3-540-25142-1. p 1395 DOI: 10.1021/ja0598309

Block Copolymers in Solution:  Fundamentals and Applications By Ian W. Hamley (University of Reading, UK). John Wiley & Sons, Ltd.:  Chichester. 2005. xii + 288 pp. $180.00. ISBN 0-470-01557-8. Ralph H. Colby p 1395 DOI: 10.1021/ja059842u

Annual Review of Physical Chemistry, Volume 56, 2005 Edited by Stephen R. Leone, Paul Alivisatos (University of California, Berkeley), and Ann E. McDermott (Columbia University). Annual Reviews:  Palo Alto, CA. 2005. xiv + 640 pp. $82.00. ISBN 0-8243-1056-X. pp 1395–1396 DOI: 10.1021/ja059824c

Metal-Catalysed Reactions of Hydrocarbons By Geoffrey C. Bond (Brunel University, Uxbridge, UK). Springer:  New York. 2005. xxii + 666 pp. $129.00. ISBN 0-387-24141-8. Colin D. Abernethy p 1396 DOI: 10.1021/ja0598154

Inorganic Polymeric Nanocomposites and Membranes. Advances in Polymer Science, 179 Springer:  Berlin, Heidelberg, New York, 2005. x + 220 pp. $209.00. ISBN 3-540-253254. p 1396 DOI: 10.1021/ja059838i

Issue 05

Directed DNA Metallization Glenn A. Burley, Johannes Gierlich, Mohammad R. Mofid, Hadar Nir, Shay Tal, Yoav Eichen, and Thomas Carell pp 1398–1399 DOI: 10.1021/ja055517v Supporting Info

Analysis of Lanthanide-Induced NMR Shifts of the Ce@C82 Anion Michio Yamada, Takatsugu Wakahara, Yongfu Lian, Takahiro Tsuchiya, Takeshi Akasaka, Markus Waelchli, Naomi Mizorogi, Shigeru Nagase, and Karl M. Kadish pp 1400–1401 DOI: 10.1021/ja055882m Supporting Info

Synthesis and Structural Characterization of Endohedral Pyrrolidinodimetallofullerene:  La2@C80(CH2)2NTrt Michio Yamada, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Naomi Mizorogi, and Shigeru Nagase pp 1402–1403 DOI: 10.1021/ja056560l Supporting Info

PNA-Based Reagents for the Direct and Site-Specific Synthesis of Thymine Dimer Lesions in Genomic DNA J. Carsten Pieck, David Kuch, Friederike Grolle, Uwe Linne, Clemens Haas, and Thomas Carell pp 1404–1405 DOI: 10.1021/ja056358i Supporting Info

Palladium(0)-Catalyzed Alkylative Cyclization of Alkynals and Alkynones:  Remarkable trans-Addition of Organoboronic Reagents Hirokazu Tsukamoto, Tatsuhiko Ueno, and Yoshinori Kondo pp 1406–1407 DOI: 10.1021/ja056458o Supporting Info

Free Energies of Molecular Crystal Surfaces by Computer Simulation:  Application to Tetrathiophene Valentina Marcon and Guido Raos pp 1408–1409 DOI: 10.1021/ja056548t Supporting Info

Non-SELEX Selection of Aptamers Maxim Berezovski, Michael Musheev, Andrei Drabovich, and Sergey N. Krylov pp 1410–1411 DOI: 10.1021/ja056943j Supporting Info

Multifunctional Chemical Vapor Sensors of Aligned Carbon Nanotube and Polymer Composites Chen Wei, Liming Dai, Ajit Roy, and Tia Benson Tolle pp 1412–1413 DOI: 10.1021/ja0570335 Supporting Info

Self-Adhesion among Phospholipid Vesicles F. M. Menger and Hailing Zhang pp 1414–1415 DOI: 10.1021/ja057151s Supporting Info

Further Study of the Reaction of Fe2+ with CN-:  Synthesis and Characterization of cis and trans [FeII,III(CN)4L2]n- Complexes Gina M. Chiarella, Doris Y. Melgarejo, and Stephen A. Koch pp 1416–1417 DOI: 10.1021/ja0571951 Supporting Info

One-Dimensional Metallic Conducting Pathway of Cyclohexyl-Substituted Spiro-Biphenalenyl Neutral Radical Molecular Crystal Jingsong Huang and Miklos Kertesz pp 1418–1419 DOI: 10.1021/ja057198d Supporting Info

The Dehydratase Activity of Lacticin 481 Synthetase is Highly Processive Leah M. Miller, Champak Chatterjee, Wilfred A. van der Donk, and Neil L. Kelleher pp 1420–1421 DOI: 10.1021/ja057203d Supporting Info

Thionitroxides, RSNHO•:  The Structure of the SNO Moiety in “S-Nitrosohemoglobin”, A Possible NO Reservoir and Transporter Yi-Lei Zhao and K. N. Houk pp 1422–1423 DOI: 10.1021/ja057097f Supporting Info

Highly Enantioselective Synthesis of Tetrahydro-β-Carbolines and Tetrahydro-γ-Carbolines Via Pd-Catalyzed Intramolecular Allylic Alkylation Marco Bandini, Alfonso Melloni, Fabio Piccinelli, Riccardo Sinisi, Simona Tommasi, and Achille Umani-Ronchi pp 1424–1425 DOI: 10.1021/ja054109o Supporting Info

A New Approach to Promoting Sluggish Diels−Alder Reactions:  Dihapto-Coordination of the Diene Weijun Liu, Fei You, Christopher J. Mocella, and W. Dean Harman pp 1426–1427 DOI: 10.1021/ja0553654 Supporting Info

Priming Type II Polyketide Synthases via a Type II Nonribosomal Peptide Synthetase Mechanism Miho Izumikawa, Qian Cheng, and Bradley S. Moore pp 1428–1429 DOI: 10.1021/ja0559707 Supporting Info

Ion Pair Driven Self-Assembly of a Flexible Bis-Zwitterion in Polar Solution:  Formation of Discrete Nanometer-Sized Cyclic Dimers Carsten Schmuck, Thomas Rehm, Franziska Gröhn, Katja Klein, and Frank Reinhold pp 1430–1431 DOI: 10.1021/ja056465c Supporting Info

A Two-Stage One-Pot Enzymatic Synthesis of TDP-l-mycarose from Thymidine and Glucose-1-phosphate Haruko Takahashi, Yung-nan Liu, and Hung-wen Liu pp 1432–1433 DOI: 10.1021/ja0562144 Supporting Info

Low-Valent Niobium-Mediated Double Activation of C−F/C−H Bonds:  Fluorene Synthesis from o-Arylated α,α,α-Trifluorotoluene Derivatives Kohei Fuchibe and Takahiko Akiyama pp 1434–1435 DOI: 10.1021/ja0565323 Supporting Info

Highly Porous Fibers by Electrospinning into a Cryogenic Liquid Jesse T. McCann, Manuel Marquez, and Younan Xia pp 1436–1437 DOI: 10.1021/ja056810y Supporting Info

The Role of Methyl Groups in the Formation of Hydrogen Bond in DMSO−Methanol Mixtures Qingzhong Li, Guoshi Wu, and Zhiwu Yu pp 1438–1439 DOI: 10.1021/ja0569149 Supporting Info

Oximate-Bridged Trinuclear Dy−Cu−Dy Complex Behaving as a Single-Molecule Magnet and Its Mechanistic Investigation Fumihito Mori, Tetsuya Nyui, Takayuki Ishida, Takashi Nogami, Kwang-Yong Choi, and Hiroyuki Nojiri pp 1440–1441 DOI: 10.1021/ja057183f Supporting Info

Efficient Synthesis of Cyclopentenones from Enynyl Acetates via Tandem Au(I)-Catalyzed 3,3-Rearrangement and the Nazarov Reaction Liming Zhang and Shaozhong Wang pp 1442–1443 DOI: 10.1021/ja057327q Supporting Info

Dynamics of Nitric Oxide Rebinding and Escape in Horseradish Peroxidase Xiong Ye, Anchi Yu, and Paul M. Champion pp 1444–1445 DOI: 10.1021/ja057172m Supporting Info

Anti-Markovnikov N−H and O−H Additions to Electron-Deficient Olefins Catalyzed by Well-Defined Cu(I) Anilido, Ethoxide, and Phenoxide Systems Colleen Munro-Leighton, Elizabeth D. Blue, and T. Brent Gunnoe pp 1446–1447 DOI: 10.1021/ja057622a Supporting Info

Total Synthesis of (±)-Welwitindolinone A Isonitrile Sarah E. Reisman, Joseph M. Ready, Atsushi Hasuoka, Catherine J. Smith, and John L. Wood pp 1448–1449 DOI: 10.1021/ja057640s Supporting Info

Ti Coordination in Titanium Silicalite-1 Wallace O. Parker, Jr. and Roberto Millini pp 1450–1451 DOI: 10.1021/ja0576785 Supporting Info

Iterative, Aqueous Synthesis of β3-Oligopeptides without Coupling Reagents Nancy Carrillo, Eric A. Davalos, Justin A. Russak, and Jeffrey W. Bode pp 1452–1453 DOI: 10.1021/ja057706j Supporting Info

Axially Chiral Guanidine as Enantioselective Base Catalyst for 1,4-Addition Reaction of 1,3-Dicarbonyl Compounds with Conjugated Nitroalkenes Masahiro Terada, Hitoshi Ube, and Yusuke Yaguchi pp 1454–1455 DOI: 10.1021/ja057848d Supporting Info

Checkerboard-Type Charge-Ordered State of a Pressure-Induced Superconductor, β-(meso-DMBEDT-TTF)2PF6 Shinya Kimura, Hideaki Suzuki, Tomoko Maejima, Hatsumi Mori, Jun-Ichi Yamaura, Toru Kakiuchi, Hiroshi Sawa, and Hiroshi Moriyama pp 1456–1457 DOI: 10.1021/ja057307o Supporting Info

Multiple C−H Bond Activation in Group 3 Chemistry:  Synthesis and Structural Characterization of an Yttrium−Aluminum−Methine Cluster H. Martin Dietrich, Hilde Grove, Karl W. Törnroos, and Reiner Anwander pp 1458–1459 DOI: 10.1021/ja057618z Supporting Info

Palladium(II)-Catalyzed Aerobic Dialkoxylation of Styrenes:  A Profound Influence of an o-Phenol Mitchell J. Schultz and Matthew S. Sigman pp 1460–1461 DOI: 10.1021/ja0579053 Supporting Info

Macroporous Manganese Oxides with Regenerative Mesopores Eric S. Toberer, Thomas D. Schladt, and Ram Seshadri pp 1462–1463 DOI: 10.1021/ja0579412

Catalytic Four-Component Assembly Based on Allenylboronate Platform:  New Access to Privileged Allylic Amine Structures Keisuke Tonogaki, Kenichiro Itami, and Jun-ichi Yoshida pp 1464–1465 DOI: 10.1021/ja057778a Supporting Info

Springs, Rings, and Spirals of Rutile-Structured Tin Oxide Nanobelts Rusen Yang and Zhong Lin Wang pp 1466–1467 DOI: 10.1021/ja0578000 Supporting Info

Photoinduced Phase Separation Ana Vesperinas, Julian Eastoe, Paul Wyatt, Isabelle Grillo, Richard K. Heenan, Jonathan M. Richards, and Gordon A. Bell pp 1468–1469 DOI: 10.1021/ja058070z Supporting Info

Iron-Assisted Vapor-Phase Hydrothermal Method:  A Low-Temperature Approach To Synthesize Blue Light Emissive SiOx Nanowires with Single-Crystal Structure of P21212 Ping Chen, Songhai Xie, Nan Ren, Yahong Zhang, Angang Dong, Ying Chen, and Yi Tang pp 1470–1471 DOI: 10.1021/ja057440g Supporting Info

Umpolung of Michael Acceptors Catalyzed by N-Heterocyclic Carbenes Christian Fischer, Sean W. Smith, David A. Powell, and Gregory C. Fu pp 1472–1473 DOI: 10.1021/ja058222q Supporting Info

The “Somersault” Mechanism for the P-450 Hydroxylation of Hydrocarbons. The Intervention of Transient Inverted Metastable Hydroperoxides Robert D. Bach and Olga Dmitrenko pp 1474–1488 DOI: 10.1021/ja052111+ Supporting Info

Operating Molecular Elevators Jovica D. Badjic, Célia M. Ronconi, J. Fraser Stoddart, Vincenzo Balzani, Serena Silvi, and Alberto Credi pp 1489–1499 DOI: 10.1021/ja0543954 Supporting Info

Synthesis and Photoelectron Spectroscopic Studies of N(CH2CH2NMe)3PE (E = O, S, NH, CH2) Tamás Kárpáti, Tamás Veszprémi, Natesan Thirupathi, Xiaodong Liu, Zhigang Wang, Arkady Ellern, László Nyulászi, and John G. Verkade pp 1500–1512 DOI: 10.1021/ja0547533 Supporting Info

Ruthenium Molecular Wires with Conjugated Bridging Ligands:  Onset of Band Formation in Linear Inorganic Conjugated Oligomers Samuel Flores-Torres, Geoffrey R. Hutchison, Leonard J. Soltzberg, and Héctor D. Abruña pp 1513–1522 DOI: 10.1021/ja0552139 Supporting Info

Exploring the Energy Landscape of a Small RNA Hairpin Hairong Ma, David J. Proctor, Elzbieta Kierzek, Ryszard Kierzek, Philip C. Bevilacqua, and Martin Gruebele pp 1523–1530 DOI: 10.1021/ja0553856

Selective Formation of a Self-Assembling Homo or Hetero Cavitand Cage via Metal Coordination Based on Thermodynamic or Kinetic Control Masamichi Yamanaka, Yoshifumi Yamada, Yoshihisa Sei, Kentaro Yamaguchi, and Kenji Kobayashi pp 1531–1539 DOI: 10.1021/ja0555365

Probing the Decay Coordinate of the Green Fluorescent Protein:  Arrest of Cis−Trans Isomerization by the Protein Significantly Narrows the Fluorescence Spectra Solomon S. Stavrov, Kyril M. Solntsev, Laren M. Tolbert, and Dan Huppert pp 1540–1546 DOI: 10.1021/ja0555421

Characterizing Challenging Microcrystalline Solids with Solid-State NMR Shift Tensor and Synchrotron X-ray Powder Diffraction Data:  Structural Analysis of Ambuic Acid James K. Harper, David M. Grant, Yuegang Zhang, Peter L. Lee, and Robert Von Dreele pp 1547–1552 DOI: 10.1021/ja055570j Supporting Info

A DFT/CDM Study of Metal−Carboxylate Interactions in Metalloproteins:  Factors Governing the Maximum Number of Metal-Bound Carboxylates Todor Dudev and Carmay Lim pp 1553–1561 DOI: 10.1021/ja055797e Supporting Info

pH Rate Profiles of FnY356−R2s (n = 2, 3, 4) in Escherichia coli Ribonucleotide Reductase:  Evidence that Y356 Is a Redox-Active Amino Acid along the Radical Propagation Pathway Mohammad R. Seyedsayamdost, Cyril S. Yee, Steven Y. Reece, Daniel G. Nocera, and JoAnne Stubbe pp 1562–1568 DOI: 10.1021/ja055927j Supporting Info

Mono-, Di-, Tri-, and Tetra-Substituted Fluorotyrosines:  New Probes for Enzymes That Use Tyrosyl Radicals in Catalysis Mohammad R. Seyedsayamdost, Steven Y. Reece, Daniel G. Nocera, and JoAnne Stubbe pp 1569–1579 DOI: 10.1021/ja055926r Supporting Info

The A-FX to FA/B Step in Synechocystis 6803 Photosystem I Is Entropy Driven Harvey J. M. Hou and David Mauzerall pp 1580–1586 DOI: 10.1021/ja054870y

Aerosol Assisted Chemical Vapor Deposition Using Nanoparticle Precursors:  A Route to Nanocomposite Thin Films Robert G. Palgrave and Ivan P. Parkin pp 1587–1597 DOI: 10.1021/ja055563v

Determination of Equilibrium Constants for Atom Transfer Radical Polymerization Wei Tang, Nicolay V. Tsarevsky, and Krzysztof Matyjaszewski pp 1598–1604 DOI: 10.1021/ja0558591 Supporting Info

A Comprehensive Approach to the Synthesis of Sulfate Esters Levi S. Simpson and Theodore S. Widlanski pp 1605–1610 DOI: 10.1021/ja056086j Supporting Info

Bismuth-Catalyzed Intermolecular Hydroamination of 1,3-Dienes with Carbamates, Sulfonamides, and Carboxamides Hongbo Qin, Noriyuki Yamagiwa, Shigeki Matsunaga, and Masakatsu Shibasaki pp 1611–1614 DOI: 10.1021/ja056112d Supporting Info

Substrate Specificity of an Active Dinuclear Zn(II) Catalyst for Cleavage of RNA Analogues and a Dinucleoside AnnMarie O'Donoghue, Sang Yong Pyun, Meng-Yin Yang, Janet R. Morrow, and John P. Richard pp 1615–1621 DOI: 10.1021/ja056167f

Marinomycins A−D, Antitumor-Antibiotics of a New Structure Class from a Marine Actinomycete of the Recently Discovered Genus “Marinispora” Hak Cheol Kwon, Christopher A. Kauffman, Paul R. Jensen, and William Fenical pp 1622–1632 DOI: 10.1021/ja0558948 Supporting Info

NMR Structure and Dynamic Studies of an Anion-Binding, Channel-Forming Heptapeptide Gabriel A. Cook, Robert Pajewski, Mahalaxmi Aburi, Paul E. Smith, Om Prakash, John M. Tomich, and George W. Gokel pp 1633–1638 DOI: 10.1021/ja055887j

Rotational and Translational Diffusion of Peptide-Coated CdSe/CdS/ZnS Nanorods Studied by Fluorescence Correlation Spectroscopy James M. Tsay, Sören Doose, and Shimon Weiss pp 1639–1647 DOI: 10.1021/ja056162i Supporting Info

Double-Ink Dip-Pen Nanolithography Studies Elucidate Molecular Transport Jennifer R. Hampton, Arrelaine A. Dameron, and Paul S. Weiss pp 1648–1653 DOI: 10.1021/ja056369b

The Chemistry of Dinuclear Analogues of the Anticancer Drug Cisplatin. A DFT/CDM Study Dirk V. Deubel pp 1654–1663 DOI: 10.1021/ja055741k Supporting Info

Design of Highly Active Binary Catalyst Systems for CO2/Epoxide Copolymerization:  Polymer Selectivity, Enantioselectivity, and Stereochemistry Control Xiao-Bing Lu, Lei Shi, Yi-Ming Wang, Rong Zhang, Ying-Ju Zhang, Xiao-Jun Peng, Zhi-Chao Zhang, and Bo Li pp 1664–1674 DOI: 10.1021/ja056383o Supporting Info

The Concept of Delayed Nucleation in Nanocrystal Growth Demonstrated for the Case of Iron Oxide Nanodisks Maria F. Casula, Young-wook Jun, David J. Zaziski, Emory M. Chan, Anna Corrias, and A. Paul Alivisatos pp 1675–1682 DOI: 10.1021/ja056139x Supporting Info

Effect of Single-Point Sequence Alterations on the Aggregation Propensity of a Model Protein Dusan Bratko, Troy Cellmer, John M. Prausnitz, and Harvey W. Blanch pp 1683–1691 DOI: 10.1021/ja056837h

Polymer Crystallization-Driven, Periodic Patterning on Carbon Nanotubes Lingyu Li, Christopher Y. Li, and Chaoying Ni pp 1692–1699 DOI: 10.1021/ja056923h Supporting Info

Relationship between Two-Photon Absorption and the π-Conjugation Pathway in Porphyrin Arrays through Dihedral Angle Control Tae Kyu Ahn, Kil Suk Kim, Deok Yun Kim, Su Bum Noh, Naoki Aratani, Chusaku Ikeda, Atsuhiro Osuka, and Dongho Kim pp 1700–1704 DOI: 10.1021/ja056773a Supporting Info

Toward Single Molecule DNA Sequencing:  Direct Identification of Ribonucleoside and Deoxyribonucleoside 5‘-Monophosphates by Using an Engineered Protein Nanopore Equipped with a Molecular Adapter Yann Astier, Orit Braha, and Hagan Bayley pp 1705–1710 DOI: 10.1021/ja057123+ Supporting Info

Redox Enzymes in Tethered Membranes Lars J. C. Jeuken, Simon D. Connell, Peter J. F. Henderson, Robert B. Gennis, Stephen D. Evans, and Richard J. Bushby pp 1711–1716 DOI: 10.1021/ja056972u Supporting Info

Utilization of the Pleiotropy of a Peptidic Aptamer To Fabricate Heterogeneous Nanodot-Containing Multilayer Nanostructures Ken-Ichi Sano, Hiroyuki Sasaki, and Kiyotaka Shiba pp 1717–1722 DOI: 10.1021/ja057262r

A Comprehensive Study of Self-Assembled Monolayers of Anthracenethiol on Gold:  Solvent Effects, Structure, and Stability Daniel Käfer, Gregor Witte, Piotr Cyganik, Andreas Terfort, and Christof Wöll pp 1723–1732 DOI: 10.1021/ja0571592 Supporting Info

A Threaded Loop Conformation Adopted by a Family of Peptoid Nonamers Kai Huang, Cindy W. Wu, Tracy J. Sanborn, James A. Patch, Kent Kirshenbaum, Ronald N. Zuckermann, Annelise E. Barron, and Ishwar Radhakrishnan pp 1733–1738 DOI: 10.1021/ja0574318 Supporting Info

Tuning the Reactivity of Osmium(II) and Ruthenium(II) Arene Complexes under Physiological Conditions Anna F. A. Peacock, Abraha Habtemariam, Rafael Fernández, Victoria Walland, Francesca P. A. Fabbiani, Simon Parsons, Rhona E. Aird, Duncan I. Jodrell, and Peter J. Sadler pp 1739–1748 DOI: 10.1021/ja055886r Supporting Info

Electrochemical Growth of Highly Oriented Organic−Inorganic Superlattices Using Solid-Supported Multilamellar Membranes as Templates Li-Li Xing, Da-Peng Li, Shu-Xin Hu, Huai-Yu Jing, Honglan Fu, Zhen-Hong Mai, and Ming Li pp 1749–1754 DOI: 10.1021/ja056448n Supporting Info

Controlled Clustering of Superparamagnetic Nanoparticles Using Block Copolymers: Design of New Contrast Agents for Magnetic Resonance Imaging Jean-François Berret, Nicolas Schonbeck, Florence Gazeau, Delphine El Kharrat, Olivier Sandre, Annie Vacher, and Marc Airiau pp 1755–1761 DOI: 10.1021/ja0562999

Aliphatic/Aromatic Polyimide Ionomers as a Proton Conductive Membrane for Fuel Cell Applications Naoki Asano, Makoto Aoki, Shinsuke Suzuki, Kenji Miyatake, Hiroyuki Uchida, and Masahiro Watanabe pp 1762–1769 DOI: 10.1021/ja0571491 Supporting Info

Structural and Spectroscopic Demonstration of Agostic C−C Interactions in Electron-Deficient Metallacyclobutanes and Related Cage Complexes:  Possible Implications for Olefin Polymerizations and Metatheses  [J. Am. Chem. Soc. 2005, 127, 12426−12435]. Benjamin G. Harvey, Charles L. Mayne, Atta M. Arif, Robert Tomaszewski, and Richard D. Ernst p 1770 DOI: 10.1021/ja059925a

Tris(chloranilato)ferrate(III) Anionic Building Block Containing the (Dihydroxo)oxodiiron(III) Dimer Cation:  Synthesis and Characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5·1.5MeOH·H2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate] [J. Am. Chem. Soc. 2006, 128, 40−41]. Kil Sik Min, Arnold L. Rheingold, and Joel S. Miller p 1770 DOI: 10.1021/ja069951o

Enantiomer Separation:  Fundamentals and Practical Methods Edited by Fumio Toda (Okayama University of Science, Japan). Kluwer Academic Publishers:  Dordrecht, Boston, London. 2004. viii + 334 pp. $149.00. ISBN 1-4020-2336-7. Thomas K. Green p 1771 DOI: 10.1021/ja0597698

Dictionary of Microscopy By Julian P. Heath (Cambridge, UK). John Wiley & Sons, Ltd:  Chichester, UK. 2005. 358 pp. $49.95. ISBN 0-470-01199-8. p 1771 DOI: 10.1021/ja059843m

Microwaves in Organic and Medicinal Chemistry, Volume 25 By C. Oliver Kappe and Alexander Stadler (Karl-Franzens-University Graz). From the Series, Methods and Principles in Medicinal Chemistry. Edited by R. Mannhold, H. Kubinyi, and G. Folkers. Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xii + 410 pp. $170.00. ISBN 3-527-31210-2. James J. Kiddle pp 1771–1772 DOI: 10.1021/ja059814b

Advances in Heterocyclic Chemistry, Volume 88 Edited by Alan R. Katritzky (University of Florida, Gainesville). Elsevier Academic Press:  San Diego, CA. 2005. x + 324 pp. $180.00. ISBN 0-12-020788-5. Eric Block pp 1772–1773 DOI: 10.1021/ja0598208

Poly(arylene ethynylene)s:  From Synthesis to Application. Advances in Polymer Science, Volume 177 Edited by Christoph Weder (Case Western Reserve University). Springer:  Berlin, Heidelberg, New York. xii + 272 pp. $226.00. ISBN 3-540-23366-0. Kirk S. Schanze pp 1773–1774 DOI: 10.1021/ja059823k

Issue 06

Broadband Homonuclear Correlation Spectroscopy at High Magnetic Fields and MAS Frequencies Gaël De Paëpe, Marvin J. Bayro, Józef Lewandowski, and Robert G. Griffin pp 1776–1777 DOI: 10.1021/ja0550430 Supporting Info

Characterization of Nonbiological Antimicrobial Polymers in Aqueous Solution and at Water−Lipid Interfaces from All-Atom Molecular Dynamics Ivaylo Ivanov, Satyavani Vemparala, Vojislava Pophristic, Kenichi Kuroda, William F. DeGrado, J. Andrew McCammon, and Michael L. Klein pp 1778–1779 DOI: 10.1021/ja0564665 Supporting Info

Enhanced CO Tolerance for Hydrogen Activation in Au−Pt Dendritic Heteroaggregate Nanostructures Shenghu Zhou, Kevin McIlwrath, Greg Jackson, and Bryan Eichhorn pp 1780–1781 DOI: 10.1021/ja056924+ Supporting Info

Electron Hopping in π-Stacked Covalent and Self-Assembled Perylene Diimides Observed by ENDOR Spectroscopy Michael J. Tauber, Richard F. Kelley, Jovan M. Giaimo, Boris Rybtchinski, and Michael R. Wasielewski pp 1782–1783 DOI: 10.1021/ja057031k Supporting Info

Rotaxanes of Cyclic Peptides Vincent Aucagne, David A. Leigh, Julia S. Lock, and Andrew R. Thomson pp 1784–1785 DOI: 10.1021/ja057206q Supporting Info

Single Unit Cell Thick Samaria Nanowires and Nanoplates Taekyung Yu, Jin Joo, Yong Il Park, and Taeghwan Hyeon pp 1786–1787 DOI: 10.1021/ja057264b Supporting Info

Chemical Complementarity in the Contacts for Nanoscale Organic Field-Effect Transistors George S. Tulevski, Qian Miao, Ali Afzali, Teresita O. Graham, Cherie R. Kagan, and Colin Nuckolls pp 1788–1789 DOI: 10.1021/ja0574926 Supporting Info

Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt−Tetraoxolene Complex Jun Tao, Hiroyuki Maruyama, and Osamu Sato pp 1790–1791 DOI: 10.1021/ja057488u Supporting Info

Stereocontrolled Synthesis of Spiroketals via Ti(Oi-Pr)4-Mediated Kinetic Spirocyclization of Glycal Epoxides with Retention of Configuration Sirkka B. Moilanen, Justin S. Potuzak, and Derek S. Tan pp 1792–1793 DOI: 10.1021/ja057908f Supporting Info

Selective Functionalization of Independently Addressed Microelectrodes by Electrochemical Activation and Deactivation of a Coupling Catalyst Neal K. Devaraj, Peter H. Dinolfo, Christopher E. D. Chidsey, and James P. Collman pp 1794–1795 DOI: 10.1021/ja058380h Supporting Info

Selective Functionalization of 3-D Polymer Microstructures Richard A. Farrer, Christopher N. LaFratta, Linjie Li, Julie Praino, Michael J. Naughton, Bahaa E. A. Saleh, Malvin C. Teich, and John T. Fourkas pp 1796–1797 DOI: 10.1021/ja0583620

Gold(I)-Catalyzed Intra- and Intermolecular Hydroamination of Unactivated Olefins Junliang Zhang, Cai-Guang Yang, and Chuan He pp 1798–1799 DOI: 10.1021/ja053864z Supporting Info

Catalyzed CO Oxidation at 70 K on an Extended Au/Ni Surface Alloy David L. Lahr and Sylvia T. Ceyer pp 1800–1801 DOI: 10.1021/ja053866j

Photo-CIDNP Reveals Differences in Compaction of Non-Native States of Lysozyme Christian Schlörb, Sarah Mensch, Christian Richter, and Harald Schwalbe pp 1802–1803 DOI: 10.1021/ja056757d

Three-Coordinate Co(I) Provides Access to Unsaturated Dihydrido-Co(III) and Seven-Coordinate Co(V) Michael Ingleson, Hongjun Fan, Maren Pink, John Tomaszewski, and Kenneth G. Caulton pp 1804–1805 DOI: 10.1021/ja0572452 Supporting Info

Nickel(0)-Catalyzed Isomerization of an Aryne Complex:  Formation of a Dinuclear Ni(I) Complex via C−H Rather than C−F Bond Activation Alana L. Keen and Samuel A. Johnson pp 1806–1807 DOI: 10.1021/ja0572553 Supporting Info

Self-Reporting Fluorescent Substrates of Protein Tyrosine Kinases Qunzhao Wang, Sean M. Cahill, Michael Blumenstein, and David S. Lawrence pp 1808–1809 DOI: 10.1021/ja0577692 Supporting Info

Catalytic, Enantioselective [4 + 2]-Cycloadditions of Ketene Enolates and o-Quinones:  Efficient Entry to Chiral, α-Oxygenated Carboxylic Acid Derivatives Tefsit Bekele, Meha H. Shah, Jamison Wolfer, Ciby J. Abraham, Anthony Weatherwax, and Thomas Lectka pp 1810–1811 DOI: 10.1021/ja058077g Supporting Info

Isolation and Crystal Structures of Two Singlet Bis(Triarylamine) Dications with Nonquinoidal Geometries Shijun Zheng, Stephen Barlow, Chad Risko, Tiffany L. Kinnibrugh, Viktor N. Khrustalev, Simon C. Jones, Mikhail Yu. Antipin, Neil M. Tucker, Tatiana V. Timofeeva, Veaceslav Coropceanu, Jean-Luc Brédas, and Seth R. Marder pp 1812–1817 DOI: 10.1021/ja0541534 Supporting Info

Energy and Photoinduced Electron Transfer in a Wheel-Shaped Artificial Photosynthetic Antenna-Reaction Center Complex Gerdenis Kodis, Yuichi Terazono, Paul A. Liddell, Joakim Andréasson, Vikas Garg, Michael Hambourger, Thomas A. Moore, Ana L. Moore, and Devens Gust pp 1818–1827 DOI: 10.1021/ja055903c Supporting Info

A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes Adam M. Johns, Masaru Utsunomiya, Christopher D. Incarvito, and John F. Hartwig pp 1828–1839 DOI: 10.1021/ja056003z Supporting Info

Highly Active Chiral Ruthenium Catalysts for Asymmetric Ring-Closing Olefin Metathesis Timothy W. Funk, Jacob M. Berlin, and Robert H. Grubbs pp 1840–1846 DOI: 10.1021/ja055994d Supporting Info

Alkane C−H Bond Activation in Zeolites:  Evidence for Direct Protium Exchange Matthew J. Truitt, Stan S. Toporek, Rosimar Rovira-Truitt, and Jeffery L. White pp 1847–1852 DOI: 10.1021/ja0558802

Detection of Second Hydration Shells in Ionic Solutions by XANES:  Computed Spectra for Ni2+ in Water Based on Molecular Dynamics Paola D'Angelo, Otello Maria Roscioni, Giovanni Chillemi, Stefano Della Longa, and Maurizio Benfatto pp 1853–1858 DOI: 10.1021/ja0562503

Inhibition of HLA-DQ2-Mediated Antigen Presentation by Analogues of a High Affinity 33-Residue Peptide from α2-Gliadin Jiang Xia, Matthew Siegel, Elin Bergseng, Ludvig M. Sollid, and Chaitan Khosla pp 1859–1867 DOI: 10.1021/ja056423o

Effect of Pressure on a Heavy-Atom Isotope Effect of Yeast Alcohol Dehydrogenase Hyun Park, Gary G. Girdaukas, and Dexter B. Northrop pp 1868–1872 DOI: 10.1021/ja056525e

Effect of Molecular Chirality on Racemate Stability:  α-Amino Acids with Nonpolar R Groups Jun Huang and Lian Yu pp 1873–1878 DOI: 10.1021/ja0571693

Inhibition of Thioredoxin and Thioredoxin Reductase by 4-Hydroxy-2-nonenal in Vitro and in Vivo Jianguo Fang and Arne Holmgren pp 1879–1885 DOI: 10.1021/ja057358l

Cobalt(diamine)-Catalyzed Cross-coupling Reaction of Alkyl Halides with Arylmagnesium Reagents:  Stereoselective Constructions of Arylated Asymmetric Carbons and Application to Total Synthesis of AH13205 Hirohisa Ohmiya, Hideki Yorimitsu, and Koichiro Oshima pp 1886–1889 DOI: 10.1021/ja057560o Supporting Info

Spontaneous Fibril Formation by Polyalanines; Discontinuous Molecular Dynamics Simulations Hung D. Nguyen and Carol K. Hall pp 1890–1901 DOI: 10.1021/ja0539140

Application of Badger's Rule to Heme and Non-Heme Iron−Oxygen Bonds:  An Examination of Ferryl Protonation States Michael T. Green pp 1902–1906 DOI: 10.1021/ja054074s Supporting Info

Functionalized Gold Nanoparticles as Phosphorescent Nanomaterials and Sensors Binil Itty Ipe, Karuvath Yoosaf, and Kakkudiyil George Thomas pp 1907–1913 DOI: 10.1021/ja054347j Supporting Info

Thermodynamics of Interactions of Water-Soluble Porphyrins with RNA Duplexes Ara A. Ghazaryan, Yeva B. Dalyan, Samvel G. Haroutiunian, Anna Tikhomirova, Nicolas Taulier, James W. Wells, and Tigran V. Chalikian pp 1914–1921 DOI: 10.1021/ja054070n

Electroreduction of a Series of Alkylcobalamins:  Mechanism of Stepwise Reductive Cleavage of the Co−C Bond Ronald L. Birke, Qingdong Huang, Tudor Spataru, and David K. Gosser, Jr. pp 1922–1936 DOI: 10.1021/ja054479c Supporting Info

Structural Insights into Homo- and Heterotropic Allosteric Coupling in the Zinc Sensor S. aureus CzrA from Covalently Fused Dimers Sunbae Lee, Alphonse I. Arunkumar, Xiaohua Chen, and David P. Giedroc pp 1937–1947 DOI: 10.1021/ja0546828 Supporting Info

The Nature of the H3O+ Hydronium Ion in Benzene and Chlorinated Hydrocarbon Solvents. Conditions of Existence and Reinterpretation of Infrared Data Evgenii S. Stoyanov, Kee-Chan Kim, and Christopher A. Reed pp 1948–1958 DOI: 10.1021/ja0551335 Supporting Info

Molecular Engineering and Measurements To Test Hypothesized Mechanisms in Single Molecule Conductance Switching Amanda M. Moore, Arrelaine A. Dameron, Brent A. Mantooth, Rachel K. Smith, Daniel J. Fuchs, Jacob W. Ciszek, Francisco Maya, Yuxing Yao, James M. Tour, and Paul S. Weiss pp 1959–1967 DOI: 10.1021/ja055761m

Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide Tomoyuki Fujita, Koji Nakano, Makoto Yamashita, and Kyoko Nozaki pp 1968–1975 DOI: 10.1021/ja055862k Supporting Info

Building Up Key Segments of N-Glycans in the Gas Phase:  Intrinsic Structural Preferences of the α(1,3) and α(1,6) Dimannosides Pierre Çarçabal, Isabel Hünig, David P. Gamblin, Bo Liu, Rebecca A. Jockusch, Romano T. Kroemer, Lavina C. Snoek, Anthony J. Fairbanks, Benjamin G. Davis, and John P. Simons pp 1976–1981 DOI: 10.1021/ja055891v Supporting Info

Resonating Valence Bond Ground State in Oxygen-Functionalized Phenalenyl-Based Neutral Radical Molecular Conductors Swadhin K. Mandal, Satyabrata Samanta, Mikhail E. Itkis, Dell W. Jensen, Robert W. Reed, Richard T. Oakley, Fook S. Tham, Bruno Donnadieu, and Robert C. Haddon pp 1982–1994 DOI: 10.1021/ja0560276 Supporting Info

Probing the Structural Requirements of Peptoids That Inhibit HDM2−p53 Interactions Toshiaki Hara, Stewart R. Durell, Michael C. Myers, and Daniel H. Appella pp 1995–2004 DOI: 10.1021/ja056344c Supporting Info

Kinetics and Mechanism of Methane, Methanol, and Dimethyl Ether C−H Activation with Electrophilic Platinum Complexes Jonathan S. Owen, Jay A. Labinger, and John E. Bercaw pp 2005–2016 DOI: 10.1021/ja056387t Supporting Info

Electronic Structure of Binuclear Mixed Valence Copper Azacryptates Derived from Integrated Advanced EPR and DFT Calculations Shifra Kababya, Jane Nelson, Carlos Calle, Frank Neese, and Daniella Goldfarb pp 2017–2029 DOI: 10.1021/ja056207f Supporting Info

Phase Behavior of a Phospholipid/Fatty Acid/Water Mixture Studied in Atomic Detail Volker Knecht, Alan E. Mark, and Siewert-Jan Marrink pp 2030–2034 DOI: 10.1021/ja056619o

De Novo Structure-Based Design of Bisurea Hosts for Tetrahedral Oxoanion Guests Vyacheslav S. Bryantsev and Benjamin P. Hay pp 2035–2042 DOI: 10.1021/ja056699w Supporting Info

Experimental and Computational Investigation of the Uncatalyzed Rearrangement and Elimination Reactions of Isochorismate Michael S. DeClue, Kim K. Baldridge, Peter Kast, and Donald Hilvert pp 2043–2051 DOI: 10.1021/ja056714x Supporting Info

Effective Disruption of Phosphoprotein−Protein Surface Interaction Using Zn(II) Dipicolylamine-Based Artificial Receptors via Two-Point Interaction Akio Ojida, Masa-aki Inoue, Yasuko Mito-oka, Hiroshi Tsutsumi, Kazuki Sada, and Itaru Hamachi pp 2052–2058 DOI: 10.1021/ja056585k Supporting Info

Carbon Monoxide Promoted Reductive Elimination of Hydrogen from Tp‘ Platinum Complexes Nathan M. West, Stefan Reinartz, Peter S. White, and Joseph L. Templeton pp 2059–2066 DOI: 10.1021/ja056766m Supporting Info

A Reversible pH-Driven DNA Nanoswitch Array Dongsheng Liu, Andreas Bruckbauer, Chris Abell, Shankar Balasubramanian, Dae-Joon Kang, David Klenerman, and Dejian Zhou pp 2067–2071 DOI: 10.1021/ja0568300 Supporting Info

Thioindigo Dyes:  Highly Accurate Visible Spectra with TD-DFT Denis Jacquemin, Julien Preat, Valérie Wathelet, Michèle Fontaine, and Eric A. Perpète pp 2072–2083 DOI: 10.1021/ja056676h Supporting Info

Electrochemistry of Immobilized Redox Enzymes:  Kinetic Characteristics of NADH Oxidation Catalysis at Diaphorase Monolayers Affinity Immobilized on Electrodes. Benoît Limoges, Damien Marchal, François Mavré, and Jean-Michel Savéant pp 2084–2092 DOI: 10.1021/ja0569196

Experimental and Density Functional Theoretical Investigations of Linkage Isomerism in Six-Coordinate {FeNO}6 Iron Porphyrins with Axial Nitrosyl and Nitro Ligands Irina V. Novozhilova, Philip Coppens, Jonghyuk Lee, George B. Richter-Addo, and Kimberly A. Bagley pp 2093–2104 DOI: 10.1021/ja0567891 Supporting Info

Highly Enantioselective Synthesis of Glycidic Amides Using Camphor-Derived Sulfonium Salts. Mechanism and Applications in Synthesis Varinder K. Aggarwal, Jonathan P. H. Charmant, Daniel Fuentes, Jeremy N. Harvey, George Hynd, Diasuke Ohara, Willy Picoul, Raphaël Robiette, Catherine Smith, Jean-Luc Vasse, and Caroline L. Winn pp 2105–2114 DOI: 10.1021/ja0568345 Supporting Info

Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods Xiaohua Huang, Ivan H. El-Sayed, Wei Qian, and Mostafa A. El-Sayed pp 2115–2120 DOI: 10.1021/ja057254a

Solid-State 35/37Cl NMR Spectroscopy of Hydrochloride Salts of Amino Acids Implicated in Chloride Ion Transport Channel Selectivity:  Opportunities at 900 MHz David L. Bryce, Gregory D. Sward, and Samyuktha Adiga pp 2121–2134 DOI: 10.1021/ja057253i Supporting Info

Conductance of Single Alkanedithiols:  Conduction Mechanism and Effect of Molecule−Electrode Contacts Xiulan Li, Jin He, Joshua Hihath, Bingqian Xu, Stuart M. Lindsay, and Nongjian Tao pp 2135–2141 DOI: 10.1021/ja057316x

Strategies for Electrooptic Film Fabrication. Influence of Pyrrole−Pyridine-Based Dibranched Chromophore Architecture on Covalent Self-Assembly, Thin-Film Microstructure, and Nonlinear Optical Response Antonio Facchetti, Luca Beverina, Milko E. van der Boom, Pulak Dutta, Guennadi Evmenenko, Atindra D. Shukla, Charlotte E. Stern, Giorgio A. Pagani, and Tobin J. Marks pp 2142–2153 DOI: 10.1021/ja057556c Supporting Info

Sequential Catalytic Asymmetric Heck-Iminium Ion Cyclization:  Enantioselective Total Synthesis of the Strychnos Alkaloid Minfiensine  [J. Am. Chem. Soc. 2005, 127, 10186−10187].  Amy B. Dounay, Larry E. Overman, and Aaron D. Wrobleski p 2154 DOI: 10.1021/ja059922y

Issue 07

Hydrophobic and Hydrophilic Yoctowells as Receptors in Water Sidhanath Bhosale, Sheshanath Bhosale, Tianyu Wang, Marta Kopaczynska, and Jurgen-Hinrich Fuhrhop pp 2156–2157 DOI: 10.1021/ja053816e Supporting Info

Atomic-Level Description of Amyloid β-Dimer Formation S. Gnanakaran, Ruth Nussinov, and Angel E. García pp 2158–2159 DOI: 10.1021/ja0548337 Supporting Info

NMR Distinction of Single- and Multiple-Mode Binding of Small-Molecule Protein Ligands Mikhail Reibarkh, Thomas J. Malia, and Gerhard Wagner pp 2160–2161 DOI: 10.1021/ja055971z

Cytochrome Display on Amyloid Fibrils Andrew J. Baldwin, Reto Bader, John Christodoulou, Cait E. MacPhee, Christopher M. Dobson, and Paul D. Barker pp 2162–2163 DOI: 10.1021/ja0565673 Supporting Info

Paramagnetic Active Site Models for the Molybdenum−Copper Carbon Monoxide Dehydrogenase Craig Gourlay, David J. Nielsen, Jonathan M. White, Sushilla Z. Knottenbelt, Martin L. Kirk, and Charles G. Young pp 2164–2165 DOI: 10.1021/ja056500f Supporting Info

Eight-Membered Ring Construction by [4 + 2 + 2] Annulation Involving β-Carbon Elimination Masahiro Murakami, Shinji Ashida, and Takanori Matsuda pp 2166–2167 DOI: 10.1021/ja0552895 Supporting Info

Formation of Nanostructured Materials via Coalescence of Amphiphilic Hollow Particles Panya Sunintaboon, Kin Man Ho, Pei Li, Stephen Z. D. Cheng, and Frank W. Harris pp 2168–2169 DOI: 10.1021/ja056065p Supporting Info

15N HYSCORE Characterization of the Fully Deprotonated, Reduced Form of the Archaeal Rieske [2Fe−2S] Center Toshio Iwasaki, Asako Kounosu, Rimma I. Samoilova, and Sergei A. Dikanov pp 2170–2171 DOI: 10.1021/ja0562393 Supporting Info

MercuryII-Mediated Formation of Thymine−HgII−Thymine Base Pairs in DNA Duplexes Yoko Miyake, Humika Togashi, Mitsuru Tashiro, Hiroshi Yamaguchi, Shuji Oda, Megumi Kudo, Yoshiyuki Tanaka, Yoshinori Kondo, Ryuichi Sawa, Takashi Fujimoto, Tomoya Machinami, and Akira Ono pp 2172–2173 DOI: 10.1021/ja056354d Supporting Info

Enantioselective 1,3-Dipolar Cycloaddition Reaction between Diazoacetates and α-Substituted Acroleins:  Total Synthesis of Manzacidin A Taichi Kano, Takuya Hashimoto, and Keiji Maruoka pp 2174–2175 DOI: 10.1021/ja056851u Supporting Info

Stoichiometric Hydrosilylation of Nitriles with Hydrido(hydrosilylene)tungsten Complexes:  Formation of W−Si−N Three-Membered Ring Complexes and Their Unique Thermal Behaviors Takahito Watanabe, Hisako Hashimoto, and Hiromi Tobita pp 2176–2177 DOI: 10.1021/ja056715p Supporting Info

Asymmetric Synthesis of 4,5,6- and 3,4,5,6-Substituted Azepanes by a Highly Diastereoselective and Enantioselective Lithiation−Conjugate Addition Sequence Suk Joong Lee and Peter Beak pp 2178–2179 DOI: 10.1021/ja057592b Supporting Info

A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols Manuel A. Fernández-Rodríguez, Qilong Shen, and John F. Hartwig pp 2180–2181 DOI: 10.1021/ja0580340 Supporting Info

Discovery of EGFR Selective 4,6-Disubstituted Pyrimidines from a Combinatorial Kinase-Directed Heterocycle Library Qiong Zhang, Yi Liu, Feng Gao, Qiang Ding, Charles Cho, Wooyoung Hur, Yunho Jin, Tetsuo Uno, Claudio A. P. Joazeiro, and Nathanael Gray pp 2182–2183 DOI: 10.1021/ja0567485 Supporting Info

Characterization of Proton Transport across a Waveguide-Supported Lipid Bilayer Todd W. McBee, Liying Wang, Chenhao Ge, Brooke M. Beam, Ana L. Moore, Devens Gust, Thomas A. Moore, Neal R. Armstrong, and S. Scott Saavedra pp 2184–2185 DOI: 10.1021/ja056750w Supporting Info

Catalytic “Click” Rotaxanes:  A Substoichiometric Metal-Template Pathway to Mechanically Interlocked Architectures Vincent Aucagne, Kevin D. Hänni, David A. Leigh, Paul J. Lusby, and D. Barney Walker pp 2186–2187 DOI: 10.1021/ja056903f Supporting Info

Network Single-Walled Carbon Nanotube-Field Effect Transistors (SWNT-FETs) with Increased Schottky Contact Area for Highly Sensitive Biosensor Applications Hye Ryung Byon and Hee Cheul Choi pp 2188–2189 DOI: 10.1021/ja056897n Supporting Info

A Comprehensive Theoretical View of the Bonding in Actinide Molecular Complexes Laurence Petit, Laurent Joubert, Pascale Maldivi, and Carlo Adamo pp 2190–2191 DOI: 10.1021/ja056908c Supporting Info

PC Bond Cleavage of (silox)3NbPMe3 (silox = tBu3SiO) under Dihydrogen Leads to (silox)3NbCH2, (silox)3NbPH or (silox)3NbP(H)Nb(silox)3, and CH4 Kurt F. Hirsekorn, Adam S. Veige, and Peter T. Wolczanski pp 2192–2193 DOI: 10.1021/ja057747f Supporting Info

Aggregation-Induced Folding of a De Novo Designed Polypeptide Immobilized on Gold Nanoparticles Daniel Aili, Karin Enander, Johan Rydberg, Ingemar Lundström, Lars Baltzer, and Bo Liedberg pp 2194–2195 DOI: 10.1021/ja057056j

Random Coils, β-Sheet Ribbons, and α-Helical Fibers:  One Peptide Adopting Three Different Secondary Structures at Will Kevin Pagel, Sara C. Wagner, Kerim Samedov, Hans von Berlepsch, Christoph Böttcher, and Beate Koksch pp 2196–2197 DOI: 10.1021/ja057450h Supporting Info

4f−5f Heterotrimetallic Complexes Exhibiting Electrochemical and Magnetic Communication Eric J. Schelter, Jacqueline M. Veauthier, Joe D. Thompson, Brian L. Scott, Kevin D. John, David E. Morris, and Jaqueline L. Kiplinger pp 2198–2199 DOI: 10.1021/ja057808+ Supporting Info

Hot Spots in Silver Nanowire Bundles for Surface-Enhanced Raman Spectroscopy Seung Joon Lee, Andrew R. Morrill, and Martin Moskovits pp 2200–2201 DOI: 10.1021/ja0578350 Supporting Info

Expanding the Thioglycoligase Strategy to the Synthesis of α-Linked Thioglycosides Allows Structural Investigation of the Parent Enzyme/Substrate Complex Young-Wan Kim, Andrew L. Lovering, Hongming Chen, Terrence Kantner, Lawrence P. McIntosh, Natalie C. J. Strynadka, and Stephen G. Withers pp 2202–2203 DOI: 10.1021/ja057904a Supporting Info

The Ionothermal Synthesis of Cobalt Aluminophosphate Zeolite Frameworks Emily R. Parnham and Russell E. Morris pp 2204–2205 DOI: 10.1021/ja057933l Supporting Info

Four-Membered Group 13 Metal(I) N-Heterocyclic Carbene Analogues:  Synthesis, Characterization, and Theoretical Studies Cameron Jones, Peter C. Junk, Jamie A. Platts, and Andreas Stasch pp 2206–2207 DOI: 10.1021/ja057967t Supporting Info

A Screening Method for Chiral Selectors that Does Not Require Covalent Attachment Zhi Chen, Yanhong Yang, Stefan Werner, Peter Wipf, and Stephen G. Weber pp 2208–2209 DOI: 10.1021/ja058004x Supporting Info

Palladium-Catalyzed Stereo- and Regiospecific Allylation of Aryl Halides with Homoallyl Alcohols via Retro-Allylation:  Selective Generation and Use of σ-Allylpalladium Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima pp 2210–2211 DOI: 10.1021/ja058055u Supporting Info

Photogenerated Hole Mobility in DNA Measured by Time-Resolved Microwave Conductivity Ryuhei Yamagami, Kazuo Kobayashi, Akinori Saeki, Shu Seki, and Seiichi Tagawa pp 2212–2213 DOI: 10.1021/ja058057e

Kinase-Catalyzed Modification of Gold Nanoparticles:  A New Approach to Colorimetric Kinase Activity Screening Zhenxin Wang, Raphaël Lévy, David G. Fernig, and Mathias Brust pp 2214–2215 DOI: 10.1021/ja058135y Supporting Info

Electronic Control of Amide cis−trans Isomerism via the Aromatic−Prolyl Interaction Krista M. Thomas, Devan Naduthambi, and Neal J. Zondlo pp 2216–2217 DOI: 10.1021/ja057901y Supporting Info

Dendritic Folate Rosettes as Ion Channels in Lipid Bilayers Naomi Sakai, Yuko Kamikawa, Masayuki Nishii, Toru Matsuoka, Takashi Kato, and Stefan Matile pp 2218–2219 DOI: 10.1021/ja058157k Supporting Info

Formation of Ordered Mesoporous Films from In situ Structure Inversion of Azo Polymer Colloidal Arrays Yaobang Li, Xiaolan Tong, Yaning He, and Xiaogong Wang pp 2220–2221 DOI: 10.1021/ja058167l Supporting Info

Tris(pyrone) Chelates of Gd(III) as High Solubility MRI-CA David T. Puerta, Mauro Botta, Christoph J. Jocher, Eric J. Werner, Stefano Avedano, Kenneth N. Raymond, and Seth M. Cohen pp 2222–2223 DOI: 10.1021/ja057954f Supporting Info

A Chemo-Enzymatic Route to Enantiomerically Pure Cyclic Tertiary Amines Colin J. Dunsmore, Reuben Carr, Toni Fleming, and Nicholas J. Turner pp 2224–2225 DOI: 10.1021/ja058536d Supporting Info

Contrast Viscosity Changes upon Photoirradiation for Mixtures of Poly(acrylic acid)-Based α-Cyclodextrin and Azobenzene Polymers Itsuro Tomatsu, Akihito Hashidzume, and Akira Harada pp 2226–2227 DOI: 10.1021/ja058345a Supporting Info

Quantum-Dot/Aptamer-Based Ultrasensitive Multi-Analyte Electrochemical Biosensor Jacob A. Hansen, Joseph Wang, Abdel-Nasser Kawde, Yun Xiang, Kurt V. Gothelf, and Greg Collins pp 2228–2229 DOI: 10.1021/ja060005h Supporting Info

Radiosensitization by a Modified Nucleotide that Produces DNA Interstrand Cross-Links under Hypoxic Conditions In Seok Hong, Hui Ding, and Marc M. Greenberg pp 2230–2231 DOI: 10.1021/ja058290c Supporting Info

Ene Reaction of Arynes with Alkynes Thiruvellore Thatai Jayanth, Masilamani Jeganmohan, Mu-Jeng Cheng, San-Yan Chu, and Chien-Hong Cheng pp 2232–2233 DOI: 10.1021/ja058418q Supporting Info

High-Throughput Enzymatic Method for Enantiomeric Excess Determination of O-Acetylated Cyanohydrins Anders Hamberg, Stina Lundgren, Maël Penhoat, Christina Moberg, and Karl Hult pp 2234–2235 DOI: 10.1021/ja058474r Supporting Info

NMR Chemical Shift Powder Pattern Recoupling at High Spinning Speed and Theoretical Tensor Evaluation Applied to Silk Fibroin Raiker Witter, Ulrich Sternberg, and Anne S. Ulrich pp 2236–2243 DOI: 10.1021/ja051730f Supporting Info

Total Synthesis and Structural Elucidation of Azaspiracid-1. Construction of Key Building Blocks for Originally Proposed Structure K. C. Nicolaou, Petri M. Pihko, Federico Bernal, Michael O. Frederick, Wenyuan Qian, Noriaki Uesaka, Nicole Diedrichs, Jürgen Hinrichs, Theocharis V. Koftis, Eriketi Loizidou, Goran Petrovic, Manuela Rodriquez, David Sarlah, and Ning Zou pp 2244–2257 DOI: 10.1021/ja0547477 Supporting Info

Total Synthesis and Structural Elucidation of Azaspiracid-1. Synthesis-Based Analysis of Originally Proposed Structures and Indication of Their Non-Identity to the Natural Product K. C. Nicolaou, David Y.-K. Chen, Yiwei Li, Noriaki Uesaka, Goran Petrovic, Theocharis V. Koftis, Federico Bernal, Michael O. Frederick, Mugesh Govindasamy, Taotao Ling, Petri M. Pihko, Wenjun Tang, and Stepan Vyskocil pp 2258–2267 DOI: 10.1021/ja054748z Supporting Info

Photoactivated H/D Exchange in Tyrosine:  Involvement of a Radical Anion Intermediate Robert E. London and Scott A. Gabel pp 2268–2275 DOI: 10.1021/ja055011c

Monoliths of Aligned Silica-Polypeptide Hexagonal Platelets Enrico G. Bellomo and Timothy J. Deming pp 2276–2279 DOI: 10.1021/ja056227h Supporting Info

Rewritable DNA Microarrays W. C. E. Schofield, J. McGettrick, T. J. Bradley, J. P. S. Badyal, and S. Przyborski pp 2280–2285 DOI: 10.1021/ja056367r

Stereochemistry of Imine Reduction by a Hydroxycyclopentadienyl Ruthenium Hydride Charles P. Casey, Galina A. Bikzhanova, and Ilia A. Guzei pp 2286–2293 DOI: 10.1021/ja056402u Supporting Info

A Europium Complex That Selectively Stains Nucleoli of Cells Junhua Yu, David Parker, Robert Pal, Robert A. Poole, and Martin J. Cann pp 2294–2299 DOI: 10.1021/ja056303g Supporting Info

The 2,6-Diisocyanoazulene Motif:  Synthesis and Efficient Mono- and Heterobimetallic Complexation with Controlled Orientation of the Azulenic Dipole Thomas C. Holovics, Randall E. Robinson, Edward C. Weintrob, Masaharu Toriyama, Gerald H. Lushington, and Mikhail V. Barybin pp 2300–2309 DOI: 10.1021/ja053933+ Supporting Info

One-Dimensional Transition Metal−Benzene Sandwich Polymers:  Possible Ideal Conductors for Spin Transport Hongjun Xiang, Jinlong Yang, J. G. Hou, and Qingshi Zhu pp 2310–2314 DOI: 10.1021/ja054751i Supporting Info

CNT−CdTe Versatile Donor−Acceptor Nanohybrids Dirk M. Guldi, G. M. Aminur Rahman, Vito Sgobba, Nicholas A. Kotov, Davide Bonifazi, and Maurizio Prato pp 2315–2323 DOI: 10.1021/ja0550733 Supporting Info

Solution State Structure Determination of Silicate Oligomers by 29Si NMR Spectroscopy and Molecular Modeling Herman Cho, Andrew R. Felmy, Raluca Craciun, J. Patrick Keenum, Neil Shah, and David A. Dixon pp 2324–2335 DOI: 10.1021/ja0559202 Supporting Info

Large Area Liquid Crystal Monodomain Field-Effect Transistors Albert J. J. M. van Breemen, Peter T. Herwig, Ceciel H. T. Chlon, Jörgen Sweelssen, Herman F. M. Schoo, Sepas Setayesh, Willie M. Hardeman, Christian A. Martin, Dago M. de Leeuw, Josué J. P. Valeton, Cees W. M. Bastiaansen, Dirk J. Broer, Andreea R. Popa-Merticaru, and Stefan C. J. Meskers pp 2336–2345 DOI: 10.1021/ja055337l Supporting Info

Solvent Isotope Effects on Interfacial Protein Electron Transfer in Crystals and Electrode Films Seong A. Kang, Kevin R. Hoke, and Brian R. Crane pp 2346–2355 DOI: 10.1021/ja0557482

Low-Temperature Protein Dynamics:  A Simulation Analysis of Interprotein Vibrations and the Boson Peak at 150 K Vandana Kurkal-Siebert and Jeremy C. Smith pp 2356–2364 DOI: 10.1021/ja055962q Supporting Info

Specific and Stable Fluorescence Labeling of Histidine-Tagged Proteins for Dissecting Multi-Protein Complex Formation Suman Lata, Martynas Gavutis, Robert Tampé, and Jacob Piehler pp 2365–2372 DOI: 10.1021/ja0563105 Supporting Info

Structural Evolution in a Hydrothermal Reaction between Nb2O5 and NaOH Solution:  From Nb2O5 Grains to Microporous Na2Nb2O6·2/3H2O Fibers and NaNbO3 Cubes Huaiyong Zhu, Zhanfeng Zheng, Xueping Gao, Yining Huang, Zhimin Yan, Jin Zou, Hongming Yin, Qingdi Zou, Scott H. Kable, Jincai Zhao, Yunfei Xi, Wayde N. Martens, and Ray L. Frost pp 2373–2384 DOI: 10.1021/ja056301w Supporting Info

Quantum Dot Solar Cells. Harvesting Light Energy with CdSe Nanocrystals Molecularly Linked to Mesoscopic TiO2 Films István Robel, Vaidyanathan Subramanian, Masaru Kuno, and Prashant V. Kamat pp 2385–2393 DOI: 10.1021/ja056494n Supporting Info

Reactivity and Selectivity in the Wittig Reaction:  A Computational Study Raphaël Robiette, Jeffery Richardson, Varinder K. Aggarwal, and Jeremy N. Harvey pp 2394–2409 DOI: 10.1021/ja056650q Supporting Info

Oxazolidin-2-one-Containing Pseudopeptides That Fold into β-Bend Ribbon Spirals Claudia Tomasini, Gianluigi Luppi, and Magda Monari pp 2410–2420 DOI: 10.1021/ja056762h Supporting Info

Pattern Recognition of Proteins Based on an Array of Functionalized Porphyrins Huchen Zhou, Laura Baldini, Jason Hong, Andrew J. Wilson, and Andrew D. Hamilton pp 2421–2425 DOI: 10.1021/ja056833c

Ultrafast Cooling of Photoexcited Electrons in Gold Nanoparticle−Thiolated DNA Conjugates Involves the Dissociation of the Gold−Thiol Bond Prashant K. Jain, Wei Qian, and Mostafa A. El-Sayed pp 2426–2433 DOI: 10.1021/ja056769z

Mechanism of the Gold(I)-Catalyzed Rautenstrauch Rearrangement:  A Center-to-Helix-to-Center Chirality Transfer Olalla Nieto Faza, Carlos Silva López, Rosana Álvarez, and Angel R. de Lera pp 2434–2437 DOI: 10.1021/ja057127e Supporting Info

Demonstration of the Ring Conformation in Polyproline by the Raman Optical Activity Josef Kapitán, Vladimír Baumruk, and Petr Bouř pp 2438–2443 DOI: 10.1021/ja057337r Supporting Info

Tetrathiafulvalene-Calix[4]pyrroles:  Synthesis, Anion Binding, and Electrochemical Properties Kent A. Nielsen, Won-Seob Cho, Joël Lyskawa, Eric Levillain, Vincent M. Lynch, Jonathan L. Sessler, and Jan O. Jeppesen pp 2444–2451 DOI: 10.1021/ja057367u Supporting Info

Experimental and Computational Studies on the Mechanism of N-Heterocycle C−H Activation by Rh(I) Sean H. Wiedemann, Jared C. Lewis, Jonathan A. Ellman, and Robert G. Bergman pp 2452–2462 DOI: 10.1021/ja0576684 Supporting Info

Di-organoiron Mixed Valent Complexes Featuring “(η2-dppe)(η5-C5Me5)Fe” Endgroups:  Smooth Class-III to Class-II Transition Induced by Successive Insertion of 1,4-Phenylene Units in a Butadiyne-Diyl Bridge Safaa Ibn Ghazala, Frédéric Paul, Loic Toupet, Thierry Roisnel, Philippe Hapiot, and Claude Lapinte pp 2463–2476 DOI: 10.1021/ja057665r Supporting Info

Directed Evolution and Substrate Specificity Profile of Homing Endonuclease I-SceI Jeffrey B. Doyon, Vikram Pattanayak, Carissa B. Meyer, and David R. Liu pp 2477–2484 DOI: 10.1021/ja057519l Supporting Info

Combined C−H Activation/Cope Rearrangement as a Strategic Reaction in Organic Synthesis:  Total Synthesis of (−)-Colombiasin A and (−)-Elisapterosin B Huw M. L. Davies, Xing Dai, and Matthew S. Long pp 2485–2490 DOI: 10.1021/ja056877l Supporting Info

Addition of Cyclopropyl Alkynes to a Brook Silene:  Definitive Evidence for a Biradical Intermediate Kaarina K. Milnes, Michael C. Jennings, and Kim M. Baines pp 2491–2501 DOI: 10.1021/ja057596g Supporting Info

Anion Sensing. Topics in Current Chemistry, 255 Edited by Ivan Stibor (Praha Institute of Chemical Technology, Prague, Czech Republic). Springer:  Berlin, Heidelberg, New York. 2005. x + 238 pp. $219.00. ISBN 3-540-23247-8. Kristin Bowman-James p 2502 DOI: 10.1021/ja059822s

Food Flavor and Chemistry:  Explorations into the 21st Century Edited by A. M. Spanier (U.S. Department of Agriculture, Rockville, MD), F. Shahidi (Memorial University of Newfoundland, St. John's, NF, Canada), T. H. Parliment (Parliment Consulting, New City, NY), C. Mussinan (IFF R&D, Union Beach, NJ), C.-T. Ho (Rutgers University, New Brunswick, NJ), and E. Tratras Contis (Eastern Michigan University, Ypsilanti, MI). Royal Society of Chemistry:  Cambridge, UK. 2005. xii + 510 pp. $210.00. ISBN 0-85404-653-4. p 2502 DOI: 10.1021/ja059833l

Issue 08

Formation and Characterization of the XeOO+ Cation in Solid Argon Mingfei Zhou, Yanying Zhao, Yu Gong, and Jun Li pp 2504–2505 DOI: 10.1021/ja055650n Supporting Info

Biosynthetic 13C Labeling of Aromatic Side Chains in Proteins for NMR Relaxation Measurements Kaare Teilum, Ulrika Brath, Patrik Lundström, and Mikael Akke pp 2506–2507 DOI: 10.1021/ja055660o Supporting Info

Insertion of Molecular Oxygen into a Palladium(II) Hydride Bond Melanie C. Denney, Nicole A. Smythe, Kara L. Cetto, Richard A. Kemp, and Karen I. Goldberg pp 2508–2509 DOI: 10.1021/ja0562292 Supporting Info

Testing the Conformational Hypothesis of Passive Membrane Permeability Using Synthetic Cyclic Peptide Diastereomers Taha Rezai, Bin Yu, Glenn L. Millhauser, Matthew P. Jacobson, and R. Scott Lokey pp 2510–2511 DOI: 10.1021/ja0563455 Supporting Info

A Surprisingly Stable S-Nitrosothiol Complex Laura L. Perissinotti, Darío A. Estrin, Gregory Leitus, and Fabio Doctorovich pp 2512–2513 DOI: 10.1021/ja0565976 Supporting Info

N-Sulfonyloxy Carbamates as Reoxidants for the Tethered Aminohydroxylation Reaction Timothy J. Donohoe, Majid J. Chughtai, David J. Klauber, David Griffin, and Andrew D. Campbell pp 2514–2515 DOI: 10.1021/ja057389g Supporting Info

Vinylcyclopropanation of Olefins via 3-Methoxy-1-propenylrhodium(I) Tomoya Miura, Taisuke Sasaki, Tatsuro Harumashi, and Masahiro Murakami pp 2516–2517 DOI: 10.1021/ja0575326 Supporting Info

Microgram-Scale Testing of Reaction Conditions in Solution Using Nanoliter Plugs in Microfluidics with Detection by MALDI-MS Takuji Hatakeyama, Delai L. Chen, and Rustem F. Ismagilov pp 2518–2519 DOI: 10.1021/ja057720w Supporting Info

One-Pot Synthesis of Copper−Indium Sulfide Nanocrystal Heterostructures with Acorn, Bottle, and Larva Shapes Sang-Hyun Choi, Eung-Gyu Kim, and Taeghwan Hyeon pp 2520–2521 DOI: 10.1021/ja0577342 Supporting Info

Site-Specific Replacement of Y356 with 3,4-Dihydroxyphenylalanine in the β2 Subunit of E. coli Ribonucleotide Reductase Mohammad R. Seyedsayamdost and JoAnne Stubbe pp 2522–2523 DOI: 10.1021/ja057776q Supporting Info

Ligand-Induced Control of C−H versus Aliphatic C−C Migration Reactions of Rh Carbenoids Maxime Vitale, Thomas Lecourt, Chris G. Sheldon, and Varinder K. Aggarwal pp 2524–2525 DOI: 10.1021/ja057739z Supporting Info

Size Series of Small Indium Arsenide−Zinc Selenide Core−Shell Nanocrystals and Their Application to In Vivo Imaging John P. Zimmer, Sang-Wook Kim, Shunsuke Ohnishi, Eichii Tanaka, John V. Frangioni, and Moungi G. Bawendi pp 2526–2527 DOI: 10.1021/ja0579816 Supporting Info

Mild Aerobic Oxidative Palladium (II) Catalyzed C−H Bond Functionalization:  Regioselective and Switchable C−H Alkenylation and Annulation of Pyrroles Elizabeth M. Beck, Neil P. Grimster, Richard Hatley, and Matthew J. Gaunt pp 2528–2529 DOI: 10.1021/ja058141u Supporting Info

Aromaticity on the Pancake-Bonded Dimer of Neutral Phenalenyl Radical as Studied by MS and NMR Spectroscopies and NICS Analysis Shuichi Suzuki, Yasushi Morita, Kozo Fukui, Kazunobu Sato, Daisuke Shiomi, Takeji Takui, and Kazuhiro Nakasuji pp 2530–2531 DOI: 10.1021/ja058387z Supporting Info

A Designed Receptor for pH-Switchable Ion Binding in Water Stephen G. Tajc and Benjamin L. Miller pp 2532–2533 DOI: 10.1021/ja058126p Supporting Info

Phenylborylene:  Direct Spectroscopic Characterization in Inert Gas Matrices Holger F. Bettinger pp 2534–2535 DOI: 10.1021/ja0548642 Supporting Info

Transition-Metal-Free Synthesis of Alternating Thiophene−Perfluoroarene Copolymers Yongfeng Wang and Mark D. Watson pp 2536–2537 DOI: 10.1021/ja056074y Supporting Info

Redirecting the Coat Protein of a Spherical Virus to Assemble into Tubular Nanostructures Santanu Mukherjee, Cory M. Pfeifer, Jennifer M. Johnson, Jay Liu, and Adam Zlotnick pp 2538–2539 DOI: 10.1021/ja056656f

Palladium-Catalyzed Chemo- and Enantioselective Oxidation of Allylic Esters and Carbonates Barry M. Trost, Jeffery Richardson, and Kelvin Yong pp 2540–2541 DOI: 10.1021/ja057163d Supporting Info

Design and Synthesis of a Chemically Cleavable Fluorescent Nucleotide, 3‘-O-Allyl-dGTP-allyl-Bodipy-FL-510, as a Reversible Terminator for DNA Sequencing by Synthesis Lanrong Bi, Dae Hyun Kim, and Jingyue Ju pp 2542–2543 DOI: 10.1021/ja057136n Supporting Info

Allylic Selenosulfide Rearrangement:  A Method for Chemical Ligation to Cysteine and Other Thiols David Crich, Venkataramanan Krishnamurthy, and Thomas K. Hutton pp 2544–2545 DOI: 10.1021/ja057521c Supporting Info

Versatile Precursors of Functional RAFT Agents. Application to the Synthesis of Bio-Related End-Functionalized Polymers Maël Bathfield, Franck D'Agosto, Roger Spitz, Marie-Thérèse Charreyre, and Thierry Delair pp 2546–2547 DOI: 10.1021/ja057481c Supporting Info

Asymmetric Strecker Reaction of Aldimines Using Aqueous Potassium Cyanide by Phase-Transfer Catalysis of Chiral Quaternary Ammonium Salts with a Tetranaphthyl Backbone Takashi Ooi, Yukitaka Uematsu, and Keiji Maruoka pp 2548–2549 DOI: 10.1021/ja058066n Supporting Info

Comparative Diels−Alder Reactivities within a Family of Valence Bond Isomers:  A Biomimetic Total Synthesis of (±)-UCS1025A Thomas R. Hoye and Vadims Dvornikovs pp 2550–2551 DOI: 10.1021/ja0581999 Supporting Info

Asymmetric Synthesis of Hydrobenzofuranones via Desymmetrization of Cyclohexadienones Using the Intramolecular Stetter Reaction Qin Liu and Tomislav Rovis pp 2552–2553 DOI: 10.1021/ja058337u Supporting Info

Catalytic Enantioselective Nozaki−Hiyama Allylation Reaction with Tethered Bis(8-quinolinolato) (TBOx) Chromium Complex Guoyao Xia and Hisashi Yamamoto pp 2554–2555 DOI: 10.1021/ja058454p Supporting Info

Rhodium-Catalyzed Asymmetric Hydroarylation of Diphenylphosphinylallenes with Arylboronic Acids Takahiro Nishimura, Sho Hirabayashi, Yuichi Yasuhara, and Tamio Hayashi pp 2556–2557 DOI: 10.1021/ja058763f Supporting Info

Ultrafast Time-Resolved Transient Absorption and Resonance Raman Spectroscopy Study of the Photodeprotection and Rearrangement Reactions of p-Hydroxyphenacyl Caged Phosphates Chensheng Ma, Wai Ming Kwok, Wing Sum Chan, Yong Du, Jovi Tze Wai Kan, Patrick H. Toy, and David Lee Phillips pp 2558–2570 DOI: 10.1021/ja0532032 Supporting Info

Measuring Protein Concentrations by NMR Spectroscopy Gerhard Wider and Lars Dreier pp 2571–2576 DOI: 10.1021/ja055336t

Evidence for Two Forms, Double Hydrogen Tunneling, and Proximity of Excited States in Bridge-Substituted Porphycenes:  Supersonic Jet Studies Alexander Vdovin, Jerzy Sepioł, Natalia Urbańska, Marek Pietraszkiewicz, Andrzej Mordziński, and Jacek Waluk pp 2577–2586 DOI: 10.1021/ja054745m Supporting Info

Diastereoselective Diels−Alder Reactions of N-Sulfonyl-1-aza-1,3-butadienes with Optically Active Enol Ethers:  An Asymmetric Variant of the 1-Azadiene Diels−Alder Reaction Ryan C. Clark, Steven S. Pfeiffer, and Dale L. Boger pp 2587–2593 DOI: 10.1021/ja0571646 Supporting Info

Evolution of a Strategy for the Synthesis of Structurally Complex Batzelladine Alkaloids. Enantioselective Total Synthesis of the Proposed Structure of Batzelladine F and Structural Revision Frederick Cohen and Larry E. Overman pp 2594–2603 DOI: 10.1021/ja0574320 Supporting Info

Enantioselective Total Synthesis of Batzelladine F and Definition of Its Structure Frederick Cohen and Larry E. Overman pp 2604–2608 DOI: 10.1021/ja057433s Supporting Info

Synthetic Studies and Mechanistic Insight in Nickel-Catalyzed [4+2+1] Cycloadditions Yike Ni and John Montgomery pp 2609–2614 DOI: 10.1021/ja057741q Supporting Info

Photochemical Generation of Dihydrogen Complexes of Chromium and Tungsten Steven L. Matthews and D. Michael Heinekey pp 2615–2620 DOI: 10.1021/ja057912r

Molecular Recognition between Protein and Nicotinamide Dinucleotide in Intact, Proton-Translocating Transhydrogenase Studied by ATR-FTIR Spectroscopy Masayo Iwaki, Nick P. J. Cotton, Philip G. Quirk, Peter R. Rich, and J. Baz Jackson pp 2621–2629 DOI: 10.1021/ja0556272 Supporting Info

Reactivities of Mononuclear Non-Heme Iron Intermediates Including Evidence that Iron(III)−Hydroperoxo Species Is a Sluggish Oxidant Mi Joo Park, Jimin Lee, Yumi Suh, Jinheung Kim, and Wonwoo Nam pp 2630–2634 DOI: 10.1021/ja055709q Supporting Info

Rigid, Specific, and Discrete Gold Nanoparticle/Antibody Conjugates Christopher J. Ackerson, Pablo D. Jadzinsky, Grant J. Jensen, and Roger D. Kornberg pp 2635–2640 DOI: 10.1021/ja0555668 Supporting Info

Cyclo[n]pyrroles:  Size and Site-Specific Binding to G-Quadruplexes Erin Shammel Baker, Jeong Tae Lee, Jonathan L. Sessler, and Michael T. Bowers pp 2641–2648 DOI: 10.1021/ja0564968 Supporting Info

In Silico Design of a Mutant of Cytochrome P450 Containing Selenocysteine Shimrit Cohen, Devesh Kumar, and Sason Shaik pp 2649–2653 DOI: 10.1021/ja056586c Supporting Info

μ-η2:η2-Peroxodicopper(II) Complex with a Secondary Diamine Ligand:  A Functional Model of Tyrosinase Liviu M. Mirica, Deanne Jackson Rudd, Michael A. Vance, Edward I. Solomon, Keith O. Hodgson, Britt Hedman, and T. Daniel P. Stack pp 2654–2665 DOI: 10.1021/ja056740v Supporting Info

Theoretical Investigations on Chalcogen−Chalcogen Interactions:  What Makes These Nonbonded Interactions Bonding? Christian Bleiholder, Daniel B. Werz, Horst Köppel, and Rolf Gleiter pp 2666–2674 DOI: 10.1021/ja056827g Supporting Info

Design of a Peptide Hairpin Containing a Central Three-Residue Loop Rajkishor Rai, Srinivasarao Raghothama, and Padmanabhan Balaram pp 2675–2681 DOI: 10.1021/ja056861v Supporting Info

Adding a New Dimension to the Investigation of Platinum-Mediated Arene C−H Activation Reactions Using 2D NMR Exchange Spectroscopy. Dynamics of Pt(II) Phenyl/Benzene Site Exchange Bror Johan Wik, Martin Lersch, Alexander Krivokapic, and Mats Tilset pp 2682–2696 DOI: 10.1021/ja056694z Supporting Info

Insertion and Assembly of Membrane Proteins via Simulation Peter J. Bond and Mark S. P. Sansom pp 2697–2704 DOI: 10.1021/ja0569104

Metadynamics Simulation of Prion Protein:  β-Structure Stability and the Early Stages of Misfolding Alessandro Barducci, Riccardo Chelli, Piero Procacci, Vincenzo Schettino, Francesco L. Gervasio, and Michele Parrinello pp 2705–2710 DOI: 10.1021/ja057076l

Observing a Molecular Knife at Work Xiaoyun Chen, Haizhong Tang, Mark A. Even, Jie Wang, Gregory N. Tew, and Zhan Chen pp 2711–2714 DOI: 10.1021/ja057029t Supporting Info

Preparation and Evaluation of Unimolecular Pentavalent and Hexavalent Antigenic Constructs Targeting Prostate and Breast Cancer:  A Synthetic Route to Anticancer Vaccine Candidates Govind Ragupathi, Fusataka Koide, Philip O. Livingston, Young Shin Cho, Atsushi Endo, Qian Wan, Maria K. Spassova, Stacy J. Keding, Jennifer Allen, Ouathek Ouerfelli, Rebecca M. Wilson, and Samuel J. Danishefsky pp 2715–2725 DOI: 10.1021/ja057244+ Supporting Info

Protein Ligand Design:  From Phage Display to Synthetic Protein Epitope Mimetics in Human Antibody Fc-Binding Peptidomimetics Ricardo L. A. Dias, Rudi Fasan, Kerstin Moehle, Annabelle Renard, Daniel Obrecht, and John A. Robinson pp 2726–2732 DOI: 10.1021/ja057513w Supporting Info

Phase Behavior in Thin Films of Confined Colloid−Polymer Mixtures Chun-lai Ren and Yu-qiang Ma pp 2733–2737 DOI: 10.1021/ja057569q

Creating Polymer Structures of Tunable Electric Functionality by Nanoscale Discharge-Assisted Cross-Linking and Oxygenation Xian Ning Xie, Mu Deng, Hai Xu, Shuo Wang Yang, Dong Chen Qi, Xing Yu Gao, Hong Jing Chung, Chorng Haur Sow, Vincent B. C. Tan, and Andrew Thye Shen Wee pp 2738–2744 DOI: 10.1021/ja0577241 Supporting Info

Self-Assembly of Block Copolymer Micelles in an Ionic Liquid Yiyong He, Zhibo Li, Peter Simone, and Timothy P. Lodge pp 2745–2750 DOI: 10.1021/ja058091t Supporting Info

Metallophosphite-Catalyzed Asymmetric Acylation of α,β-Unsaturated Amides Mary R. Nahm, Justin R. Potnick, Peter S. White, and Jeffrey S. Johnson pp 2751–2756 DOI: 10.1021/ja056018x Supporting Info

Progress in Colloid and Polymer Science:  Scattering Methods and the Properties of Polymer Materials, Volume 130 Edited by Norbert Stribeck (University of Hamburg, Germany) and Bernd Smarsly (Max Planck Institute of Colloids and Interfaces, Potsdam-Golm, Germany). Springer:  Berlin, Heidelberg, New York. 2005. x + 176 pp. $129.00. ISBN 3-540-25323-8. p 2757 DOI: 10.1021/ja059834d

Macrocyclic Chemistry:  Current Trends and Future Perspectives Edited by Karsten Gloe (Technische Universität Dresden, Germany). Springer:  Dordrecht. 2005. x + 450 pp. $179.00. ISBN 1-4020-3364-8. p 2757 DOI: 10.1021/ja0598457

Interphases and Mesophases in Polymer Crystallization I. Advances in Polymer Science, 180 Edited by Giuseppe Allegra (Polyitechnico Di Milano, Italy). Springer:  Berlin, Heidelberg, New York. 2005. xiv + 220 pp. $219.00. ISBN 3-540-25345-9. p 2757 DOI: 10.1021/ja059853n

Theoretical Aspects of Transition Metal Catalysis. Topics in Organometallic Chemistry, 12 Edited by Gernot Frenking (Philipps-Universität Marburg). Springer:  Berlin, Heidelberg, New York. 2005. x + 266 pp. $239.00. ISBN 3-540-23510-8. John P. Fackler, Jr. pp 2757–2758 DOI: 10.1021/ja059827p

Organic Solid State Reactions. Topics in Current Chemistry, 254 Edited by Fumio Toda (Okayama University of Science). Springer:  Berlin, Heidelberg, New York. 2005. xii + 314 pp. $289.00. ISBN 3-540-22982-5. Kenneth M. Doxsee p 2758 DOI: 10.1021/ja0597799

Issue 09

Natural Product Diversification Using a Non-natural Cofactor Analogue of S-Adenosyl-l-methionine Changsheng Zhang, Rachel L. Weller, Jon S. Thorson, and Scott R. Rajski pp 2760–2761 DOI: 10.1021/ja056231t Supporting Info

Insight into Indole Interactions from Alkali Metal Chloride Effects on a Tryptophan Zipper β-Hairpin Peptide Christopher E. Dempsey and Philip E. Mason pp 2762–2763 DOI: 10.1021/ja0564012 Supporting Info

An Alkoxide-Directed Carbometalation of Internal Alkynes Jamie Ryan and Glenn C. Micalizio pp 2764–2765 DOI: 10.1021/ja057352w Supporting Info

Microarrays of Synthetic Heparin Oligosaccharides Jose L. de Paz, Christian Noti, and Peter H. Seeberger pp 2766–2767 DOI: 10.1021/ja057584v Supporting Info

Transport at the Air/Water Interface is the Reason for Rings in Protein Microarrays Yang Deng and X.-Y ZhuTaryn Kienlen and Athena Guo pp 2768–2769 DOI: 10.1021/ja057669w

Catalytic, Efficient, and syn-Selective Construction of Deoxypolypropionates and Other Chiral Compounds via Zr-Catalyzed Asymmetric Carboalumination of Allyl Alcohol Bo Liang, Tibor Novak, Ze Tan, and Ei-ichi Negishi pp 2770–2771 DOI: 10.1021/ja0530974 Supporting Info

Rhodium-Catalyzed Asymmetric Synthesis of Indanones:  Development of a New “Axially Chiral” Bisphosphine Ligand Ryo Shintani, Keiji Yashio, Tomoaki Nakamura, Kazuhiro Okamoto, Toyoshi Shimada, and Tamio Hayashi pp 2772–2773 DOI: 10.1021/ja056584s Supporting Info

Asymmetric Synthesis of All-Carbon Benzylic Quaternary Stereocenters via Cu-Catalyzed Conjugate Addition of Dialkylzinc Reagents to 5-(1-Arylalkylidene) Meldrum's Acids Eric Fillion and Ashraf Wilsily pp 2774–2775 DOI: 10.1021/ja056692e Supporting Info

Size-Selective Shell Cross-Linked Interior Functionalized Siloxane Nanocages Young-Woong Suh, Mayfair C. Kung, Yingmin Wang, and Harold H. Kung pp 2776–2777 DOI: 10.1021/ja057092i Supporting Info

A Direct Catalytic Asymmetric Mannich-type Reaction via a Dinuclear Zinc Catalyst:  Synthesis of Either anti- or syn-α-Hydroxy-β-Amino Ketones Barry M. Trost, Jaray Jaratjaroonphong, and Vichai Reutrakul pp 2778–2779 DOI: 10.1021/ja057498v Supporting Info

Highly Enantioselective Hydrovinylation of α-Alkyl Vinylarenes. An Approach to the Construction of All-Carbon Quaternary Stereocenters Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, and Qi-Lin Zhou pp 2780–2781 DOI: 10.1021/ja057654y Supporting Info

Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Alkynes Robert T. Yu and Tomislav Rovis pp 2782–2783 DOI: 10.1021/ja057803c Supporting Info

Synthesis, Molecular Structure, and Reactivity of the Isolable Silylenoid with a Tricoordinate Silicon Gregory Molev, Dmitry Bravo-Zhivotovskii, Miriam Karni, Boris Tumanskii, Mark Botoshansky, and Yitzhak Apeloig pp 2784–2785 DOI: 10.1021/ja0575880 Supporting Info

Asymmetric Catalytic Synthesis of P-Stereogenic Phosphines via a Nucleophilic Ruthenium Phosphido Complex Vincent S. Chan, Ian C. Stewart, Robert G. Bergman, and F. Dean Toste pp 2786–2787 DOI: 10.1021/ja058100y Supporting Info

Platinum-Catalyzed Asymmetric Alkylation of Secondary Phosphines:  Enantioselective Synthesis of P-Stereogenic Phosphines Corina Scriban and David S. Glueck pp 2788–2789 DOI: 10.1021/ja058096q Supporting Info

Microwave Synthesis of Highly Aligned Ultra Narrow Semiconductor Rods and Wires Asit Baran Panda, Garry Glaspell, and M. Samy El-Shall pp 2790–2791 DOI: 10.1021/ja058148b Supporting Info

Total Synthesis of FR901464, an Antitumor Agent that Regulates the Transcription of Oncogenes and Tumor Suppressor Genes Brian J. Albert, Ananthapadmanabhan Sivaramakrishnan, Tadaatsu Naka, and Kazunori Koide pp 2792–2793 DOI: 10.1021/ja058216u Supporting Info

Palladium(II)-Catalyzed Aerobic Hydroalkoxylation of Styrenes Containing a Phenol Keith M. Gligorich, Mitchell J. Schultz, and Matthew S. Sigman pp 2794–2795 DOI: 10.1021/ja0585533 Supporting Info

Total Synthesis of Dolabelide D Peter K. Park, Steven J. O'Malley, Darby R. Schmidt, and James L. Leighton pp 2796–2797 DOI: 10.1021/ja058692k Supporting Info

Alkyne-to-Vinylidene Transformation on trans-(Cl)Rh(phosphine)2:  Acceleration by a Heterocyclic Ligand and Absence of Bimolecular Mechanism Douglas B. Grotjahn, Xi Zeng, and Andrew L. Cooksy pp 2798–2799 DOI: 10.1021/ja058736p Supporting Info

Capture of Phosphorus(I) and Arsenic(I) Moieties by a 1,2-Bis(arylimino)acenaphthene (Aryl-BIAN) Ligand. A Case of Intramolecular Charge Transfer Gregor Reeske, Clint R. Hoberg, Nicholas J. Hill, and Alan H. Cowley pp 2800–2801 DOI: 10.1021/ja058459m Supporting Info

Antibody Interference with N-Acyl Homoserine Lactone-Mediated Bacterial Quorum Sensing Gunnar F. Kaufmann, Rafaella Sartorio, Sang-Hyeup Lee, Jenny M. Mee, Laurence J. Altobell, III, David P. Kujawa, Emily Jeffries, Bruce Clapham, Michael M. Meijler, and Kim D. Janda pp 2802–2803 DOI: 10.1021/ja0578698 Supporting Info

“Oxidatively Induced” Reductive Elimination of Dioxygen from an η2-Peroxopalladium(II) Complex Promoted by Electron-Deficient Alkenes Brian V. Popp and Shannon S. Stahl pp 2804–2805 DOI: 10.1021/ja057753b Supporting Info

Enforced Face-to-Face Stacking of Organic Semiconductor Building Blocks within Hydrogen-Bonded Molecular Cocrystals Anatoliy N. Sokolov, Tomislav Frišić, and Leonard R. MacGillivray pp 2806–2807 DOI: 10.1021/ja057939a Supporting Info

Carbon−Halide Oxidative Addition and Carbon−Carbon Reductive Elimination at a (PNP)Rh Center Sylvain Gatard, Remle Çelenligil-Çetin, Chengyun Guo, Bruce M. Foxman, and Oleg V. Ozerov pp 2808–2809 DOI: 10.1021/ja057948j Supporting Info

Effects of Solvent Viscosity on Ligand Interconversion Dynamics in the Primary Docking Site of Heme Proteins Seongheun Kim, Jeonghee Heo, and Manho Lim pp 2810–2811 DOI: 10.1021/ja058201w Supporting Info

HIV-1 Protease Flaps Spontaneously Close to the Correct Structure in Simulations Following Manual Placement of an Inhibitor into the Open State Viktor Hornak, Asim Okur, Robert C. Rizzo, and Carlos Simmerling pp 2812–2813 DOI: 10.1021/ja058211x Supporting Info

Tuning the Properties at Heterobimetallic Core:  Mixed-Ligand Bismuth−Rhodium Paddlewheel Carboxylates Evgeny V. Dikarev, Bo Li, and Haitao Zhang pp 2814–2815 DOI: 10.1021/ja058294h Supporting Info

Electronic Spectroscopy of Cold, Protonated Tryptophan and Tyrosine Oleg V. Boyarkin, Sébastien R. Mercier, Anthi Kamariotis, and Thomas R. Rizzo pp 2816–2817 DOI: 10.1021/ja058383u

Modulating the Sensory Response of a Conjugated Polymer by Proteins:  An Agglutination Assay for Mercury Ions in Water Ik-Bum Kim and Uwe H. F. Bunz pp 2818–2819 DOI: 10.1021/ja058431a Supporting Info

Efficient Electronic Communication between Two Identical Ferrocene Centers in a Hydrogen-Bonded Dimer Hao Sun, Jennifer Steeb, and Angel E. Kaifer pp 2820–2821 DOI: 10.1021/ja060386z Supporting Info

Identification and Specificity Profiling of Protein Prenyltransferase Inhibitors Using New Fluorescent Phosphoisoprenoids Beatrice Dursina, Reinhard Reents, Christine Delon, Yaowen Wu, Mahesh Kulharia, Michael Thutewohl, Alexei Veligodsky, Alexandr Kalinin, Vladimir Evstifeev, Doina Ciobanu, Stefan E. Szedlacsek, Herbert Waldmann, Roger S. Goody, and Kirill Alexandrov pp 2822–2835 DOI: 10.1021/ja052196e Supporting Info

Barriers of Hydrogen Abstraction vs Halogen Exchange:  An Experimental Manifestation of Charge-Shift Bonding Philippe C. Hiberty, Claire Megret, Lingchun Song, Wei Wu, and Sason Shaik pp 2836–2843 DOI: 10.1021/ja053130m Supporting Info

Effect of Antifreeze Proteins on the Nucleation, Growth, and the Memory Effect during Tetrahydrofuran Clathrate Hydrate Formation Huang Zeng, Lee D. Wilson, Virginia K. Walker, and John A. Ripmeester pp 2844–2850 DOI: 10.1021/ja0548182 Supporting Info

BF3-Activated Oxidation of Alkanes by MnO4- William W. Y. Lam, Shek-Man Yiu, Joyce M. N. Lee, Sammi K. Y. Yau, Hoi-Ki Kwong, Tai-Chu Lau, Dan Liu, and Zhenyang Lin pp 2851–2858 DOI: 10.1021/ja0552951 Supporting Info

Total Synthesis and Structural Elucidation of Azaspiracid-1. Final Assignment and Total Synthesis of the Correct Structure of Azaspiracid-1 K. C. Nicolaou, Theocharis V. Koftis, Stepan Vyskocil, Goran Petrovic, Wenjun Tang, Michael O. Frederick, David Y.-K. Chen, Yiwei Li, Taotao Ling, and Yoichi M. A. Yamada pp 2859–2872 DOI: 10.1021/ja054750q Supporting Info

Circuit Resonance Energy:  A Key Quantity That Links Energetic and Magnetic Criteria of Aromaticity Jun-ichi Aihara pp 2873–2879 DOI: 10.1021/ja056430c

Proton Diffusion across Membranes of Vesicles of Poly(styrene-b-acrylic Acid) Diblock Copolymers Jun Wu and Adi Eisenberg pp 2880–2884 DOI: 10.1021/ja056064x Supporting Info

Total Synthesis and Evaluation of [Ψ[CH2NH]Tpg4]Vancomycin Aglycon:  Reengineering Vancomycin for Dual d-Ala-d-Ala and d-Ala-d-Lac Binding Brendan M. Crowley and Dale L. Boger pp 2885–2892 DOI: 10.1021/ja0572912 Supporting Info

Intramolecular Pd-Catalyzed Carboetherification and Carboamination. Influence of Catalyst Structure on Reaction Mechanism and Product Stereochemistry Josephine S. Nakhla, Jeff W. Kampf, and John P. Wolfe pp 2893–2901 DOI: 10.1021/ja057489m Supporting Info

Charge-Localized Naphthalene-Bridged Bis-hydrazine Radical Cations Stephen F. Nelsen, Asgeir E. Konradsson, and Yoshio Teki pp 2902–2910 DOI: 10.1021/ja054639k Supporting Info

Pyridine−Ag20 Cluster:  A Model System for Studying Surface-Enhanced Raman Scattering Linlin Zhao, Lasse Jensen, and George C. Schatz pp 2911–2919 DOI: 10.1021/ja0556326 Supporting Info

Theoretical Investigation of Enolborane Addition to α-Heteroatom-Substituted Aldehydes. Relevance of the Cornforth and Polar Felkin−Anh Models for Asymmetric Induction Victor J. Cee, Christopher J. Cramer, and David A. Evans pp 2920–2930 DOI: 10.1021/ja0555670 Supporting Info

Switching-on Superparamagnetism in Mn/CdSe Quantum Dots Donny Magana, Susanthri C. Perera, Andrew G. Harter, Naresh S. Dalal, and Geoffrey F. Strouse pp 2931–2939 DOI: 10.1021/ja055785t

Mechanical Properties of Reversibly Cross-Linked Ultrathin Polyelectrolyte Complexes Jad A. Jaber and Joseph B. Schlenoff pp 2940–2947 DOI: 10.1021/ja055892n Supporting Info

Triradical Cation of p-Phenylenediamine Having Two Nitroxide Radical Groups:  Spin Alignment Mediated by Delocalized Spin Akihiro Ito, Yoshiaki Nakano, Masashi Urabe, Tatsuhisa Kato, and Kazuyoshi Tanaka pp 2948–2953 DOI: 10.1021/ja056318e

Large Dynamic Stokes Shift of DNA Intercalation Dye Thiazole Orange has Contribution from a High-Frequency Mode Venugopal Karunakaran, J. Luis Pérez Lustres, Lijuan Zhao, Nikolaus P. Ernsting, and Oliver Seitz pp 2954–2962 DOI: 10.1021/ja056862n

How Phonons Govern the Behavior of Short, Strong Hydrogen Bonds in Urea−Phosphoric Acid Fabien Fontaine-Vive, Mark R. Johnson, Gordon J. Kearley, Judith A. K. Howard, and Stewart F. Parker pp 2963–2969 DOI: 10.1021/ja0569712 Supporting Info

The Deacylation Mechanism of AmpC β-Lactamase at Ultrahigh Resolution Yu Chen, George Minasov, Tomer A. Roth, Fabio Prati, and Brian K. Shoichet pp 2970–2976 DOI: 10.1021/ja056806m

Formation and Dissociation of Intra−Intermolecular Hydrogen-Bonded Solute−Solvent Complexes:  Chemical Exchange Two-Dimensional Infrared Vibrational Echo Spectroscopy Junrong Zheng, Kyungwon Kwak, Xin Chen, John B. Asbury, and M. D. Fayer pp 2977–2987 DOI: 10.1021/ja0570584 Supporting Info

NO Dimer and Dinitrosyl Formation on Pd(111):  From Ultra-High-Vacuum to Elevated Pressure Conditions Christian Hess, Emrah Ozensoy, Cheol-Woo Yi, and D. Wayne Goodman pp 2988–2994 DOI: 10.1021/ja057131q

Asymmetric Hydrogenation of Trisubstituted Olefins with Iridium−Phosphine Thiazole Complexes:  A Further Investigation of the Ligand Structure Christian Hedberg, Klas Källström, Peter Brandt, Lars Kristian Hansen, and Pher G. Andersson pp 2995–3001 DOI: 10.1021/ja057178b Supporting Info

Pendant Bases as Proton Relays in Iron Hydride and Dihydrogen Complexes Renee M. Henry, Richard K. Shoemaker, Daniel L. DuBois, and M. Rakowski DuBois pp 3002–3010 DOI: 10.1021/ja057242p Supporting Info

Ultrahigh Resolution Crystal Structures of Human Carbonic Anhydrases I and II Complexed with “Two-Prong” Inhibitors Reveal the Molecular Basis of High Affinity Kevin M. Jude, Abir L. Banerjee, Manas K. Haldar, Sumathra Manokaran, Bidhan Roy, Sanku Mallik, D. K. Srivastava, and David W. Christianson pp 3011–3018 DOI: 10.1021/ja057257n

Potentials of Mean Force for Acetylcholine Unbinding from the Alpha7 Nicotinic Acetylcholine Receptor Ligand-Binding Domain Deqiang Zhang, Justin Gullingsrud, and J. Andrew McCammon pp 3019–3026 DOI: 10.1021/ja057292u Supporting Info

Hydrothermal Growth of Mesoporous SBA-15 Silica in the Presence of PVP-Stabilized Pt Nanoparticles:  Synthesis, Characterization, and Catalytic Properties Hyunjoon Song, Robert M. Rioux, James D. Hoefelmeyer, Russell Komor, Krisztian Niesz, Michael Grass, Peidong Yang, and Gabor A. Somorjai pp 3027–3037 DOI: 10.1021/ja057383r Supporting Info

Using a Kinase/Phosphatase Switch to Regulate a Supramolecular Hydrogel and Forming the Supramolecular Hydrogel in Vivo Zhimou Yang, Gaolin Liang, Ling Wang, and Bing Xu pp 3038–3043 DOI: 10.1021/ja057412y Supporting Info

2,7-Diphenyl[1]benzoselenopheno[3,2-b][1]benzoselenophene as a Stable Organic Semiconductor for a High-Performance Field-Effect Transistor Kazuo Takimiya, Yoshihito Kunugi, Yasushi Konda, Hideaki Ebata, Yuta Toyoshima, and Tetsuo Otsubo pp 3044–3050 DOI: 10.1021/ja057641k Supporting Info

Silicon-Containing Polyphilic Bent-Core Molecules:  The Importance of Nanosegregation for the Development of Chirality and Polar Order in Liquid Crystalline Phases Formed by Achiral Molecules Christina Keith, R. Amaranatha Reddy, Anton Hauser, Ute Baumeister, and Carsten Tschierske pp 3051–3066 DOI: 10.1021/ja057685t Supporting Info

Extender Unit and Acyl Carrier Protein Specificity of Ketosynthase Domains of the 6-Deoxyerythronolide B Synthase Alice Y. Chen, Nathan A. Schnarr, Chu-Young Kim, David E. Cane, and Chaitan Khosla pp 3067–3074 DOI: 10.1021/ja058093d Supporting Info

Binding of Molecular O2 to Di- and Triligated [UO2]+ Gary S. Groenewold, Kevin C. Cossel, Garold L. Gresham, Anita K. Gianotto, Anthony D. Appelhans, John E. Olson, Michael J. Van Stipdonk, and Winnie Chien pp 3075–3084 DOI: 10.1021/ja0573209 Supporting Info

Heparan Sulfate Degradation via Reductive Homolysis of Its N-Chloro Derivatives Martin D. Rees and Michael J. Davies pp 3085–3097 DOI: 10.1021/ja0577239 Supporting Info

Electrowetting of Ionic Liquids Stefano Millefiorini, Alan H. Tkaczyk, Rossen Sedev, Jim Efthimiadis, and John Ralston pp 3098–3101 DOI: 10.1021/ja057606d

Iron-Assisted Vapor-Phase Hydrothermal Method:  A Low-Temperature Approach to Synthesize Blue Light Emissive SiOx Nanowires with Single-Crystal Structure of P21212 [J. Am. Chem. Soc. 2006, 128, 1470−1471]. Ping Chen, Songhai Xie, Nan Ren, Yahong Zhang, Angang Dong, Ying Chen, and Yi Tang p 3102 DOI: 10.1021/ja069952g Supporting Info

Site-Specific Phenylation of Pyridine Catalyzed by Phosphido-Bridged Ruthenium Dimer Complexes:  A Prototype for C−H Arylation of Electron-Deficient Heteroarenes [J. Am. Chem. Soc. 2005, 127, 3648−3649]. Kamil Godula, Bengü Sezen, and Dalibor Sames p 3102 DOI: 10.1021/ja069956l

Oxidative C-Arylation of Free (NH)-Heterocycles via Direct (sp3) C−H Bond Functionalization [J. Am. Chem. Soc. 2004, 126, 13244−13246]. Bengü Sezen and Dalibor Sames p 3102 DOI: 10.1021/ja069957d

Selective and Catalytic Arylation of N-Phenylpyrrolidine:  sp3 C−H Bond Functionalization in the Absence of a Directing Group [J. Am. Chem. Soc. 2005, 127, 5284−5285]. Bengü Sezen and Dalibor Sames p 3102 DOI: 10.1021/ja0699586

Amsterdam Density Functional 2005 Scientific Computing and Modelling NV, Vrije Universiteit, Theoretical Chemistry, De Boelelaan 1083, 1081 HV Amsterdam, the Netherlands. http://www.scm.com. See Web site for pricing information. Yannick J. Bomble p 3103 DOI: 10.1021/ja0598311

Macromolecules Containing Metal and Metal-Like Elements, Volume 5:  Metal-Coordination Polymers Edited by Alaa S. Abd-El-Aziz (The University of Winnipeg), Charles E. Carraher, Jr. (Florida Atlantic University), Charles U. Pittman, Jr. (Mississippi State University), and Martel Zeldin (Hobart and William Smith Colleges). Wiley & Sons:  Hoboken, NJ. 2005. xvi + 408 pp. $150.00. ISBN 0-471-68237-3. Gregory N. Tew p 3104 DOI: 10.1021/ja059806v

Crystallization of Polymers, 2nd ed., Volume 2:  Kinetics and Mechanisms By Leo Mandelkern (Florida State University). Cambridge University Press:  Cambridge, U.K. 2004. x + 468 pp. $160.00. ISBN 0-521-81682-3. Buckley Crist pp 3104–3105 DOI: 10.1021/ja041049y

Macromolecular Nanostructured Materials. Springer Series in Materials Science, 78 Edited by Norikazu Ueyama and Akira Harada (Osaka University). Springer:  Berlin, Heidelberg, New York, and Kodansha, Tokyo. 2004. xvi + 336 pp. $149.00. ISBN 3-540-22327-4. T. Andrew Taton pp 3105–3106 DOI: 10.1021/ja059733f

Issue 10

Regiospecificity of the Peptidyl tRNA Ester within the Ribosomal P Site Kevin S. Huang, Joshua S. Weinger, Ethan B. Butler, and Scott A. Strobel pp 3108–3109 DOI: 10.1021/ja0554099 Supporting Info

New Type of Near-Infrared to Visible Photon Upconversion in Tm2+-Doped CsCaI3 Eva Beurer, Judith Grimm, Pascal Gerner, and Hans U. Güdel pp 3110–3111 DOI: 10.1021/ja0567790

Room Temperature Au(I)-Catalyzed exo-Selective Cycloisomerization of Acetylenic Acids:  An Entry to Functionalized γ-Lactones Emilie Genin, Patrick Yves Toullec, Sylvain Antoniotti, Célia Brancour, Jean-Pierre Genêt, and Véronique Michelet pp 3112–3113 DOI: 10.1021/ja056857j Supporting Info

Cerasome as an Infusible, Cell-Friendly, and Serum-Compatible Transfection Agent in a Viral Size Kazuki Matsui, Shinsuke Sando, Takashi Sera, Yasuhiro Aoyama, Yoshihiro Sasaki, Takayoshi Komatsu, Takashi Terashima, and Jun-ichi Kikuchi pp 3114–3115 DOI: 10.1021/ja058016i Supporting Info

Asymmetric Conjugate Addition of Alkynylboronates to Enones:  Rationale for the Intriguing Catalysis Exerted by Binaphthols Silvina C. Pellegrinet and Jonathan M. Goodman pp 3116–3117 DOI: 10.1021/ja056727a Supporting Info

Enantioselective Synthesis of Pentacycloanammoxic Acid Vincent Mascitti and E. J. Corey pp 3118–3119 DOI: 10.1021/ja058370g Supporting Info

A New Route to Antimony Telluride Nanoplates from a Single-Source Precursor Shivram S. Garje, Dana J. Eisler, Jamie S. Ritch, Mohammad Afzaal, Paul O'Brien, and Tristram Chivers pp 3120–3121 DOI: 10.1021/ja0582408 Supporting Info

New Bioluminogenic Substrates for Monoamine Oxidase Assays Wenhui Zhou, Michael P. Valley, John Shultz, Erika M. Hawkins, Laurent Bernad, Troy Good, Dave Good, Terry L. Riss, Dieter H. Klaubert, and Keith V. Wood pp 3122–3123 DOI: 10.1021/ja058519o Supporting Info

Direct Observation of β-Aryl Eliminations from Rh(I) Alkoxides Pinjing Zhao, Christopher D. Incarvito, and John F. Hartwig pp 3124–3125 DOI: 10.1021/ja058550q Supporting Info

Surfactant-Induced Modulation of Fluorosensor Activity:  A Simple Way to Maximize the Sensor Efficiency Arabinda Mallick, Malay C. Mandal, Basudeb Haldar, Alok Chakrabarty, Paramita Das, and Nitin Chattopadhyay pp 3126–3127 DOI: 10.1021/ja058359g

Enantioselective Total Synthesis of FD-891 Michael T. Crimmins and Franck Caussanel pp 3128–3129 DOI: 10.1021/ja060018v Supporting Info

Pd(II)-Catalyzed Enantioselective Oxidative Tandem Cyclization Reactions. Synthesis of Indolines through C−N and C−C Bond Formation Kai-Tai Yip, Min Yang, Ka-Lun Law, Nian-Yong Zhu, and Dan Yang pp 3130–3131 DOI: 10.1021/ja060291x Supporting Info

Inaccessibility of β-Hydride Elimination from −OH Functional Groups in Wacker-Type Oxidation John A. Keith, Jonas Oxgaard, and William A. Goddard, III pp 3132–3133 DOI: 10.1021/ja0533139 Supporting Info

Rectifying Diodes from Asymmetrically Functionalized Single-Wall Carbon Nanotubes Zhong Wei, Mykola Kondratenko, Lê H. Dao, and Dmitrii F. Perepichka pp 3134–3135 DOI: 10.1021/ja053950z Supporting Info

Facile Autoreduction of Iron Oxide/Carbon Nanotube Encapsulates Wei Chen, Xiulian Pan, Marc-Georg Willinger, Dang Sheng Su, and Xinhe Bao pp 3136–3137 DOI: 10.1021/ja056721l Supporting Info

An Electronic, Aptamer-Based Small-Molecule Sensor for the Rapid, Label-Free Detection of Cocaine in Adulterated Samples and Biological Fluids Brian R. Baker, Rebecca Y. Lai, McCall S. Wood, Elaine H. Doctor, Alan J. Heeger, and Kevin W. Plaxco pp 3138–3139 DOI: 10.1021/ja056957p Supporting Info

Very Strong Ferromagnetic Interaction in a New Binuclear μ-Methoxo-Bridged Mn(III) Complex: Synthesis, Crystal Structure, Magnetic Properties, and DFT Calculations Chahrazed Beghidja, Guillaume Rogez, Jens Kortus, Marcel Wesolek, and Richard Welter pp 3140–3141 DOI: 10.1021/ja0575023 Supporting Info

A Microfluidic Device for Kinetic Optimization of Protein Crystallization and In Situ Structure Determination Carl L. Hansen, Scott Classen, James M. Berger, and Stephen R. Quake pp 3142–3143 DOI: 10.1021/ja0576637 Supporting Info

Design of a Hyperstable Protein by Rational Consideration of Unfolded State Interactions Burcu Anil, Rebecca Craig-Schapiro, and Daniel P. Raleigh pp 3144–3145 DOI: 10.1021/ja057874b Supporting Info

A Solvent-Stable Nanocrystal-Silica Composite Laser Yinthai Chan, Preston T. Snee, Jean-Michel Caruge, Brian K. Yen, Gautham P. Nair, Daniel G. Nocera, and Moungi G. Bawendi pp 3146–3147 DOI: 10.1021/ja057980d Supporting Info

Cortistatins A, B, C, and D, Anti-angiogenic Steroidal Alkaloids, from the Marine Sponge Corticium simplex Shunji Aoki, Yasuo Watanabe, Mami Sanagawa, Andi Setiawan, Naoyuki Kotoku, and Motomasa Kobayashi pp 3148–3149 DOI: 10.1021/ja057404h Supporting Info

Cationic Shape-Persistent Macrocycles:  The Unexpected Formation of a Nano-Size Supramolecular Dimer Svetlana Klyatskaya, Nico Dingenouts, Christine Rosenauer, Beate Müller, and Sigurd Höger pp 3150–3151 DOI: 10.1021/ja057999g Supporting Info

19-Electron Intermediates in the Ligand Substitution of CpW(CO)3• with a Lewis Base James F. Cahoon, Matthias F. Kling, Karma R. Sawyer, Heinz Frei, and Charles B. Harris pp 3152–3153 DOI: 10.1021/ja058258i Supporting Info

Backbone Conformational Constraints in a Microcrystalline U-15N-Labeled Protein by 3D Dipolar-Shift Solid-State NMR Spectroscopy W. Trent Franks, Benjamin J. Wylie, Sara A. Stellfox, and Chad M. Rienstra pp 3154–3155 DOI: 10.1021/ja058292x Supporting Info

A New Role for Old Ligands:  Discerning Chelators for Zinc Metalloproteinases Faith E. Jacobsen, Jana A. Lewis, and Seth M. Cohen pp 3156–3157 DOI: 10.1021/ja057957s Supporting Info

Spreading and Segregation of Lipids in Air-Stable Lipid Microarrays Ye Fang pp 3158–3159 DOI: 10.1021/ja058166t Supporting Info

The Structure of the Strongest Brønsted Acid:  The Carborane Acid H(CHB11Cl11) Evgenii S. Stoyanov, Stephan P. Hoffmann, Mark Juhasz, and Christopher A. Reed pp 3160–3161 DOI: 10.1021/ja058581l Supporting Info

Recognition-Directed Orthogonal Self-Assembly of Polymers and Nanoparticles on Patterned Surfaces Hao Xu, Rui Hong, Tongxiang Lu, Oktay Uzun, and Vincent M. Rotello pp 3162–3163 DOI: 10.1021/ja058686o Supporting Info

Azobenzene on Cu(110):  Adsorption Site-Dependent Diffusion Jill A. Miwa, Sigrid Weigelt, Henkjan Gersen, Flemming Besenbacher, Federico Rosei, and Trolle R. Linderoth pp 3164–3165 DOI: 10.1021/ja058413t

Structural Evidence for an Enolate Intermediate in GFP Fluorophore Biosynthesis David P. Barondeau, John A. Tainer, and Elizabeth D. Getzoff pp 3166–3168 DOI: 10.1021/ja0552693

Gas-Phase Dynamics of Spiropyran and Spirooxazine Molecules Lionel Poisson, Kevin D. Raffael, Benoît Soep, Jean-Michel Mestdagh, and Guy Buntinx pp 3169–3178 DOI: 10.1021/ja055079s Supporting Info

Neutral Complexes of First Row Transition Metals Bearing Unbound Thiocyanates and Their Assembly on Metallic Surfaces Jacob W. Ciszek, Zachary K. Keane, Long Cheng, Michael P. Stewart, Lam H. Yu, Douglas Natelson, and James M. Tour pp 3179–3189 DOI: 10.1021/ja055459d Supporting Info

Rapid Purification and Size Separation of Gold Nanoparticles via Diafiltration Scott F. Sweeney, Gerd H. Woehrle, and James E. Hutchison pp 3190–3197 DOI: 10.1021/ja0558241 Supporting Info

Diastereoselective DNA Cleavage Recognition by Ni(II)•Gly-Gly-His-Derived Metallopeptides Ya-Yin Fang, Craig A. Claussen, Kenny B. Lipkowitz, and Eric C. Long pp 3198–3207 DOI: 10.1021/ja0569757 Supporting Info

Zeolite Framework Stabilized Copper Complex Inspired by the 2-His-1-carboxylate Facial Triad Motif Yielding Oxidation Catalysts Kaisa Kervinen, Pieter C. A. Bruijnincx, Andrew M. Beale, J. Gerbrand Mesu, Gerard van Koten, Robertus J. M. Klein Gebbink, and Bert M. Weckhuysen pp 3208–3217 DOI: 10.1021/ja0567992 Supporting Info

Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate Alexandre Vimont, Jean-Michel Goupil, Jean-Claude Lavalley, Marco Daturi, Suzy Surblé, Christian Serre, Franck Millange, Gerard Férey, and Nathalie Audebrand pp 3218–3227 DOI: 10.1021/ja056906s Supporting Info

Designing Molecules by Optimizing Potentials Mingliang Wang, Xiangqian Hu, David N. Beratan, and Weitao Yang pp 3228–3232 DOI: 10.1021/ja0572046 Supporting Info

Proton Permeation into Single Vesicles Occurs via a Sequential Two-Step Mechanism and Is Heterogeneous Christopher L. Kuyper, Jason S. Kuo, Sarah A. Mutch, and Daniel T. Chiu pp 3233–3240 DOI: 10.1021/ja057349c

PbTe Colloidal Nanocrystals:  Synthesis, Characterization, and Multiple Exciton Generation James E. Murphy, Matthew C. Beard, Andrew G. Norman, S. Phillip Ahrenkiel, Justin C. Johnson, Pingrong Yu, Olga I. Mićić, Randy J. Ellingson, and Arthur J. Nozik pp 3241–3247 DOI: 10.1021/ja0574973

Self-Assembly of PbTe Quantum Dots into Nanocrystal Superlattices and Glassy Films Jeffrey J. Urban, Dmitri V. Talapin, Elena V. Shevchenko, and Christopher B. Murray pp 3248–3255 DOI: 10.1021/ja058269b

Adsorption and Reaction of CO2 and SO2 at a Water Surface Teresa L. Tarbuck and Geraldine L. Richmond pp 3256–3267 DOI: 10.1021/ja057375a

Replication of DNA Microarrays from Zip Code Masters Haohao Lin, Joohoon Kim, Li Sun, and Richard M. Crooks pp 3268–3272 DOI: 10.1021/ja0578799

One-Pot and Sequential Organic Chemistry on an Enzyme Surface to Tether a Fluorescent Probe at the Proximity of the Active Site with Restoring Enzyme Activity Yousuke Takaoka, Hiroshi Tsutsumi, Noriyuki Kasagi, Eiji Nakata, and Itaru Hamachi pp 3273–3280 DOI: 10.1021/ja057926x Supporting Info

Uniquely Strong Electronic Communication between [Mo2] Units Linked by Dioxolene Dianions F. Albert Cotton, Carlos A. Murillo, Dino Villagrán, and Rongmin Yu pp 3281–3290 DOI: 10.1021/ja0582962 Supporting Info

Reactive Carbon-Chain Molecules:  Synthesis of 1-Diazo-2,4-pentadiyne and Spectroscopic Characterization of Triplet Pentadiynylidene (H−CC−−CC−H) Nathan P. Bowling, Robert J. Halter, Jonathan A. Hodges, Randal A. Seburg, Phillip S. Thomas, Christopher S. Simmons, John F. Stanton, and Robert J. McMahon pp 3291–3302 DOI: 10.1021/ja058252t Supporting Info

Competitive ArC−H and ArC−X (X = Cl, Br) Activation in Halobenzenes at Cationic Titanium Centers Kuangbiao Ma, Warren E. Piers, and Masood Parvez pp 3303–3312 DOI: 10.1021/ja0583618 Supporting Info

Synthesis, Structure, and Magnetic Properties of Li-Doped Manganese-Phthalocyanine, Lix[MnPc] (0 x 4) Yasujiro Taguchi, Toshiaki Miyake, Serena Margadonna, Kenichi Kato, Kosmas Prassides, and Yoshihiro Iwasa pp 3313–3323 DOI: 10.1021/ja0582657 Supporting Info

Synthesis and Retrostructural Analysis of Libraries of AB3 and Constitutional Isomeric AB2 Phenylpropyl Ether-Based Supramolecular Dendrimers Virgil Percec, Mihai Peterca, Monika J. Sienkowska, Marc A. Ilies, Emad Aqad, Jan Smidrkal, and Paul A. Heiney pp 3324–3334 DOI: 10.1021/ja060062a Supporting Info

The Electronic Origin of the Dual Fluorescence in Donor−Acceptor Substituted Benzene Derivatives Semyon Cogan, Shmuel Zilberg, and Yehuda Haas pp 3335–3345 DOI: 10.1021/ja0548945 Supporting Info

Cytochrome P450-Catalyzed Oxidation of N-Benzyl-N-cyclopropylamine Generates Both Cyclopropanone Hydrate and 3-Hydroxypropionaldehyde via Hydrogen Abstraction, Not Single Electron Transfer Matthew A. Cerny and Robert P. Hanzlik pp 3346–3354 DOI: 10.1021/ja054938+ Supporting Info

A Combined Kinetic−Quantum Mechanical Model for Assessment of Catalytic Cycles:  Application to Cross-Coupling and Heck Reactions Sebastian Kozuch and Sason Shaik pp 3355–3365 DOI: 10.1021/ja0559146 Supporting Info

Resolving Intermediate Solution Structures during the Formation of Mesoporous SBA-15 Sharon Ruthstein, Judith Schmidt, Ellina Kesselman, Yeshayahu Talmon, and Daniella Goldfarb pp 3366–3374 DOI: 10.1021/ja0559911

NMR Studies of Solvent-Assisted Proton Transfer in a Biologically Relevant Schiff Base:  Toward a Distinction of Geometric and Equilibrium H-Bond Isotope Effects Shasad Sharif, Gleb S. Denisov, Michael D. Toney, and Hans-Heinrich Limbach pp 3375–3387 DOI: 10.1021/ja056251v Supporting Info

Alkylation of Inorganic Oxo Compounds and Insights on Preventing DNA Damage Elizabeth E. Hamilton, Phillip E. Fanwick, and Jonathan J. Wilker pp 3388–3395 DOI: 10.1021/ja056568v Supporting Info

One-Step Template-Directed Synthesis of a Macrocyclic Tetraarylporphyrin Hexamer Based on Supramolecular Interactions with a C3-Symmetric Tetraarylporphyrin Trimer Simona Rucareanu, Anne Schuwey, and Albert Gossauer pp 3396–3413 DOI: 10.1021/ja057117d Supporting Info

Synthesis of the Trypanosoma cruzi LPPG Heptasaccharyl myo-Inositol Markus Hederos and Peter Konradsson pp 3414–3419 DOI: 10.1021/ja057339b Supporting Info

Living Ziegler−Natta Polymerization by Early Transition Metals:  Synthesis and Evaluation of Cationic Zirconium Alkyl Complexes Bearing β-Hydrogens as Models for Propagating Centers Matthew B. Harney, Richard J. Keaton, James C. Fettinger, and Lawrence R. Sita pp 3420–3432 DOI: 10.1021/ja057866v Supporting Info

Insights into the Hydrogen-Abstraction Reactions of Diol Dehydratase:  Relevance to the Catalytic Mechanism and Suicide Inactivation Gregory M. Sandala, David M. Smith, Michelle L. Coote, Bernard T. Golding, and Leo Radom pp 3433–3444 DOI: 10.1021/ja057902q Supporting Info

Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate−Cu(I) Complexes:  Probing the Role of the Methionine Ligand in Copper Monooxygenases Nermeen W. Aboelella, Benjamin F. Gherman, Lyndal M. R. Hill, John T. York, Nicole Holm, Victor G. Young, Jr., Christopher J. Cramer, and William B. Tolman pp 3445–3458 DOI: 10.1021/ja057745v Supporting Info

Triphenylamine−Thienylenevinylene Hybrid Systems with Internal Charge Transfer as Donor Materials for Heterojunction Solar Cells Sophie Roquet, Antonio Cravino, Philippe Leriche, Olivier Alévêque, Pierre Frère, and Jean Roncali pp 3459–3466 DOI: 10.1021/ja058178e Supporting Info

An Annulation toward Fused Bicyclolactones [J. Am. Chem. Soc. 2005, 127, 17184−17185]. Rene-Viet Nguyen and Chao-Jun Li p 3467 DOI: 10.1021/ja060508n

Impact of Protein Flexibility on Hydride-Transfer Parameters in Thermophilic and Psychrophilic Alcohol Dehydrogenases [J. Am. Chem. Soc. 2004, 126, 9500−9501]. Zhao-Xun Liang, Iason Tsigos, Vassilis Bouriotis, and Judith P. Klinman p 3467 DOI: 10.1021/ja069955t

Chalcogenocarboxylic Acid Derivatives. Topics in Current Chemistry, Volume 251 Edited by Shinzi Kato (Chubu University, Japan). Springer:  Berlin, Heidelberg, New York. 2005. x + 280 pp. $259.00. ISBN 3-540-23012-2. Thomas G. Back p 3468 DOI: 10.1021/ja059812r

Analytical Atomic Spectrometry with Flames and Plasmas:  Second, Completely Revised and Extended Edition By José Broekaert (Universität Hamburg). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xii + 474 pp. $130. ISBN 3-527-31282-X. Ian Brindle p 3468 DOI: 10.1021/ja059839a

Advances in Quantum Chemistry, Volume 48 Edited by John R. Sabin (University of Florida, Gainesville), Erkki Brändas (Uppsala University, Sweden), and Lene B. Oddershede (The Niels Bohr Institute, Copenhagen, Denmark). Elsevier Academic Press:  San Diego, CA. 2005. xxviii + 500 pp. $180.00. ISBN 0-12-034848-9. Paul W. Ayers pp 3468–3469 DOI: 10.1021/ja059816w

Strategies and Tactics in Organic Synthesis, Volume 6 Edited by Michael Harmata (University of Missouri, Columbia). Elsevier B. V.:  Amsterdam. 2005. xxiv + 476 pp. $199.95. ISBN 0-12-450288-1. p 3469 DOI: 10.1021/ja059858k

Nanostructured and Advanced Materials Edited by A. Vaseashta (Marshall University, Huntington, WV), D. Dimova-Malinovska (Bulgarian Academy of Sciences, Sofia, Bulgaria), and J. M. Marshall (University of Wales, Swansea, UK). Springer:  Dordrecht. 2005. xii + 426 pp. $199.00. ISBN 1-4020-3560-8. p 3469 DOI: 10.1021/ja059859c

DNA Binders and Related Subjects. Topics in Current Chemistry, 253 Edited by Michael J. Waring (University of Cambridge, UK) and Jonathan B. Chaires (University of Louisville, KY). Springer:  Berlin, Heidelberg, New York. 2005. x + 210 pp. $179.00. ISBN 3-540-22835-7. Paul J. Hergenrother pp 3469–3470 DOI: 10.1021/ja059748d

Organosilicon Chemistry VI:  from Molecules to Materials, Volumes 1−2 Edited by Norbert Auner (University of Frankfurt) and Johann Weis (Consortium of Electrochemical Industry GmbH, Munich). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xviii + xviii + 1020 pp. $210. ISBN 3-527-31214-5 (Set). p 3470 DOI: 10.1021/ja059848j

Issue 11

Tumor Targeting by Surface-Modified Protein Microspheres Farah Jean-Jacques Toublan, Stephen Boppart, and Kenneth S. Suslick pp 3472–3473 DOI: 10.1021/ja0544455

Interfacial Thermocapillary Vortical Flow for Microfluidic Mixing Ramanathan Muruganathan, Yi Zhang, and Thomas M. Fischer pp 3474–3475 DOI: 10.1021/ja0566883 Supporting Info

Place Exchange Reactions of Alkyl Thiols on Gold Nanoparticles Adil Kassam, Glen Bremner, Brad Clark, Gerardo Ulibarri, and R. Bruce Lennox pp 3476–3477 DOI: 10.1021/ja057091q Supporting Info

Deuteration Effects on the Structure and Infrared Spectrum of CH5+ Xinchuan Huang, Lindsay M. Johnson, Joel M. Bowman, and Anne B. McCoy pp 3478–3479 DOI: 10.1021/ja057514o Supporting Info

Nanostructure Dependence of Field-Effect Mobility in Regioregular Poly(3-hexylthiophene) Thin Film Field Effect Transistors Rui Zhang, Bo Li, Mihaela C. Iovu, Malika Jeffries-EL, Geneviève Sauvé, Jessica Cooper, Shijun Jia, Stephanie Tristram-Nagle, Detlef M. Smilgies, David N. Lambeth, Richard D. McCullough, and Tomasz Kowalewski pp 3480–3481 DOI: 10.1021/ja055192i Supporting Info

Three-Dimensional Chiral Imaging by Sum-Frequency Generation Na Ji, Kai Zhang, Haw Yang, and Yuen-Ron Shen pp 3482–3483 DOI: 10.1021/ja057775y Supporting Info

Tubular Organization with Coiled Ribbon from Amphiphilic Rigid−Flexible Macrocycle Won-Young Yang, Eunji Lee, and Myongsoo Lee pp 3484–3485 DOI: 10.1021/ja057823e Supporting Info

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η5-C5H5)M(CO)3H (M = Mo, W) and Bases Natalia V. Belkova, Evgenii I. Gutsul, Oleg A. Filippov, Vladislava A. Levina, Dmitriy A. Valyaev, Lina M. Epstein, Agusti Lledos, and Elena S. Shubina pp 3486–3487 DOI: 10.1021/ja057867n Supporting Info

Electrochemically Triggered Open and Closed Pacman Bis-metalloporphyrins Grégory Pognon, Corinne Boudon, Kurt J. Schenk, Michel Bonin, Benoit Bach, and Jean Weiss pp 3488–3489 DOI: 10.1021/ja058132l Supporting Info

Cell-Permeable and Biocompatible Polymeric Nanoparticles for Apoptosis Imaging Kwangmeyung Kim, Misu Lee, Hyungkyu Park, Jong-Ho Kim, Sungwon Kim, Hesson Chung, Kuiwon Choi, In-San Kim, Baik L. Seong, and Ick Chan Kwon pp 3490–3491 DOI: 10.1021/ja057712f Supporting Info

Surface-Enhanced Hyper-Raman Spectra and Enhancement Factors for Three SERS Chromophores. SEHRS Spectra on Ag Films at Pulse Energies below 2 pJ Weinan Leng and Anne Myers Kelley pp 3492–3493 DOI: 10.1021/ja057946z Supporting Info

Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks Antek G. Wong-Foy, Adam J. Matzger, and Omar M. Yaghi pp 3494–3495 DOI: 10.1021/ja058213h Supporting Info

An α-Helical Peptidomimetic Inhibitor of the HIV-1 Rev−RRE Interaction Nicholas L. Mills, Matthew D. Daugherty, Alan D. Frankel, and R. Kiplin Guy pp 3496–3497 DOI: 10.1021/ja0582051 Supporting Info

Exploiting Phosphonate Chemistry in Metal-Mediated Dearomatization:  Stereoselective Construction of Functionalized Spirolactams from Arene Ruthenium Complexes F. Christopher Pigge, John J. Coniglio, and Rashmi Dalvi pp 3498–3499 DOI: 10.1021/ja058342y Supporting Info

Dynamics of Solvated Electron Transfer in Thin Ice Film Leading to a Large Enhancement in Photodissociation of CFCl3 Sunmin Ryu, Jinyoung Chang, Hyuksang Kwon, and Seong Keun Kim pp 3500–3501 DOI: 10.1021/ja058323o Supporting Info

Molecular Geometry Directed Kagomé and Honeycomb Networks:  Toward Two-Dimensional Crystal Engineering Shuhei Furukawa, Hiroshi Uji-i, Kazukuni Tahara, Tomoyuki Ichikawa, Motohiro Sonoda, Frans C. De Schryver, Yoshito Tobe, and Steven De Feyter pp 3502–3503 DOI: 10.1021/ja0583362 Supporting Info

High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol Shijun Liao, Kerry-Anne Holmes, Haralampos Tsaprailis, and Viola I. Birss pp 3504–3505 DOI: 10.1021/ja0578653 Supporting Info

Observation of Enhanced Energy Transfer in Individual Quantum Dot−Oligophenylene Vinylene Nanostructures Michael Y. Odoi, Nathan I. Hammer, Kevin Sill, Todd Emrick, and Michael D. Barnes pp 3506–3507 DOI: 10.1021/ja058429j Supporting Info

Highly Active Water-Soluble Olefin Metathesis Catalyst Soon Hyeok Hong and Robert H. Grubbs pp 3508–3509 DOI: 10.1021/ja058451c Supporting Info

Pd Complex-Promoted Cyclopolymerization of Functionalized α,ω-Dienes and Copolymerization with Ethylene to Afford Polymers with Cyclic Repeating Units Sehoon Park, Daisuke Takeuchi, and Kohtaro Osakada pp 3510–3511 DOI: 10.1021/ja058408p Supporting Info

Formation and Cleavage of C−H, C−C, and C−O Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals Patricia Lara, Margarita Paneque, Manuel L. Poveda, Verónica Salazar, Laura L. Santos, and Ernesto Carmona pp 3512–3513 DOI: 10.1021/ja0586790 Supporting Info

Ruthenium-Catalyzed Isomerization of Oxa/Azabicyclic Alkenes:  an Expedient Route for the Synthesis of 1,2-Naphthalene Oxides and Imines Karine Villeneuve and William Tam pp 3514–3515 DOI: 10.1021/ja058621l Supporting Info

Colloidal HgTe Nanocrystals with Widely Tunable Narrow Band Gap Energies:  From Telecommunications to Molecular Vibrations Maksym V. Kovalenko, Erich Kaufmann, Dietmar Pachinger, Jürgen Roither, Martin Huber, Julian Stangl, Günter Hesser, Friedrich Schäffler, and Wolfgang Heiss pp 3516–3517 DOI: 10.1021/ja058440j Supporting Info

DNA Functionalization of Carbon Nanotubes for Ultrathin Atomic Layer Deposition of High κ Dielectrics for Nanotube Transistors with 60 mV/Decade Switching Yuerui Lu, Sarunya Bangsaruntip, Xinran Wang, Li Zhang, Yoshio Nishi, and Hongjie Dai pp 3518–3519 DOI: 10.1021/ja058836v Supporting Info

Mimicking [2,2]Paracyclophane Topology: Molecular Clips for the Coordination-Driven Cofacial Assembly of π-Conjugated Systems Brigitte Nohra, Sébastien Graule, Christophe Lescop, and Régis Réau pp 3520–3521 DOI: 10.1021/ja058617+ Supporting Info

Stoichiometric Inhibition of Amyloid β-Protein Aggregation with Peptides Containing Alternating α,α-Disubstituted Amino Acids Marcus A. Etienne, Jed P. Aucoin, Yanwen Fu, Robin L. McCarley, and Robert P. Hammer pp 3522–3523 DOI: 10.1021/ja0600678 Supporting Info

Enthalpy versus Entropy-Driven Binding of Bisphosphonates to Farnesyl Diphosphate Synthase Fenglin Yin, Rong Cao, Amanda Goddard, Yonghui Zhang, and Eric Oldfield pp 3524–3525 DOI: 10.1021/ja0601639

Pd−Fe Nanoparticles as Electrocatalysts for Oxygen Reduction Min-Hua Shao, Kotaro Sasaki, and Radoslav R. Adzic pp 3526–3527 DOI: 10.1021/ja060167d Supporting Info

Interaction of Nitric Oxide with Tetrathiolato Iron(II) Complexes:  Relevance to the Reaction Pathways of Iron Nitrosyls in Sulfur-Rich Biological Coordination Environments Todd C. Harrop, Datong Song, and Stephen J. Lippard pp 3528–3529 DOI: 10.1021/ja060186n Supporting Info

Face-Driven Corner-Linked Octahedral Nanocages:  M6L8 Cages Formed by C3-Symmetric Triangular Facial Ligands Linked via C4-Symmetric Square Tetratopic PdII Ions at Truncated Octahedron Corners Dohyun Moon, Sangmi Kang, Jaejoon Park, Kyungjae Lee, Rohith P. John, Hosik Won, Gi Hun Seong, Yang Sun Kim, Ghyung Hwa Kim, Hakjune Rhee, and Myoung Soo Lah pp 3530–3531 DOI: 10.1021/ja060051h Supporting Info

Structure and Bonding in Yb4MgGe4:  Yb2+/Yb3+ Mixed-Valency and Charge Separation Paul H. Tobash and Svilen Bobev pp 3532–3533 DOI: 10.1021/ja0601383 Supporting Info

Poly-Oxygenated Tricyclobutabenzenes via Repeated [2 + 2] Cycloaddition of Benzyne and Ketene Silyl Acetal Toshiyuki Hamura, Yousuke Ibusuki, Hidehiro Uekusa, Takashi Matsumoto, and Keisuke Suzuki pp 3534–3535 DOI: 10.1021/ja0602647 Supporting Info

A New Strategy for Preparing Molecular Imaging and Therapy Agents Using Fluorine-Rich (Fluorous) Soluble Supports Amanda Donovan, Jane Forbes, Peter Dorff, Paul Schaffer, John Babich, and John F. Valliant pp 3536–3537 DOI: 10.1021/ja0600375 Supporting Info

Enantioselective, Palladium-Catalyzed α-Arylation of N-Boc-pyrrolidine Kevin R. Campos, Artis Klapars, Jacob H. Waldman, Peter G. Dormer, and Cheng-yi Chen pp 3538–3539 DOI: 10.1021/ja0605265 Supporting Info

Modulating Amyloid Self-Assembly and Fibril Morphology with Zn(II) Jijun Dong, Jacob E. Shokes, Robert A. Scott, and David G. Lynn pp 3540–3542 DOI: 10.1021/ja055973j Supporting Info

Origins of Stereoselectivity in Diels−Alder Cycloadditions Catalyzed by Chiral Imidazolidinones Ruth Gordillo and K. N. Houk pp 3543–3553 DOI: 10.1021/ja0525859 Supporting Info

On the Affinity Regulation of the Metal-Ion-Dependent Adhesion Sites in Integrins Eider San Sebastian, Jose M. Mercero, Roland H. Stote, Annick Dejaegere, Fernando P. Cossío, and Xabier Lopez pp 3554–3563 DOI: 10.1021/ja054142a Supporting Info

Potential Energy Landscape of the Photoinduced Multiple Proton-Transfer Process in the Green Fluorescent Protein:  Classical Molecular Dynamics and Multiconfigurational Electronic Structure Calculations Oriol Vendrell, Ricard Gelabert, Miquel Moreno, and José M. Lluch pp 3564–3574 DOI: 10.1021/ja0549998 Supporting Info

NMR Analysis of a Tau Phosphorylation Pattern Isabelle Landrieu, Ludovic Lacosse, Arnaud Leroy, Jean-Michel Wieruszeski, Xavier Trivelli, Alain Sillen, Nathalie Sibille, Harald Schwalbe, Krishna Saxena, Thomas Langer, and Guy Lippens pp 3575–3583 DOI: 10.1021/ja054656+

Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes Shashank Shekhar, Per Ryberg, and John F. HartwigJinu S. Mathew and Donna G. BlackmondEric R. Strieter and Stephen L. Buchwald pp 3584–3591 DOI: 10.1021/ja045533c Supporting Info

Mid-Infrared Spectroscopy of Protected Peptides in the Gas Phase:  A Probe of the Backbone Conformation Isabelle Compagnon, Jos Oomens, Gerard Meijer, and Gert von Helden pp 3592–3597 DOI: 10.1021/ja055378h Supporting Info

In Situ Adsorption Studies of a 14-Amino Acid Leucine-Lysine Peptide onto Hydrophobic Polystyrene and Hydrophilic Silica Surfaces Using Quartz Crystal Microbalance, Atomic Force Microscopy, and Sum Frequency Generation Vibrational Spectroscopy Ozzy Mermut, Diana C. Phillips, Roger L. York, Keith R. McCrea, Robert S. Ward, and Gabor A. Somorjai pp 3598–3607 DOI: 10.1021/ja056031h

G-Quadruplexes Can Maintain Their Structure in the Gas Phase Manuel Rueda, F. Javier Luque, and Modesto Orozco pp 3608–3619 DOI: 10.1021/ja055936s Supporting Info

Structural Characterization of Self-Assembled Multifunctional Binary Nanoparticle Superlattices Elena V. Shevchenko, Dmitri V. Talapin, Christopher B. Murray, and Stephen O'Brien pp 3620–3637 DOI: 10.1021/ja0564261 Supporting Info

Total Synthesis of Phosphatidylinositol Mannosides of Mycobacterium tuberculosis Xinyu Liu, Bridget L. Stocker, and Peter H. Seeberger pp 3638–3648 DOI: 10.1021/ja0565368 Supporting Info

Magneto-Optic Spectroscopy of a Protein Tetramer Binding Two Exciton-Coupled Chlorophylls Joseph L. Hughes, Reza Razeghifard, Mark Logue, Aaron Oakley, Tom Wydrzynski, and Elmars Krausz pp 3649–3658 DOI: 10.1021/ja056576b Supporting Info

Density Functional Theory and DFT+U Study of Transition Metal Porphines Adsorbed on Au(111) Surfaces and Effects of Applied Electric Fields Kevin Leung, Susan B. Rempe, Peter A. Schultz, Eduardo M. Sproviero, Victor S. Batista, Michael E. Chandross, and Craig J. Medforth pp 3659–3668 DOI: 10.1021/ja056630o Supporting Info

Structure and Multinuclear Solid-State NMR of a Highly Birefringent Lead−Gold Cyanide Coordination Polymer Michael J. Katz, Pedro M. Aguiar, Raymond J. Batchelor, Alexei A. Bokov, Zuo-Guang Ye, Scott Kroeker, and Daniel B. Leznoff pp 3669–3676 DOI: 10.1021/ja0566634 Supporting Info

Electrodeposition of Au Monolayer on Pt(111) Mediated by Self-Assembled Monolayers Yaw-Chia Yang, Shueh-Lin Yau, and Yuh-Lang Lee pp 3677–3682 DOI: 10.1021/ja0569407

Evidence for Cu−O2 Intermediates in Superoxide Oxidations by Biomimetic Copper(II) Complexes Valeriy V. Smirnov and Justine P. Roth pp 3683–3695 DOI: 10.1021/ja056741n Supporting Info

Lanthanide Labeling Offers Fast NMR Approach to 3D Structure Determinations of Protein−Protein Complexes Guido Pintacuda, Ah Young Park, Max A. Keniry, Nicholas E. Dixon, and Gottfried Otting pp 3696–3702 DOI: 10.1021/ja057008z

Polymeric Self-Assembly into Micelles and Hollow Spheres with Multiscale Cavities Driven by Inclusion Complexation Jing Wang and Ming Jiang pp 3703–3708 DOI: 10.1021/ja056775v Supporting Info

DNA−Gold Nanorod Conjugates for Remote Control of Localized Gene Expression by near Infrared Irradiation Chia-Chun Chen, Yen-Ping Lin, Chih-Wei Wang, Hsiao-Chien Tzeng, Chia-Hsuan Wu, Yi-Cheng Chen, Chin-Pei Chen, Li-Chyong Chen, and Yi-Chun Wu pp 3709–3715 DOI: 10.1021/ja0570180

Detection of Bacillus subtilis Spores Using Peptide-Functionalized Cantilever Arrays Babita Dhayal, Walter A. Henne, Derek D. Doorneweerd, Ronald G. Reifenberger, and Philip S. Low pp 3716–3721 DOI: 10.1021/ja0570887 Supporting Info

Solution Kinetics of CC-1065 A-Ring Opening:  Substituent Effects and General Acid/Base Catalysis Daniel V. LaBarbera and Edward B. Skibo pp 3722–3727 DOI: 10.1021/ja057289a

Balancing Solvation and Intramolecular Interactions:  Toward a Consistent Generalized Born Force Field Jianhan Chen, Wonpil Im, and Charles L. Brooks III pp 3728–3736 DOI: 10.1021/ja057216r Supporting Info

Acid−Base Bifunctional and Dielectric Outer-Sphere Effects in Heterogeneous Catalysis:  A Comparative Investigation of Model Primary Amine Catalysts John D. Bass, Andrew Solovyov, Andrew J. Pascall, and Alexander Katz pp 3737–3747 DOI: 10.1021/ja057395c Supporting Info

3,3‘-Bis(trisarylsilyl)-Substituted Binaphtholate Rare Earth Metal Catalysts for Asymmetric Hydroamination Denis V. Gribkov, Kai C. Hultzsch, and Frank Hampel pp 3748–3759 DOI: 10.1021/ja058287t Supporting Info

Guided Growth of Nanoscale Conducting Polymer Structures on Surface-Functionalized Nanopatterns Michael Woodson and Jie Liu pp 3760–3763 DOI: 10.1021/ja057500i Supporting Info

Semibiological Molecular Machine with an Implemented “AND” Logic Gate for Regulation of Protein Folding Shinichi Muramatsu, Kazushi Kinbara, Hideki Taguchi, Noriyuki Ishii, and Takuzo Aida pp 3764–3769 DOI: 10.1021/ja057604t

Two-Dimensional Networks Based on Mn4 Complex Linked by Dicyanamide Anion:  From Single-Molecule Magnet to Classical Magnet Behavior Hitoshi Miyasaka, Kazuya Nakata, Lollita Lecren, Claude Coulon, Yasuhiro Nakazawa, Tatsuya Fujisaki, Ken-ichi Sugiura, Masahiro Yamashita, and Rodolphe Clérac pp 3770–3783 DOI: 10.1021/ja0574062 Supporting Info

Solvent-Induced Morphological Transition in Core-Cross-Linked Block Copolymer Micelles Haiying Huang, Richard Hoogenboom, Mark A. M. Leenen, Pierre Guillet, Alain M. Jonas, Ulrich S. Schubert, and Jean-François Gohy pp 3784–3788 DOI: 10.1021/ja057762k

Molecular Wires Comprising π-Extended Ethynyl- and Butadiynyl-2,5-Diphenyl-1,3,4-Oxadiazole Derivatives:  Synthesis, Redox, Structural, and Optoelectronic Properties Changsheng Wang, Lars-Olof Pålsson, Andrei S. Batsanov, and Martin R. Bryce pp 3789–3799 DOI: 10.1021/ja0577600 Supporting Info

Chain Packing in the Inverted Hexagonal Phase of Phospholipids:  A Study by X-ray Anomalous Diffraction on Bromine-labeled Chains Deng Pan, Wangchen Wang, Wenhan Liu, Lin Yang, and Huey W. Huang pp 3800–3807 DOI: 10.1021/ja058045t

Direct Measurement by Laser Flash Photolysis of Intramolecular Electron Transfer in a Two-Domain Construct of Murine Inducible Nitric Oxide Synthase Changjian Feng, Clayton Thomas, Michael A. Holliday, Gordon Tollin, John C. Salerno, Dipak K. Ghosh, and John H. Enemark pp 3808–3811 DOI: 10.1021/ja0578606 Supporting Info

The Shape of β-Alanine M. Eugenia Sanz, Alberto Lesarri, M. Isabel Peña, Vanesa Vaquero, Vanessa Cortijo, Juan C. López, and José L. Alonso pp 3812–3817 DOI: 10.1021/ja058194b Supporting Info

Template Synthesis of 1,4,7-Triphosphacyclononanes Peter G. Edwards, Robert Haigh, Dongmei Li, and Paul D. Newman pp 3818–3830 DOI: 10.1021/ja0578956 Supporting Info

A Two-Photon Antenna for Photochemical Delivery of Nitric Oxide from a Water-Soluble, Dye-Derivatized Iron Nitrosyl Complex Using NIR Light Stephen R. Wecksler, Alexander Mikhailovsky, Dmitry Korystov, and Peter C. Ford pp 3831–3837 DOI: 10.1021/ja057977u Supporting Info

Biosynthesis of Pipecolic Acid by RapL, a Lysine Cyclodeaminase Encoded in the Rapamycin Gene Cluster Gregory J. Gatto, Jr., Michael T. Boyne, II, Neil L. Kelleher, and Christopher T. Walsh pp 3838–3847 DOI: 10.1021/ja0587603

Synthesis of Multiwalled Carbon Nanotubes through a Modified Wolff−Kishner Reduction Process [J. Am. Chem. Soc. 2005, 127, 18018−18019]. Wenzhong Wang, Bed Poudel, D. Z. Wang, and Z. F. Ren p 3848 DOI: 10.1021/ja0699539

Issue 12

Chlorination−Methylation of the Hydrogen-Terminated Silicon(111) Surface Can Induce a Stacking Fault in the Presence of Etch Pits Santiago D. Solares, Hongbin Yu, Lauren J. Webb, Nathan S. Lewis, James R. Heath, and William A. Goddard, III pp 3850–3851 DOI: 10.1021/ja055408g Supporting Info

Biocleavable Polyrotaxane−Plasmid DNA Polyplex for Enhanced Gene Delivery Tooru Ooya, Hak Soo Choi, Atsushi Yamashita, Nobuhiko Yui, Yuko Sugaya, Arihiro Kano, Atsushi Maruyama, Hidetaka Akita, Rie Ito, Kentaro Kogure, and Hideyoshi Harashima pp 3852–3853 DOI: 10.1021/ja055868+ Supporting Info

A Sensitive Probe for the Detection of Zn(II) by Time-Resolved Fluorescence Maksim Royzen, Alexander Durandin, Victor G. Young, Jr., Nicholas E. Geacintov, and James W. Canary pp 3854–3855 DOI: 10.1021/ja056631g Supporting Info

CEESY:  Characterizing the Conformation of Unobservable Protein States Hugo van Ingen, Geerten W. Vuister, Sybren Wijmenga, and Marco Tessari pp 3856–3857 DOI: 10.1021/ja0568749 Supporting Info

Phorboxazole Analogues Induce Association of cdk4 with Extranuclear Cytokeratin Intermediate Filaments Craig J. Forsyth, Lu Ying, Jiehao Chen, and James J. La Clair pp 3858–3859 DOI: 10.1021/ja057087e Supporting Info

Femtomolar Electrochemical Detection of DNA Targets Using Metal Sulfide Nanoparticles Jacob A. Hansen, Rupa Mukhopadhyay, Jonas Ø. Hansen, and Kurt V. Gothelf pp 3860–3861 DOI: 10.1021/ja0574116 Supporting Info

An Optical Biosensor for Rapid and Label-Free Detection of Cells Ghanashyam Acharya, Chun-Li Chang, and Cagri Savran pp 3862–3863 DOI: 10.1021/ja057490l Supporting Info

Electron Binding Energies of Hydrated H3O+ and OH-:  Photoelectron Spectroscopy of Aqueous Acid and Base Solutions Combined with Electronic Structure Calculations Bernd Winter, Manfred Faubel, Ingolf V. Hertel, Christian Pettenkofer, Stephen E. Bradforth, Barbara Jagoda-Cwiklik, Lukasz Cwiklik, and Pavel Jungwirth pp 3864–3865 DOI: 10.1021/ja0579154 Supporting Info

Conformation of the Group II Intron Branch Site in Solution Jörg C. Schlatterer, Samuel H. Crayton, and Nancy L. Greenbaum pp 3866–3867 DOI: 10.1021/ja0578754 Supporting Info

Planar Gold Nanoparticle Clusters as Microscale Mirrors Jin Young Kim and Frank E. Osterloh pp 3868–3869 DOI: 10.1021/ja057958k Supporting Info

Energy Transfer in Calixarene-Based Cofacial-Positioned Perylene Bisimide Arrays Catharina Hippius, Felix Schlosser, Myroslav O. Vysotsky, Volker Böhmer, and Frank Würthner pp 3870–3871 DOI: 10.1021/ja058007+ Supporting Info

Magnetic Transitions of Single-Component Molecular Metal [Au(tmdt)2] and Its Alloy Systems Biao Zhou, Mina Shimamura, Emiko Fujiwara, Akiko Kobayashi, Takeshi Higashi, Eiji Nishibori, Makoto Sakata, HengBo Cui, Kazuyuki Takahashi, and Hayao Kobayashi pp 3872–3873 DOI: 10.1021/ja0581144

Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand Takahiro Matsumoto, Hideki Furutachi, Masashi Kobino, Masato Tomii, Shigenori Nagatomo, Takehiko Tosha, Takao Osako, Shuhei Fujinami, Shinobu Itoh, Teizo Kitagawa, and Masatatsu Suzuki pp 3874–3875 DOI: 10.1021/ja058117g Supporting Info

Flexibility and Lengths of Bis-peptide Nanostructures by Electron Spin Resonance Soraya Pornsuwan, Gregory Bird, Christian E. Schafmeister, and Sunil Saxena pp 3876–3877 DOI: 10.1021/ja058143e Supporting Info

Accurate Measurements of 13C−13C J-Couplings in the Rhodopsin Chromophore by Double-Quantum Solid-State NMR Spectroscopy Wai Cheu Lai, Neville McLean, Axel Gansmüller, Michiel A. Verhoeven, Gian Carlo Antonioli, Marina Carravetta, Luminita Duma, Petra H. M. Bovee-Geurts, Ole G. Johannessen, Huub J. M. de Groot, Johan Lugtenburg, Lyndon Emsley, Steven P. Brown, Richard C. D. Brown, Willem J. DeGrip, and Malcolm H. Levitt pp 3878–3879 DOI: 10.1021/ja0581604 Supporting Info

Patterning Organic Semiconductors Using “Dry” Poly(dimethylsiloxane) Elastomeric Stamps for Thin Film Transistors Alejandro L. Briseno, Mark Roberts, Mang-Mang Ling, Hyunsik Moon, E. Joseph Nemanick, and Zhenan Bao pp 3880–3881 DOI: 10.1021/ja058226v Supporting Info

Structure of Bistramide A−Actin Complex at a 1.35 Å Resolution Syed Alipayam Rizvi, Valentina Tereshko, Anthony A. Kossiakoff, and Sergey A. Kozmin pp 3882–3883 DOI: 10.1021/ja058319c Supporting Info

Geometric Properties of Covalently Bonded DNA on Single-Crystalline Diamond Bohuslav Rezek, Dongchan Shin, Takako Nakamura, and Christoph E. Nebel pp 3884–3885 DOI: 10.1021/ja058181y

Single-Molecule Force Spectroscopy of Bimolecular Reactions:  System Homology in the Mechanical Activation of Ligand Substitution Reactions Farrell R. Kersey, Wayne C. Yount, and Stephen L. Craig pp 3886–3887 DOI: 10.1021/ja058516b Supporting Info

Pulsed Electron Paramagnetic Resonance Experiments Identify the Paramagnetic Intermediates in the Pyruvate Ferredoxin Oxidoreductase Catalytic Cycle Andrei V. Astashkin, Javier Seravalli, Steven O. Mansoorabadi, George H. Reed, and Stephen W. Ragsdale pp 3888–3889 DOI: 10.1021/ja0585275 Supporting Info

Theoretical Prediction of Heterogeneous Molecular Wires on the Si(001) Surface Jin-Ho Choi and Jun-Hyung Cho pp 3890–3891 DOI: 10.1021/ja058672i Supporting Info

Competing Mechanisms in the Optically Activated Functionalization of the Hydrogen-Terminated Si(111) Surface Yosuke Kanai and Annabella Selloni pp 3892–3893 DOI: 10.1021/ja058698+ Supporting Info

Cavitands with Revolving Doors Regulate Binding Selectivities and Rates in Water Richard J. Hooley, Hillary J. Van Anda, and Julius Rebek, Jr. pp 3894–3895 DOI: 10.1021/ja058727g Supporting Info

An Interweaving MOF with High Hydrogen Uptake Daofeng Sun, Shengqian Ma, Yanxiong Ke, David J. Collins, and Hong-Cai Zhou pp 3896–3897 DOI: 10.1021/ja058777l Supporting Info

Surface-Functionalized CdSe Nanorods for Assembly in Diblock Copolymer Templates Qingling Zhang, Suresh Gupta, Todd Emrick, and Thomas P. Russell pp 3898–3899 DOI: 10.1021/ja058615p

Halogenation of Unactivated Carbon Centers in Natural Product Biosynthesis:  Trichlorination of Leucine during Barbamide Biosynthesis Danica P. Galonić, Frédéric H. Vaillancourt, and Christopher T. Walsh pp 3900–3901 DOI: 10.1021/ja060151n Supporting Info

Charge Transfer Enhances Two-Photon Absorption in Transition Metal Porphyrins Jonathan L. Humphrey and Darius Kuciauskas pp 3902–3903 DOI: 10.1021/ja0588353 Supporting Info

A Kinetic Study on Rh/Binap-Catalyzed 1,4-Addition of Phenylboronic Acid to Enones:  Negative Nonlinear Effect Caused by Predominant Homochiral Dimer Contribution Asato Kina, Hiroshi Iwamura, and Tamio Hayashi pp 3904–3905 DOI: 10.1021/ja060225v Supporting Info

Time-Resolved X-ray Excited Optical Luminescence from Tris(2-phenyl bipyridine)iridium Franziskus Heigl, Simone Lam, Tom Regier, Ian Coulthard, and Tsun-Kong Sham pp 3906–3907 DOI: 10.1021/ja060243c

Total Synthesis of (±)-Haouamine A Phil S. Baran and Noah Z. Burns pp 3908–3909 DOI: 10.1021/ja0602997 Supporting Info

Stable Photogenerated Carriers in Magnetic Semiconductor Nanocrystals William K. Liu, Kelly M. Whitaker, Kevin R. Kittilstved, and Daniel R. Gamelin pp 3910–3911 DOI: 10.1021/ja060488p Supporting Info

Observation of Solid-State 103Rh NMR by Cross-Polarization Brian L. Phillips, Jacqueline R. Houston, Jian Feng, and William H. Casey pp 3912–3913 DOI: 10.1021/ja057347s Supporting Info

Solution Processable Organic Field-Effect Transistors Utilizing an α,α‘-Dihexylpentathiophene-Based Swivel Cruciform Achmad Zen, Askin Bilge, Frank Galbrecht, Ronald Alle, Klaus Meerholz, Jörg Grenzer, Dieter Neher, Ullrich Scherf, and Tony Farrell pp 3914–3915 DOI: 10.1021/ja0573357 Supporting Info

15N NMR Spin Relaxation Dispersion Study of the Molecular Crowding Effects on Protein Folding under Native Conditions Xuanjun Ai, Zheng Zhou, Yawen Bai, and Wing-Yiu Choy pp 3916–3917 DOI: 10.1021/ja057832n Supporting Info

Protonless NMR Experiments for Sequence-Specific Assignment of Backbone Nuclei in Unfolded Proteins Wolfgang Bermel, Ivano Bertini, Isabella C. Felli, Yong-Min Lee, Claudio Luchinat, and Roberta Pierattelli pp 3918–3919 DOI: 10.1021/ja0582206 Supporting Info

Preparation of Oriented Mesoporous Carbon Nano-Filaments within the Pores of Anodic Alumina Membranes Dáire J. Cott, Nikolay Petkov, Michael A. Morris, Barbara Platschek, Thomas Bein, and Justin D. Holmes pp 3920–3921 DOI: 10.1021/ja058441b Supporting Info

A Very Simple, Highly Stereoselective and Modular Synthesis of Ferrocene-Based P-Chiral Phosphine Ligands Weiping Chen, William Mbafor, Stanley M. Roberts, and John Whittall pp 3922–3923 DOI: 10.1021/ja058531g Supporting Info

The Effect of Heme Environment on the Hydrogen Abstraction Reaction of Camphor in P450cam Catalysis:  A QM/MM Study Ahmet Altun, Victor Guallar, Richard A. Friesner, Sason Shaik, and Walter Thiel pp 3924–3925 DOI: 10.1021/ja058196w Supporting Info

A Synthesis of (+)-Saxitoxin James J. Fleming and J. Du Bois pp 3926–3927 DOI: 10.1021/ja0608545 Supporting Info

Dual-Function Cinchona Alkaloid Catalysis:  Catalytic Asymmetric Tandem Conjugate Addition−Protonation for the Direct Creation of Nonadjacent Stereocenters Yi Wang, Xiaofeng Liu, and Li Deng pp 3928–3930 DOI: 10.1021/ja060312n Supporting Info

Palladium-Catalyzed Asymmetric Allylic Alkylation of meso- and dl-1,2-Divinylethylene Carbonate Barry M. Trost and Aaron Aponick pp 3931–3933 DOI: 10.1021/ja0578348 Supporting Info

Synthesis of Urea-Tethered Neoglycoconjugates and Pseudooligosaccharides in Water Yoshiyasu Ichikawa, Yohei Matsukawa, and Minoru Isobe pp 3934–3938 DOI: 10.1021/ja056253f Supporting Info

Surface Tailoring for Controlled Protein Adsorption:  Effect of Topography at the Nanometer Scale and Chemistry Paul Roach, David Farrar, and Carole C. Perry pp 3939–3945 DOI: 10.1021/ja056278e Supporting Info

P-Hydrogen-Substituted 1,3,2-Diazaphospholenes:  Molecular Hydrides Sebastian Burck, Dietrich Gudat, Martin Nieger, and Wolf-Walther Du Mont pp 3946–3955 DOI: 10.1021/ja057827j Supporting Info

Cobalt Particle Size Effects in the Fischer−Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts G. Leendert Bezemer, Johannes H. Bitter, Herman P. C. E. Kuipers, Heiko Oosterbeek, Johannes E. Holewijn, Xiaoding Xu, Freek Kapteijn, A. Jos van Dillen, and Krijn P. de Jong pp 3956–3964 DOI: 10.1021/ja058282w

Assembly of an Allenylidene Ligand, a Terminal Alkyne, and an Acetonitrile Molecule:  Formation of Osmacyclopentapyrrole Derivatives Tamara Bolaño, Ricardo Castarlenas, Miguel A. Esteruelas, and Enrique Oñate pp 3965–3973 DOI: 10.1021/ja058355b Supporting Info

Highly Stable Cp*−Ir(III) Complexes with N-Heterocyclic Carbene Ligands as C−H Activation Catalysts for the Deuteration of Organic Molecules Rosa Corberán, Mercedes Sanaú, and Eduardo Peris pp 3974–3979 DOI: 10.1021/ja058253l Supporting Info

Use of Weakly Coordinating Anions to Develop an Integrated Approach to the Tuning of ΔE1/2 Values by Medium Effects Frédéric Barrière and William E. Geiger pp 3980–3989 DOI: 10.1021/ja058171x Supporting Info

Dynamics of Proteins Encapsulated in Silica Sol−Gel Glasses Studied with IR Vibrational Echo Spectroscopy Aaron M. Massari, Ilya J. Finkelstein, and Michael D. Fayer pp 3990–3997 DOI: 10.1021/ja058745y Supporting Info

A Columnar Phase of Dendritic Lipid−Based Cationic Liposome−DNA Complexes for Gene Delivery:  Hexagonally Ordered Cylindrical Micelles Embedded in a DNA Honeycomb Lattice Kai K. Ewert, Heather M. Evans, Alexandra Zidovska, Nathan F. Bouxsein, Ayesha Ahmad, and Cyrus R. Safinya pp 3998–4006 DOI: 10.1021/ja055907h Supporting Info

The Role of Exciton Hopping and Direct Energy Transfer in the Efficient Quenching of Conjugated Polyelectrolytes Jürgen G. Müller, Evrim Atas, Chunyan Tan, Kirk S. Schanze, and Valeria D. Kleiman pp 4007–4016 DOI: 10.1021/ja055630l Supporting Info

Identifying an O2 Supply Pathway in CO Oxidation on Au/TiO2(110):  A Density Functional Theory Study on the Intrinsic Role of Water L. M. Liu, B. McAllister, H. Q. Ye, and P. Hu pp 4017–4022 DOI: 10.1021/ja056801p

Asymmetric Synthesis of Highly Substituted Azapolycyclic Compounds via 2-Alkenyl Sulfoximines:  Potential Scaffolds for Peptide Mimetics Michael Reggelin, Bernd Junker, Timo Heinrich, Stefan Slavik, and Philipp Bühle pp 4023–4034 DOI: 10.1021/ja057012a Supporting Info

An Efficient Thermally Induced RNA Conformational Switch as a Framework for the Functionalization of RNA Nanostructures Xianglan Li, Satoru Horiya, and Kazuo Harada pp 4035–4040 DOI: 10.1021/ja0572093 Supporting Info

Quantitative Structure−Activity Relationship Based Quantification of the Impacts of Enzyme−Substrate Binding on Rates of Peroxidase-Mediated Reactions of Estrogenic Phenolic Chemicals Lisa M. Colosi, Qingguo Huang, and Walter J. Weber, Jr. pp 4041–4047 DOI: 10.1021/ja057430f Supporting Info

The Origin of Chemo- and Enantioselectivity in the Hydrogenation of Diketones on Platinum Simon Diezi, Davide Ferri, Angelo Vargas, Tamas Mallat, and Alfons Baiker pp 4048–4057 DOI: 10.1021/ja057586f Supporting Info

Beyond Switches:  Ratcheting a Particle Energetically Uphill with a Compartmentalized Molecular Machine Manashi N. Chatterjee, Euan R. Kay, and David A. Leigh pp 4058–4073 DOI: 10.1021/ja057664z Supporting Info

Microfaceting Explains Complicated Structures on Rutile TiO2 Surfaces Toshitaka Kubo, Kazuhiro Sayama, and Hisakazu Nozoye pp 4074–4078 DOI: 10.1021/ja0578808

Allenylidene-to-Indenylidene Rearrangement in Arene−Ruthenium Complexes: A Key Step to Highly Active Catalysts for Olefin Metathesis Reactions Ricardo Castarlenas, Chloé Vovard, Cédric Fischmeister, and Pierre H. Dixneuf pp 4079–4089 DOI: 10.1021/ja0579762

The Ozonation of Silanes and Germanes:  An Experimental and Theoretical Investigation Janez Cerkovnik, Tell Tuttle, Elfi Kraka, Nika Lendero, Božo Plesniar, and Dieter Cremer pp 4090–4100 DOI: 10.1021/ja058065v Supporting Info

Modified (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes for Room-Temperature Suzuki−Miyaura and Buchwald−Hartwig Reactions Nicolas Marion, Oscar Navarro, Jianguo Mei, Edwin D. Stevens, Natalie M. Scott, and Steven P. Nolan pp 4101–4111 DOI: 10.1021/ja057704z Supporting Info

Stabilization of Charge-Separated States in Phthalocyanine−Fullerene Ensembles through Supramolecular Donor−Acceptor Interactions Andrés de la Escosura, M. Victoria Martínez-Díaz, Dirk M. Guldi, and Tomás Torres pp 4112–4118 DOI: 10.1021/ja058123c Supporting Info

A Directly Fused Tetrameric Porphyrin Sheet and Its Anomalous Electronic Properties That Arise from the Planar Cyclooctatetraene Core Yasuyuki Nakamura, Naoki Aratani, Hiroshi Shinokubo, Akihiko Takagi, Tomoji Kawai, Takuya Matsumoto, Zin Seok Yoon, Deok Yun Kim, Tae Kyu Ahn, Dongho Kim, Atsuya Muranaka, Nagao Kobayashi, and Atsuhiro Osuka pp 4119–4127 DOI: 10.1021/ja057812l Supporting Info

A Three-State Model for the Polymorphism in Linear Tricobalt Compounds Dimitrios A. Pantazis and John E. McGrady pp 4128–4135 DOI: 10.1021/ja0581402 Supporting Info

Kinetic Performance and Energy Profile in a Roller Coaster Electron Transfer Chain:  A Study of Modified Tetraheme-Reaction Center Constructs Jean Alric, Jérôme Lavergne, Fabrice Rappaport, André Verméglio, Katsumi Matsuura, Keizo Shimada, and Kenji V. P. Nagashima pp 4136–4145 DOI: 10.1021/ja058131t Supporting Info

High Molar Extinction Coefficient Heteroleptic Ruthenium Complexes for Thin Film Dye-Sensitized Solar Cells Daibin Kuang, Seigo Ito, Bernard Wenger, Cedric Klein, Jacques-E Moser, Robin Humphry-Baker, Shaik M. Zakeeruddin, and Michael Grätzel pp 4146–4154 DOI: 10.1021/ja058540p Supporting Info

Deltahedral Germanium Clusters:  Insertion of Transition-Metal Atoms and Addition of Organometallic Fragments Jose M. Goicoechea and Slavi C. Sevov pp 4155–4161 DOI: 10.1021/ja058652g Supporting Info

Bismuth-Catalyzed Intermolecular Hydroamination of 1,3-Dienes with Carbamates, Sulfonamides, and Carboxamides  [J. Am. Chem. Soc. 2006, 128, 1611−1614]. Hongbo Qin, Noriyuki Yamagiwa, Shigeki Matsunaga, and Masakatsu Shibasaki p 4162 DOI: 10.1021/ja060684w

Organic Reactions, Volume 66 Editor-in-Chief:  Larry E. Overman (University of California, Irvine). John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. x + 654 pp. $125.00. ISBN 0-471-68258-6. p 4163 DOI: 10.1021/ja059846z

Molecular Wires:  From Design to Properties. Topics in Current Chemistry, 257 Edited by L. De Cola (Westfälische Wilhelms-Universität, Münster, Germany). Springer:  Berlin, Heidelberg, New York. 2005. x + 170 pp. $159. ISBN 3-350-25793-4. Dennis W. Bennett p 4163 DOI: 10.1021/ja059850a

Nanotubes and Nanowires By C. N. R. Rao and A. Govindaraj (Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore, India). Royal Society of Chemistry:  Cambridge. 2005. xii + 272 pp. $149.00. ISBN 0-85404-832-4. Robert J. Hamers pp 4163–4164 DOI: 10.1021/ja059884i

Cinnolines and Phthalazines, Supplement II. The Chemistry of Heterocyclic Compounds, Volume 64 Edited by D. J. Brown (Australian National University, Canberra). Series Edited by Edward C. Taylor and Peter Wipf. John Wiley & Sons, Inc.:  Hoboken, NJ. 2005. xviii + 482 pp. $425. ISBN 0-471-48587-X. p 4164 DOI: 10.1021/ja059847r

Encyclopedia of Inorganic Chemistry, 2nd ed Edited by R. Bruce King (University of Georgia). John Wiley and Sons, Inc.:  Hoboken, NJ. 2005. 6696 pp. $5450.00. ISBN 0-470-86078-2. p 4164 DOI: 10.1021/ja059849b

Progress in Heterocyclic Chemistry, Volume 17 Edited by Gordon W. Gribble (Dartmouth College, Hanover, NH) and John A. Joule (The University of Manchester, UK). Elsevier Science Ltd.:  Kidlington. 2005. vii + 450 pp. $275.00. ISBN 0-08-044711-2. p 4164 DOI: 10.1021/ja0598614

Issue 13

Self-Assembly of Peptide Porphyrin Complexes:  Toward the Development of Smart Biomaterials Brian C. Kovaric, Bashkim Kokona, Alexander D. Schwab, Margaret A. Twomey, Julio C. de Paula, and Robert Fairman pp 4166–4167 DOI: 10.1021/ja056357q Supporting Info

Multifunctional Polymeric Nanoparticles from Diverse Bioactive Agents Paul A. Bertin, Julianne M. Gibbs, Clifton Kwang-Fu Shen, C. Shad Thaxton, William A. Russin, Chad A. Mirkin, and SonBinh T. Nguyen pp 4168–4169 DOI: 10.1021/ja056378k Supporting Info

Polar Networks Control Oligomeric Assembly in Membranes Chad D. Tatko, Vikas Nanda, James D. Lear, and William F. DeGrado pp 4170–4171 DOI: 10.1021/ja055561a Supporting Info

Role of the Guanine N1 Imino Proton in the Migration and Reaction of Radical Cations in DNA Oligomers Avik K. Ghosh and Gary B. Schuster pp 4172–4173 DOI: 10.1021/ja0573763 Supporting Info

Mechanistic Implications in the Morita−Baylis−Hillman Alkylation:  Isolation and Characterization of an Intermediate Marie E. Krafft, Thomas F. N. Haxell, Kimberly A. Seibert, and Khalil A. Abboud pp 4174–4175 DOI: 10.1021/ja057595o Supporting Info

Superactivation of the Botulinum Neurotoxin Serotype A Light Chain Metalloprotease:  A New Wrinkle in Botulinum Neurotoxin Laura A. McAllister, Mark S. Hixon, Jack P. Kennedy, Tobin J. Dickerson, and Kim D. Janda pp 4176–4177 DOI: 10.1021/ja057699z Supporting Info

Molecularly Imprinted Nanoreactors for Regioselective Huisgen 1,3-Dipolar Cycloaddition Reaction Huiqi Zhang, Theeraphon Piacham, Mark Drew, Marcel Patek, Klaus Mosbach, and Lei Ye pp 4178–4179 DOI: 10.1021/ja057781u Supporting Info

Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid):  A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability Long Pan, Brett Parker, Xiaoying Huang, David H. Olson, JeongYong Lee, and Jing Li pp 4180–4181 DOI: 10.1021/ja057667b Supporting Info

Fluorophilicity Switch by Solvation Akihiro Orita, Sumiyo Man-e, and Junzo Otera pp 4182–4183 DOI: 10.1021/ja058105v Supporting Info

Positive Homotropic Allosteric Binding of Silver(I) Cations in a Schiff Base Oligopyrrolic Macrocycle Jonathan L. Sessler, Elisa Tomat, and Vincent M. Lynch pp 4184–4185 DOI: 10.1021/ja0582004 Supporting Info

Living Polymerization of α-Olefins with an α-Diimine Ni(II) Catalyst:  Formation of Well-Defined Ethylene−Propylene Copolymers through Controlled Chain-Walking Jeffrey M. Rose, Anna E. Cherian, and Geoffrey W. Coates pp 4186–4187 DOI: 10.1021/ja058183i Supporting Info

Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis:  Asymmetric Rhodium-Catalyzed Hydrogenation Martine Weis, Christoph Waloch, Wolfgang Seiche, and Bernhard Breit pp 4188–4189 DOI: 10.1021/ja058202o Supporting Info

Chemical Analysis of Norrisolide-Induced Golgi Vesiculation Gianni Guizzunti, Thomas P. Brady, Vivek Malhotra, and Emmanuel A. Theodorakis pp 4190–4191 DOI: 10.1021/ja058259a Supporting Info

Negative Regulation of a Protein Tyrosine Phosphatase by Tyrosine Phosphorylation Dirk Schwarzer, Zhongsen Zhang, Weiping Zheng, and Philip A. Cole pp 4192–4193 DOI: 10.1021/ja0585174 Supporting Info

Generation of Complex, Static Solution Gradients in Microfluidic Channels Hongkai Wu, Bo Huang, and Richard N. Zare pp 4194–4195 DOI: 10.1021/ja058530o Supporting Info

Chemistry of [Et4N][MoIV(SPh)(PPh3)(mnt)2] as an Analogue of Dissimilatory Nitrate Reductase with Its Inactivation on Substitution of Thiolate by Chloride Amit Majumdar, Kuntal Pal, and Sabyasachi Sarkar pp 4196–4197 DOI: 10.1021/ja0586135 Supporting Info

Imaging Adsorbate O−H Bond Cleavage:  Methanol on TiO2(110) Zhenrong Zhang, Oleksandr Bondarchuk, J. M. White, Bruce D. Kay, and Zdenek Dohnálek pp 4198–4199 DOI: 10.1021/ja058466a Supporting Info

DNA-Programmed Control of Photosensitized Singlet Oxygen Production Emiliano Cló, John W. Snyder, Niels V. Voigt, Peter R. Ogilby, and Kurt V. Gothelf pp 4200–4201 DOI: 10.1021/ja058713a Supporting Info

Printed Silver Ohmic Contacts for High-Mobility Organic Thin-Film Transistors Yiliang Wu, Yuning Li, and Beng S. Ong pp 4202–4203 DOI: 10.1021/ja058725w Supporting Info

Synthetic Ligands for Apo-Neocarzinostatin Stephen Caddick, Frederick W. Muskett, Rhys G. Stoneman, and Derek N. Woolfson pp 4204–4205 DOI: 10.1021/ja058419i Supporting Info

Metal-Enhanced Fluorescence-Based RNA Sensing Kadir Aslan, Jun Huang, Gerald M. Wilson, and Chris D. Geddes pp 4206–4207 DOI: 10.1021/ja0601179 Supporting Info

Bond-Forming Reactions of Molecular Dications as a New Route to Polyaromatic Hydrocarbons Jana Roithová and Detlef Schröder pp 4208–4209 DOI: 10.1021/ja0600429 Supporting Info

Electrophilic C−H Activation at {Cp*Ir}:  Ancillary-Ligand Control of the Mechanism of C−H Activation David L. Davies, Steven M. A. Donald, Omar Al-Duaij, Stuart A. Macgregor, and Manuel Pölleth pp 4210–4211 DOI: 10.1021/ja060173+ Supporting Info

Rational Modulation of the Periodicity in Linear Hydrogen-Bonded Assemblies of Trimesic Acid on Surfaces Krishna G. Nath, Oleksandr Ivasenko, Jill A. Miwa, Hung Dang, James D. Wuest, Antonio Nanci, Dmitrii F. Perepichka, and Federico Rosei pp 4212–4213 DOI: 10.1021/ja0602896 Supporting Info

An S = 6 Cyanide-Bridged Octanuclear FeIII4NiII4 Complex that Exhibits Slow Relaxation of the Magnetization Dongfeng Li, Sean Parkin, Guangbin Wang, Gordon T. Yee, Rodolphe Clérac, Wolfgang Wernsdorfer, and Stephen M. Holmes pp 4214–4215 DOI: 10.1021/ja058626i Supporting Info

Rational Design and HT Techniques Allow the Synthesis of New IWR Zeolite Polymorphs Angel Cantín, Avelino Corma, Maria J. Diaz-Cabanas, Jose L. Jordá, and Manuel Moliner pp 4216–4217 DOI: 10.1021/ja0603599 Supporting Info

2D Supramolecular Structures of a Shape-Persistent Macrocycle and Co-deposition with Fullerene on HOPG Ge-Bo Pan, Xiao-Hong Cheng, Sigurd Höger, and Werner Freyland pp 4218–4219 DOI: 10.1021/ja060469f Supporting Info

Photochemical Stitching of a Tubularly Assembled Hexabenzocoronene Amphiphile by Dimerization of Coumarin Pendants Jin Motoyanagi, Takanori Fukushima, Noriyuki Ishii, and Takuzo Aida pp 4220–4221 DOI: 10.1021/ja060593z Supporting Info

Immobilization of Sodium Ions on the Pore Surface of a Porous Coordination Polymer Satoshi Horike, Ryotaro Matsuda, Daisuke Tanaka, Motohiro Mizuno, Kazunaka Endo, and Susumu Kitagawa pp 4222–4223 DOI: 10.1021/ja0606879 Supporting Info

Critical Properties of Aluminum Divesh Bhatt, Ahren W. Jasper, Nathan E. Schultz, J. Ilja Siepmann, and Donald G. Truhlar pp 4224–4225 DOI: 10.1021/ja0577950 Supporting Info

An Improved Class of Sugar-Binding Boronic Acids, Soluble and Capable of Complexing Glycosides in Neutral Water Meenakshi Dowlut and Dennis G. Hall pp 4226–4227 DOI: 10.1021/ja057798c Supporting Info

Synthesis, Structure, and Bonding of Stable Dialkylsilaketenimines Takashi Abe, Takeaki Iwamoto, Chizuko Kabuto, and Mitsuo Kira pp 4228–4229 DOI: 10.1021/ja057917o Supporting Info

Kinetic Resolution of Protected α-Amino Acid Derivatives by a Chiral O-Nucleophilic Acyl Transfer Catalyst Gregory T. Notte and Tarek Sammakia pp 4230–4231 DOI: 10.1021/ja058010t Supporting Info

Asymmetric Claisen Rearrangements Enabled by Catalytic Asymmetric Di(allyl) Ether Synthesis Scott G. Nelson and Kan Wang pp 4232–4233 DOI: 10.1021/ja058172p Supporting Info

An O-GlcNAcase-Specific Inhibitor and Substrate Engineered by the Extension of the N-Acetyl Moiety Eun Ju Kim, Melissa Perreira, Craig J. Thomas, and John A. Hanover pp 4234–4235 DOI: 10.1021/ja0582915 Supporting Info

Corking Nano Test Tubes by Chemical Self-Assembly Heather Hillebrenner, Fatih Buyukserin, Myungchan Kang, Miguel O. Mota, Jon D. Stewart, and Charles R. Martin pp 4236–4237 DOI: 10.1021/ja058455h Supporting Info

An Efficient Route to Well-Defined Macrocyclic Polymers via “Click” Cyclization Boyd A. Laurent and Scott M. Grayson pp 4238–4239 DOI: 10.1021/ja0585836 Supporting Info

Radical Phosphination of Organic Halides and Alkyl Imidazole-1-carbothioates Akinori Sato, Hideki Yorimitsu, and Koichiro Oshima pp 4240–4241 DOI: 10.1021/ja058783h Supporting Info

DDQ-Mediated Direct Cross-Dehydrogenative-Coupling (CDC) between Benzyl Ethers and Simple Ketones Yuhua Zhang and Chao-Jun Li pp 4242–4243 DOI: 10.1021/ja060050p Supporting Info

Tight Binding Inhibitors of N-Acyl Amino Sugar and N-Acyl Amino Acid Deacetylases Chengfu Xu, Richard Hall, Jennifer Cummings, and Frank M. Raushel pp 4244–4245 DOI: 10.1021/ja0600680 Supporting Info

Room Temperature Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Forrest E. Michael and Brian M. Cochran pp 4246–4247 DOI: 10.1021/ja060126h Supporting Info

Reducing Power of Three-Coordinate Cobalt(I) Michael J. Ingleson, Maren Pink, and Kenneth G. Caulton pp 4248–4249 DOI: 10.1021/ja0607279 Supporting Info

Reflective Interferometric Fourier Transform Spectroscopy:  A Self-Compensating Label-Free Immunosensor Using Double-Layers of Porous SiO2 Claudia Pacholski, Christine Yu, Gordon M. Miskelly, Denis Godin, and Michael J. Sailor pp 4250–4252 DOI: 10.1021/ja056702b Supporting Info

Ultrafast Charge Separation in a Photoreactive Rhenium-Appended Porphyrin Assembly Monitored by Picosecond Transient Infrared Spectroscopy Anders Gabrielsson, František Hartl, Hong Zhang, John R. Lindsay Smith, Michael Towrie, Antonín Vlek, Jr., and Robin N. Perutz pp 4253–4266 DOI: 10.1021/ja0539802 Supporting Info

8-Bromo-7-hydroxyquinoline as a Photoremovable Protecting Group for Physiological Use:  Mechanism and Scope Yue Zhu, Christopher M. Pavlos, John P. Toscano, and Timothy M. Dore pp 4267–4276 DOI: 10.1021/ja0555320 Supporting Info

J-Aggregation in α-Sexithiophene Submonolayer Films on Silicon Dioxide Enrico Da Como, Maria Antonietta Loi, Mauro Murgia, Roberto Zamboni, and Michele Muccini pp 4277–4281 DOI: 10.1021/ja056060s

Probing the Intrinsic Electronic Structure of the Bis(dithiolene) Anions [M(mnt)2]2- and [M(mnt)2]1- (M = Ni, Pd, Pt; mnt = 1,2-S2C2(CN)2) in the Gas Phase by Photoelectron Spectroscopy Tom Waters, Hin-Koon Woo, Xue-Bin Wang, and Lai-Sheng Wang pp 4282–4291 DOI: 10.1021/ja056342s Supporting Info

CP/MAS 13C NMR Characterization of the Isomeric States and Intermolecular Packing in Tris(8-hydroxyquinoline) Aluminum(III) (Alq3) Hironori Kaji, Yasunari Kusaka, Goro Onoyama, and Fumitaka Horii pp 4292–4297 DOI: 10.1021/ja0565774 Supporting Info

Tandem Chain Walking Polymerization and Atom Transfer Radical Polymerization for Efficient Synthesis of Dendritic Nanoparticles for Bioconjugation Guanghui Chen, Devan Huynh, Philip L. Felgner, and Zhibin Guan pp 4298–4302 DOI: 10.1021/ja0573864 Supporting Info

Spiropyran-Based Photochromic Polymer Nanoparticles with Optically Switchable Luminescence Ming-Qiang Zhu, Linyong Zhu, Jason J. Han, Wuwei Wu, James K. Hurst, and Alexander D. Q. Li pp 4303–4309 DOI: 10.1021/ja0567642

Monitoring Temporal Evolution of Silicate Species during Hydrolysis and Condensation of Silicates Using Mass Spectrometry Stefan A. Pelster, Wolfgang Schrader, and Ferdi Schüth pp 4310–4317 DOI: 10.1021/ja057423r

Nature of the Bottom t2g-Block Bands of Layered Perovskites. Implications for the Transport Properties of Phases Where These Bands Are Partially Filled Gerard Tobias and Enric Canadell pp 4318–4329 DOI: 10.1021/ja0572755 Supporting Info

NO Reductase Activity of the Tetraheme Cytochrome c554 of Nitrosomonas europaea Anup K. Upadhyay, Alan B. Hooper, and Michael P. Hendrich pp 4330–4337 DOI: 10.1021/ja055183+ Supporting Info

Interplay of Stereoelectronic and Enviromental Effects in Tuning the Structural and Magnetic Properties of a Prototypical Spin Probe:  Further Insights from a First Principle Dynamical Approach Michele Pavone, Paola Cimino, Filippo De Angelis, and Vincenzo Barone pp 4338–4347 DOI: 10.1021/ja0574872 Supporting Info

Mechanism of Pd(OAc)2/DMSO-Catalyzed Aerobic Alcohol Oxidation:  Mass-Transfer-Limitation Effects and Catalyst Decomposition Pathways Bradley A. Steinhoff and Shannon S. Stahl pp 4348–4355 DOI: 10.1021/ja057914b Supporting Info

Electron Donor−Bridge−Acceptor Molecules with Bridging Nitronyl Nitroxide Radicals:  Influence of a Third Spin on Charge- and Spin-Transfer Dynamics Erin T. Chernick, Qixi Mi, Richard F. Kelley, Emily A. Weiss, Brooks A. Jones, Tobin J. Marks, Mark A. Ratner, and Michael R. Wasielewski pp 4356–4364 DOI: 10.1021/ja0576435 Supporting Info

Excited-State Dynamics of Structurally Characterized [ReI(CO)3(phen)(HisX)]+ (X = 83, 109) Pseudomonas aeruginosa Azurins in Aqueous Solution Ana María Blanco-Rodríguez, Michael Busby, Cristian Grdinaru, Brian R. Crane, Angel J. Di Bilio, Pavel Matousek, Michael Towrie, Brian S. Leigh, John H. Richards, Antonín Vlek, Jr., and Harry B. Gray pp 4365–4370 DOI: 10.1021/ja057451+

Conformational Fluctuations Affect Protein Alignment in Dilute Liquid Crystal Media Martti Louhivuori, Renee Otten, Kresten Lindorff-Larsen, and Arto Annila pp 4371–4376 DOI: 10.1021/ja0576334 Supporting Info

Stereoretentive Elimination and Trans-olefination of the Dicationic Dipalladium Moiety [Pd2Ln]2+ Bound on 1,3,5-Trienes Tetsuro Murahashi, Hiromitsu Nakashima, Tomoki Nagai, Yukari Mino, Taketoshi Okuno, M. Abdul Jalil, and Hideo Kurosawa pp 4377–4388 DOI: 10.1021/ja0576740 Supporting Info

Site-Directed Parallel Spin-Labeling and Paramagnetic Relaxation Enhancement in Structure Determination of Membrane Proteins by Solution NMR Spectroscopy Binyong Liang, John H. Bushweller, and Lukas K. Tamm pp 4389–4397 DOI: 10.1021/ja0574825 Supporting Info

Three-Dimensional Structure of the Water-Insoluble Protein Crambin in Dodecylphosphocholine Micelles and Its Minimal Solvent-Exposed Surface Hee-Chul Ahn, Nenad Juranić, Slobodan Macura, and John L. Markley pp 4398–4404 DOI: 10.1021/ja057773d Supporting Info

Hyperbaric Laser Chemical Vapor Deposition of Carbon Fibers from the 1-Alkenes, 1-Alkynes, and Benzene James L. Maxwell, Mats Boman, Robert W. Springer, Jaikumar Narayan, and Saiprasanna Gnanavelu pp 4405–4413 DOI: 10.1021/ja057666j

A Study of DNA Tube Formation Mechanisms Using 4-, 8-, and 12-Helix DNA Nanostructures Yonggang Ke, Yan Liu, Junping Zhang, and Hao Yan pp 4414–4421 DOI: 10.1021/ja058145z Supporting Info

Vibrational Markers for the Open-Shell Character of Transition Metal Bis-dithiolenes:  An Infrared, Resonance Raman, and Quantum Chemical Study Taras Petrenko, Kallol Ray, Karl E. Wieghardt, and Frank Neese pp 4422–4436 DOI: 10.1021/ja0578451 Supporting Info

Molecular Probe Location in Reverse Micelles Determined by NMR Dipolar Interactions Debbie C. Crans, Christopher D. Rithner, Bharat Baruah, Bridget L. Gourley, and Nancy E. Levinger pp 4437–4445 DOI: 10.1021/ja0583721 Supporting Info

Molecular Wiring of Nanocrystals:  NCS-Enhanced Cross-Surface Charge Transfer in Self-Assembled Ru-Complex Monolayer on Mesoscopic Oxide Films Qing Wang, Shaik M. Zakeeruddin, Md. K. Nazeeruddin, Robin Humphry-Baker, and Michael Grätzel pp 4446–4452 DOI: 10.1021/ja058616h Supporting Info

Efficient Ribosomal Peptidyl Transfer Critically Relies on the Presence of the Ribose 2‘-OH at A2451 of 23S rRNA Matthias D. Erlacher, Kathrin Lang, Brigitte Wotzel, Renate Rieder, Ronald Micura, and Norbert Polacek pp 4453–4459 DOI: 10.1021/ja0588454 Supporting Info

Total Synthesis and Biological Evaluation of Halipeptins A and D and Analogues K. C. Nicolaou, Dimitrios E. Lizos, David W. Kim, Daniel Schlawe, Rita G. de Noronha, Deborah A. Longbottom, Manuela Rodriquez, Mariarosaria Bucci, and Giuseppe Cirino pp 4460–4470 DOI: 10.1021/ja060064v Supporting Info

Copolymerization Kinetics of Methyl Methacrylate−Styrene Obtained by PLP-MALDI-ToF-MS Robin X. E. Willemse and Alex M. van Herk pp 4471–4480 DOI: 10.1021/ja0579715 Supporting Info

Kinetic Resolution Displaying Zeroth Order Dependence on Substrate Consumption:  Copper-Catalyzed Asymmetric Alcoholysis of Azlactones Makoto Tokunaga, Junya Kiyosu, Yasushi Obora, and Yasushi Tsuji pp 4481–4486 DOI: 10.1021/ja058112j Supporting Info

Propeller-like Hydrogen-Bonded Banana−Melamine Complexes Inducing Helical Supramolecular Organizations Joaquín Barberá, Laura Puig, Pilar Romero, José Luis Serrano, and Teresa Sierra pp 4487–4492 DOI: 10.1021/ja0585477 Supporting Info

Potentials of Mean Force for Acetylcholine Unbinding from the Alpha7 Nicotinic Acetylcholine Receptor Ligand-Binding Domain  [J. Am. Chem. Soc. 2006, 128, 3019−3026].  Deqiang Zhang, Justin Gullingsrud, and J. Andrew McCammon p 4493 DOI: 10.1021/ja069959y Supporting Info

Bioactive Marine Natural Products By D. S. Bhakuni (Central Drug Research Institute, Lucknow, India) and D. S. Rawat (University of Delhi, Delhi, India). Springer:  New York and Anamaya Publishers:  New Delhi. 2005. xv + 382 pp. $159.00. ISBN 1-4020-3472-5. Carole A. Bewley p 4494 DOI: 10.1021/ja059852v

Overviews of Recent Research on Energetic Materials, Advanced Series in Physical Chemistry, Volume 16 Edited by Robert W. Shaw (Army Research Office), Thomas B. Brill (University of Delaware), and Donald L. Thompson (University of Missouri). World Scientific Publishing Co. Pte. Ltd:  Singapore. 2005. xx + 510 pp. $92.00. ISBN 98-256-171-4. G. K. Surya Prakash pp 4494–4495 DOI: 10.1021/ja0598513

Catalysis of Organic Reactions Edited by John R. Sowa, Jr. (Seton Hall University). CRC Press (an imprint of Taylor & Francis Group):  Boca Raton, FL. 2005. xvi + 574 pp. $199.95. ISBN 0-8247-2729-0. p 4495 DOI: 10.1021/ja0598558

Chemistry of Peptide Synthesis By N. Leo Benoiton (University of Ottawa). CRC Press (an imprint of Taylor & Frances Group):  Boca Raton, FL. 2006. xiv + 290 pp. $139.95. ISBN 1-57444-454-9. p 4495 DOI: 10.1021/ja059857s

Oxidation and Antioxidants in Organic Chemistry and Biology By Evgeny T. Denisov (Russian Academy of Sciences, Chernogolovka, Russia) and Igor B. Afanas'ev (Vitamin Research Institute, Moscow, Russia). CRC Press (an imprint of Taylor & Francis Group):  Boca Raton, FL. 2005. xxxviii + 982 pp. $199.95. ISBN 0-8247-5356-9. Gerald B. Hammond pp 4495–4496 DOI: 10.1021/ja059854f

Issue 14

Supramolecular Probe for Bicarbonate Exhibiting Anomalous Pyrene Fluorescence in Aqueous Media Iwao Suzuki, Mihoko Ui, and Akiyo Yamauchi pp 4498–4499 DOI: 10.1021/ja055772f Supporting Info

Fluorescent Sensors for Organophosphorus Nerve Agent Mimics Trevor J. Dale and Julius Rebek, Jr. pp 4500–4501 DOI: 10.1021/ja057449i Supporting Info

Controlled Encapsidation of Gold Nanoparticles by a Viral Protein Shell LiNa Loo, Richard H. Guenther, Veronica R. Basnayake, Steven A. Lommel, and Stefan Franzen pp 4502–4503 DOI: 10.1021/ja057332u Supporting Info

Rigid Molecular Architectures That Comprise a 1,3,5-Trisubstituted Benzene Core and Three Oligoaryleneethynylene Arms:  Light-Emitting Characteristics and π Conjugation between the Arms Yoshihiro Yamaguchi, Takanori Ochi, Satoshi Miyamura, Takahiro Tanaka, Shigeya Kobayashi, Tateaki Wakamiya, Yoshio Matsubara, and Zen-ichi Yoshida pp 4504–4505 DOI: 10.1021/ja057751r Supporting Info

Alkenylsilane Effects on Organotitanium-Catalyzed Ethylene Polymerization. Toward Simultaneous Polyolefin Branch and Functional Group Introduction Smruti B. Amin and Tobin J. Marks pp 4506–4507 DOI: 10.1021/ja057947r Supporting Info

From Gene to HSQC in under Five Hours:  High-Throughput NMR Proteomics Shiranthi Keppetipola, Wieslaw Kudlicki, Bao D. Nguyen, Xi Meng, Kevin J. Donovan, and A. J. Shaka pp 4508–4509 DOI: 10.1021/ja0580791 Supporting Info

Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol Orla M. Wilson, Marc R. Knecht, Joaquin C. Garcia-Martinez, and Richard M. Crooks pp 4510–4511 DOI: 10.1021/ja058217m Supporting Info

Aerosol-Assisted Self-Assembly of Single-Crystal Core/Nanoporous Shell Particles as Model Controlled Release Capsules Xingmao Jiang and C. Jeffrey Brinker pp 4512–4513 DOI: 10.1021/ja058260+ Supporting Info

Orbital Energetics and Molecular Recognition Aaron George, Yonas Abraham, Carlo Sbraccia, Vishali Mogallapu, Rebecca Harris, Roberto Car, and Jeffrey D. Schmitt pp 4514–4515 DOI: 10.1021/ja057826r Supporting Info

A Simple Tagging System for Protein Encapsulation Florian P. Seebeck, Kenneth J. Woycechowsky, Wei Zhuang, Jürgen P. Rabe, and Donald Hilvert pp 4516–4517 DOI: 10.1021/ja058363s Supporting Info

Electron Hopping Dynamics in Au38 Nanoparticle Langmuir Monolayers at the Air/Water Interface Junhyung Kim and Dongil Lee pp 4518–4519 DOI: 10.1021/ja058395f Supporting Info

A Unidirectional Energy Transfer Cascade Process in a Ruthenium Junction Self-Assembled by α- and β-Cyclodextrins Jonathan A. Faiz, René M. Williams, Maria José J. Pereira Silva, Luisa De Cola, and Zoe Pikramenou pp 4520–4521 DOI: 10.1021/ja058541h Supporting Info

Engineering a Rhodopsin Protein Mimic Rachael M. Crist, Chrysoula Vasileiou, Montserrat Rabago-Smith, James H. Geiger, and Babak Borhan pp 4522–4523 DOI: 10.1021/ja058591m Supporting Info

A Second Transition State for Chain Transfer to Monomer in Olefin Polymerization Promoted by Group 4 Metal Catalysts Giovanni Talarico and Peter H. M. Budzelaar pp 4524–4525 DOI: 10.1021/ja0586034 Supporting Info

Conformational Flexibility in the Peripheral Site of Torpedo californica Acetylcholinesterase Revealed by the Complex Structure with a Bifunctional Inhibitor Jacques Ph. Colletier, Benoît Sanson, Florian Nachon, Emanuele Gabellieri, Caterina Fattorusso, Giuseppe Campiani, and Martin Weik pp 4526–4527 DOI: 10.1021/ja058683b Supporting Info

Metal-Chelate Dye-Controlled Organization of Cd32S14(SPh)404- Nanoclusters into Three-Dimensional Molecular and Covalent Open Architecture Nanfeng Zheng, Haiwei Lu, Xianhui Bu, and Pingyun Feng pp 4528–4529 DOI: 10.1021/ja060006+ Supporting Info

Unexpected Deacetylation Mechanism Suggested by a Density Functional Theory QM/MM Study of Histone-Deacetylase-Like Protein Clémence Corminboeuf, Po Hu, Mark E. Tuckerman, and Yingkai Zhang pp 4530–4531 DOI: 10.1021/ja0600882 Supporting Info

One-Dimensional Energy/Electron Transfer through a Helical Channel Oh-Kil Kim, Jongtae Je, and Joseph S. Melinger pp 4532–4533 DOI: 10.1021/ja060122c Supporting Info

Multi-Frequency High-Field EPR Study of Iron Centers in Malarial Pigments Andrzej Sienkiewicz, J. Krzystek, Bertrand Vileno, Guillaume Chatain, Aaron J. Kosar, D. Scott Bohle, and László Forró pp 4534–4535 DOI: 10.1021/ja058420h Supporting Info

A Mechanism-Based Inactivator for Histone Demethylase LSD1 Jeffrey C. Culhane, Lawrence M. Szewczuk, Xin Liu, Guoping Da, Ronen Marmorstein, and Philip A. Cole pp 4536–4537 DOI: 10.1021/ja0602748 Supporting Info

New Helical Foldamers:  Heterogeneous Backbones with 1:2 and 2:1 α:β-Amino Acid Residue Patterns Margaret A. Schmitt, Soo Hyuk Choi, Ilia A. Guzei, and Samuel H. Gellman pp 4538–4539 DOI: 10.1021/ja060281w Supporting Info

Spatially Selective Guided Growth of High-Coverage Arrays and Random Networks of Single-Walled Carbon Nanotubes and Their Integration into Electronic Devices Coskun Kocabas, Moonsub Shim, and John A. Rogers pp 4540–4541 DOI: 10.1021/ja0603150 Supporting Info

Transglutaminase-Catalyzed Site-Specific Conjugation of Small-Molecule Probes to Proteins in Vitro and on the Surface of Living Cells Chi-Wang Lin and Alice Y. Ting pp 4542–4543 DOI: 10.1021/ja0604111 Supporting Info

Formation of Highly Ordered Mesoporous Titania Films Consisting of Crystalline Nanopillars with Inverse Mesospace by Structural Transformation Chia-Wen Wu, Tetsu Ohsuna, Makoto Kuwabara, and Kazuyuki Kuroda pp 4544–4545 DOI: 10.1021/ja060453p Supporting Info

Total Synthesis of Enantiopure β-d-Mannosyl Phosphomycoketides from Mycobacterium tuberculosis Ruben P. van Summeren, D. Branch Moody, Ben L. Feringa, and Adriaan J. Minnaard pp 4546–4547 DOI: 10.1021/ja060499i Supporting Info

Highly Luminescent Gels and Mesogens Based on Elaborated Borondipyrromethenes Franck Camerel, Laure Bonardi, Marc Schmutz, and Raymond Ziessel pp 4548–4549 DOI: 10.1021/ja0606069 Supporting Info

Light-Driven OR and XOR Programmable Chemical Logic Gates Konrad Szaciłowski, Wojciech Macyk, and Grażyna Stochel pp 4550–4551 DOI: 10.1021/ja060694x

Electrochemical and Homogeneous Proton-Coupled Electron Transfers:  Concerted Pathways in the One-Electron Oxidation of a Phenol Coupled with an Intramolecular Amine-Driven Proton Transfer Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 4552–4553 DOI: 10.1021/ja060527x Supporting Info

Enabling Gate Dielectric Design for All Solution-Processed, High-Performance, Flexible Organic Thin-Film Transistors Ping Liu, Yiliang Wu, Yuning Li, Beng S. Ong, and Shiping Zhu pp 4554–4555 DOI: 10.1021/ja060620l Supporting Info

Triazabicyclodecene:  A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters Russell C. Pratt, Bas G. G. Lohmeijer, David A. Long, Robert M. Waymouth, and James L. Hedrick pp 4556–4557 DOI: 10.1021/ja060662+ Supporting Info

Hydroacylation of Activated Ketones Catalyzed by N-Heterocyclic Carbenes Audrey Chan and Karl A. Scheidt pp 4558–4559 DOI: 10.1021/ja060833a Supporting Info

Microcontainers with Electrochemically Reversible Permeability Dmitry G. Shchukin, Karen Köhler, and Helmuth Möhwald pp 4560–4561 DOI: 10.1021/ja061028z Supporting Info

Magnetic Tuning of the Electrochemical Reactivity through Controlled Surface Orientation of Catalytic Nanowires Joseph Wang, Matteo Scampicchio, Rawiwan Laocharoensuk, Federica Valentini, Olga González-García, and Jared Burdick pp 4562–4563 DOI: 10.1021/ja061070u Supporting Info

Metal-Mediated Efficient Synthesis, Structural Characterization, and Skeletal Rearrangement of Octasubstituted Semibullvalenes Chao Wang, Jian Yuan, Guotao Li, Zitao Wang, Shiwei Zhang, and Zhenfeng Xi pp 4564–4565 DOI: 10.1021/ja0579208 Supporting Info

Regiospecific Radical Polymerization of a Tetrasubstituted Ethylene Monomer with Molecular Oxygen for the Synthesis of a New Degradable Polymer Akikazu Matsumoto and Shuji Taketani pp 4566–4567 DOI: 10.1021/ja0580385 Supporting Info

New Chiral Synthons for Efficient Introduction of Bispropionates via Stereospecific Oxonia−Cope Rearrangements Yi-Hung Chen and Frank E. McDonald pp 4568–4569 DOI: 10.1021/ja061082f Supporting Info

In situ Synthesis of Mixed-Valent Manganese Oxide Nanocrystals:  An In situ Synchrotron X-ray Diffraction Study Xiong-Fei Shen, Yun-Shuang Ding, Jonathan C. Hanson, Mark Aindow, and Steven L. Suib pp 4570–4571 DOI: 10.1021/ja058456+ Supporting Info

The Genetic Incorporation of a Distance Probe into Proteins in Escherichia coli Meng-Lin Tsao, Daniel Summerer, Youngha Ryu, and Peter G. Schultz pp 4572–4573 DOI: 10.1021/ja058262u Supporting Info

Nanoscale Phase Separation in Mixed Poly(tert-butyl acrylate)/Polystyrene Brushes on Silica Nanoparticles under Equilibrium Melt Conditions Bin Zhao and Lei Zhu pp 4574–4575 DOI: 10.1021/ja058560r Supporting Info

[3,3]-Rearrangements of Phosphonium Ylides Marcelle L. Ferguson, Todd D. Senecal, Todd M. Groendyke, and Anna K. Mapp pp 4576–4577 DOI: 10.1021/ja058746q Supporting Info

Amino Acid-Bearing ROMP Polymers with a Stereoregular Backbone Jae Chul Lee, Kathlyn A. Parker, and Nicole S. Sampson pp 4578–4579 DOI: 10.1021/ja058801v Supporting Info

Cytochrome P450 Compound I Martin Newcomb, Rui Zhang, R. Esala P. Chandrasena, James A. Halgrimson, John H. Horner, Thomas M. Makris, and Stephen G. Sligar pp 4580–4581 DOI: 10.1021/ja060048y Supporting Info

Translucent Thin Film Fe2O3 Photoanodes for Efficient Water Splitting by Sunlight:  Nanostructure-Directing Effect of Si-Doping Ilkay Cesar, Andreas Kay, José A. Gonzalez Martinez, and Michael Grätzel pp 4582–4583 DOI: 10.1021/ja060292p Supporting Info

1,1‘-Binaphthyl-2,2‘-diyl Phosphoroselenoyl Chloride as a Chiral Molecular Tool for the Preparation of Enantiomerically Pure Alcohols and Amines Toshiaki Murai, Daichi Matsuoka, and Ken Morishita pp 4584–4585 DOI: 10.1021/ja060308b Supporting Info

Enantioselective Synthesis of Axially Chiral Anilides through Rhodium-Catalyzed [2+2+2] Cycloaddition of 1,6-Diynes with Trimethylsilylynamides Ken Tanaka, Kenzo Takeishi, and Keiichi Noguchi pp 4586–4587 DOI: 10.1021/ja060348f Supporting Info

Direct Boronation of Allyl Alcohols with Diboronic Acid Using Palladium Pincer-Complex Catalysis. A Remarkably Facile Allylic Displacement of the Hydroxy Group under Mild Reaction Conditions Vilhelm J. Olsson, Sara Sebelius, Nicklas Selander, and Kálmán J. Szabó pp 4588–4589 DOI: 10.1021/ja060468n Supporting Info

Molybdenum-Catalyzed Asymmetric Allylation of 3-Alkyloxindoles:  Application to the Formal Total Synthesis of (−)-Physostigmine Barry M. Trost and Yong Zhang pp 4590–4591 DOI: 10.1021/ja060560j Supporting Info

Synthesis of Substituted Pyridine Derivatives via the Ruthenium-Catalyzed Cycloisomerization of 3-Azadienynes Mohammad Movassaghi and Matthew D. Hill pp 4592–4593 DOI: 10.1021/ja060626a Supporting Info

Catalytic Enantioselective O−H Insertion Reactions Thomas C. Maier and Gregory C. Fu pp 4594–4595 DOI: 10.1021/ja0607739 Supporting Info

C−H Bond Activation and Subsequent C−C Bond Formation Promoted by Osmium:  2-Vinylpyridine−Acetylene Couplings Miguel A. Esteruelas, Francisco J. Fernández-Alvarez, Montserrat Oliván, and Enrique Oñate pp 4596–4597 DOI: 10.1021/ja060901t Supporting Info

The Effect of Carbonyl Substitution on the Strain Energy of Small Ring Compounds and Their Six-Member Ring Reference Compounds Robert D. Bach and Olga Dmitrenko pp 4598–4611 DOI: 10.1021/ja055086g Supporting Info

Assemblies of Supramolecular Porphyrin Dimers in Pentagonal and Hexagonal Arrays Exhibiting Light-Harvesting Antenna Function Fatin Hajjaj, Zin Seok Yoon, Min-Chul Yoon, Jaehong Park, Akiharu Satake, Dongho Kim, and Yoshiaki Kobuke pp 4612–4623 DOI: 10.1021/ja0583214 Supporting Info

Unprecedented Alkene Complex of Zinc(II):  Structures and Bonding of Divinylzinc Complexes Alfred Wooten, Patrick J. Carroll, Aaron G. Maestri, and Patrick J. Walsh pp 4624–4631 DOI: 10.1021/ja058700x Supporting Info

Unexpected H2O-Induced Ar−X Activation with Trifluoromethylpalladium(II) Aryls Vladimir V. Grushin and William J. Marshall pp 4632–4641 DOI: 10.1021/ja0602389 Supporting Info

New Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions Genia Sklute and Ilan Marek pp 4642–4649 DOI: 10.1021/ja060498q Supporting Info

Density Functional Theory Analysis of the Reaction Pathway for Methane Oxidation to Acetic Acid Catalyzed by Pd2+ in Sulfuric Acid Shaji Chempath and Alexis T. Bell pp 4650–4657 DOI: 10.1021/ja055756i Supporting Info

Morphology Phase Diagram of Ultrathin Anatase TiO2 Films Templated by a Single PS-b-PEO Block Copolymer Ya-Jun Cheng and Jochen S. Gutmann, pp 4658–4674 DOI: 10.1021/ja0562853 Supporting Info

Concepts in Receptor Optimization:  Targeting the RGD Peptide Wei Chen, Chia-en Chang, and Michael K. Gilson pp 4675–4684 DOI: 10.1021/ja056600l Supporting Info

Understanding GFP Posttranslational Chemistry:  Structures of Designed Variants that Achieve Backbone Fragmentation, Hydrolysis, and Decarboxylation David P. Barondeau, Carey J. Kassmann, John A. Tainer, and Elizabeth D. Getzoff pp 4685–4693 DOI: 10.1021/ja056635l Supporting Info

Tandem Mass Spectrometry of Intact GroEL−Substrate Complexes Reveals Substrate-Specific Conformational Changes in the trans Ring Esther van Duijn, Douglas A. Simmons, Robert H. H. van den Heuvel, Patrick J. Bakkes, Harm van Heerikhuizen, Ron M. A. Heeren, Carol V. Robinson, Saskia M. van der Vies, and Albert J. R. Heck pp 4694–4702 DOI: 10.1021/ja056756l

Reductive Bergman-Type Cyclizations of Cross-Conjugated Enediynes to Fulvene and Fulvalene Anions:  The Role of the Substituent Noach Treitel, Lior Eshdat, Tuvia Sheradsky, Patrick M. Donovan, Rik R. Tykwinski, Lawrence T. Scott, Henning Hopf, and Mordecai Rabinovitz pp 4703–4709 DOI: 10.1021/ja0566477 Supporting Info

A Redox-Active Two-Dimensional Coordination Polymer:  Preparation of Silver and Gold Nanoparticles and Crystal Dynamics on Guest Removal Myunghyun Paik Suh, Hoi Ri Moon, Eun Young Lee, and Seung Yeon Jang pp 4710–4718 DOI: 10.1021/ja056963l Supporting Info

Direct Hydrogen-Atom Abstraction by Activated Bleomycin:  An Experimental and Computational Study Andrea Decker, Marina S. Chow, Jyllian N. Kemsley, Nicolai Lehnert, and Edward I. Solomon pp 4719–4733 DOI: 10.1021/ja057378n Supporting Info

Stochastic Modeling of CW-ESR Spectroscopy of [60]Fulleropyrrolidine Bisadducts with Nitroxide Probes Antonino Polimeno, Mirco Zerbetto, Lorenzo Franco, Michele Maggini, and Carlo Corvaja pp 4734–4741 DOI: 10.1021/ja057414i Supporting Info

Tuning Anisotropy Barriers in a Family of Tetrairon(III) Single-Molecule Magnets with an S = 5 Ground State Stefania Accorsi, Anne-Laure Barra, Andrea Caneschi, Guillaume Chastanet, Andrea Cornia, Antonio C. Fabretti, Dante Gatteschi, Cecilia Mortalò, Emiliano Olivieri, Francesca Parenti, Patrick Rosa, Roberta Sessoli, Lorenzo Sorace, Wolfgang Wernsdorfer, and Laura Zobbi pp 4742–4755 DOI: 10.1021/ja0576381 Supporting Info

Single-Site Homogeneous and Heterogeneized Gold(III) Hydrogenation Catalysts:  Mechanistic Implications Aleix Comas-Vives, C. González-Arellano, A. Corma, M. Iglesias, F. Sánchez, and Gregori Ujaque pp 4756–4765 DOI: 10.1021/ja057998o Supporting Info

Reaction Progress of Chromophore Biogenesis in Green Fluorescent Protein Liping Zhang, Hetal N. Patel, Jason W. Lappe, and Rebekka M. Wachter pp 4766–4772 DOI: 10.1021/ja0580439 Supporting Info

Electron Transfer from Sodium to Oriented Nitromethane, CH3NO2:  Probing the Spatial Extent of Unoccupied Orbitals Philip R. Brooks, Peter W. Harland, and Crystal E. Redden pp 4773–4778 DOI: 10.1021/ja058206t Supporting Info

Intramolecular Electron Transfer through the 20-Position of a Chlorophyll a Derivative:  An Unexpectedly Efficient Conduit for Charge Transport Richard F. Kelley, Michael J. Tauber, and Michael R. Wasielewski pp 4779–4791 DOI: 10.1021/ja058233j Supporting Info

Dynamics and Mechanism of Bridge-Dependent Charge Separation in Pyrenylurea−Nitrobenzene π-Stacked Protophanes Frederick D. Lewis, Pierre Daublain, Grace B. Delos Santos, Weizhong Liu, Arpine M. Asatryan, Shriaz A. Markarian, Torsten Fiebig, Milen Raytchev, and Qiang Wang pp 4792–4801 DOI: 10.1021/ja058050x Supporting Info

Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+ Complexes in the Gas Phase:  Comparison with Theory Gary S. Groenewold, Anita K. Gianotto, Kevin C. Cossel, Michael J. Van Stipdonk, David T. Moore, Nick Polfer, Jos Oomens, Wibe A. de Jong, and Lucas Visscher pp 4802–4813 DOI: 10.1021/ja058106n Supporting Info

Probing Lipid Vesicles by Bimolecular Association and Dissociation Trajectories of Single Molecules Feng Gao, Erwen Mei, Manho Lim, and Robin M. Hochstrasser pp 4814–4822 DOI: 10.1021/ja058098a

Synthesis of Neoglycopolymers by a Combination of “Click Chemistry” and Living Radical Polymerization Vincent Ladmiral, Giuseppe Mantovani, Guy J. Clarkson, Solene Cauet, Jacob L. Irwin, and David M. Haddleton pp 4823–4830 DOI: 10.1021/ja058364k Supporting Info

Molecular Tweezer and Clip in Aqueous Solution:  Unexpected Self-Assembly, Powerful Host−Guest Complex Formation, Quantum Chemical 1H NMR Shift Calculation Frank-Gerrit Klärner, Björn Kahlert, Anke Nellesen, Jan Zienau, Christian Ochsenfeld, and Thomas Schrader pp 4831–4841 DOI: 10.1021/ja058410g Supporting Info

[Fe(bpym)(CN)4]-: A New Building Block for Designing Single-Chain Magnets Luminita Marilena Toma, Rodrigue Lescouëzec, Jorge Pasán, Catalina Ruiz-Pérez, Jacqueline Vaissermann, Joan Cano, Rosa Carrasco, Wolfgang Wernsdorfer, Francesc Lloret, and Miguel Julve pp 4842–4853 DOI: 10.1021/ja058030v Supporting Info

Surface-Rolling Molecules Yasuhiro Shirai, Andrew J. Osgood, Yuming Zhao, Yuxing Yao, Lionel Saudan, Hanbiao Yang, Chiu Yu-Hung, Lawrence B. Alemany, Takashi Sasaki, Jean-François Morin, Jason M. Guerrero, Kevin F. Kelly, and James M. Tour pp 4854–4864 DOI: 10.1021/ja058514r Supporting Info

A Molecular Full-Adder and Full-Subtractor, an Additional Step toward a Moleculator David Margulies, Galina Melman, and Abraham Shanzer pp 4865–4871 DOI: 10.1021/ja058564w

Synthesis, Anion Exchange, and Delamination of Co−Al Layered Double Hydroxide:  Assembly of the Exfoliated Nanosheet/Polyanion Composite Films and Magneto-Optical Studies Zhaoping Liu, Renzhi Ma, Minoru Osada, Nobuo Iyi, Yasuo Ebina, Kazunori Takada, and Takayoshi Sasaki pp 4872–4880 DOI: 10.1021/ja0584471 Supporting Info

Benzonitrile Extrusion from Molybdenum(IV) Ketimide Complexes Obtained via Radical C−E (E = O, S, Se) Bond Formation:  Toward a New Nitrogen Atom Transfer Reaction Arjun Mendiratta, Christopher C. Cummins, Olga P. Kryatova, Elena V. Rybak-Akimova, James E. McDonough, and Carl D. Hoff pp 4881–4891 DOI: 10.1021/ja0587796 Supporting Info

Nanostructuration of Phenylenevinylenediimide-Bridged Silsesquioxane:  From Electroluminescent Molecular J-Aggregates to Photoresponsive Polymeric H-Aggregates Olivier J. Dautel, Guillaume Wantz, Robert Almairac, David Flot, Lionel Hirsch, Jean-Pierre Lere-Porte, Jean-Paul Parneix, Françoise Serein-Spirau, Laurence Vignau, and Joël J. E. Moreau pp 4892–4901 DOI: 10.1021/ja058680z Supporting Info

Internal Water Molecules and Magnetic Relaxation in Agarose Gels Fabian Vaca Chávez, Erik Persson, and Bertil Halle pp 4902–4910 DOI: 10.1021/ja058837n

Synthesis and Photovoltaic Properties of Two-Dimensional Conjugated Polythiophenes with Bi(thienylenevinylene) Side Chains Jianhui Hou, Zhan'ao Tan, Yong Yan, Youjun He, Chunhe Yang, and Yongfang Li pp 4911–4916 DOI: 10.1021/ja060141m Supporting Info

Synthesis of an Artificial Cell Surface Receptor that Enables Oligohistidine Affinity Tags to Func-tion as Metal-Dependent Cell-Penetrating Peptides [J. Am. Chem. Soc. 2006, 128, 386−387]. Siwarutt Boonyarattanakalin, Sonalee Athavankar, Qi Sun, and Blake R. Peterson p 4917 DOI: 10.1021/ja0612091

Artificial Enzymes Edited by Ronald Breslow (Columbia University). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xii + 182 pp. $99.95. ISBN 3-527-31165-3. Timothy Snowden p 4918 DOI: 10.1021/ja0598412

Analytical Techniques in DNA Sequencing Edited by Brian K. Nunnally (Wyeth Laboratories, Durham, NC). Taylor & Francis Group:  Boca Raton, FL. 2005. xii + 238 pp. $189.95. ISBN 0-8247-5342-9. p 4918 DOI: 10.1021/ja0598661

Computational Methods in Photochemistry. Molecular and Supramolecular Photochemistry, Volume 13 Edited by Andrei G. Kutateladze (University of Denver). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, 2005. x + 518 pp. $179.96. ISBN 0-8247-5345-3. Steven M. Bachrach pp 4918–4919 DOI: 10.1021/ja0598715

Quantitation of Amino Acids and Amines by Chromatography:  Methods and Protocols. Journal of the Chromatography Library, Volume 70 Edited by Ibolya Molnár-Perl (L. Eötvös University, Hungary). Elsevier B. V.:  Amsterdam. 2005. xii + 654 pp. $274. ISBN 0-444-52050-3. Jaycoda S. Major p 4919 DOI: 10.1021/ja059837q

Macromolecules Containing Metal and Metal-Like Elements, Volume 7:  Nanoscale Interactions of Metal-Containing Polymers Edited by Alaa S. Abd-El-Aziz (The University of Winnipeg), Charles E. Carraher Jr. (Florida Atlantic University), Charles U. Pittman Jr. (Mississippi State University), and Martel Zeldin (University of Richmond). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xvi + 234 pp. $150. ISBN 0-471-68440-6. David S. Glueck p 4919 DOI: 10.1021/ja059879e

Theory and Applications of Computational Chemistry:  The First Forty Years Edited by Clifford E. Dykstra (Indiana University-Purdue University, Indianapolis, IN, USA), Gernot Frenking (Phillips-Universität Marburg, Germany), Kwang S. Kim (Pohang University of Science and Technology, Pohang, Republic of Korea), and Gustavo E. Scuseria (Rice University, Houston, TX, USA). Elsevier:  Amsterdam. 2005. xxviii + 1308 pp. $110.00. ISBN 0-444-51904-1. André D. Bandrauk pp 4919–4920 DOI: 10.1021/ja059883q

Issue 15

Resolving Electron Transfer Kinetics at the Nanocrystal/Solution Interface Peter Liljeroth and Bernadette M. Quinn pp 4922–4923 DOI: 10.1021/ja057474o Supporting Info

Complexation, Structure, and Superoxide Dismutase Activity of the Imidazolate-Bridged Dinuclear Copper Moiety with β-Cyclodextrin and Its Guanidinium-Containing Derivative Heng Fu, Ying-Hua Zhou, Wei-Lin Chen, Zhuo-Ga Deqing, Ming-Liang Tong, Liang-Nian Ji, and Zong-Wan Mao pp 4924–4925 DOI: 10.1021/ja057717c Supporting Info

A Photo-Hydrogen-Evolving Molecular Device Driving Visible-Light-Induced EDTA-Reduction of Water into Molecular Hydrogen Hironobu Ozawa, Masa-aki Haga, and Ken Sakai pp 4926–4927 DOI: 10.1021/ja058087h Supporting Info

Gate-Planarized Low-Operating Voltage Organic Field-Effect Transistors Enabled by Hot Polymer Pressing/Embedding of Conducting Metal Lines Antonio Facchetti, Myung-Han Yoon, and Tobin J. Marks pp 4928–4929 DOI: 10.1021/ja058266z Supporting Info

Experimental Investigation of Particle-Assisted Wetting Ailin Ding and Werner A. Goedel pp 4930–4931 DOI: 10.1021/ja058293p

Direct Nucleophilic Acylation of Nitroalkenes Promoted by a Fluoride Anion/Thiourea Combination Anita E. Mattson, Andrea M. Zuhl, Troy E. Reynolds, and Karl A. Scheidt pp 4932–4933 DOI: 10.1021/ja056565i Supporting Info

Reversible Redox Behavior between Stannole Dianion and Bistannole-1,2-Dianion Ryuta Haga, Masaichi Saito, and Michikazu Yoshioka pp 4934–4935 DOI: 10.1021/ja057228c Supporting Info

Enantioselective Total Synthesis of Bistramide A Michael T. Crimmins and Amy C. DeBaillie pp 4936–4937 DOI: 10.1021/ja057686l Supporting Info

A Mixed-Valent Ruthenium−Oxo Oxalato Cluster Na7[Ru4(μ3-O)4(C2O4)6] with Potent Anti-HIV Activities Ella Lai-Ming Wong, Raymond Wai-Yin Sun, Nancy P.-Y. Chung, Chen-Lung Steve Lin, Nianyong Zhu, and Chi-Ming Che pp 4938–4939 DOI: 10.1021/ja057883k Supporting Info

Highly Enantioselective Addition of Me2Zn to Aldehydes Catalyzed by ClCr(Salen) Pier Giorgio Cozzi and Peter Kotrusz pp 4940–4941 DOI: 10.1021/ja057969d Supporting Info

Sequential Rearrangement of 1,2,4Z,7-Tetraenes Involving [1,5]-Hydrogen Migration and Electrocyclization:  An Efficient Synthesis of Eight-Membered Cyclic Compounds Shengming Ma and Zhenhua Gu pp 4942–4943 DOI: 10.1021/ja057985a Supporting Info

Preparation of Highly Dispersed Core/Shell-type Titania Nanocapsules Containing a Single Ag Nanoparticle Hideki Sakai, Takashi Kanda, Hirobumi Shibata, Takahiro Ohkubo, and Masahiko Abe pp 4944–4945 DOI: 10.1021/ja058083c

Synthesis of Indoles via 6π-Electrocyclic Ring Closures of Trienecarbamates Thomas J. Greshock and Raymond L. Funk pp 4946–4947 DOI: 10.1021/ja060282o Supporting Info

Does Urea Denature Hydrophobic Interactions? Maeng-Eun Lee and Nico F. A. van der Vegt pp 4948–4949 DOI: 10.1021/ja058600r Supporting Info

Communicating Chemical Congregation:  A Molecular AND Logic Gate with Three Chemical Inputs as a “Lab-on-a-Molecule” Prototype David C. Magri, Gareth J. Brown, Gareth D. McClean, and A. Prasanna de Silva pp 4950–4951 DOI: 10.1021/ja058295+ Supporting Info

Distributions of Conduction Electrons as Manifested in MAS NMR of Gallium Nitride James P. Yesinowski, Andrew P. Purdy, Huaqiang Wu, Michael G. Spencer, Janet Hunting, and Francis J. DiSalvo pp 4952–4953 DOI: 10.1021/ja0604865 Supporting Info

A Gold Nanoparticle Based Approach for Screening Triplex DNA Binders Min Su Han, Abigail K. R. Lytton-Jean, and Chad A. Mirkin pp 4954–4955 DOI: 10.1021/ja0606475 Supporting Info

Characterization of the Terminal Iron(IV) Imides {[PhBPtBu2(pz‘)]FeIVNAd}+ Christine M. Thomas, Neal P. Mankad, and Jonas C. Peters pp 4956–4957 DOI: 10.1021/ja0604358 Supporting Info

Amphiphilic Gold Nanoparticles with V-Shaped Arms Eugene R. Zubarev, Jun Xu, Arshad Sayyad, and Jacob D. Gibson pp 4958–4959 DOI: 10.1021/ja060782h Supporting Info

A Non-Steroidal Facial Amphiphile Fredric M. Menger and Jennifer L. Sorrells pp 4960–4961 DOI: 10.1021/ja0608747 Supporting Info

Gyroscope-like Molecules Consisting of PdX2/PtX2 Rotators Encased in Three-Spoke Stators:  Synthesis via Alkene Metathesis, and Facile Substitution and Demetalation Agnieszka J. Nawara, Takanori Shima, Frank Hampel, and J. A. Gladysz pp 4962–4963 DOI: 10.1021/ja061044w Supporting Info

The syn-Oriented 2-OH Provides a Favorable Proton Transfer Geometry in 1,2-Diol Monoester Aminolysis:  Implications for the Ribosome Mechanism Miroslav A. Rangelov, Georgi N. Vayssilov, Vihra M. Yomtova, and Dimiter D. Petkov pp 4964–4965 DOI: 10.1021/ja060648x Supporting Info

Organocatalytic Direct Michael Reaction of Ketones and Aldehydes with β-Nitrostyrene in Brine Nobuyuki Mase, Kaori Watanabe, Hidemi Yoda, Kunihiko Takabe, Fujie Tanaka, and Carlos F. Barbas III pp 4966–4967 DOI: 10.1021/ja060338e Supporting Info

Micelle Directed Synthesis of Polyoxometalate Nanoparticles and Their Improved Catalytic Activity for the Aerobic Oxidation of Sulfides Galia Maayan, Ronit Popovitz-Biro, and Ronny Neumann pp 4968–4969 DOI: 10.1021/ja060696h Supporting Info

Correlation between HOMO Alignment and Contact Resistance in Molecular Junctions:  Aromatic Thiols versus Aromatic Isocyanides BongSoo Kim, Jeremy M. Beebe, Yongseok Jun, X.-Y. Zhu, and C. Daniel Frisbie pp 4970–4971 DOI: 10.1021/ja0607990 Supporting Info

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles Nicholas R. Deprez, Dipannita Kalyani, Andrew Krause, and Melanie S. Sanford pp 4972–4973 DOI: 10.1021/ja060809x Supporting Info

Quantitative Measurement of Molecular Diffusion Coefficients by NMR Spectroscopy Shanmin Zhang pp 4974–4975 DOI: 10.1021/ja060659q Supporting Info

Palladium-Catalyzed Intermolecular α-Arylation of Zinc Amide Enolates under Mild Conditions Takuo Hama, Darcy A. Culkin, and John F. Hartwig pp 4976–4985 DOI: 10.1021/ja056076i Supporting Info

Insulin Capture by an Insulin-Linked Polymorphic Region G-Quadruplex DNA Oligonucleotide Adam C. Connor, Kimberley A. Frederick, Elizabeth J. Morgan, and Linda B. McGown pp 4986–4991 DOI: 10.1021/ja056097c Supporting Info

Analysis of Human Telomerase Activity and Function by Two Color Single Molecule Coincidence Fluorescence Spectroscopy Xiaojun Ren, Haitao Li, Richard W. Clarke, David A. Alves, Liming Ying, David Klenerman, and Shankar Balasubramanian pp 4992–5000 DOI: 10.1021/ja056613z Supporting Info

Electronic and Molecular Structure of Photoexcited [RuII(bpy)3]2+ Probed by Picosecond X-ray Absorption Spectroscopy Wojciech Gawelda, Melanie Johnson, Frank M. F. de Groot, Rafael Abela, Christian Bressler, and Majed Chergui pp 5001–5009 DOI: 10.1021/ja054932k Supporting Info

Spectroscopic Studies of the Corrinoid/Iron−Sulfur Protein from Moorella thermoacetica Troy A. Stich, Javier Seravalli, Swarnalatha Venkateshrao, Thomas G. Spiro, Stephen W. Ragsdale, and Thomas C. Brunold pp 5010–5020 DOI: 10.1021/ja054690o Supporting Info

ENDOR of NO-Ligated Cytochrome c‘ Oleg M. Usov, Peter S.-T. Choi, James P. Shapleigh, and Charles P. Scholes pp 5021–5032 DOI: 10.1021/ja055323f Supporting Info

Aryl Transfer between Pd(II) Centers or Pd(IV) Intermediates in Pd-Catalyzed Domino Reactions Diego J. Cárdenas, Belén Martín-Matute, and Antonio M. Echavarren pp 5033–5040 DOI: 10.1021/ja056661j Supporting Info

Microbead Chemical Switches:  An Approach to Detection of Reactive Organophosphate Chemical Warfare Agent Vapors Sandra Bencic-Nagale, Tamar Sternfeld, and David R. Walt pp 5041–5048 DOI: 10.1021/ja057057b

Transition States for Glucopyranose Interconversion Brett E. Lewis, Nankishoresing Choytun, Vern L. Schramm, and Andrew J. Bennet pp 5049–5058 DOI: 10.1021/ja0573054 Supporting Info

The 5-Deoxy-5-methylthio-xylofuranose Residue in Mycobacterial Lipoarabinomannan. Absolute Stereochemistry, Linkage Position, Conformation, and Immunomodulatory Activity Maju Joe, Daniel Sun, Hashem Taha, Gladys C. Completo, Joanne E. Croudace, David A. Lammas, Gurdyal S. Besra, and Todd L. Lowary pp 5059–5072 DOI: 10.1021/ja057373q Supporting Info

Probing Methyl Dynamics from 13C Autocorrelated and Cross-Correlated Relaxation Xu Zhang, Xiaogang Sui, and Daiwen Yang pp 5073–5081 DOI: 10.1021/ja057579r Supporting Info

Dynamics of Low Temperature Induced Water Shedding from AOT Reverse Micelles Alana K. Simorellis, Wade D. Van Horn, and Peter F. Flynn pp 5082–5090 DOI: 10.1021/ja0568401

Synthesis of an Anionically Chargeable, High-Molar-Mass, Second-Generation Dendronized Polymer and the Observation of Branching by Scanning Force Microscopy Edis Kasëmi, Wei Zhuang, Jürgen P. Rabe, Karl Fischer, Manfred Schmidt, Martin Colussi, Helmut Keul, Ding Yi, Helmut Cölfen, and A. Dieter Schlüter pp 5091–5099 DOI: 10.1021/ja057964g Supporting Info

Aluminacyclopropene:  Syntheses, Characterization, and Reactivity toward Terminal Alkynes Hongping Zhu, Rainer B. Oswald, Hongjun Fan, Herbert W. Roesky, Qingjun Ma, Zhi Yang, Hans-Georg Schmidt, Mathias Noltemeyer, Kerstin Starke, and Narayan S. Hosmane pp 5100–5108 DOI: 10.1021/ja057731p Supporting Info

A Biohybrid Dynamic Random Access Memory Jon Sinclair, Daniel Granfeldt, Johan Pihl, Maria Millingen, Per Lincoln, Cecilia Farre, Lena Peterson, and Owe Orwar pp 5109–5113 DOI: 10.1021/ja0580993

Selective Interaction of Large or Charge-Transfer Aromatic Molecules with Metallic Single-Wall Carbon Nanotubes:  Critical Role of the Molecular Size and Orientation Jing Lu, Shigeru Nagase, Xinwei Zhang, Dan Wang, Ming Ni, Yutaka Maeda, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, Takeshi Akasaka, Zhengxiang Gao, Dapeng Yu, Hengqiang Ye, W. N. Mei, and Yunsong Zhou pp 5114–5118 DOI: 10.1021/ja058214+ Supporting Info

The Structure of Liquid Tetrahydrofuran Daniel T. Bowron, John L. Finney, and Alan K. Soper pp 5119–5126 DOI: 10.1021/ja0583057

Fine Tuning of the Rotary Motion by Structural Modification in Light-Driven Unidirectional Molecular Motors Javier Vicario, Martin Walko, Auke Meetsma, and Ben L. Feringa pp 5127–5135 DOI: 10.1021/ja058303m Supporting Info

Crystal Structures of Salinosporamide A (NPI-0052) and B (NPI-0047) in Complex with the 20S Proteasome Reveal Important Consequences of β-Lactone Ring Opening and a Mechanism for Irreversible Binding Michael Groll, Robert Huber, and Barbara C. M. Potts pp 5136–5141 DOI: 10.1021/ja058320b Supporting Info

Simulating FRET from Tryptophan:  Is the Rotamer Model Correct? Frank R. Beierlein, Olaf G. Othersen, Harald Lanig, Siegfried Schneider, and Timothy Clark pp 5142–5152 DOI: 10.1021/ja058414l Supporting Info

Enantioselective Synthesis of Cyclic Enol Ethers and All-Carbon Quaternary Stereogenic Centers Through Catalytic Asymmetric Ring-Closing Metathesis Ai-Lan Lee, Steven J. Malcolmson, Alessandra Puglisi, Richard R. Schrock, and Amir H. Hoveyda pp 5153–5157 DOI: 10.1021/ja058428r Supporting Info

Theoretical Study on Tertiary Structural Elements of β-peptides:  Nanotubes Formed from Parallel-Sheet-Derived Assemblies of β-Peptides Tamás Beke, Imre G. Csizmadia, and András Perczel pp 5158–5167 DOI: 10.1021/ja0585127 Supporting Info

Role of Topology, Nonadditivity, and Water-Mediated Interactions in Predicting the Structures of α/β Proteins Chenghang Zong, Garegin A. Papoian, Johan Ulander, and Peter G. Wolynes pp 5168–5176 DOI: 10.1021/ja058589v Supporting Info

Mechanism of AlIII-Catalyzed Transamidation of Unactivated Secondary Carboxamides Justin M. Hoerter, Karin M. Otte, Samuel H. Gellman, and Shannon S. Stahl pp 5177–5183 DOI: 10.1021/ja060331x Supporting Info

Fluorescent Signal Amplification of Carbocyanine Dyes Using Engineered Viral Nanoparticles Carissa M. Soto, Amy Szuchmacher Blum, Gary J. Vora, Nikolai Lebedev, Carolyn E. Meador, Angela P. Won, Anju Chatterji, John E. Johnson, and Banahalli R. Ratna pp 5184–5189 DOI: 10.1021/ja058574x Supporting Info

51V Solid-State Magic Angle Spinning NMR Spectroscopy of Vanadium Chloroperoxidase Neela Pooransingh-Margolis, Rokus Renirie, Zulfiqar Hasan, Ron Wever, Alexander J. Vega, and Tatyana Polenova pp 5190–5208 DOI: 10.1021/ja060480f Supporting Info

Changing the Ligation of the Distal [4Fe4S] Cluster in NiFe Hydrogenase Impairs Inter- and Intramolecular Electron Transfers Sébastien Dementin, Valérie Belle, Patrick Bertrand, Bruno Guigliarelli, Géraldine Adryanczyk-Perrier, Antonio L. De Lacey, Victor M. Fernandez, Marc Rousset, and Christophe Léger pp 5209–5218 DOI: 10.1021/ja060233b Supporting Info

Synthesis, Structure, and Reactivity of 13-Vertex Carboranes and 14-Vertex Metallacarboranes Liang Deng, Hoi-Shan Chan, and Zuowei Xie pp 5219–5230 DOI: 10.1021/ja0605772 Supporting Info

Molecular Self-Assembly at Bare Semiconductor Surfaces:  Preparation and Characterization of Highly Organized Octadecanethiolate Monolayers on GaAs(001) Christine L. McGuiness, Andrey Shaporenko, Carole K. Mars, Sundararajan Uppili, Michael Zharnikov, and David L. Allara pp 5231–5243 DOI: 10.1021/ja058657d Supporting Info

Solution Synthesis of Germanium Nanowires Using a Ge2+ Alkoxide Precursor Henry Gerung, Timothy J. Boyle, Louis J. Tribby, Scott D. Bunge, C. Jeffrey Brinker, and Sang M. Han pp 5244–5250 DOI: 10.1021/ja058524s Supporting Info

Synthesis and Biochemical Evaluation of Phosphonoformate Oligodeoxyribonucleotides Christina M. Yamada, Douglas J. Dellinger, and Marvin H. Caruthers pp 5251–5261 DOI: 10.1021/ja060112b Supporting Info

Probing the Transition State Ensemble of a Protein Folding Reaction by Pressure-Dependent NMR Relaxation Dispersion Dmitry M. Korzhnev, Irina Bezsonova, Ferenc Evanics, Nicolas Taulier, Zheng Zhou, Yawen Bai, Tigran V. Chalikian, R. Scott Prosser, and Lewis E. Kay pp 5262–5269 DOI: 10.1021/ja0601540 Supporting Info

Triple-Ion Interactions for the Construction of Supramolecular Capsules Gennady V. Oshovsky, David N. Reinhoudt, and Willem Verboom pp 5270–5278 DOI: 10.1021/ja0602290 Supporting Info

Metal Supported on Dendronized Magnetic Nanoparticles:  Highly Selective Hydroformylation Catalysts Raed Abu-Reziq, Howard Alper, Dashan Wang, and Michael L. Post pp 5279–5282 DOI: 10.1021/ja060140u Supporting Info

A New Photostable Terrylene Diimide Dye for Applications in Single Molecule Studies and Membrane Labeling Christophe Jung, Barbara K. Müller, Don C. Lamb, Fabian Nolde, Klaus Müllen, and Christoph Bräuchle pp 5283–5291 DOI: 10.1021/ja0588104 Supporting Info

Evolution of a Total Synthesis of (−)-Kendomycin Exploiting a Petasis−Ferrier Rearrangement/Ring-Closing Olefin Metathesis Strategy Amos B. Smith, III, Eugen F. Mesaros, and Emmanuel A. Meyer pp 5292–5299 DOI: 10.1021/ja060369+ Supporting Info

Solution NMR Spectroscopy of the Human Vasopressin V2 Receptor, A G Protein-Coupled Receptor [J. Am. Chem. Soc. 2005, 127, 8010−8011]. Changlin Tian, Richard M. Breyer, Hak Jun Kim, Murthy D. Karra, David B. Friedman, Anne Karpay, and Charles R. Sanders p 5300 DOI: 10.1021/ja061475e Supporting Info

Capture of Phosphorus(I) and Arsenic(I) Moieties by a 1,2-Bis(arylimino)acenaphthene (Aryl-BIAN) Ligand. A Case of Intramolecular Charge Transfer [J. Am. Chem. Soc. 2006, 128, 2800−2801]. Gregor Reeske, Clint R. Hoberg, Nicholas J. Hill, and Alan H. Cowley p 5300 DOI: 10.1021/ja069961p

Issue 16

Synthesis and Hydrogenation of Bis(imino)pyridine Iron Imides Suzanne C. Bart, Emil Lobkovsky, Eckhard Bill, and Paul J. Chirik pp 5302–5303 DOI: 10.1021/ja057165y Supporting Info

Responsive Periodic Mesoporous Polydiacetylene/Silica Nanocomposites Huisheng Peng, Jing Tang, Lu Yang, Jiebin Pang, Henry S. Ashbaugh, C. Jeffery Brinker, Zhengzhong Yang, and Yunfeng Lu pp 5304–5305 DOI: 10.1021/ja0575732 Supporting Info

Can the Disproportion of Oxidation State III Be Favored in RuII−OH2/RuIVO Systems? Ester Masllorens, Montserrat Rodríguez, Isabel Romero, Anna Roglans, Teodor Parella, Jordi Benet-Buchholz, Macarena Poyatos, and Antoni Llobet pp 5306–5307 DOI: 10.1021/ja057733+ Supporting Info

High-Field NMR Studies of Molecular Recognition and Structure−Function Relationships in Antimicrobial Piscidins at the Water−Lipid Bilayer Interface Eduard Y. Chekmenev, Shiela M. Jones, Yelena N. Nikolayeva, Breanna S. Vollmar, Tim J. Wagner, Peter L. Gor'kov, William W. Brey, McKenna N. Manion, Ken C. Daugherty, and Myriam Cotten pp 5308–5309 DOI: 10.1021/ja058385e Supporting Info

Design, Synthesis and X-ray Structure of Protein−Ligand Complexes:  Important Insight into Selectivity of Memapsin 2 (β-Secretase) Inhibitors Arun K. Ghosh, Nagaswamy Kumaragurubaran, Lin Hong, Hui Lei, Khaja Azhar Hussain, Chun-Feng Liu, Thippeswamy Devasamudram, Vajira Weerasena, Robert Turner, Gerald Koelsch, Geoffrey Bilcer, and Jordan Tang pp 5310–5311 DOI: 10.1021/ja058636j Supporting Info

Tandem Nazarov Cyclization−Michael Addition Sequence Catalyzed by an Ir(III) Complex Mesfin Janka, Wei He, Inga E. Haedicke, Frank R. Fronczek, Alison J. Frontier, and Richard Eisenberg pp 5312–5313 DOI: 10.1021/ja058772o Supporting Info

Expanded Capsules with Reversibly Added Spacers Dariush Ajami and Julius Rebek, Jr. pp 5314–5315 DOI: 10.1021/ja060095q Supporting Info

Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction Chengdu Liang and Sheng Dai pp 5316–5317 DOI: 10.1021/ja060242k Supporting Info

Reflection Symmetry Breaking in Achiral Rod-Shaped Smectic Liquid Crystals? David M. Walba, Eva Korblova, Cheng-Cher Huang, Renfan Shao, Michi Nakata, and Noel A. Clark pp 5318–5319 DOI: 10.1021/ja060478o Supporting Info

Photoinduced Magnetization with a High Curie Temperature and a Large Coercive Field in a Cyano-Bridged Cobalt−Tungstate Bimetallic Assembly Shin-ichi Ohkoshi, Satoru Ikeda, Toshiya Hozumi, Toshinori Kashiwagi, and Kazuhito Hashimoto pp 5320–5321 DOI: 10.1021/ja060510e Supporting Info

Design of Effective Zeolite Catalysts for the Complete Hydrogenation of CO2 Bun Chan and Leo Radom pp 5322–5323 DOI: 10.1021/ja0602492 Supporting Info

Quantum-Dot-Based Nanosensor for RRE IIB RNA−Rev Peptide Interaction Assay Chun-yang Zhang and Lawrence W. Johnson pp 5324–5325 DOI: 10.1021/ja060537y Supporting Info

Highly Reversible and Multi-Stage Cantilever Actuation Driven by Polyelectrolyte Brushes Feng Zhou, Wenmiao Shu, Mark E. Welland, and Wilhelm T S Huck pp 5326–5327 DOI: 10.1021/ja060649p Supporting Info

A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction Ruchi Shukla, Sergey V. Lindeman, and Rajendra Rathore pp 5328–5329 DOI: 10.1021/ja060502y Supporting Info

Force-Induced Insulin Dimer Dissociation:  A Molecular Dynamics Study Taeho Kim, Alexander Rhee, and Christopher M. Yip pp 5330–5331 DOI: 10.1021/ja0607382 Supporting Info

Pseudotetrahedral Polyhalocubanes:  Synthesis, Structures, and Parity Violating Energy Differences Andrey A. Fokin, Peter R. Schreiner, Robert Berger, Gregory H. Robinson, Pingrong Wei, and Charles F. Campana pp 5332–5333 DOI: 10.1021/ja060781p Supporting Info

Synthesis and Structure of a Nucleoside with π-Conjugated Nitroxide Spin Label Forming a One-Dimensional Ferromagnetic Chain Kausik Das, Maren Pink, Suchada Rajca, and Andrzej Rajca pp 5334–5335 DOI: 10.1021/ja060846o Supporting Info

A Nanoring−Nanosphere Molecule, {Mo214V30}:  Pushing the Boundaries of Controllable Inorganic Structural Organization at the Molecular Level Bogdan Botar, Paul Kögerler, and Craig L. Hill pp 5336–5337 DOI: 10.1021/ja060886s Supporting Info

Rhodium-Catalyzed Tandem Vinylcyclopropanation of Strained Alkenes Nai-Wen Tseng, John Mancuso, and Mark Lautens pp 5338–5339 DOI: 10.1021/ja060877j Supporting Info

Total Synthesis of (−)-Dictyostatin Gregory W. O'Neil and Andrew J. Phillips pp 5340–5341 DOI: 10.1021/ja0609708 Supporting Info

Butterfly Diradical Intermediates in Photochemical Reactions of Fe2(CO)6(μ-S2) Ioan Silaghi-Dumitrescu, Thomas E. Bitterwolf, and R. Bruce King pp 5342–5343 DOI: 10.1021/ja061272q Supporting Info

Tuning the Coordination Number of Hydroxypyridonate-Based Gadolinium Complexes:  Implications for MRI Contrast Agents1 Valérie C. Pierre, Mauro Botta, Silvio Aime, and Kenneth N. Raymond pp 5344–5345 DOI: 10.1021/ja057805x Supporting Info

One-Electron Oxidation of DNA Oligomers That Lack Guanine:  Reaction and Strand Cleavage at Remote Thymines by Long-Distance Radical Cation Hopping Abraham Joy, Avik K. Ghosh, and Gary B. Schuster pp 5346–5347 DOI: 10.1021/ja058758b

Dimerization of Cyclopropyl Ketones and Crossed Reactions of Cyclopropyl Ketones with Enones as an Entry to Five-Membered Rings Lei Liu and John Montgomery pp 5348–5349 DOI: 10.1021/ja0602187 Supporting Info

Formation of Nickeladihydropyran by Oxidative Addition of Cyclopropyl Ketone. Key Intermediate in Nickel-Catalyzed Cycloaddition Sensuke Ogoshi, Midue Nagata, and Hideo Kurosawa pp 5350–5351 DOI: 10.1021/ja060220y Supporting Info

Selective Shortening of Single-Crystalline Gold Nanorods by Mild Oxidation Chia-Kuang Tsung, Xiaoshan Kou, Qihui Shi, Jinping Zhang, Man Hau Yeung, Jianfang Wang, and Galen D. Stucky pp 5352–5353 DOI: 10.1021/ja060447t Supporting Info

Rhodium(I)-Catalyzed [4+2+2] Cycloadditions of 1,3-Dienes, Alkenes, and Alkynes for the Synthesis of Cyclooctadienes Paul A. Wender and Justin P. Christy pp 5354–5355 DOI: 10.1021/ja060878b Supporting Info

Development of the 1,2-Oxaza-Cope Rearrangement Armen Zakarian and Chong-Dao Lu pp 5356–5357 DOI: 10.1021/ja0609710 Supporting Info

Free-Radical Version of the Strecker Synthesis of α-Aminoamides Promoted by Aqueous H2O2/TiCl3/HCONH2 System Rosalba Cannella, Angelo Clerici, Walter Panzeri, Nadia Pastori, Carlo Punta, and Ombretta Porta pp 5358–5359 DOI: 10.1021/ja061092g Supporting Info

Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides, Including Secondary Alkyl Chlorides, with Arylboronic Acids Francisco González-Bobes and Gregory C. Fu pp 5360–5361 DOI: 10.1021/ja0613761 Supporting Info

Nickel-Catalyzed, Carbonyl-Ene-Type Reactions:  Selective for Alpha Olefins and More Efficient with Electron-Rich Aldehydes Chun-Yu Ho, Sze-Sze Ng, and Timothy F. Jamison pp 5362–5363 DOI: 10.1021/ja061471+ Supporting Info

A Solid-State NMR Study of the Dynamics and Interactions of Phenylalanine Rings in a Statherin Fragment Bound to Hydroxyapatite Crystals James M. Gibson, Jennifer M. Popham, Vinodhkumar Raghunathan, Patrick S. Stayton, and Gary P. Drobny pp 5364–5370 DOI: 10.1021/ja056731m

Role of Interstitial Voids in Oxides on Formation and Stabilization of Reactive Radicals:  Interstitial HO2 Radicals in F2-Laser-Irradiated Amorphous SiO2 Koichi Kajihara, Masahiro Hirano, Linards Skuja, and Hideo Hosono pp 5371–5374 DOI: 10.1021/ja0571390

Molecular Organization of Cholesterol in Unsaturated Phosphatidylethanolamines:  X-ray Diffraction and Solid State 2H NMR Reveal Differences with Phosphatidylcholines Saame Raza Shaikh, Vadim Cherezov, Martin Caffrey, Smita P. Soni, Daniel LoCascio, William Stillwell, and Stephen R. Wassall pp 5375–5383 DOI: 10.1021/ja057949b

Prediction of Microclimate pH in Poly(lactic-co-glycolic Acid) Films Amy G. Ding, Anna Shenderova, and Steven P. Schwendeman pp 5384–5390 DOI: 10.1021/ja055287k Supporting Info

Synthesis of a 10,000-Membered Library of Molecules Resembling Carpanone and Discovery of Vesicular Traffic Inhibitors Brian C. Goess, Rami N. Hannoush, Lawrence K. Chan, Tomas Kirchhausen, and Matthew D. Shair pp 5391–5403 DOI: 10.1021/ja056338g Supporting Info

Deconvoluting the Structural and Drug-Recognition Complexity of the G-Quadruplex-Forming Region Upstream of the bcl-2 P1 Promoter Thomas S. Dexheimer, Daekyu Sun, and Laurence H. Hurley pp 5404–5415 DOI: 10.1021/ja0563861

Characterization of Weak NH−π Intermolecular Interactions of Ammonia with Various Substituted π-Systems Sascha Vaupel, Bernhard Brutschy, Pilarisetty Tarakeshwar, and Kwang S. Kim pp 5416–5426 DOI: 10.1021/ja056454j Supporting Info

Modeling of Ligation-Induced Helix/Loop Displacements in Myoglobin:  Toward an Understanding of Hemoglobin Allostery Victor Guallar, Andrzej A. Jarzecki, Richard A. Friesner, and Thomas G. Spiro pp 5427–5435 DOI: 10.1021/ja057318h Supporting Info

In Silico Discovery of β-Secretase Inhibitors Danzhi Huang, Urs Lüthi, Peter Kolb, Marco Cecchini, Alcide Barberis, and Amedeo Caflisch pp 5436–5443 DOI: 10.1021/ja0573108 Supporting Info

The Redox Chemistry of the Covalently Immobilized Native and Low-pH Forms of Yeast Iso-1-cytochrome c Carlo Augusto Bortolotti, Gianantonio Battistuzzi, Marco Borsari, Paolo Facci, Antonio Ranieri, and Marco Sola pp 5444–5451 DOI: 10.1021/ja0573662 Supporting Info

Oxidative Addition of Dihydrogen to (η6-Arene)Mo(PMe3)3 Complexes: Origin of the Naphthalene and Anthracene Effects Guang Zhu, Kevin E. Janak, Joshua S. Figueroa, and Gerard Parkin pp 5452–5461 DOI: 10.1021/ja058107f Supporting Info

Fluorescent Lifetime Quenching near d = 1.5 nm Gold Nanoparticles:  Probing NSET Validity T. L. Jennings, M. P. Singh, and G. F. Strouse pp 5462–5467 DOI: 10.1021/ja0583665

Ordered Mesoporous Fe2O3 with Crystalline Walls Feng Jiao, Andrew Harrison, Jean-Claude Jumas, Alan V. Chadwick, Winfried Kockelmann, and Peter G. Bruce pp 5468–5474 DOI: 10.1021/ja0584774 Supporting Info

One-Pot Organocatalytic Domino Michael-Aldol and Intramolecular SN2 Reactions. Asymmetric Synthesis of Highly Functionalized Epoxycyclohexanone Derivatives Mauro Marigo, Søren Bertelsen, Aitor Landa, and Karl Anker Jørgensen pp 5475–5479 DOI: 10.1021/ja058490o Supporting Info

Topology Variation and Loop Structural Homology in Crystal and Simulated Structures of a Bimolecular DNA Quadruplex Pascale Hazel, Gary N. Parkinson, and Stephen Neidle pp 5480–5487 DOI: 10.1021/ja058577+ Supporting Info

Nanostructured Oligo(p-phenylene Vinylene)/Silicate Hybrid Films:  One-Step Fabrication and Energy Transfer Studies Keisuke Tajima, Liang-shi Li, and Samuel I. Stupp pp 5488–5495 DOI: 10.1021/ja058610s

Two-Site Ionic Labeling with Pyranine:  Implications for Structural Dynamics Studies of Polymers and Polypeptides by Time-Resolved Fluorescence Anisotropy Jai Sharma, Dina Tleugabulova, Wojciech Czardybon, and John D. Brennan pp 5496–5505 DOI: 10.1021/ja058707e Supporting Info

Resonant Electron Capture by Some Amino Acids and Their Methyl Esters Yury V. Vasil'ev, Benjamin J. Figard, Valery G. Voinov, Douglas F. Barofsky, and Max L. Deinzer pp 5506–5515 DOI: 10.1021/ja058464q Supporting Info

Probing Molecular Structure at Interfaces for Comparison with Bulk Solution Behavior:  Water/2-Propanol Mixtures Monitored by Vibrational Sum Frequency Spectroscopy Sho Kataoka and Paul S. Cremer pp 5516–5522 DOI: 10.1021/ja060156k

Shape/Size-Controlled Syntheses of Metal Nanoparticles for Site-Selective Modification of Carbon Nanotubes Liangti Qu, Liming Dai, and Eiji Osawa pp 5523–5532 DOI: 10.1021/ja060296u

Vibrational Circular Dichroism Study of Optically Pure Cryptophane-A Thierry Brotin, Dominique Cavagnat, Jean-Pierre Dutasta, and Thierry Buffeteau pp 5533–5540 DOI: 10.1021/ja0603148 Supporting Info

Alternating Diacetylene Copolymer Utilizing Perfluorophenyl−Phenyl Interactions Rui Xu, Volker Gramlich, and Holger Frauenrath pp 5541–5547 DOI: 10.1021/ja0603204 Supporting Info

What is Syncrystallization? States of the pH Indicator Methyl Red in Crystals of Phthalic Acid Jason B. Benedict, Dawn E. Cohen, Scott Lovell, Andrew L. Rohl, and Bart Kahr pp 5548–5559 DOI: 10.1021/ja0601181 Supporting Info

DABCO-Induced Self-Assembly of a Trisporphyrin Double-Decker Cage:  Thermodynamic Characterization and Guest Recognition Pablo Ballester, Ana I. Oliva, Antoni Costa, Pere M. Deyà, Antonio Frontera, Rosa M. Gomila, and Christopher A. Hunter pp 5560–5569 DOI: 10.1021/ja060608t Supporting Info

One-Dimensional Ion-Conductive Polymer Films:  Alignment and Fixation of Ionic Channels Formed by Self-Organization of Polymerizable Columnar Liquid Crystals Masafumi Yoshio, Takayoshi Kagata, Koji Hoshino, Tomohiro Mukai, Hiroyuki Ohno, and Takashi Kato pp 5570–5577 DOI: 10.1021/ja0606935 Supporting Info

Inverse Miniemulsion ATRP:  A New Method for Synthesis and Functionalization of Well-Defined Water-Soluble/Cross-Linked Polymeric Particles Jung Kwon Oh, Chuanbing Tang, Haifeng Gao, Nicolay V. Tsarevsky, and Krzysztof Matyjaszewski pp 5578–5584 DOI: 10.1021/ja060586a Supporting Info

CRC Handbook of Chemistry and Physics, 86th Edition Edited by David R. Lide (National Institute of Standards and Technology). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, FL. 2005. 2544 pp. $125.96. ISBN 0-8493-0486-5. p 5585 DOI: 10.1021/ja059868l

Trace Environmental Quantitative Analysis:  Principles, Techniques and Applications, 2nd Edition By Paul R. Loconto (Michigan Department of Community Health, Lansing). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. xii + 732 pp. $139.95. ISBN 0-8247-5853-6. Grady Hanrahan p 5585 DOI: 10.1021/ja0599418

Ion Mobility Spectrometry, 2nd Edition By Gary A. Eiceman (New Mexico State University, Las Cruces, NM) and Zeev Karpas (Nuclear Research Center, Beer-Sheva, Israel). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, FL. 2005. xvi + 350 pp. ISBN 0-8493-2247-2. Robert G. Ewing pp 5585–5586 DOI: 10.1021/ja0598560

Handbook of Industrial Biocatalysis Edited by Ching T. Hou (United States Department of Agriculture, Peoria, IL). CRC Press (an imprint of Taylor and Francis):  Boca Raton, FL. 2005. 616 pp. $179.95. ISBN 0-82472-423-2. p 5586 DOI: 10.1021/ja059862w

Templates in Chemistry II. Topics in Current Chemistry, 249 Edited by Christoph A. Schalley, Fritz Vögtle, and Karl H. Dötz (Kekulé-Institut für Organische Chemie und Biochemie, Bonn). Springer:  Berlin, Heidelberg, New York. 2005. x + 372 pp. $279. ISBN 3-540-23087-4. Eugene R. Zubarev pp 5586–5587 DOI: 10.1021/ja0598356

Anticancer Agents from Natural Products Edited by Gordon M. Cragg (National Cancer Institute, Frederick, MD), David G. I. Kingston (Virginia Polytechnic Institute and State University, Blacksburg, VA), and David J. Newman (National Cancer Institute, Frederick, MD). CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2005. xiv + 578 pp. $179.95. ISBN:  0-8493-1863-7. p 5587 DOI: 10.1021/ja059863o

Polymeric and Inorganic Fibers. Advances in Polymer Science, 178 Springer:  Berlin, Heidelberg, New York. 2005. x + 168 pp. $169.00. ISBN:  3-540-24016-0. p 5587 DOI: 10.1021/ja059864g

Handbook of Reagents for Organic Synthesis:  Reagents for Glycoside, Nucleotide, and Peptide Synthesis Edited by David Crich (University of Illinois at Chicago). John Wiley and Sons, Ltd.:  Chichester. 2005. xiv + 769 pp. $170.00. ISBN 0-470-02304-X. p 5587 DOI: 10.1021/ja0598659

Reagent Chemicals:  Specifications and Procedures, 10th Edition By the ACS Committee on Analytical Reagents, Paul A. Bouis, Chair. American Chemical Society:  Washington, DC and Oxford University Press:  New York. 2006. x + 806 pp. $274.50. ISBN 0-8412-3945-2. p 5587 DOI: 10.1021/ja059867t

Heterocycles from Transition Metal Catalysis:  Formation and Functionalization. Catalysis by Metal Complexes, Volume 28 By András Kotschy (Eötvös Lorand University, Budapest, Hungary) and Géza Timári (CHINOIN Co. Ltd of the Sanofi-Aventis Group, Budapest, Hungary). Springer:  Dordrecht. 2005. xii + 202 pp. $159.00. ISBN 1-4020-3624-8. Keith Fagnou pp 5587–5588 DOI: 10.1021/ja059887v

Issue 17

Design of a Protein Kinase-Inducible Domain Shalini Balakrishnan and Neal J. Zondlo pp 5590–5591 DOI: 10.1021/ja057692h Supporting Info

π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence Yu Liu, Masayoshi Nishiura, Yue Wang, and Zhaomin Hou pp 5592–5593 DOI: 10.1021/ja058188f Supporting Info

Functionalized Surface Arrays for Spatial Targeting of Immune Cell Signaling Wageesha Senaratne, Prabuddha Sengupta, Vladimir Jakubek, David Holowka, Christopher K. Ober, and Barbara Baird pp 5594–5595 DOI: 10.1021/ja058701p Supporting Info

Identification of Sugar Isomers by Single-Molecule Force Spectroscopy Qingmin Zhang and Piotr E. Marszalek pp 5596–5597 DOI: 10.1021/ja058828e Supporting Info

Rapid Freeze-Quench ENDOR Study of Chloroperoxidase Compound I:  The Site of the Radical Sun Hee Kim, Roshan Perera, Lowell P. Hager, John H. Dawson, and Brian M. Hoffman pp 5598–5599 DOI: 10.1021/ja060776l Supporting Info

Enantioselective, Facially Selective Carbomagnesation of Cyclopropenes Xiaozhong Liu and Joseph M. Fox pp 5600–5601 DOI: 10.1021/ja058101q Supporting Info

Use of an Electron-Reservoir Complex Together with Air to Generate N-Heterocyclic Carbenes Denise Méry, Jaime Ruiz Aranzaes, and Didier Astruc pp 5602–5603 DOI: 10.1021/ja058421+ Supporting Info

Stereoselective Alkylation of α,β-Unsaturated Imines via C−H Bond Activation Denise A. Colby, Robert G. Bergman, and Jonathan A. Ellman pp 5604–5605 DOI: 10.1021/ja0584931 Supporting Info

Linear Aglycones Are the Substrates for Glycosyltransferase DesVII in Methymycin Biosynthesis:  Analysis and Implications Chai-Lin Kao, Svetlana A. Borisova, Hak Joong Kim, and Hung-wen Liu pp 5606–5607 DOI: 10.1021/ja058433v Supporting Info

Thermal Isomerizations of 2-d-1-(E)-Propenylcyclobutanes to 4-d-3-Methylcyclohexenes John E. Baldwin and Jean-Marie Fedé pp 5608–5609 DOI: 10.1021/ja0586586 Supporting Info

Li+-Catalyzed Radical Polymerization of Simple Terminal Alkenes Kamesh Vyakaranam, Josiah B. Barbour, and Josef Michl pp 5610–5611 DOI: 10.1021/ja060087+ Supporting Info

Metallic Polycrystalline Thin Films of the Single-Component Neutral Molecular Solid Ni(tmdt)2 Isabelle Malfant, Klauss Rivasseau, Jordi Fraxedas, Christophe Faulmann, Dominique de Caro, Lydie Valade, Lakhemici Kaboub, Jean Marc Fabre, and François Senocq pp 5612–5613 DOI: 10.1021/ja060690s Supporting Info

A Simple Numerical Calculation Correctly Predicts the Observed Size Regime for Growth of Tetrapodal Chalcogenide Nanocrystals P. John Thomas and Paul O'Brien pp 5614–5615 DOI: 10.1021/ja060825u Supporting Info

A Selective Activity-Based Probe for the Papain Family Cysteine Protease Dipeptidyl Peptidase I/Cathepsin C Fang Yuan, Steven H. L. Verhelst, Galia Blum, Lisa M. Coussens, and Matthew Bogyo pp 5616–5617 DOI: 10.1021/ja060835v Supporting Info

Diphenylmethane-Mediated Transmethylation of Methylbenzenes over H-Zeolites Stian Svelle, Unni Olsbye, Karl-Petter Lillerud, Stein Kolboe, and Morten Bjørgen pp 5618–5619 DOI: 10.1021/ja060931w

All-Carbon Quaternary Centers via Catalytic Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem Aibin Zhang and T. V. RajanBabu pp 5620–5621 DOI: 10.1021/ja060999b Supporting Info

Directing the Growth of Highly Aligned Gold Nanorods through a Surface Chemical Amidation Reaction Aneta J. Mieszawska, Grzegorz W. Slawinski, and Francis P. Zamborini pp 5622–5623 DOI: 10.1021/ja061046g Supporting Info

Catalytic Enantioselective Synthesis of Chiral Phthalides by SmI2-Mediated Reductive Cyclization of 2-Acylarylcarboxylates Ling-Lin Huang, Ming-Hua Xu, and Guo-Qiang Lin pp 5624–5625 DOI: 10.1021/ja061114z Supporting Info

Sugar-Assisted Glycopeptide Ligation Ashraf Brik, Yu-Ying Yang, Simon Ficht, and Chi-Huey Wong pp 5626–5627 DOI: 10.1021/ja061165w Supporting Info

Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters:  Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides Ryo Shintani, Wei-Liang Duan, and Tamio Hayashi pp 5628–5629 DOI: 10.1021/ja061430d Supporting Info

Palmerolide A, a Cytotoxic Macrolide from the Antarctic Tunicate Synoicum adareanum Thushara Diyabalanage, Charles D. Amsler, James B. McClintock, and Bill J. Baker pp 5630–5631 DOI: 10.1021/ja0588508 Supporting Info

Low-Temperature Solution-Phase Synthesis of Quantum Well Structured CdSe Nanoribbons Jin Joo, Jae Sung Son, Soon Gu Kwon, Jung Ho Yu, and Taeghwan Hyeon pp 5632–5633 DOI: 10.1021/ja0601686 Supporting Info

Density Functional Theory Analysis of Carboxylate-Bridged Diiron Units in Two-Dimensional Metal−Organic Grids Ari P. Seitsonen, Magalí Lingenfelder, Hannes Spillmann, Alexandre Dmitriev, Sebastian Stepanow, Nian Lin, Klaus Kern, and Johannes V. Barth pp 5634–5635 DOI: 10.1021/ja060180y Supporting Info

Hydride Transfer versus Hydrogen Radical Transfer in Thymidylate Synthase Baoyu Hong, Majd Haddad, Frank Maley, Jan H. Jensen, and Amnon Kohen pp 5636–5637 DOI: 10.1021/ja060196o Supporting Info

Orientation of a Key Glutamine Residue in the BLUF Domain from AppA Revealed by Mutagenesis, Spectroscopy, and Quantum Chemical Calculations Masashi Unno, Shinji Masuda, Taka-aki Ono, and Seigo Yamauchi pp 5638–5639 DOI: 10.1021/ja060633z Supporting Info

Cross-Reactive Conjugated Polymers:  Analyte-Specific Aggregative Response for Structurally Similar Diamines Toby L. Nelson, Caroline O'Sullivan, Nathanial T. Greene, Marc S. Maynor, and John J. Lavigne pp 5640–5641 DOI: 10.1021/ja060589n Supporting Info

Synthesis and Biological Activity of Phospholipase C-Resistant Analogues of Phosphatidylinositol 4,5-bisphosphate Honglu Zhang, Yong Xu, Zheng Zhang, Emily R. Liman, and Glenn D. Prestwich pp 5642–5643 DOI: 10.1021/ja060621d Supporting Info

Direct Synthesis of a Metalloporphyrin Complex on a Surface J. Michael Gottfried, Ken Flechtner, Andreas Kretschmann, Thomas Lukasczyk, and Hans-Peter Steinrück pp 5644–5645 DOI: 10.1021/ja0610333 Supporting Info

Synthesis of the Pyrazolo[4,3-e][1,2,4]triazine Family of Natural Products:  Nostocine A, Fluviol A, and Pseudoiodinine T. Ross Kelly, Eric L. Elliott, Rimma Lebedev, and Jaione Pagalday pp 5646–5647 DOI: 10.1021/ja060937l Supporting Info

The Oxidative Mannich Reaction Catalyzed by Dirhodium Caprolactamate Arthur J. Catino, Jason M. Nichols, Brian J. Nettles, and Michael P. Doyle pp 5648–5649 DOI: 10.1021/ja061146m Supporting Info

Two-Dimensional Surface Chirality Control by Solvent-Induced Helicity Inversion of a Helical Polyacetylene on Graphite Shin-ichiro Sakurai, Kento Okoshi, Jiro Kumaki, and Eiji Yashima pp 5650–5651 DOI: 10.1021/ja061238b Supporting Info

Pattern-Based Discrimination of Enantiomeric and Structurally Similar Amino Acids:  An Optical Mimic of the Mammalian Taste Response J. Frantz Folmer-Andersen, Masanori Kitamura, and Eric V. Anslyn pp 5652–5653 DOI: 10.1021/ja061313i Supporting Info

A Mismatch-Selective Bifunctional Rhodium−Oregon Green Conjugate:  A Fluorescent Probe for Mismatched DNA Brian M. Zeglis and Jacqueline K. Barton pp 5654–5655 DOI: 10.1021/ja061409c Supporting Info

Controlled Microfluidic Encapsulation of Cells, Proteins, and Microbeads in Lipid Vesicles Yung-Chieh Tan, Kanaka Hettiarachchi, Maria Siu, Yen-Ru Pan, and Abraham Phillip Lee pp 5656–5658 DOI: 10.1021/ja056641h Supporting Info

Protein−Cofactor Interactions and EPR Parameters for the QH Quinone Binding Site of Quinol Oxidase. A Density Functional Study Sylwia Kacprzak, Martin Kaupp, and Fraser MacMillan pp 5659–5671 DOI: 10.1021/ja053988b Supporting Info

Two-Dimensional Self-Assembly of 1-Pyrylphosphonic Acid:  Transfer of Stacks on Structured Surface Hin-Lap Yip, Hong Ma, Alex K.-Y. Jen, Jianchun Dong, and Babak A. Parviz pp 5672–5679 DOI: 10.1021/ja0563152 Supporting Info

Air-Initiated Radical Polymerization of Lithium Salts of ω-(Undecamethylcarba-closo-dodecaboran-1‘-yl)alk-1-enes, CH2CH(CH2)n-2C(BMe)11- Li+ Kamesh Vyakaranam, Stefanie Körbe, and Josef Michl pp 5680–5686 DOI: 10.1021/ja054967k Supporting Info

Molecular Motion of Tethered Molecules in Bulk and Surface-Functionalized Materials:  A Comparative Study of Confinement Jessica L. Defreese, Son-Jong Hwang, A. Nicholas G. Parra-Vasquez, and Alexander Katz pp 5687–5694 DOI: 10.1021/ja0556474 Supporting Info

Mechanism of Thio Acid/Azide Amidation Robert V. Kolakowski, Ning Shangguan, Ronald R. Sauers, and Lawrence J. Williams pp 5695–5702 DOI: 10.1021/ja057533y Supporting Info

Characterization of Lysine−Guanine Cross-Links upon One-Electron Oxidation of a Guanine-Containing Oligonucleotide in the Presence of a Trilysine Peptide Sandrine Perrier, Jörg Hau, Didier Gasparutto, Jean Cadet, Alain Favier, and Jean-Luc Ravanat pp 5703–5710 DOI: 10.1021/ja057656i Supporting Info

Evidence for Resonance Optical Trapping of Individual Fluorophore-Labeled Antibodies Using Single Molecule Fluorescence Spectroscopy Haitao Li, Dejian Zhou, Helena Browne, and David Klenerman pp 5711–5717 DOI: 10.1021/ja056997t Supporting Info

Functional Dynamics of Human FKBP12 Revealed by Methyl 13C Rotating Frame Relaxation Dispersion NMR Spectroscopy Ulrika Brath, Mikael Akke, Daiwen Yang, Lewis E. Kay, and Frans A. A. Mulder pp 5718–5727 DOI: 10.1021/ja0570279 Supporting Info

Thermodynamics of Formation of Host−Guest Supramolecular Polymers Victor Hugo Soto Tellini, Aida Jover, Jorge Carrazana García, Luciano Galantini, Francisco Meijide, and José Vázquez Tato pp 5728–5734 DOI: 10.1021/ja0572809 Supporting Info

A Strategy for the Analysis of Chiral Polyoxotungstates by Multinuclear (31P, 183W) NMR Spectroscopy Applied to the Assignment of the 183W NMR Spectra of α1-[P2W17O61]10- and α1-[YbP2W17O61]7- Géraldine Lenoble, Bernold Hasenknopf, and René Thouvenot pp 5735–5744 DOI: 10.1021/ja0575934 Supporting Info

Self-Assembled Monolayers on Pt(111):  Molecular Packing Structure and Strain Effects Observed by Scanning Tunneling Microscopy Sangyeob Lee, Jung Park, Regina Ragan, Sehun Kim, Zonghoon Lee, Do Kyung Lim, Douglas A. A. Ohlberg, and R. Stanley Williams pp 5745–5750 DOI: 10.1021/ja058037c Supporting Info

A New Reverse Wormlike Micellar System:  Mixtures of Bile Salt and Lecithin in Organic Liquids Shih-Huang Tung, Yi-En Huang, and Srinivasa R. Raghavan pp 5751–5756 DOI: 10.1021/ja0583766 Supporting Info

Non-uniformly Sampled Double-TROSY hNcaNH Experiments for NMR Sequential Assignments of Large Proteins Dominique P. Frueh, Zhen-Yu J. Sun, David A. Vosburg, Christopher T. Walsh, Jeffrey C. Hoch, and Gerhard Wagner pp 5757–5763 DOI: 10.1021/ja0584222 Supporting Info

High-Resolution Terahertz Spectroscopy of Crystalline Trialanine:  Extreme Sensitivity to β-Sheet Structure and Cocrystallized Water Karen Siegrist, Christine R. Bucher, Idan Mandelbaum, Angela R. Hight Walker, Radhakrishnan Balu, Susan K. Gregurick, and David F. Plusquellic pp 5764–5775 DOI: 10.1021/ja058176u Supporting Info

Solution Structures of Human LL-37 Fragments and NMR-Based Identification of a Minimal Membrane-Targeting Antimicrobial and Anticancer Region Xia Li, Yifeng Li, Huiyun Han, Donald W. Miller, and Guangshun Wang pp 5776–5785 DOI: 10.1021/ja0584875 Supporting Info

Conformational Equilibrium of Cytochrome P450 BM-3 Complexed with N-Palmitoylglycine:  A Replica Exchange Molecular Dynamics Study Krishna Pratap Ravindranathan, Emilio Gallicchio, Richard A. Friesner, Ann E. McDermott, and Ronald M. Levy pp 5786–5791 DOI: 10.1021/ja058465i Supporting Info

Fluorocarbon-Modified Organic Semiconductors:  Molecular Architecture, Electronic, and Crystal Structure Tuning of Arene- versus Fluoroarene-Thiophene Oligomer Thin-Film Properties Myung-Han Yoon, Antonio Facchetti, Charlotte E. Stern, and Tobin J. Marks pp 5792–5801 DOI: 10.1021/ja060016a Supporting Info

The Paradoxical Thermodynamic Basis for the Interaction of Ethylene Glycol, Glycine, and Sarcosine Chains with Bovine Carbonic Anhydrase II:  An Unexpected Manifestation of Enthalpy/Entropy Compensation Vijay M. Krishnamurthy, Brooks R. Bohall, Vincent Semetey, and George M. Whitesides pp 5802–5812 DOI: 10.1021/ja060070r

Detailed Structure of Diamond-Type Lipid Cubic Nanoparticles Borislav Angelov, Angelina Angelova, Brigitte Papahadjopoulos-Sternberg, Sylviane Lesieur, Jean-François Sadoc, Michel Ollivon, and Patrick Couvreur pp 5813–5817 DOI: 10.1021/ja060082c

Dramatic Acceleration of the Pd-Catalyzed [4+2] Benzannulation Reaction of Enynes and Diynes in the Presence of Lewis Acids and Bases:  Expanded Scope and New Mechanistic Insights Marina Rubina, Matthew Conley, and Vladimir Gevorgyan pp 5818–5827 DOI: 10.1021/ja060085p Supporting Info

Electron Binding Motifs of (H2O)n- Clusters Thomas Sommerfeld and Kenneth D. Jordan pp 5828–5833 DOI: 10.1021/ja0587446

Intermolecular Transfer of Copper Ions from the CopC Protein of Pseudomonas syringae. Crystal Structures of Fully Loaded CuICuII Forms Lianyi Zhang, Melissa Koay, Megan J. Maher, Zhiguang Xiao, and Anthony G. Wedd pp 5834–5850 DOI: 10.1021/ja058528x Supporting Info

Measurement of Long-Range 1H−19F Scalar Coupling Constants and Their Glycosidic Torsion Dependence in 5-Fluoropyrimidine-Substituted RNA Mirko Hennig, Markéta L. Munzarová, Wolfgang Bermel, Lincoln G. Scott, Vladimír Sklenář, and James R. Williamson pp 5851–5858 DOI: 10.1021/ja060165t Supporting Info

C7 and C9 Carbon-Rich Bridges in Diruthenium Systems:  Synthesis, Spectroscopic, and Theoretical Investigations of Different Oxidation States Stéphane Rigaut, Céline Olivier, Karine Costuas, Sylvie Choua, Omrane Fadhel, Julien Massue, Philippe Turek, Jean-Yves Saillard, Pierre H. Dixneuf, and Daniel Touchard pp 5859–5876 DOI: 10.1021/ja0603453 Supporting Info

Nanoscale Patterning of Two Metals on Silicon Surfaces Using an ABC Triblock Copolymer Template Masato Aizawa and Jillian M. Buriak pp 5877–5886 DOI: 10.1021/ja060366x Supporting Info

Design, Synthesis, and Conformational Dynamics of a Gated Molecular Basket Veselin Maslak, Zhiqing Yan, Shijing Xia, Judith Gallucci, Christopher M. Hadad, and Jovica D. Badjić pp 5887–5894 DOI: 10.1021/ja060534l Supporting Info

Anion−π Interactions as Controlling Elements in Self-Assembly Reactions of Ag(I) Complexes with π-Acidic Aromatic Rings Brandi L. Schottel, Helen T. Chifotides, Mikhail Shatruk, Abdellatif Chouai, Lisa M. Pérez, John Bacsa, and Kim R. Dunbar pp 5895–5912 DOI: 10.1021/ja0606273 Supporting Info

Uncovering Quantitative Protein Interaction Networks for Mouse PDZ Domains Using Protein Microarrays Michael A. Stiffler, Viara P. Grantcharova, Mark Sevecka, and Gavin MacBeath pp 5913–5922 DOI: 10.1021/ja060943h Supporting Info

Chiral Amphiphilic Self-Assembled α,α‘-Linked Quinque-, Sexi-, and Septithiophenes:  Synthesis, Stability and Odd−Even Effects Oliver Henze, W. James Feast, Fabrice Gardebien, Pascal Jonkheijm, Roberto Lazzaroni, Philippe Leclère, E. W. Meijer, and Albertus P. H. J. Schenning pp 5923–5929 DOI: 10.1021/ja0607234 Supporting Info

Reaction of the Acetals with TESOTf−Base Combination; Speculation of the Intermediates and Efficient Mixed Acetal Formation Hiromichi Fujioka, Takashi Okitsu, Yoshinari Sawama, Nobutaka Murata, Ruichuan Li, and Yasuyuki Kita pp 5930–5938 DOI: 10.1021/ja060328d Supporting Info

Lithiated Imines:  Solvent-Dependent Aggregate Structures and Mechanisms of Alkylation Stephan J. Zuend, Antonio Ramirez, Emil Lobkovsky, and David B. Collum pp 5939–5948 DOI: 10.1021/ja060363k Supporting Info

Physiochemical Pathway for Cyclic Dehydrogenation and Rehydrogenation of LiAlH4 Jun Wang, Armin D. Ebner, and James A. Ritter pp 5949–5954 DOI: 10.1021/ja060045l

A New Class of Versatile Chiral-Bridged Atropisomeric Diphosphine Ligands:  Remarkably Efficient Ligand Syntheses and Their Applications in Highly Enantioselective Hydrogenation Reactions Liqin Qiu, Fuk Yee Kwong, Jing Wu, Wai Har Lam, Shusun Chan, Wing-Yiu Yu, Yue-Ming Li, Rongwei Guo, Zhongyuan Zhou, and Albert S. C. Chan pp 5955–5965 DOI: 10.1021/ja0602694 Supporting Info

Engineering the Quadruplex Fold:  Nucleoside Conformation Determines Both Folding Topology and Molecularity in Guanine Quadruplexes Chung-Fei Tang and Richard H. Shafer pp 5966–5973 DOI: 10.1021/ja0603958

Methane Activation by Titanium Monoxide Molecules:  A Matrix Isolation Infrared Spectroscopic and Theoretical Study Guanjun Wang, Yu Gong, Mohua Chen, and Mingfei Zhou pp 5974–5980 DOI: 10.1021/ja0604010 Supporting Info

Rare Beryllium Icosahedra in the Intermediate Valence Compound CeBe13 [J. Am. Chem. Soc. 2004, 126, 13926−13927]. Zakiya S. Wilson, Robin T. Macaluso, E. D. Bauer, J. L. Smith, J. D. Thompson, Z. Fisk, George G. Stanley, and Julia Y. Chan p 5981 DOI: 10.1021/ja043190c

Macromolecules Containing Metal and Metal-Like Elements, Volume 6:  Transition Metal-Containing Polymers Edited by Alaa S. Abd-El-Aziz (The University of Winnipeg), Charles E. Carraher, Jr. (Florida Atlantic University), Charles U. Pittman, Jr. (Mississippi State University), and Martel Zelden (University of Richmond). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xiv + 220 pp. $150.00. ISBN 0-471-68445-7. Jonathan Veinot p 5982 DOI: 10.1021/ja059878m

A Practical Guide to Supramolecular Chemistry Edited by Peter J. Cragg (University of Brighton, UK). John Wiley and Sons, Ltd.:  Chichester. 2005. x + 204 pp. $65.00. ISBN 0-470-86654-3. p 5982 DOI: 10.1021/ja0598816

Handbook of C−H Transformations:  Applications in Organic Synthesis, Volumes 1−2 Edited by Gerald Dyker (Bochum University, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xxvi + xxvi + 662 pp. $385. ISBN 3-527-31074-6. p 5982 DOI: 10.1021/ja059882y

Issue 18

Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations:  Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones Subhabrata Chaudhury and William A. Donaldson pp 5984–5985 DOI: 10.1021/ja055668y Supporting Info

Cellular Uptake of PNA−Terpyridine Conjugates and Its Enhancement by Zn2+ Ions Andreas Füssl, Andreas Schleifenbaum, Mareike Göritz, Andrew Riddell, Carsten Schultz, and Roland Krämer pp 5986–5987 DOI: 10.1021/ja0571139 Supporting Info

Semipermeable Polymer Vesicle (PICsome) Self-Assembled in Aqueous Medium from a Pair of Oppositely Charged Block Copolymers:  Physiologically Stable Micro-/Nanocontainers of Water-Soluble Macromolecules Aya Koide, Akihiro Kishimura, Kensuke Osada, Woo-Dong Jang, Yuichi Yamasaki, and Kazunori Kataoka pp 5988–5989 DOI: 10.1021/ja057993r Supporting Info

Synthesis and Characterization of a Bisadduct of La@C82 Lai Feng, Takahiro Tsuchiya, Takatsugu Wakahara, Tsukasa Nakahodo, Qiuyue Piao, Yutaka Maeda, Takeshi Akasaka, Tatsuhisa Kato, Kenji Yoza, Ernst Horn, Naomi Mizorogi, and Shigeru Nagase pp 5990–5991 DOI: 10.1021/ja058390i Supporting Info

Stabilization of G-Quadruplex DNA and Inhibition of Telomerase Activity by Square-Planar Nickel(II) Complexes Julie E. Reed, Anna Arola Arnal, Stephen Neidle, and Ramón Vilar pp 5992–5993 DOI: 10.1021/ja058509n Supporting Info

The Importance of Dynamics in Substrate-Assisted Catalysis and Specificity Qin Xu, Haobo Guo, Alexander Wlodawer, and Hong Guo pp 5994–5995 DOI: 10.1021/ja058831y Supporting Info

Acquisition of a “Group A”-Selective Src Kinase Inhibitor via a Global Targeting Strategy Jung-Mi Hah, Vyas Sharma, Haishan Li, and David S. Lawrence pp 5996–5997 DOI: 10.1021/ja060136i Supporting Info

Pt and Pd 1,4-Shifts at the Edge of Dibenz[a,c]anthracene Anupam Singh and Paul R. Sharp pp 5998–5999 DOI: 10.1021/ja060159x Supporting Info

Conformational Analysis of Chiral Helical Perfluoroalkyl Chains by VCD Kenji Monde, Nobuaki Miura, Mai Hashimoto, Tohru Taniguchi, and Tamotsu Inabe pp 6000–6001 DOI: 10.1021/ja0602041 Supporting Info

Chemical Routes to Nanocrystalline Thermoelectrically Relevant AgPbmSbTem+2 Materials Abhijeet J. Karkamkar and Mercouri G. Kanatzidis pp 6002–6003 DOI: 10.1021/ja060352r Supporting Info

A Highly Selective Fluorescent Probe for the Detection and Imaging of Peroxynitrite in Living Cells Dan Yang, Hua-Li Wang, Zhen-Ning Sun, Nga-Wai Chung, and Jian-Gang Shen pp 6004–6005 DOI: 10.1021/ja0603756 Supporting Info

The Influence of Macromolecular Crowding on HIV-1 Protease Internal Dynamics David D. L. Minh, Chia-en Chang, Joanna Trylska, Valentina Tozzini, and J. Andrew McCammon pp 6006–6007 DOI: 10.1021/ja060483s

Chemisorbed Benzoate-to-Benzene Conversion via Phenyl Radicals on Cu(110):  Kinetic Observation of Conformational Effects Junseok Lee, Daniel B. Dougherty, and John T. Yates, Jr. pp 6008–6009 DOI: 10.1021/ja060533t

Transmission of Extramembrane Conformational Change into Current:  Construction of Metal-Gated Ion Channel Tatsuto Kiwada, Kazuhiro Sonomura, Yukio Sugiura, Koji Asami, and Shiroh Futaki pp 6010–6011 DOI: 10.1021/ja060515b Supporting Info

Searching for Cyclin-Dependent Kinase Inhibitors Using a New Variant of the Cope Elimination Roger J. Griffin, Andrew Henderson, Nicola J. Curtin, Aude Echalier, Jane A. Endicott, Ian R. Hardcastle, David R. Newell, Martin E. M. Noble, Lan-Zhen Wang, and Bernard T. Golding pp 6012–6013 DOI: 10.1021/ja060595j Supporting Info

High Amplification Rates from the Association of Two Enzymes Confined within a Nanometric Layer Immobilized on an Electrode:  Modeling and Illustrating Example Benoît Limoges, Damien Marchal, Francois Mavré, and Jean-Michel Savéant pp 6014–6015 DOI: 10.1021/ja060801n Supporting Info

A One-Dimensional Coordination Polymer, BBDTA·InCl4:  Possible Spin-Peierls Transition with High Critical Temperature of 108 K Wataru Fujita, Kunio Awaga, Ryusuke Kondo, and Seiichi Kagoshima pp 6016–6017 DOI: 10.1021/ja060979+ Supporting Info

Mono(dinitrogen) and Carbon Monoxide Adducts of Bis(cyclopentadienyl) Titanium Sandwiches Tamara E. Hanna, Emil Lobkovsky, and Paul J. Chirik pp 6018–6019 DOI: 10.1021/ja061213c Supporting Info

Hyperdimensional NMR Spectroscopy Ēriks Kupe and Ray Freeman pp 6020–6021 DOI: 10.1021/ja0609598 Supporting Info

Genome Mining in Streptomyces coelicolor:  Molecular Cloning and Characterization of a New Sesquiterpene Synthase Xin Lin, Russell Hopson, and David E. Cane pp 6022–6023 DOI: 10.1021/ja061292s Supporting Info

Site-Selective Binding and Dual Mode Recognition of Serum Albumin by a Squaraine Dye Vadakkancheril S. Jisha, Kalliat T. Arun, Mahesh Hariharan, and Danaboyina Ramaiah pp 6024–6025 DOI: 10.1021/ja061301x Supporting Info

Hydrogenation and Hydrocarbonation and Etching of Single-Walled Carbon Nanotubes Guangyu Zhang, Pengfei Qi, Xinran Wang, Yuerui Lu, David Mann, Xiaolin Li, and Hongjie Dai pp 6026–6027 DOI: 10.1021/ja061324b Supporting Info

Efforts toward Developing Direct Probes of Protein Dynamics Matthew E. Cremeens, Hiroshi Fujisaki, Yong Zhang, Jörg Zimmermann, Laura B. Sagle, Shigeo Matsuda, Philip E. Dawson, John E. Straub, and Floyd E. Romesberg pp 6028–6029 DOI: 10.1021/ja061328g Supporting Info

Structure and Bonding between an Aryl Group and Metal Surfaces De-en Jiang, Bobby G. Sumpter, and Sheng Dai pp 6030–6031 DOI: 10.1021/ja061439f Supporting Info

Chiral Discrimination of Cryptochiral Saturated Quaternary and Tertiary Hydrocarbons by Asymmetric Autocatalysis Tsuneomi Kawasaki, Hiroyuki Tanaka, Takashi Tsutsumi, Toshinari Kasahara, Itaru Sato, and Kenso Soai pp 6032–6033 DOI: 10.1021/ja061429e Supporting Info

Pressure-Induced Sequential Magnetic Pole Inversion and Antiferromagnetic−Ferromagnetic Crossover in a Trimetallic Prussian Blue Analogue Lindsay Egan, Konstantin Kamenev, Dionisis Papanikolaou, Yasuhiro Takabayashi, and Serena Margadonna pp 6034–6035 DOI: 10.1021/ja061514m Supporting Info

Chromatographic Isolation of “Missing” Au55 Clusters Protected by Alkanethiolates Hironori Tsunoyama, Yuichi Negishi, and Tatsuya Tsukuda pp 6036–6037 DOI: 10.1021/ja061659t Supporting Info

Synthesis and Structure of Ruthenium−Silylene Complexes:  Activation of Si−Cl Bonds in N-Heterocyclic Silanes Hyojong Yoo, Patrick J. Carroll, and Donald H. Berry pp 6038–6039 DOI: 10.1021/ja0580744 Supporting Info

Measuring Amide Nitrogen Quadrupolar Coupling by High-Resolution 14N/13C NMR Correlation under Magic-Angle Spinning Zhehong Gan pp 6040–6041 DOI: 10.1021/ja0578597

Rhodium-Catalyzed Intramolecular, Anti-Markovnikov Hydroamination. Synthesis of 3-Arylpiperidines Akihiro Takemiya and John F. Hartwig pp 6042–6043 DOI: 10.1021/ja058299e Supporting Info

Palladium-Catalyzed Asymmetric Ring Expansion of Allenylcyclobutanols:  An Asymmetric Wagner−Meerwein Shift Barry M. Trost and Jia Xie pp 6044–6045 DOI: 10.1021/ja0602501 Supporting Info

Direct Asymmetric Hydroxyamination Reaction Catalyzed by an Axially Chiral Secondary Amine Catalyst Taichi Kano, Mitsuhiro Ueda, Jun Takai, and Keiji Maruoka pp 6046–6047 DOI: 10.1021/ja0604515 Supporting Info

The Mannich Reaction of Malonates with Simple Imines Catalyzed by Bifunctional Cinchona Alkaloids:  Enantioselective Synthesis of β-Amino Acids Jun Song, Yi Wang, and Li Deng pp 6048–6049 DOI: 10.1021/ja060716f Supporting Info

A Direct, One Step Synthesis of Imidazoles from Imines and Acid Chlorides:  A Palladium Catalyzed Multicomponent Coupling Approach Ali R. Siamaki and Bruce A. Arndtsen pp 6050–6051 DOI: 10.1021/ja060705m Supporting Info

Optically Transparent Au{111} Substrates:  Flat Gold Nanoparticle Platforms for High-Resolution Scanning Tunneling Microscopy Daminda H. Dahanayaka, Jane X. Wang, Sohrab Hossain, and Lloyd A. Bumm pp 6052–6053 DOI: 10.1021/ja060862l

New Class of Nucleophiles for Palladium-Catalyzed Asymmetric Allylic Alkylation. Total Synthesis of Agelastatin A Barry M. Trost and Guangbin Dong pp 6054–6055 DOI: 10.1021/ja061105q Supporting Info

“Click” Chemistry in a Supramolecular Environment:  Stabilization of Organogels by Copper(I)-Catalyzed Azide−Alkyne [3 + 2] Cycloaddition David D. Díaz, Karthikan Rajagopal, Erica Strable, Joel Schneider, and M. G. Finn pp 6056–6057 DOI: 10.1021/ja061251w Supporting Info

Enantioselective α-Hydroxylation of 2-Arylacetic Acid Derivatives and Buspirone Catalyzed by Engineered Cytochrome P450 BM-3 Marco Landwehr, Lisa Hochrein, Christopher R. Otey, Alex Kasrayan, Jan-E. Bäckvall, and Frances H. Arnold pp 6058–6059 DOI: 10.1021/ja061261x Supporting Info

Origin of the Relative Stereoselectivity of the β-Lactam Formation in the Staudinger Reaction Lei Jiao, Yong Liang, and Jiaxi Xu pp 6060–6069 DOI: 10.1021/ja056711k Supporting Info

Emergent Functionality of Nucleobase Radical Cations in Duplex DNA:  Prediction of Reactivity Using Qualitative Potential Energy Landscapes Joshy Joseph and Gary B. Schuster pp 6070–6074 DOI: 10.1021/ja060655l

Concerted Proton−Electron Transfer in the Oxidation of Hydrogen-Bonded Phenols Ian J. Rhile, Todd F. Markle, Hirotaka Nagao, Antonio G. DiPasquale, Oanh P. Lam, Mark A. Lockwood, Katrina Rotter, and James M. Mayer pp 6075–6088 DOI: 10.1021/ja054167+ Supporting Info

CB11Me11 Boronium Ylides:  Carba-closo-dodecaboranes with a Naked Boron Vertex Ilya Zharov, Zdenek Havlas, Anita M. Orendt, Dewey H. Barich, David M. Grant, Matthew G. Fete, and Josef Michl pp 6089–6100 DOI: 10.1021/ja054256m Supporting Info

Minimization and Optimization of Designed β-Hairpin Folds Niels H. Andersen, Katherine A. Olsen, R. Matthew Fesinmeyer, Xu Tan, F. Michael Hudson, Lisa A. Eidenschink, and Shabnam R. Farazi pp 6101–6110 DOI: 10.1021/ja054971w Supporting Info

Hydrogen and Deuterium Atoms in Octasilsesquioxanes:  Experimental and Computational Studies Michael Päch, Roderick M. Macrae, and Ian Carmichael pp 6111–6125 DOI: 10.1021/ja055177d Supporting Info

A Thermodynamically Stable Nanophase Material Zhang Lin, Benjamin Gilbert, Quanlin Liu, Guoqiang Ren, and Feng Huang pp 6126–6131 DOI: 10.1021/ja057121p Supporting Info

Implications of Protonation and Substituent Effects for C−O and O−P Bond Cleavage in Phosphate Monoesters Paul G. Loncke and Paul J. Berti pp 6132–6140 DOI: 10.1021/ja057435c Supporting Info

Cope Elimination:  Elucidation of Solvent Effects from QM/MM Simulations Orlando Acevedo and William L. Jorgensen pp 6141–6146 DOI: 10.1021/ja057523x Supporting Info

Evidence for Two Ferryl Species in Chloroperoxidase Compound II Kari L. Stone, Lee M. Hoffart, Rachel K. Behan, Carsten Krebs, and Michael T. Green pp 6147–6153 DOI: 10.1021/ja057876w Supporting Info

Clay−Fulleropyrrolidine Nanocomposites Dimitrios Gournis, Luboš Jankovi, Enrico Maccallini, Darja Benne, Petra Rudolf, Jean-François Colomer, Chloé Sooambar, Vasilios Georgakilas, Maurizio Prato, Marianna Fanti, Francesco Zerbetto, Ginka H. Sarova, and Dirk M. Guldi pp 6154–6163 DOI: 10.1021/ja0579661 Supporting Info

Sensing Metal Ions with DNA Building Blocks:  Fluorescent Pyridobenzimidazole Nucleosides Su Jeong Kim and Eric T. Kool pp 6164–6171 DOI: 10.1021/ja0581806 Supporting Info

Theoretical Studies on Farnesyl Cation Cyclization:  Pathways to Pentalenene Pradeep Gutta and Dean J. Tantillo pp 6172–6179 DOI: 10.1021/ja058031n Supporting Info

Photoinduced Electron Transfer in 2-tert-Butyl-3-(Anthracen-9-yl)-2,3-Diazabicyclo[2.2.2]octane Guadalupe Valverde-Aguilar, Xianghuai Wang, Stephen F. Nelsen, and Jeffrey I. Zink pp 6180–6185 DOI: 10.1021/ja0588205 Supporting Info

Coupling between Protein and Reaction Dynamics in Enzymatic Processes:  Application of Grote−Hynes Theory to Catechol O-Methyltransferase Maite Roca, Vicente Moliner, Iñaki Tuñón, and James T. Hynes pp 6186–6193 DOI: 10.1021/ja058826u

X-Shaped Electro-optic Chromophore with Remarkably Blue-Shifted Optical Absorption. Synthesis, Characterization, Linear/Nonlinear Optical Properties, Self-Assembly, and Thin Film Microstructural Characteristics Hu Kang, Guennadi Evmenenko, Pulak Dutta, Koen Clays, Kai Song, and Tobin J. Marks pp 6194–6205 DOI: 10.1021/ja060185v Supporting Info

Mechanism-Based Cofactor Derivatization of a Copper Amine Oxidase by a Branched Primary Amine Recruits the Oxidase Activity of the Enzyme to Turn Inactivator into Substrate Chunhua Qiao, Ke-Qing Ling, Eric M. Shepard, David M. Dooley, and Lawrence M. Sayre pp 6206–6219 DOI: 10.1021/ja058838f Supporting Info

Computational Study of Carbon Atom (3P and 1D) Reaction with CH2O. Theoretical Evaluation of 1B1 Methylene Production by C (1D) Hyun Joo, Philip B. Shevlin, and Michael L. McKee pp 6220–6230 DOI: 10.1021/ja060216m Supporting Info

Structural Analysis of Alanine Tripeptide with Antiparallel and Parallel β-Sheet Structures in Relation to the Analysis of Mixed β-Sheet Structures in Samia cynthia ricini Silk Protein Fiber Using Solid-State NMR Spectroscopy Tetsuo Asakura, Michi Okonogi, Yasumoto Nakazawa, and Kazuo Yamauchi pp 6231–6238 DOI: 10.1021/ja060251t

Water Soluble Cryptophanes Showing Unprecedented Affinity for Xenon:  Candidates as NMR-Based Biosensors Gaspard Huber, Thierry Brotin, Lionel Dubois, Hervé Desvaux, Jean-Pierre Dutasta, and Patrick Berthault pp 6239–6246 DOI: 10.1021/ja060266r Supporting Info

High Hydride Count Rhodium Octahedra, [Rh6(PR3)6H12][BArF4]2: Synthesis, Structures, and Reversible Hydrogen Uptake under Mild Conditions Simon K. Brayshaw, Michael J. Ingleson, Jennifer C. Green, J. Scott McIndoe, Paul R. Raithby, Gabriele Kociok-Köhn, and Andrew S. Weller pp 6247–6263 DOI: 10.1021/ja0604663 Supporting Info

Neutral Complexes of First Row Transition Metals Bearing Unbound Thiocyanates and Their Assembly on Metallic Surfaces  [J. Am. Chem. Soc. 2006, 128, 3179−3189].  Jacob W. Ciszek, Zachary K. Keane, Long Cheng, Michael P. Stewart, Lam H. Yu, Douglas Natelson, and James M. Tour p 6264 DOI: 10.1021/ja069962h Supporting Info

AMPAC 8 with AGUI (AMPAC GUI) for Mac OSX SemiChem, Inc., P.O. Box 1649, Shawnee Mission, KS 66222. http://www.semichem.com. Single-user commercial pricing $4000 with customer support, $1200 without. Single-user educational pricing $975 with customer support, $300 without. A special educational site license is available for $2000. Thomas M. Gilbert and Catherine E. Check pp 6265–6266 DOI: 10.1021/ja069723u

Adventures in Chemical Physics. Advances in Chemical Physics, Volume 132 Edited by R. Stephen Berry (The University of Chicago) and Joshua Jortner (Tel Aviv University). Series Edited by Stuart A. Rice. John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xiv + 388 pp. $175.00. ISBN 0-471-73842-5. p 6267 DOI: 10.1021/ja059890e

Handbook of Chiral Chemicals, 2nd Edition Edited by David Ager (DSM Pharma Chemicals and PharQuest LLC, Raleigh, NC). CRC Press and Taylor and Francis Group:  Boca Raton, FL. 2006. xvi + 648 pp. $179.96. ISBN 1-57444-664-9. p 6267 DOI: 10.1021/ja059893r

CRC Handbook of Fundamental Spectroscopic Correlation Charts By Thomas J. Bruno (National Institute of Standards and Technology, Boulder, CO) and Paris D. N. Svoronos (City University of New York). CRC Press and Taylor & Francis Group:  Boca Raton, FL. 2006. xiv + 226 pp. $89.96. ISBN 0-8493-3250-8. p 6267 DOI: 10.1021/ja059894j

Controlled Synthesis of Nanoparticles in Microheterogeneous Systems By Vincenzo Turco Liveri (University of Palermo, Italy). from the Series:  Nanostructure Science and Technology. Edited by David J. Lockwood. Springer Science + Business Media Inc.:  New York. 2006. xviii + 168 pp. $79.95. ISBN 0-387-26427-2. Gregory V. Hartland pp 6267–6268 DOI: 10.1021/ja069713t

Polysaccharides I:  Structure, Characterization and Use. Advances in Polymer Science, 186 Edited by Thomas Heinze (Friedrich-Schiller-Universität Jena, Germany). Springer:  Berlin, Heidelberg, New York. 2005. xii + 282 pp. $249.00. ISBN 3-540-26112-5. Robert J. Linhardt p 6268 DOI: 10.1021/ja069707x

Issue 19

Photoconversion in the Red Fluorescent Protein from the Sea Anemone Entacmaea quadricolor: Is Cis−Trans Isomerization Involved? Davey C. Loos, Satoshi Habuchi, Cristina Flors, Jun-ichi Hotta, Jörg Wiedenmann, G. Ulrich Nienhaus, and Johan Hofkens pp 6270–6271 DOI: 10.1021/ja0545113 Supporting Info

An Unusual Cationic [2 + 2] Cycloaddition in a Divergent Total Synthesis of Hongoquercin A and Rhododaurichromanic Acid A Aleksey V. Kurdyumov and Richard P. Hsung pp 6272–6273 DOI: 10.1021/ja054872i Supporting Info

Negative Differential Resistance and Hysteresis through an Organometallic Molecule from Molecular-Level Crossing Rui Liu, San-Huang Ke, Harold U. Baranger, and Weitao Yang pp 6274–6275 DOI: 10.1021/ja057054z

Captured and Cross-Linked Palladium Nanoparticles Jin Ku Cho, Romain Najman, Tony W. Dean, Osamu Ichihara, Christophe Muller, and Mark Bradley pp 6276–6277 DOI: 10.1021/ja057480k Supporting Info

Singlet Oxygen Generation from Water-Soluble Quantum Dot−Organic Dye Nanocomposites Lixin Shi, Billy Hernandez, and Matthias Selke pp 6278–6279 DOI: 10.1021/ja057959c Supporting Info

Redox-Assisted Asymmetric Ostwald Ripening of CdSe Dots to Rods Rongfu Li, Zhengtang Luo, and Fotios Papadimitrakopoulos pp 6280–6281 DOI: 10.1021/ja058102i Supporting Info

Water Activated by Atomic Oxygen on Au(111) to Oxidize CO at Low Temperatures Tae S. Kim, Jinlong Gong, Rotimi A. Ojifinni, J. M. White, and C. Buddie Mullins pp 6282–6283 DOI: 10.1021/ja058263m

Dynamic Control of Racemization Rate through E−Z Photoisomerization of Azobenzene and Subsequent Partial Photoresolution under Circular Polarized Light Nobuyuki Tamaoki and Momoyo Wada pp 6284–6285 DOI: 10.1021/ja058398s Supporting Info

Digital Readout of Target Binding with Attomole Detection Limits via Enzyme Amplification in Femtoliter Arrays David M. Rissin and David R. Walt pp 6286–6287 DOI: 10.1021/ja058425e Supporting Info

Nanopore Formation and Phosphatidylserine Externalization in a Phospholipid Bilayer at High Transmembrane Potential P. Thomas Vernier, Matthew J. Ziegler, Yinghua Sun, Wenji V. Chang, Martin A. Gundersen, and D. Peter Tieleman pp 6288–6289 DOI: 10.1021/ja0588306 Supporting Info

Orientation of Deoxyhemoglobin at High Magnetic Fields:  Structural Insights from RDCs in Solution Sarata C. Sahu, Virgil Simplaceanu, Qingguo Gong, Nancy T. Ho, John G. Glushka, James H. Prestegard, and Chien Ho pp 6290–6291 DOI: 10.1021/ja060023z

Interfacing Carbon Nanotubes with Living Cells Xing Chen, Un Chong Tam, Jennifer L. Czlapinski, Goo Soo Lee, David Rabuka, Alex Zettl, and Carolyn R. Bertozzi pp 6292–6293 DOI: 10.1021/ja060276s Supporting Info

Internal Water Molecules of the Proton-Pumping Halorhodopsin in the Presence of Azide Norikazu Muneda, Mikihiro Shibata, Makoto Demura, and Hideki Kandori pp 6294–6295 DOI: 10.1021/ja060253d

Self-Induced 1-D Molecular Chain Growth of Thiophene on Ge(100) Seok Min Jeon, Soon Jung Jung, Do Kyung Lim, Hyeong-Do Kim, Hangil Lee, and Sehun Kim pp 6296–6297 DOI: 10.1021/ja060333h Supporting Info

From Monomeric Nanofibers to PbS Nanoparticles/Polymer Composite Nanofibers through the Combined Use of γ-Irradiation and Gas/Solid Reaction Tieyu Cui, Fang Cui, Junhu Zhang, Jiayu Wang, Jing Huang, Changli Lü, Zhimin Chen, and Bai Yang pp 6298–6299 DOI: 10.1021/ja060517w Supporting Info

Glycosynthase-Mediated Synthesis of Glycosphingolipids Mark D. Vaughan, Karl Johnson, Shawn DeFrees, Xiaoping Tang, R. Antony J. Warren, and Stephen G. Withers pp 6300–6301 DOI: 10.1021/ja058469n Supporting Info

Asymmetric Catalysis of the [5 + 2] Cycloaddition Reaction of Vinylcyclopropanes and π-Systems Paul A. Wender, Lars O. Haustedt, Jaehong Lim, Jennifer A. Love, Travis J. Williams, and Joo-Yong Yoon pp 6302–6303 DOI: 10.1021/ja058590u Supporting Info

Asymmetric Synthesis of Protected Arylglycines by Rhodium-Catalyzed Addition of Arylboronic Acids to N-tert-Butanesulfinyl Imino Esters Melissa A. Beenen, Daniel J. Weix, and Jonathan A. Ellman pp 6304–6305 DOI: 10.1021/ja060529h Supporting Info

PtCl2-Catalyzed Rearrangement of Methylenecyclopropanes Alois Fürstner and Christophe Aïssa pp 6306–6307 DOI: 10.1021/ja061392y Supporting Info

Highly Enantioselective Aerobic Oxidation of α-Hydroxyphosphonates Catalyzed by Chiral Vanadyl(V) Methoxides Bearing N-Salicylidene-α-aminocarboxylates Vijay D. Pawar, Sampada Bettigeri, Shiue-Shien Weng, Jun-Qi Kao, and Chien-Tien Chen pp 6308–6309 DOI: 10.1021/ja060639o Supporting Info

A Short Enantioselective Pathway for the Synthesis of the Anti-Influenza Neuramidase Inhibitor Oseltamivir from 1,3-Butadiene and Acrylic Acid Ying-Yeung Yeung, Sungwoo Hong, and E. J. Corey pp 6310–6311 DOI: 10.1021/ja0616433 Supporting Info

De Novo Synthesis of Tamiflu via a Catalytic Asymmetric Ring-Opening of meso-Aziridines with TMSN3 Yuhei Fukuta, Tsuyoshi Mita, Nobuhisa Fukuda, Motomu Kanai, and Masakatsu Shibasaki pp 6312–6313 DOI: 10.1021/ja061696k Supporting Info

Palladium-Catalyzed Enantioselective C-3 Allylation of 3-Substituted-1H-Indoles Using Trialkylboranes Barry M. Trost and Jean Quancard pp 6314–6315 DOI: 10.1021/ja0608139 Supporting Info

Nanotube Confinement Denatures Protein Helices Eric J. Sorin and Vijay S. Pande pp 6316–6317 DOI: 10.1021/ja060917j Supporting Info

The Triplet Energy of Thymine in DNA Francisco Bosca, Virginie Lhiaubet-Vallet, M. Consuelo Cuquerella, Jose V. Castell, and Miguel A. Miranda pp 6318–6319 DOI: 10.1021/ja060651g

Periodic Mesoporous Organosilica Hollow Spheres with Tunable Wall Thickness H. Djojoputro, X. F. Zhou, S. Z. Qiao, L. Z. Wang, C. Z. Yu, and G. Q. Lu pp 6320–6321 DOI: 10.1021/ja0607537 Supporting Info

Dearomatization and Functionalization of Terpyridine by Lutetium(III) Alkyl Complexes Kimberly C. Jantunen, Brian L. Scott, P. Jeffrey Hay, John C. Gordon, and Jaqueline L. Kiplinger pp 6322–6323 DOI: 10.1021/ja061161r Supporting Info

Single Quantum Dot-Micelles Coated with Silica Shell as Potentially Non-Cytotoxic Fluorescent Cell Tracers Zhivko Zhelev, Hideki Ohba, and Rumiana Bakalova pp 6324–6325 DOI: 10.1021/ja061137d Supporting Info

A High-Resolution Solid-State NMR Approach for the Structural Studies of Bicelles Sergey Dvinskikh, Ulrich Dürr, Kazutoshi Yamamoto, and Ayyalusamy Ramamoorthy pp 6326–6327 DOI: 10.1021/ja061153a Supporting Info

Perfectly Straight Nanowires of Fullerenes Bearing Long Alkyl Chains on Graphite Takashi Nakanishi, Naoko Miyashita, Tsuyoshi Michinobu, Yutaka Wakayama, Tohru Tsuruoka, Katsuhiko Ariga, and Dirk G. Kurth pp 6328–6329 DOI: 10.1021/ja061450f Supporting Info

Palladium-Catalyzed [3 + 3] Cycloaddition of Trimethylenemethane with Azomethine Imines Ryo Shintani and Tamio Hayashi pp 6330–6331 DOI: 10.1021/ja061662c Supporting Info

Nickel-Catalyzed Multicomponent Connection of Dimethylzinc, Alkynes, 1,3-Butadiene, Aldehydes, and Amines Masanari Kimura, Keisuke Kojima, Yasushi Tatsuyama, and Yoshinao Tamaru pp 6332–6333 DOI: 10.1021/ja0616332 Supporting Info

Xenon Biosensor Amplification via Dendrimer−Cage Supramolecular Constructs Justin L. Mynar, Thomas J. Lowery, David E. Wemmer, Alexander Pines, and Jean M. J. Fréchet pp 6334–6335 DOI: 10.1021/ja061735s Supporting Info

Rhodium-Catalyzed Cycloisomerization of N-Propargyl Enamine Derivatives Hahn Kim and Chulbom Lee pp 6336–6337 DOI: 10.1021/ja0619758 Supporting Info

Ultrafast T-Jump in Water:  Studies of Conformation and Reaction Dynamics at the Thermal Limit Hairong Ma, Chaozhi Wan, and Ahmed H. Zewail pp 6338–6340 DOI: 10.1021/ja0613862

On the Origin of the Unique Properties of Supported Au Nanoparticles Mingshu Chen, Yun Cai, Zhen Yan, and D. Wayne Goodman pp 6341–6346 DOI: 10.1021/ja0557536

Chiroptical and Computational Studies of a Bridled Chiroporphyrin and of Its Nickel(II), Copper(II), and Zinc(II) Complexes Géraldine Maheut, Anna Castaings, Jacques Pécaut, Latévi Max Lawson Daku, Gennaro Pescitelli, Lorenzo Di Bari, and Jean-Claude Marchon pp 6347–6356 DOI: 10.1021/ja054926o Supporting Info

Effect of Hydration on Coordination Properties of Uranyl(VI) Complexes. A First-Principles Molecular Dynamics Study Michael Bühl, Hendrik Kabrede, Romain Diss, and Georges Wipff pp 6357–6368 DOI: 10.1021/ja057301z Supporting Info

Optimization of Unnatural Base Pair Packing for Polymerase Recognition Shigeo Matsuda, Allison A. Henry, and Floyd E. Romesberg pp 6369–6375 DOI: 10.1021/ja057575m Supporting Info

Experimental and Theoretical Investigations of New Dinuclear Palladium Complexes as Precatalysts for the Amination of Aryl Chlorides Ute Christmann, Dimitrios A. Pantazis, Jordi Benet-Buchholz, John E. McGrady, Feliu Maseras, and Ramón Vilar pp 6376–6390 DOI: 10.1021/ja057825z Supporting Info

Modulation of the Axial Water Hydrogen-Bonding Properties by Chemical Modification of the Substrate in Resting State, Substrate-Bound Heme Oxygenase from Neisseria meningitidis; Coupling to the Distal H-Bond Network via Ordered Water Molecules Li-Hua Ma, Yangzhong Liu, Xuhong Zhang, Tadashi Yoshida, Kevin C. Langry, Kevin M. Smith, and Gerd N. La Mar pp 6391–6399 DOI: 10.1021/ja0578505 Supporting Info

Photoreversible DNA Condensation Using Light-Responsive Surfactants Anne-Laure M. Le Ny and C. Ted Lee, Jr. pp 6400–6408 DOI: 10.1021/ja0576738

High Resolution Spectral Differentiation of Enantiomers:  Benzo[a]Pyrene Tetrols Complexed with a Promiscuous Antibody Nenad M. Grubor, Ying Liu, Xinxin Han, Daniel W. Armstrong, and Ryszard Jankowiak pp 6409–6413 DOI: 10.1021/ja058424m

Site-Saturated Mutagenesis of Histidine 234 of Saccharomyces cerevisiae Oxidosqualene-Lanosterol Cyclase Demonstrates Dual Functions in Cyclization and Rearrangement Reactions Tung-Kung Wu, Yuan-Ting Liu, Cheng-Hsiang Chang, Mei-Ting Yu, and Hisng-Ju Wang pp 6414–6419 DOI: 10.1021/ja058782p Supporting Info

Dynamical Valence Fluctuation at the Charge−Density−Wave Phase Boundary in Iodide-Bridged Pt Compound [Pt(chxn)2I]I2 Shinya Takaishi, Daisuke Kawakami, Masahiro Yamashita, Mari Sasaki, Takashi Kajiwara, Hitoshi Miyasaka, Ken-ichi Sugiura, Yusuke Wakabayashi, Hiroshi Sawa, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Harutaka Watanabe, Hisaaki Tanaka, Kazuhiro Marumoto, Hiroshi Ito, and Shin-ichi Kuroda pp 6420–6425 DOI: 10.1021/ja060193b Supporting Info

High-Quality Sodium Rare-Earth Fluoride Nanocrystals:  Controlled Synthesis and Optical Properties Hao-Xin Mai, Ya-Wen Zhang, Rui Si, Zheng-Guang Yan, Ling-dong Sun, Li-Ping You, and Chun-Hua Yan pp 6426–6436 DOI: 10.1021/ja060212h Supporting Info

17O Solid-State NMR Spectroscopic Studies of the Involvement of Water Vapor in Molecular Sieve Formation by Dry-Gel Conversion Banghao Chen and Yining Huang pp 6437–6446 DOI: 10.1021/ja060286t Supporting Info

A New Class of Silica Cross-Linked Micellar Core−Shell Nanoparticles Qisheng Huo, Jun Liu, Li-Qiong Wang, Yingbing Jiang, Timothy N. Lambert, and Erica Fang pp 6447–6453 DOI: 10.1021/ja060367p Supporting Info

Synthesis of Bis(indenyl)zirconium Dihydrides and Subsequent Rearrangement to η5,η3-4,5-Dihydroindenediyl Ligands:  Evidence for Intermediates during the Hydrogenation to Tetrahydroindenyl Derivatives Christopher A. Bradley, Emil Lobkovsky, Ivan Keresztes, and Paul J. Chirik pp 6454–6467 DOI: 10.1021/ja060472z Supporting Info

Efficient Light Harvesting in Dye-Endcapped Conjugated Polymers Probed by Single Molecule Spectroscopy Klaus Becker and John M. Lupton pp 6468–6479 DOI: 10.1021/ja0609405

Unexpected Chemical and Electrochemical Properties of M3N@C80 (M = Sc, Y, Er) Claudia M. Cardona, Bevan Elliott, and Luis Echegoyen pp 6480–6485 DOI: 10.1021/ja061035n Supporting Info

A Pirouette on a Metallofullerene Sphere:  Interconversion of Isomers of N-Tritylpyrrolidino Ih Sc3N@C80 Ting Cai, Carla Slebodnick, Liaosa Xu, Kim Harich, Thomas E. Glass, Christopher Chancellor, James C. Fettinger, Marilyn M. Olmstead, Alan L. Balch, Harry W. Gibson, and Harry C. Dorn pp 6486–6492 DOI: 10.1021/ja0601843 Supporting Info

A Nickel Tripeptide as a Metallodithiolate Ligand Anchor for Resin-Bound Organometallics Kayla N. Green, Stephen P. Jeffery, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 6493–6498 DOI: 10.1021/ja060876r Supporting Info

Tandem Nucleophilic Addition/Fragmentation Reactions and Synthetic Versatility of Vinylogous Acyl Triflates Shin Kamijo and Gregory B. Dudley pp 6499–6507 DOI: 10.1021/ja0608085 Supporting Info

New Palladium(II)−(η3/5- or η1-Indenyl) and Dipalladium(I)−(μ,η3-Indenyl) Complexes Christine Sui-Seng, Gary D. Enright, and Davit Zargarian pp 6508–6519 DOI: 10.1021/ja060747a Supporting Info

Lewis Acid-Promoted Carbon−Carbon Bond Cleavage of Aziridines:  Divergent Cycloaddition Pathways of the Derived Ylides  [J. Am. Chem. Soc. 2004, 126, 2294−2295].  Patrick D. Pohlhaus, Roy K. Bowman, and Jeffrey S. Johnson p 6520 DOI: 10.1021/ja0622958

Supramolecular Dye Chemistry. Topics in Current Chemistry, 258 Edited by Frank Würthner (Universität Würzberg). Springer:  Berlin, Heidelberg, New York. 2005. xii + 324 pp. $299. ISBN 3-540-27758-7. Harold S. Freeman p 6521 DOI: 10.1021/ja059885a

Handbook of Affinity Chromatography, 2nd Edition Edited by David S. Hage (University of Nebraska). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. xx + 944 pp. $176.36. ISBN 0-8247-4057-2. p 6521 DOI: 10.1021/ja059898o

Targets in Heterocyclic Systems:  Chemistry and Properties, Volume 8 (2004). Reviews and Accounts on Heterocyclic Chemistry Edited by Orazio A. Attanasi (University of Urbino, Italy) and Domenico Spinelli (University of Bologna, Italy). Società Chimica Italiana:  Rome. 2005. x + 456 pp. $99.95. ISBN 88-86208-29-4. p 6521 DOI: 10.1021/ja059943s

Oxidation of Alcohols to Aldehydes and Ketones:  A Guide to Current Common Practice By Gabriel Tojo and Marcos Fernández (University of Santiago de Compostela, Spain). from the series, Reactions in Organic Synthesis. Edited by Gabriel Tojo. Springer Science + Business Media, Inc.:  2006. xx + 376 pp. $129.00. ISBN 0-387-23607-4. p 6521 DOI: 10.1021/ja069703s

Theilheimer's Synthetic Methods of Organic Chemistry, Volume 68 Edited by Alan F. Finch (Cambridge). S. Karger AG and the Thomson Corporation:  Basel, Switzerland. 2005. xxvi + 398 pp. $632.00. ISBN 3-8055-7989-6. pp 6521–6522 DOI: 10.1021/ja069704k

Natural Products Isolation, 2nd Edition. Methods in Biotechnology, 20 Edited by Satyajit D. Sarker (University of Ulster at Coleraine, Northern Ireland, UK), Zahid Latif (Molecular Nature Limited, Aberystwyth, Wales, UK), and Alexander I. Gray (University of Strathclyde, Glasgow, Scotland, UK). Humana Press:  Totowa, NJ. 2006. xii + 516 pp. $135.00. ISBN 1-58829-447-1. p 6522 DOI: 10.1021/ja0697020

Issue 20

Planar Catechin Analogues with Alkyl Side Chains:  A Potent Antioxidant and an α-Glucosidase Inhibitor Wataru Hakamata, Ikuo Nakanishi, Yu Masuda, Takehiko Shimizu, Hajime Higuchi, Yuriko Nakamura, Shinichi Saito, Shiro Urano, Tadatake Oku, Toshihiko Ozawa, Nobuo Ikota, Naoki Miyata, Haruhiro Okuda, and Kiyoshi Fukuhara pp 6524–6525 DOI: 10.1021/ja057763c Supporting Info

Releasable Luciferin−Transporter Conjugates:  Tools for the Real-Time Analysis of Cellular Uptake and Release Lisa R. Jones, Elena A. Goun, Rajesh Shinde, Jonathan B. Rothbard, Christopher H. Contag, and Paul A. Wender pp 6526–6527 DOI: 10.1021/ja0586283 Supporting Info

Probing Organic Field Effect Transistors In Situ during Operation Using SFG Hongke Ye, Ashraf Abu-Akeel, Jia Huang, Howard E. Katz, and David H. Gracias pp 6528–6529 DOI: 10.1021/ja060442w Supporting Info

Direct Synthesis of B−C−N Single-Walled Nanotubes by Bias-Assisted Hot Filament Chemical Vapor Deposition W. L. Wang, X. D. Bai, K. H. Liu, Z. Xu, D. Golberg, Y. Bando, and E. G. Wang pp 6530–6531 DOI: 10.1021/ja0606733 Supporting Info

A Chiral Ag-Based Catalyst for Practical, Efficient, and Highly Enantioselective Additions of Enolsilanes to α-Ketoesters Laura C. Akullian, Marc L. Snapper, and Amir H. Hoveyda pp 6532–6533 DOI: 10.1021/ja061166o Supporting Info

Contrast Agents for Magnetic Resonance Imaging Synthesized with Ring-Opening Metathesis Polymerization Matthew J. Allen, Ronald T. Raines, and Laura L. Kiessling pp 6534–6535 DOI: 10.1021/ja061383p Supporting Info

Kinetic Resolution of 2-Oxazolidinones via Catalytic, Enantioselective N-Acylation Vladimir B. Birman, Hui Jiang, Ximin Li, Lei Guo, and Eric W. Uffman pp 6536–6537 DOI: 10.1021/ja061560m Supporting Info

Inorganic Single Wall Nanotubes of SbPS4-xSex (0 ≤ x ≤ 3) with Tunable Band Gap Christos D. Malliakas and Mercouri G. Kanatzidis pp 6538–6539 DOI: 10.1021/ja057943m Supporting Info

Formation and Characterization of Polyglutamate Core−Shell Microspheres Elizabeth M. Dibbern, Farah Jean-Jacques Toublan, and Kenneth S. Suslick pp 6540–6541 DOI: 10.1021/ja058198g Supporting Info

Efficient Energy Transfer from Peripheral Chromophores to the Self-Assembled Zinc Chlorin Rod Antenna:  A Bioinspired Light-Harvesting System to Bridge the “Green Gap” Cornelia Röger, Marc G. Müller, Marina Lysetska, Yulia Miloslavina, Alfred R. Holzwarth, and Frank Würthner pp 6542–6543 DOI: 10.1021/ja0584469 Supporting Info

Quadruply Hydrogen Bonded Cytosine Modules for Supramolecular Applications Valérie G. H. Lafitte, Abil E. Aliev, Peter N. Horton, Michael B. Hursthouse, Kason Bala, Peter Golding, and Helen C. Hailes pp 6544–6545 DOI: 10.1021/ja0587289 Supporting Info

Photocatalytic Oxidation of Hydrocarbons by a Bis-iron(III)-μ-oxo Pacman Porphyrin Using O2 and Visible Light Joel Rosenthal, Thomas D. Luckett, Justin M. Hodgkiss, and Daniel G. Nocera pp 6546–6547 DOI: 10.1021/ja058731s Supporting Info

Development of a Ratiometric Fluorescent Zinc Ion Probe in Near-Infrared Region, Based on Tricarbocyanine Chromophore Kazuki Kiyose, Hirotatsu Kojima, Yasuteru Urano, and Tetsuo Nagano pp 6548–6549 DOI: 10.1021/ja060399c Supporting Info

One-Step One-Phase Synthesis of Monodisperse Noble-Metallic Nanoparticles and Their Colloidal Crystals Nanfeng Zheng, Jie Fan, and Galen D. Stucky pp 6550–6551 DOI: 10.1021/ja0604717 Supporting Info

Separation of Semiconducting from Metallic Carbon Nanotubes by Selective Functionalization with Azomethine Ylides Cécilia Ménard-Moyon, Nicolas Izard, Eric Doris, and Charles Mioskowski pp 6552–6553 DOI: 10.1021/ja060802f Supporting Info

Ferroelectric Metal−Organic Framework with a High Dielectric Constant Qiong Ye, Yu-Mei Song, Guo-Xi Wang, Kai Chen, Da-Wei Fu, Philip Wai Hong Chan, Jin-Song Zhu, Songping D. Huang, and Ren-Gen Xiong pp 6554–6555 DOI: 10.1021/ja060856p Supporting Info

A Biomimetic “Polysoap” for Single-Walled Carbon Nanotube Dispersion Dan Wang, Wen-Xi Ji, Zi-Chen Li, and Liwei Chen pp 6556–6557 DOI: 10.1021/ja060907i Supporting Info

Direct Crystallographic Observation of a Coordinatively Unsaturated Transition-Metal Complex in situ Generated within a Self-Assembled Cage Masaki Kawano, Yasuhiro Kobayashi, Tomoji Ozeki, and Makoto Fujita pp 6558–6559 DOI: 10.1021/ja0609250 Supporting Info

Vertical Array Growth of Small Diameter Single-Walled Carbon Nanotubes Ya-Qiong Xu, Erica Flor, Myung Jong Kim, Behrang Hamadani, Howard Schmidt, Richard E. Smalley, and Robert H. Hauge pp 6560–6561 DOI: 10.1021/ja060944+ Supporting Info

Polymer-Coated Ferromagnetic Colloids from Well-Defined Macromolecular Surfactants and Assembly into Nanoparticle Chains Bryan D. Korth, Pei Keng, Inbo Shim, Steven E. Bowles, Chuanbing Tang, Tomasz Kowalewski, Kenneth W. Nebesny, and Jeffrey Pyun pp 6562–6563 DOI: 10.1021/ja0609147 Supporting Info

Synthesis of Degradable Model Networks via ATRP and Click Chemistry Jeremiah A. Johnson, Danielle R. Lewis, David D. Díaz, M. G. Finn, Jeffrey T. Koberstein, and Nicholas J. Turro pp 6564–6565 DOI: 10.1021/ja0612910 Supporting Info

Pentalenolactone Biosynthesis. Molecular Cloning and Assignment of Biochemical Function to PtlH, A Non-Heme Iron Dioxygenase of Streptomyces avermitilis Zheng You, Satoshi Omura, Haruo Ikeda, and David E. Cane pp 6566–6567 DOI: 10.1021/ja061469i Supporting Info

Porphyrin Synthesis in Water Provides New Expanded Porphyrins with Direct Bipyrrole Linkages:  Isolation and Characterization of Two Heptaphyrins Satoru Hiroto, Hiroshi Shinokubo, and Atsuhiro Osuka pp 6568–6569 DOI: 10.1021/ja061621g Supporting Info

Diffuse Polymer Interfaces in Lobed Nanoemulsions Preserved in Aqueous Media Ginam Kim, Alioscka Sousa, Deborah Meyers, Marilyn Shope, and Matthew Libera pp 6570–6571 DOI: 10.1021/ja061377t

Facile Migratory Insertion of a N-Heterocyclic Carbene into a Ruthenium−Carbon Double Bond:  A New Type of Reaction of a NHC Ligand Eva Becker, Verena Stingl, Georg Dazinger, Michael Puchberger, Kurt Mereiter, and Karl Kirchner pp 6572–6573 DOI: 10.1021/ja061454k Supporting Info

Scanning Tunneling Spectroscopy in an Ionic Liquid Tim Albrecht, Kasper Moth-Poulsen, Jørn B. Christensen, Johan Hjelm, Thomas Bjørnholm, and Jens Ulstrup pp 6574–6575 DOI: 10.1021/ja061993p Supporting Info

Nanofibril Self-Assembly of an Arylene Ethynylene Macrocycle Kaushik Balakrishnan, Aniket Datar, Wei Zhang, Xiaomei Yang, Tammene Naddo, Jialing Huang, Jianmin Zuo, Max Yen, Jeffrey S. Moore, and Ling Zang pp 6576–6577 DOI: 10.1021/ja0618550 Supporting Info

A Tetracoordinated Rhodium Aminyl Radical Complex Pascal Maire, Martin Königsmann, Anandaram Sreekanth, Jeffrey Harmer, Arthur Schweiger, and Hansjörg Grützmacher pp 6578–6580 DOI: 10.1021/ja0612798 Supporting Info

On the Origin of the Stereoselectivity in the Alkylation of Oxazolopiperidone Enolates Ignacio Soteras, Oscar Lozano, Arantxa Gómez-Esqué, Carmen Escolano, Modesto Orozco, Mercedes Amat, Joan Bosch, and F. Javier Luque pp 6581–6588 DOI: 10.1021/ja055393m Supporting Info

Ultralow-Density Nanostructured Metal Foams:  Combustion Synthesis, Morphology, and Composition B. C. Tappan, M. H. Huynh, M. A. Hiskey, D. E. Chavez, E. P. Luther, J. T. Mang, and S. F. Son pp 6589–6594 DOI: 10.1021/ja056550k Supporting Info

Regioselective Bond Cleavage in the Dissociative Electron Transfer to Benzyl Thiocyanates:  The Role of Radical/Ion Pair Formation Emad M. Hamed, Hanh Doai, Christopher K. McLaughlin, and Abdelaziz Houmam pp 6595–6604 DOI: 10.1021/ja056730u Supporting Info

C64H4:  Production, Isolation, and Structural Characterizations of a Stable Unconventional Fulleride Chun-Ru Wang, Zhi-Qiang Shi, Li-Jun Wan, Xin Lu, Lothar Dunsch, Chun-Ying Shu, Ya-Lin Tang, and Hisanori Shinohara pp 6605–6610 DOI: 10.1021/ja0567844 Supporting Info

Design of Functional Ferritin-Like Proteins with Hydrophobic Cavities Joe Swift, William A. Wehbi, Brenna D. Kelly, Xiaoran Fu Stowell, Jeffery G. Saven, and Ivan J. Dmochowski pp 6611–6619 DOI: 10.1021/ja057069x Supporting Info

Dendritic Arrays of [Re6(μ3-Se)8]2+ Core-Containing Clusters:  Exploratory Synthesis and Electrochemical Studies Bryan K. Roland, Ware H. Flora, Hugh D. Selby, Neal R. Armstrong, and Zhiping Zheng pp 6620–6625 DOI: 10.1021/ja057548w Supporting Info

Synthesis, Photochemistry, and Electrochemistry of Single-Wall Carbon Nanotubes with Pendent Pyridyl Groups and of Their Metal Complexes with Zinc Porphyrin. Comparison with Pyridyl-Bearing Fullerenes Mercedes Alvaro, Pedro Atienzar, Pilar de la Cruz, Juan L. Delgado, Vincent Troiani, Hermenegildo Garcia, Fernando Langa, Amit Palkar, and Luis Echegoyen pp 6626–6635 DOI: 10.1021/ja057742i Supporting Info

Weakly Bound Water Molecules Shorten Single-Stranded DNA Shuxun Cui, Christian Albrecht, Ferdinand Kühner, and Hermann E. Gaub pp 6636–6639 DOI: 10.1021/ja0582298

Insights into the Mechanism and Catalysis of the Native Chemical Ligation Reaction Erik C. B. Johnson and Stephen B. H. Kent pp 6640–6646 DOI: 10.1021/ja058344i

Triplet Energy Back Transfer in Conjugated Polymers with Pendant Phosphorescent Iridium Complexes Nicholas R. Evans, Lekshmi Sudha Devi, Chris S. K. Mak, Scott E. Watkins, Sofia I. Pascu, Anna Köhler, Richard H. Friend, Charlotte K. Williams, and Andrew B. Holmes pp 6647–6656 DOI: 10.1021/ja0584267 Supporting Info

1H NMR Study of the Magnetic Properties and Electronic Structure of the Hydroxide Complex of Substrate-bound Heme Oxygenase from Neisseria Meningitidis:  Influence of the Axial Water Deprotonation on the Distal H-bond Network Li-Hua Ma, Yangzhong Liu, Xuhang Zhang, Tadashi Yoshida, and Gerd N. La Mar pp 6657–6668 DOI: 10.1021/ja0584626 Supporting Info

Self-Assembly of Surfactant Vesicles that Transform into Viscoelastic Wormlike Micelles upon Heating Tanner S. Davies, Aimee M. Ketner, and Srinivasa R. Raghavan pp 6669–6675 DOI: 10.1021/ja060021e Supporting Info

Direct Determination of Low-Dimensional Structures:  Synchrotron X-ray Scattering on One-Dimensional Charge-Ordered MMX-Chain Complexes Yusuke Wakabayashi, Atsushi Kobayashi, Hiroshi Sawa, Hiroyuki Ohsumi, Naoshi Ikeda, and Hiroshi Kitagawa pp 6676–6682 DOI: 10.1021/ja060111j

Nucleophilic−Alkylation−Reoxidation:  A Functionalization Sequence for Single-Wall Carbon Nanotubes Ralf Graupner, Jürgen Abraham, David Wunderlich, Andrea Vencelová, Peter Lauffer, Jonas Röhrl, Martin Hundhausen, Lothar Ley, and Andreas Hirsch pp 6683–6689 DOI: 10.1021/ja0607281 Supporting Info

Heterodimers Based on CoPt3−Au Nanocrystals with Tunable Domain Size Teresa Pellegrino, Angela Fiore, Elvio Carlino, Cinzia Giannini, P. Davide Cozzoli, Giuseppe Ciccarella, Marc Respaud, Luca Palmirotta, Roberto Cingolani, and Liberato Manna pp 6690–6698 DOI: 10.1021/ja0607741 Supporting Info

Host−Guest Complexation of Endohedral Metallofullerene with Azacrown Ether and Its Application Takahiro Tsuchiya, Kumiko Sato, Hiroki Kurihara, Takatsugu Wakahara, Tsukasa Nakahodo, Yutaka Maeda, Takeshi Akasaka, Kei Ohkubo, Shunich Fukuzumi, Tatsuhisa Kato, Naomi Mizorogi, Kaoru Kobayashi, and Shigeru Nagase pp 6699–6703 DOI: 10.1021/ja0608390 Supporting Info

Mixed Micelles of Fluorinated and Hydrogenated Surfactants Lars Nordstierna, István Furó, and Peter Stilbs pp 6704–6712 DOI: 10.1021/ja061029r Supporting Info

Self-Assembly, Structural, and Retrostructural Analysis of Dendritic Dipeptide Pores Undergoing Reversible Circular to Elliptical Shape Change Mihai Peterca, Virgil Percec, Andrés E. Dulcey, Sami Nummelin, Stephanie Korey, Monica Ilies, and Paul A. Heiney pp 6713–6720 DOI: 10.1021/ja0611902 Supporting Info

Expression, Purification, and Characterization of a Galactofuranosyltransferase Involved in Mycobacterium tuberculosis Arabinogalactan Biosynthesis Natisha L. Rose, Gladys C. Completo, Shuang-Jun Lin, Michael McNeil, Monica M. Palcic, and Todd L. Lowary pp 6721–6729 DOI: 10.1021/ja058254d Supporting Info

Spontaneous Transformation of CdTe Nanoparticles into Angled Te Nanocrystals:  From Particles and Rods to Checkmarks, X-Marks, and Other Unusual Shapes Zhiyong Tang, Ying Wang, Sachin Shanbhag, Michael Giersig, and Nicholas A. Kotov pp 6730–6736 DOI: 10.1021/ja0582096 Supporting Info

Micropores in Crystalline Dipeptides as Seen from the Crystal Structure, He Pycnometry, and 129Xe NMR Spectroscopy Dmitriy V. Soldatov, Igor L. Moudrakovski, Eugeny V. Grachev, and John A. Ripmeester pp 6737–6744 DOI: 10.1021/ja060474j Supporting Info

Sequential Ru−Pd Catalysis:  A Two-Catalyst One-Pot Protocol for the Synthesis of N- and O-Heterocycles Barry M. Trost, Michelle R. Machacek, and Brian D. Faulk pp 6745–6754 DOI: 10.1021/ja060812g Supporting Info

Conformational Stability of the Propylene Oxide−Water Adduct:  Direct Spectroscopic Detection of O−H···O Hydrogen Bonded Conformers Zheng Su, Qing Wen, and Yunjie Xu pp 6755–6760 DOI: 10.1021/ja061343l Supporting Info

Interphases and Mesophases in Polymer Crystallization II and III. Advances in Polymer Science, 181 and 191 Edited by Giuseppe Allegra (Politecnico di Milano, Italy). Springer:  Berlin, Heidelberg, New York. 2005. xiv + 204 pp. $199.00. ISBN 3-540-25344-0 (for II). xiv + 304 pp. $259.00. ISBN 3-540-28280-7 (for III). p 6761 DOI: 10.1021/ja069708p

Nomenclature of Inorganic Chemistry. IUPAC Recommendations 2005 Prepared for publication by Neil G. Connelly (University of Bristol, UK), Ture Damhas (Novozymes A/S, Denmark), Richard M. Hartshorn (University of Canterbury, New Zealand), and Alan T. Hutto (University of Cape Town, South Africa). International Union of Pure and Applied Chemistry and the Royal Society of Chemistry:  Cambridge. 2005. xii + 366 pp. $150.00. ISBN 0-85404-438-8. p 6761 DOI: 10.1021/ja069710g

Organic Light-Emitting Devices Edited by Klaus Müllen (Max-Planck-Institut für Polymerforschung) and Ullrich Scherf (Bergische Universität Wuppertal):  Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xviii + 410 pp. $170.00. ISBN 3-527-31218-8. Uwe H. F. Bunz p 6761 DOI: 10.1021/ja069724m

Reviews in Computational Chemistry, Volume 22 Edited by Kenny B. Lipkowitz (Howard University, Washington, DC), Thomas R. Cundari (University of North Texas, Denton), Valerie J. Gillet (University of Sheffield, UK), and Editor Emeritus, Donald B. Boyd (Indiana University−Purdue University at Indianapolis). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xxviii + 362 pp. $160.00. ISBN 0-471-77938-5. Gordon M. Crippen pp 6761–6762 DOI: 10.1021/ja069715d

Issue 21

Quadruplex-to-Duplex Transition of G-Rich Oligonucleotides Probed by Cationic Water-Soluble Conjugated Polyelectrolytes Fang He, Yanli Tang, Minghui Yu, Fude Feng, Lingling An, Huan Sun, Shu Wang, Yuliang Li, Daoben Zhu, and Guillermo C. Bazan pp 6764–6765 DOI: 10.1021/ja058075w Supporting Info

Catalytic Reduction of NO to N2O by a Designed Heme Copper Center in Myoglobin:  Implications for the Role of Metal Ions Xuan Zhao, Natasha Yeung, Brandy S. Russell, Dewain K. Garner, and Yi Lu pp 6766–6767 DOI: 10.1021/ja058822p Supporting Info

Assembly State of Catalytic Modules as Chiral Switches in Asymmetric Strecker Amino Acid Synthesis Nobuki Kato, Tsuyoshi Mita, Motomu Kanai, Bruno Therrien, Masaki Kawano, Kentaro Yamaguchi, Hiroshi Danjo, Yoshihisa Sei, Akihiro Sato, Sanae Furusho, and Masakatsu Shibasaki pp 6768–6769 DOI: 10.1021/ja060841r Supporting Info

Rational Design of a Reversible pH-Responsive Switch for Peptide Self-Assembly Yuri Zimenkov, Steven N. Dublin, Rong Ni, Raymond S. Tu, Victor Breedveld, Robert P. Apkarian, and Vincent P. Conticello pp 6770–6771 DOI: 10.1021/ja0605974 Supporting Info

Site-Specific DNA Photocleavage by Rhodium Intercalators Analyzed by MALDI-TOF Mass Spectrometry Jens Brunner and Jacqueline K. Barton pp 6772–6773 DOI: 10.1021/ja0612753 Supporting Info

Direct Writing of a Conducting Polymer with Molecular-Level Control of Physical Dimensions and Orientation Minchul Yang, Paul E. Sheehan, William P. King, and Lloyd J. Whitman pp 6774–6775 DOI: 10.1021/ja0612807 Supporting Info

Direct Observation of a 1MLCT State by Ultrafast Transient Absorption Spectroscopy in Mo2(O2C-9-anthracene)4 Gotard T. Burdzinski, Ramkrishna Ramnauth, Malcolm H. Chisholm, and Terry L. Gustafson pp 6776–6777 DOI: 10.1021/ja057687d

Isolation and Molecular Structure of the Organo-persulfuranes [12−S−6(C6)] Soichi Sato, Kaoru Matsunaga, Ernst Horn, Naomichi Furukawa, and Tatsuya Nabeshima pp 6778–6779 DOI: 10.1021/ja060497y Supporting Info

An Efficiently Extended Class of Unnatural Base Pairs Aaron M. Leconte, Shigeo Matsuda, and Floyd E. Romesberg pp 6780–6781 DOI: 10.1021/ja060853c Supporting Info

Nuclear Overhauser Effect (NOE) Enhancement of 11B NMR Spectra of Borane Adducts in the Solid State Sharon E. Ashbrook, Nicholas G. Dowell, Ivan Prokes, and Stephen Wimperis pp 6782–6783 DOI: 10.1021/ja0610939

A Highly Selective and Sensitive Inorganic/Organic Hybrid Polymer Fluorescence “Turn-on” Chemosensory System for Iron Cations Li-Juan Fan and Wayne E. Jones, Jr. pp 6784–6785 DOI: 10.1021/ja0612697 Supporting Info

Pt-Catalyzed Tandem Epoxide Fragmentation/Pentannulation of Propargylic Esters Brian G. Pujanauski, B. A. Bhanu Prasad, and Richmond Sarpong pp 6786–6787 DOI: 10.1021/ja061549m Supporting Info

Significant Enhancement of Monooxygenase Activity of Oxygen Carrier Protein Hemocyanin by Urea Chiyuki Morioka, Yoshimitsu Tachi, Shinnichiro Suzuki, and Shinobu Itoh pp 6788–6789 DOI: 10.1021/ja061631h Supporting Info

Cu(II)-Catalyzed Functionalizations of Aryl C−H Bonds Using O2 as an Oxidant Xiao Chen, Xue-Shi Hao, Charles E. Goodhue, and Jin-Quan Yu pp 6790–6791 DOI: 10.1021/ja061715q Supporting Info

The Hidden Role of Acetate in the PbSe Nanocrystal Synthesis Arjan J. Houtepen, Rolf Koole, Daniël Vanmaekelbergh, Johannes Meeldijk, and Stephen G. Hickey pp 6792–6793 DOI: 10.1021/ja061644v Supporting Info

Three-Dimensional DNA Crystals as Molecular Sieves Paul J. Paukstelis pp 6794–6795 DOI: 10.1021/ja061322r Supporting Info

Triphasic Nanocolloids Kyung-Ho Roh, David C. Martin, and Joerg Lahann pp 6796–6797 DOI: 10.1021/ja060836n Supporting Info

Room Temperature Ring-Opening Metathesis of Pyridines by a Transient TiC Linkage Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola pp 6798–6799 DOI: 10.1021/ja061590p Supporting Info

all-anti-Octasilane:  Conformation Control of Silicon Chains Using the Bicyclic Trisilane as a Building Block Aiko Fukazawa, Hayato Tsuji, and Kohei Tamao pp 6800–6801 DOI: 10.1021/ja0616231 Supporting Info

Cyclocarbophosphazene-Containing Tetrameric Assemblies Formed by the Mediation of P−O−P and P−O−Cu Linkages Vadapalli Chandrasekhar, Ramachandran Azhakar, Venkatasubbaiah Krishnan, Arunachalampillai Athimoolam, and Balasubramanian Murugesa Pandian pp 6802–6803 DOI: 10.1021/ja061635m Supporting Info

Enantioselective Organocatalytic Aminomethylation of Aldehydes:  A Role for Ionic Interactions and Efficient Access to β2-Amino Acids Yonggui Chi and Samuel H. Gellman pp 6804–6805 DOI: 10.1021/ja061731n Supporting Info

Construction of Double-Stranded Metallosupramolecular Polymers with a Controlled Helicity by Combination of Salt Bridges and Metal Coordination Masato Ikeda, Yoshie Tanaka, Takashi Hasegawa, Yoshio Furusho, and Eiji Yashima pp 6806–6807 DOI: 10.1021/ja0619096 Supporting Info

Tandem Synthesis of Core−Shell Brush Copolymers and Their Transformation to Peripherally Cross-Linked and Hollowed Nanostructures Chong Cheng, Kai Qi, Ezat Khoshdel, and Karen L. Wooley pp 6808–6809 DOI: 10.1021/ja061892r Supporting Info

α,β-Unsaturated β-Silyl Imide Substrates for Catalytic, Enantioselective Conjugate Additions:  A Total Synthesis of (+)-Lactacystin and the Discovery of a New Proteasome Inhibitor Emily P. Balskus and Eric N. Jacobsen pp 6810–6812 DOI: 10.1021/ja061970a Supporting Info

Determination of the Orientation of Adsorbed Cytochrome c on Carboxyalkanethiol Self-Assembled Monolayers by In Situ Differential Modification Jishou Xu and Edmond F. Bowden pp 6813–6822 DOI: 10.1021/ja054219v Supporting Info

Indirect NMR Spin−Spin Coupling Constants 3J(P,C) and 2J(P,H) across the P−O···H−C Link Can Be Used for Structure Determination of Nucleic Acids Vladimír Sychrovský, Jiří Šponer, Lukáš Trantírek, and Bohdan Schneider pp 6823–6828 DOI: 10.1021/ja0551180 Supporting Info

Mechanism of the Palladium-Catalyzed Homocoupling of Arylboronic Acids:  Key Involvement of a Palladium Peroxo Complex Carlo Adamo, Christian Amatore, Ilaria Ciofini, Anny Jutand, and Hakim Lakmini pp 6829–6836 DOI: 10.1021/ja0569959 Supporting Info

Rhodium-Catalyzed Ring-Opening Reactions of N-Boc-Azabenzonorbornadienes with Amine Nucleophiles Yong-hwan Cho, Valentin Zunic, Hisanori Senboku, Madeline Olsen, and Mark Lautens pp 6837–6846 DOI: 10.1021/ja0577701 Supporting Info

Antiparallel-Aligned Neutral-Ground-State and Zwitterionic Chromophores as a Nonlinear Optical Material Yi Liao, Sanchali Bhattacharjee, Kimberly A. Firestone, Bruce E. Eichinger, Rajan Paranji, Cyrus A. Anderson, Bruce H. Robinson, Philip J. Reid, and Larry R. Dalton pp 6847–6853 DOI: 10.1021/ja057903i

Controlling Semiconductor/Metal Junction Barriers by Incomplete, Nonideal Molecular Monolayers Hossam Haick, Marianna Ambrico, Teresa Ligonzo, Raymond T. Tung, and David Cahen pp 6854–6869 DOI: 10.1021/ja058224a Supporting Info

Synthesis of Fluoranthenes and Indenocorannulenes:  Elucidation of Chiral Stereoisomers on the Basis of Static Molecular Bowls Yao-Ting Wu, Tomoharu Hayama, Kim K. Baldridge, Anthony Linden, and Jay S. Siegel pp 6870–6884 DOI: 10.1021/ja058391a Supporting Info

Ultrafast Dynamics in DNA:  “Fraying” at the End of the Helix Daniele Andreatta, Sobhan Sen, J. Luis Pérez Lustres, Sergey A. Kovalenko, Nikolaus P. Ernsting, Catherine J. Murphy, Robert S. Coleman, and Mark A. Berg pp 6885–6892 DOI: 10.1021/ja0582105 Supporting Info

Flexible Biphenyl Chromophore as a Circular Dichroism Probe for Assignment of the Absolute Configuration of Carboxylic Acids Stefano Superchi, Roberto Bisaccia, Daniele Casarini, Alessandro Laurita, and Carlo Rosini pp 6893–6902 DOI: 10.1021/ja058552a Supporting Info

Direct Observation of the Release of Phenylalanine from Diphenylalanine Nanotubes Victoria L. Sedman, Lihi Adler-Abramovich, Stephanie Allen, Ehud Gazit, and Saul J. B. Tendler pp 6903–6908 DOI: 10.1021/ja060358g

Solid-State NMR Study of the Transformation of Octacalcium Phosphate to Hydroxyapatite:  A Mechanistic Model for Central Dark Line Formation Yao-Hung Tseng, Chung-Yuan Mou, and Jerry C. C. Chan pp 6909–6918 DOI: 10.1021/ja060336u Supporting Info

Synthesis of Butane-Like SiGe Hydrides:  Enabling Precursors for CVD of Ge-Rich Semiconductors Andrew V. G. Chizmeshya, Cole J. Ritter, Changwu Hu, Jesse B. Tice, John Tolle, Ronald A. Nieman, Ignatius S. T. Tsong, and John Kouvetakis pp 6919–6930 DOI: 10.1021/ja060428j Supporting Info

Synthesis of (−)-Sordarin Shunsuke Chiba, Mitsuru Kitamura, and Koichi Narasaka pp 6931–6937 DOI: 10.1021/ja060408h Supporting Info

Modulation of Luminescence Intensity of Lanthanide Complexes by Photoinduced Electron Transfer and Its Application to a Long-Lived Protease Probe Takuya Terai, Kazuya Kikuchi, Shin-ya Iwasawa, Takao Kawabe, Yasunobu Hirata, Yasuteru Urano, and Tetsuo Nagano pp 6938–6946 DOI: 10.1021/ja060729t Supporting Info

Increasing the Accuracy of Solution NMR Structures of Membrane Proteins by Application of Residual Dipolar Couplings. High-Resolution Structure of Outer Membrane Protein A Tomasz Cierpicki, Binyong Liang, Lukas K. Tamm, and John H. Bushweller pp 6947–6951 DOI: 10.1021/ja0608343

Quantitative Structure−Activity Relationships of Ruthenium Catalysts for Olefin Metathesis Giovanni Occhipinti, Hans-René Bjørsvik, and Vidar R. Jensen pp 6952–6964 DOI: 10.1021/ja060832i Supporting Info

Stepwise Formation and Characterization of Covalently Linked Multiporphyrin−Imide Architectures on Si(100) Jieying Jiao, Franklin Anariba, Hugo Tiznado, Izabela Schmidt, Jonathan S. Lindsey, Francisco Zaera, and David F. Bocian pp 6965–6974 DOI: 10.1021/ja060906q

The Properties of the [Mn12O12(O2CR)16(H2O)4] Single-Molecule Magnets in Truly Axial Symmetry:  [Mn12O12(O2CCH2Br)16(H2O)4]·4CH2Cl2 Nicole E. Chakov, Sheng-Chiang Lee, Andrew G. Harter, Philip L. Kuhns, Arneil P. Reyes, Stephen O. Hill, N. S. Dalal, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 6975–6989 DOI: 10.1021/ja060796n Supporting Info

Nanosized Polymetallic Resorcinarene-Based Host Assemblies that Strongly Bind Fullerenes O. Danny Fox, James Cookson, Emma J. S. Wilkinson, Michael G. B. Drew, Elizabeth J. MacLean, Simon J. Teat, and Paul D. Beer pp 6990–7002 DOI: 10.1021/ja060982t Supporting Info

Selective DNA Strand Scission with Binuclear Copper Complexes:  Implications for an Active Cu2−O2 Species Sunita Thyagarajan, Narasimha N. Murthy, Amy A. Narducci Sarjeant, Kenneth D. Karlin, and Steve E. Rokita pp 7003–7008 DOI: 10.1021/ja061014t Supporting Info

Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues MIIPtIV(CN)6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) Karena W. Chapman, Peter J. Chupas, and Cameron J. Kepert pp 7009–7014 DOI: 10.1021/ja060916r Supporting Info

Polymorphism of the Signaling Molecule c-di-GMP Zhaoying Zhang, Seho Kim, Barbara L. Gaffney, and Roger A. Jones pp 7015–7024 DOI: 10.1021/ja0613714 Supporting Info

Convergent, Enantioselective Syntheses of Guanacastepenes A and E Featuring a Selective Cyclobutane Fragmentation1 William D. Shipe and Erik J. Sorensen pp 7025–7035 DOI: 10.1021/ja060847g Supporting Info

Spontaneous CdTe → Alloy → CdS Transition of Stabilizer-Depleted CdTe Nanoparticles Induced by EDTA Zhiyong Tang, Ying Wang, Sachin Shanbhag, and Nicholas A. Kotov pp 7036–7042 DOI: 10.1021/ja055366w Supporting Info

Unidirectional Electronic Ring Current Driven by a Few Cycle Circularly Polarized Laser Pulse:  Quantum Model Simulations for Mg−Porphyrin Ingo Barth, Jörn Manz, Yasuteru Shigeta, and Kiyoshi Yagi pp 7043–7049 DOI: 10.1021/ja057197l

Highly Chemo-, Regio-, and Stereoselective [3+2]-Cyclization of Activated and Deactivated Allenes with Alkenyl Fischer Carbene Complexes:  A Straightforward Access to Alkylidenecyclopentanone Derivatives José Barluenga, Rubén Vicente, Luis A. López, and Miguel Tomás pp 7050–7054 DOI: 10.1021/ja0586788 Supporting Info

Synthesis and Electronic Factors in Thermal Cyclodimerization of Functionalized Aromatic Trifluorovinyl Ethers Bryan K. Spraul, S. Suresh, Jianyong Jin, and Dennis W. Smith, Jr. pp 7055–7064 DOI: 10.1021/ja0600227 Supporting Info

Hydrogenation of Arenes over Silica-Supported Catalysts That Combine a Grafted Rhodium Complex and Palladium Nanoparticles:  Evidence for Substrate Activation on Rhsingle-site−Pdmetal Moieties Pierluigi Barbaro, Claudio Bianchini, Vladimiro Dal Santo, Andrea Meli, Simonetta Moneti, Rinaldo Psaro, Adriana Scaffidi, Laura Sordelli, and Francesco Vizza pp 7065–7076 DOI: 10.1021/ja060235w Supporting Info

Reversible Carbon−Carbon Bond Formation between 1,3-Dienes and Aldehyde or Ketone on Nickel(0) Sensuke Ogoshi, Kei-ichi Tonomori, Masa-aki Oka, and Hideo Kurosawa pp 7077–7086 DOI: 10.1021/ja060580l Supporting Info

A Low-Temperature Synthesis for Organically Soluble HgTe Nanocrystals Exhibiting Near-Infrared Photoluminescence and Quantum Confinement Marc-Oliver M. Piepenbrock, Tom Stirner, Stephen M. Kelly, and Mary O'Neill pp 7087–7090 DOI: 10.1021/ja060721j

Formation and Decomposition of C3 Metallacycles from Ethylene and Methylene on MoAl Alloy Thin Films Feng Gao, Yilin Wang, and Wilfred. T. Tysoe pp 7091–7096 DOI: 10.1021/ja0607685 Supporting Info

Reversible Photoswitching of the Coordination Numbers of Silicon in Organosilicon Compounds Bearing a 2-(Phenylazo)phenyl Group Naokazu Kano, Fuminori Komatsu, Masaki Yamamura, and Takayuki Kawashima pp 7097–7109 DOI: 10.1021/ja060926s Supporting Info

Supramolecular Polymers, 2nd Edition Edited by Alberto Ciferri (Duke University and University of Genoa). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, FL. 2005. xiv + 762 pp. $125.96. ISBN 0-8247-2331-7. Dmitry M. Rudkevich p 7110 DOI: 10.1021/ja059869d

New Aspects of Zirconium Containing Organic Compounds. Topics in Organometallic Chemistry, 10 Edited by Ilan Marek (Technion-Israel Institute of Technology, Haifa). Springer:  Berlin, Heidelberg, New York. 2005. x + 176 pp. $149.00. ISBN 3-540-22221-9. Jeffrey Schwartz pp 7110–7111 DOI: 10.1021/ja059880d

Nanocrystals Forming Mesoscopic Structures Edited by Marie-Paule Pileni (Université Pierre et Marie Curie, Paris, France). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xvi + 330 pp. $175.00. ISBN 3-527-31170-X. Brian A. Korgel p 7111 DOI: 10.1021/ja059900b

Protecting Groups, 3rd Edition By Philip J. Kocienski (University of Leeds). Georg Thieme Verlag:  Stuttgart, New York. 2005. xvi + 679 pp. $89.95. ISBN 3-13-135603-0. Philip DeShong pp 7111–7112 DOI: 10.1021/ja059944k

Metal Catalysed Reactions in Ionic Liquids By Paul J. Dyson and Tilmann J. Geldbach (Ecole Polytechnique Fédérale de Lausanne, Switzerland). from the series:  Catalysis by Metal Complexes. Edited by Brian James and Piet W. N. M. van Leeuwen. Springer:  Dordrecht. 2005. x + 246 pp. $159.00. ISBN 1-4020-3914-X. Brian J. Frost p 7112 DOI: 10.1021/ja0697121

Issue 22

Formation of Halogenated Medium Chain Hydrocarbons by a Lipoxygenase/Hydroperoxide Halolyase-Mediated Transformation in Planktonic Microalgae Thomas Wichard and Georg Pohnert pp 7114–7115 DOI: 10.1021/ja057942u Supporting Info

Allylcyanation of Alkynes:  Regio- and Stereoselective Access to Functionalized Di- or Trisubstituted Acrylonitriles Yoshiaki Nakao, Tomoya Yukawa, Yasuhiro Hirata, Shinichi Oda, Jun Satoh, and Tamejiro Hiyama pp 7116–7117 DOI: 10.1021/ja060519g Supporting Info

One-Pot Synthesis of New-Phase AgInSe2 Nanorods Meng T. Ng, Chris B. Boothroyd, and Jagadese J. Vittal pp 7118–7119 DOI: 10.1021/ja060543u Supporting Info

Probing Nitrogen-Sensitive Steps in the Free-Radical-Mediated Deamination of Amino Alcohols by Ethanolamine Ammonia-Lyase Russell R. Poyner, Mark A. Anderson, Vahe Bandarian, W. Wallace Cleland, and George H. Reed pp 7120–7121 DOI: 10.1021/ja060710q Supporting Info

Supramolecular Compounds from Multiple Ugi Multicomponent Macrocyclizations:  Peptoid-based Cryptands, Cages, and Cryptophanes Daniel G. Rivera and Ludger A. Wessjohann pp 7122–7123 DOI: 10.1021/ja060720r Supporting Info

Stereoselective Synthesis of Oligo-α-(2,8)-Sialic Acids Hiroshi Tanaka, Yuji Nishiura, and Takashi Takahashi pp 7124–7125 DOI: 10.1021/ja0613613 Supporting Info

Transition State Analogue Discrimination by Related Purine Nucleoside Phosphorylases Erika A. Taylor Ringia, Peter C. Tyler, Gary B. Evans, Richard H. Furneaux, Andrew S. Murkin, and Vern L. Schramm pp 7126–7127 DOI: 10.1021/ja061403n Supporting Info

Metal-Controlled Reactivity of a Pincer-type, σ-Coordinated Naphthyl Radical Anion Christian M. Frech, Yehoshoa Ben-David, Lev Weiner, and David Milstein pp 7128–7129 DOI: 10.1021/ja0615066 Supporting Info

Mesoporous Silica−Magnetite Nanocomposite:  Fabrication and Applications in Magnetic Bioseparations Tapas Sen, Antonio Sebastianelli, and Ian James Bruce pp 7130–7131 DOI: 10.1021/ja061393q Supporting Info

Synthesis of FePt Nanocubes and Their Oriented Self-Assembly Min Chen, Jaemin Kim, J. P. Liu, Hongyou Fan, and Shouheng Sun pp 7132–7133 DOI: 10.1021/ja061704x Supporting Info

Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds Kami L. Hull, Waseem Q. Anani, and Melanie S. Sanford pp 7134–7135 DOI: 10.1021/ja061943k Supporting Info

Total Synthesis of (+)-Yatakemycin Kentaro Okano, Hidetoshi Tokuyama, and Tohru Fukuyama pp 7136–7137 DOI: 10.1021/ja0619455 Supporting Info

Photoresponsive Ion-Selective Optical Sensor Alexey Shvarev pp 7138–7139 DOI: 10.1021/ja062339c Supporting Info

Studies on the Insolubility of a Transmembrane Peptide from Signal Peptide Peptidase Erik C. B. Johnson and Stephen B. H. Kent pp 7140–7141 DOI: 10.1021/ja058377y Supporting Info

A Designed Glycoprotein Analogue of Gc-MAF Exhibits Native-like Phagocytic Activity Federica Bogani, Elizabeth McConnell, Lokesh Joshi, Yung Chang, and Giovanna Ghirlanda pp 7142–7143 DOI: 10.1021/ja0604212 Supporting Info

Electrochemical Performance of Angstrom Level Flat Sputtered Carbon Film Consisting of sp2 and sp3 Mixed Bonds Osamu Niwa, Jianbo Jia, Yukari Sato, Dai Kato, Ryoji Kurita, Kenichi Maruyama, Koji Suzuki, and Shigeru Hirono pp 7144–7145 DOI: 10.1021/ja060609l Supporting Info

Fast 2D NMR Ligand Screening Using Hadamard Spectroscopy Miguel Feliz, Jesús García, Eric Aragón, and Miquel Pons pp 7146–7147 DOI: 10.1021/ja0608949 Supporting Info

Thermodynamic Analysis of Autonomous Parallel β-Sheet Formation in Water John D. Fisk, Margaret A. Schmitt, and Samuel H. Gellman pp 7148–7149 DOI: 10.1021/ja060942p Supporting Info

Ribosomal Synthesis of Dehydroalanine-Containing Peptides Florian P. Seebeck and Jack W. Szostak pp 7150–7151 DOI: 10.1021/ja060966w Supporting Info

Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer Louise Natrajan, Fabien Burdet, Jacques Pécaut, and Marinella Mazzanti pp 7152–7153 DOI: 10.1021/ja0609809 Supporting Info

Synthesis and Electrochemistry of Double-Decker Buckyferrocenes Yutaka Matsuo, Kazukuni Tahara, and Eiichi Nakamura pp 7154–7155 DOI: 10.1021/ja061175x Supporting Info

Theoretical Prediction of Chemically Bound Compounds Made of Argon and Hydrocarbons Li Sheng, Arik Cohen, and R. Benny Gerber pp 7156–7157 DOI: 10.1021/ja0613355 Supporting Info

Thiamin Biosynthesis in Eukaryotes:  Characterization of the Enzyme-Bound Product of Thiazole Synthase from Saccharomyces cerevisiae and Its Implications in Thiazole Biosynthesis Abhishek Chatterjee, Christopher T. Jurgenson, Frank C. Schroeder, Steven E. Ealick, and Tadhg P. Begley pp 7158–7159 DOI: 10.1021/ja061413o Supporting Info

High Field 27Al ENDOR Reveals the Coordination Mode of Cu2+ in Low Si/Al Zeolites Patrick J. Carl, David E. W. Vaughan, and Daniella Goldfarb pp 7160–7161 DOI: 10.1021/ja0617643 Supporting Info

Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+ Cai-Feng Wang, Jing-Lin Zuo, Bart M. Bartlett, You Song, Jeffrey R. Long, and Xiao-Zeng You pp 7162–7163 DOI: 10.1021/ja061788+ Supporting Info

Catalytic Enantioselective Aldol Reaction to Ketones Kounosuke Oisaki, Dongbo Zhao, Motomu Kanai, and Masakatsu Shibasaki pp 7164–7165 DOI: 10.1021/ja061815w Supporting Info

Release of Nitric Oxide from a Sol−Gel Hybrid Material Containing a Photoactive Manganese Nitrosyl upon Illumination with Visible Light Aura A. Eroy-Reveles, Yvonne Leung, and Pradip K. Mascharak pp 7166–7167 DOI: 10.1021/ja061852n

Supported Lipopolymer Membranes as Nanoscale Filters:  Simultaneous Protein Recognition and Size-Selection Assays Fernando Albertorio, Susan Daniel, and Paul S. Cremer pp 7168–7169 DOI: 10.1021/ja062010r Supporting Info

Highly Enantioselective Direct Conjugate Addition of Ketones to Nitroalkenes Promoted by A Chiral Primary Amine−Thiourea Catalyst Hongbing Huang and Eric N. Jacobsen pp 7170–7171 DOI: 10.1021/ja0620890 Supporting Info

exTTF as a Building Block for Fullerene Receptors. Unexpected Solvent-Dependent Positive Homotropic Cooperativity Emilio M. Pérez, Luis Sánchez, Gustavo Fernández, and Nazario Martín pp 7172–7173 DOI: 10.1021/ja0621389 Supporting Info

Self-Location of Acceptors as “Isolated” or “Stacked” Energy Traps in a Supramolecular Donor Self-Assembly:  A Strategy to Wavelength Tunable FRET Emission Ayyappanpillai Ajayaghosh, Chakkooth Vijayakumar, Vakayil K. Praveen, S. Santhosh Babu, and Reji Varghese pp 7174–7175 DOI: 10.1021/ja0621905 Supporting Info

Oligoresorcinols Fold into Double Helices in Water Hidetoshi Goto, Hiroshi Katagiri, Yoshio Furusho, and Eiji Yashima pp 7176–7178 DOI: 10.1021/ja062171v Supporting Info

Highly Regioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and Evidence for cis-Aminopalladation and SN2 C−O Bond Formation Guosheng Liu and Shannon S. Stahl pp 7179–7181 DOI: 10.1021/ja061706h Supporting Info

A Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to β-Substituted Cyclic Enones Kang-sang Lee, M. Kevin Brown, Alexander W. Hird, and Amir H. Hoveyda pp 7182–7184 DOI: 10.1021/ja062061o Supporting Info

Ab Initio Quantum Chemistry Calculations on the Electronic Structure of Heavier Alkyne Congeners:  Diradical Character and Reactivity Yousung Jung, Marcin Brynda, Philip P. Power, and Martin Head-Gordon pp 7185–7192 DOI: 10.1021/ja055374c Supporting Info

Proton Transfer-Induced Conformational Changes and Melting In Designed Peptides in the Gas Phase Motoya Kohtani, Thaddeus C. Jones, Rajagopalan Sudha, and Martin F. Jarrold pp 7193–7197 DOI: 10.1021/ja056745s

A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation Yongjun Yan and Xumu Zhang pp 7198–7202 DOI: 10.1021/ja057065s Supporting Info

Subunit Exchange of MjHsp16.5 Studied by Single-Molecule Imaging and Fluorescence Resonance Energy Transfer Yinghua Guan, Zheng Wang, Aoneng Cao, Luhua Lai, and Xin Sheng Zhao pp 7203–7208 DOI: 10.1021/ja057499n Supporting Info

Nanotubes from a Vitamin C-Based Bolaamphiphile Moira Ambrosi, Emiliano Fratini, Viveka Alfredsson, Barry W. Ninham, Rodorico Giorgi, Pierandrea Lo Nostro, and Piero Baglioni pp 7209–7214 DOI: 10.1021/ja057730x Supporting Info

Deuterium Isotope Effects in A:T and A:U Base Pairs:  A Computational NMR Study Pietro Vidossich, Stefano Piana, Andrea Miani, and Paolo Carloni pp 7215–7221 DOI: 10.1021/ja0577903 Supporting Info

Shape-Controlled Synthesis of Ternary Chalcogenide ZnIn2S4 and CuIn(S,Se)2 Nano-/Microstructures via Facile Solution Route Xinglong Gou, Fangyi Cheng, Yunhui Shi, Li Zhang, Shengjie Peng, Jun Chen, and Panwen Shen pp 7222–7229 DOI: 10.1021/ja0580845 Supporting Info

Ytterbocene Charge-Transfer Molecular Wire Complexes Christin N. Carlson, Christopher J. Kuehl, Ryan E. Da Re, Jacqueline M. Veauthier, Eric J. Schelter, Ashley E. Milligan, Brian L. Scott, Eric D. Bauer, J. D. Thompson, David E. Morris, and Kevin D. John pp 7230–7241 DOI: 10.1021/ja058667e Supporting Info

Determination of the Oligomeric Number and Intermolecular Distances of Membrane Protein Assemblies by Anisotropic 1H-Driven Spin Diffusion NMR Spectroscopy Wenbin Luo and Mei Hong pp 7242–7251 DOI: 10.1021/ja0603406

Protein−Ligand NOE Matching:  A High-Throughput Method for Binding Pose Evaluation That Does Not Require Protein NMR Resonance Assignments Keith L. Constantine, Malcolm E. Davis, William J. Metzler, Luciano Mueller, and Brian L. Claus pp 7252–7263 DOI: 10.1021/ja060356w Supporting Info

Intrachain Electron Transfer in Conducting Oligomers and Polymers:  The Mixed Valence Approach Jean Christophe Lacroix, Kathleen Isabelle Chane-Ching, Fabrice Maquère, and François Maurel pp 7264–7276 DOI: 10.1021/ja060390a Supporting Info

Stepwise Cope Rearrangement of Cyclo-biphenalenyl via an Unusual Multicenter Covalent π-Bonded Intermediate Jingsong Huang and Miklos Kertesz pp 7277–7286 DOI: 10.1021/ja060427r Supporting Info

A Designed Branched Three-Helix Bundle Protein Dimer Gunnar T. Dolphin pp 7287–7290 DOI: 10.1021/ja060524k Supporting Info

Self-Assembly of Peptide−Amphiphile Nanofibers:  The Roles of Hydrogen Bonding and Amphiphilic Packing Sergey E. Paramonov, Ho-Wook Jun, and Jeffrey D. Hartgerink pp 7291–7298 DOI: 10.1021/ja060573x Supporting Info

Relaxation Rates of Degenerate 1H Transitions in Methyl Groups of Proteins as Reporters of Side-Chain Dynamics Vitali Tugarinov and Lewis E. Kay pp 7299–7308 DOI: 10.1021/ja060817d Supporting Info

Magnetic Resonance Imaging of the Manipulation of a Chemical Wave Using an Inhomogeneous Magnetic Field Robert Evans, Christiane R. Timmel, P. J. Hore, and Melanie M. Britton pp 7309–7314 DOI: 10.1021/ja0608287

Solvent-Controlled Intramolecular [2 + 2] Photocycloadditions of α-Substituted Enones Stephanie M. Ng, Scott J. Bader, and Marc L. Snapper pp 7315–7319 DOI: 10.1021/ja060968g Supporting Info

Four Tautomers of Isolated Guanine from Infrared Laser Spectroscopy in Helium Nanodroplets Myong Yong Choi and Roger E. Miller pp 7320–7328 DOI: 10.1021/ja060741l Supporting Info

Heterogeneously Catalyzed Asymmetric CC Hydrogenation:  Origin of Enantioselectivity in the Proline-Directed Pd/Isophorone System Alexander I. McIntosh, David J. Watson, Jonathan W. Burton, and Richard M. Lambert pp 7329–7334 DOI: 10.1021/ja061104y Supporting Info

Origin of Trans-Bent Geometries in Maximally Bonded Transition Metal and Main Group Molecules Clark R. Landis and Frank Weinhold pp 7335–7345 DOI: 10.1021/ja060992u Supporting Info

Lanthanide-Binding Tags as Luminescent Probes for Studying Protein Interactions Bianca R. Sculimbrene and Barbara Imperiali pp 7346–7352 DOI: 10.1021/ja061188a Supporting Info

Electrochemistry at Single-Walled Carbon Nanotubes:  The Role of Band Structure and Quantum Capacitance Iddo Heller, Jing Kong, Keith A. Williams, Cees Dekker, and Serge G. Lemay pp 7353–7359 DOI: 10.1021/ja061212k Supporting Info

Functionalized Chiral Vinyl Aminosulfoxonium Salts:  Asymmetric Synthesis and Application to the Synthesis of Enantiopure Unsaturated Prolines, β,γ-Dehydro Amino Acids, and Cyclopentanoid Keto Aminosulfoxonium Ylides Shashi Kant Tiwari, Hans-Joachim Gais, Andreas Lindenmaier (n Schneider), Gadamsetti Surendra Babu, Gerhard Raabe, Leleti Rajender Reddy, Franz Köhler, Markus Günter, Stefan Koep, and Vijaya Bhaskara Reddy Iska pp 7360–7373 DOI: 10.1021/ja061152i Supporting Info

Controlling Structure from the Bottom-Up:  Structural and Optical Properties of Layer-by-Layer Assembled Palladium Coordination-Based Multilayers Marc Altman, Atindra D. Shukla, Tatiana Zubkov, Guennadi Evmenenko, Pulak Dutta, and Milko E. van der Boom pp 7374–7382 DOI: 10.1021/ja061026e Supporting Info

Antibiofouling Polymer-Coated Superparamagnetic Iron Oxide Nanoparticles as Potential Magnetic Resonance Contrast Agents for in Vivo Cancer Imaging Haerim Lee, Eunhye Lee, Do Kyung Kim, Nam Kyu Jang, Yong Yeon Jeong, and Sangyong Jon pp 7383–7389 DOI: 10.1021/ja061529k Supporting Info

Effect of Side-Chain Substituents on Self-Assembly of Perylene Diimide Molecules:  Morphology Control Kaushik Balakrishnan, Aniket Datar, Tammene Naddo, Jialing Huang, Randy Oitker, Max Yen, Jincai Zhao, and Ling Zang pp 7390–7398 DOI: 10.1021/ja061810z Supporting Info

Issue 23

Synthesis of Metal Nanoparticles Stabilized by Metal−Carbon Bonds Fakhradin Mirkhalaf, Jerzy Paprotny, and David J. Schiffrin pp 7400–7401 DOI: 10.1021/ja058687g Supporting Info

High-Resolution NMR Spectroscopy of a GPCR in Aligned Bicelles Sang Ho Park, Stefan Prytulla, Anna A. De Angelis, Jonathan Miles Brown, Hans Kiefer, and Stanley J. Opella pp 7402–7403 DOI: 10.1021/ja0606632 Supporting Info

Carboxylic Solvents and O-Donor Ligand Effects on CH Activation by Pt(II) Vadim R. Ziatdinov, Jonas Oxgaard, Oleg A. Mironov, Kenneth J. H. Young, William A. Goddard III, and Roy A. Periana pp 7404–7405 DOI: 10.1021/ja060973k Supporting Info

Formylation Domain:  An Essential Modifying Enzyme for the Nonribosomal Biosynthesis of Linear Gramicidin Georg Schoenafinger, Nadine Schracke, Uwe Linne, and Mohamed A. Marahiel pp 7406–7407 DOI: 10.1021/ja0611240 Supporting Info

Superoxide Anion is the Intermediate in the Oxygen Reduction Reaction on Platinum Electrodes Min-hua Shao, Ping Liu, and Radoslav R. Adzic pp 7408–7409 DOI: 10.1021/ja061246s Supporting Info

Redox Control within Single-Site Polymerization Catalysts Charlotte K. A. Gregson, Vernon C. Gibson, Nicholas J. Long, Edward L. Marshall, Phillip J. Oxford, and Andrew J. P. White pp 7410–7411 DOI: 10.1021/ja061398n Supporting Info

The Peptide Formation Mediated by Cyanate Revisited. N-Carboxyanhydrides as Accessible Intermediates in the Decomposition of N-Carbamoylamino Acids Grégoire Danger, Laurent Boiteau, Hervé Cottet, and Robert Pascal pp 7412–7413 DOI: 10.1021/ja061339+ Supporting Info

Highly Selective Cobalt-Catalyzed Hydrovinylation of Styrene Michiel M. P. Grutters, Christian Müller, and Dieter Vogt pp 7414–7415 DOI: 10.1021/ja058095y Supporting Info

Highly Selective C−H Functionalization/Halogenation of Acetanilide Xiaobing Wan, Zhongxun Ma, Bijie Li, Keya Zhang, Shaokui Cao, Shiwei Zhang, and Zhangjie Shi pp 7416–7417 DOI: 10.1021/ja060232j Supporting Info

Asymmetric Michael Addition of Nitroalkanes to Nitroalkenes Catalyzed by C2-Symmetric Tridentate Bis(oxazoline) and Bis(thiazoline) Zinc Complexes Shao-Feng Lu, Da-Ming Du, Jiaxi Xu, and Shi-Wei Zhang pp 7418–7419 DOI: 10.1021/ja0604008 Supporting Info

Cyanoesterification of 1,2-Dienes:  Synthesis and Transformations of Highly Functionalized α-Cyanomethylacrylate Esters Yoshiaki Nakao, Yasuhiro Hirata, and Tamejiro Hiyama pp 7420–7421 DOI: 10.1021/ja0606834 Supporting Info

Palladium-Catalyzed Insertion of Isocyanides into P(O)−H Bonds:  Selective Formation of Phosphinoyl Imines and Bisphosphinoylaminomethanes Takayoshi Hirai and Li-Biao Han pp 7422–7423 DOI: 10.1021/ja060984d Supporting Info

Local Diffusion in Paramagnetic Solutions by NMR Relaxometry at One Frequency Andrea Melchior and Pascal H. Fries pp 7424–7425 DOI: 10.1021/ja061235z Supporting Info

Three-Component Coupling of Benzyne:  Domino Intermolecular Carbopalladation Jaclyn L. Henderson, Andrew S. Edwards, and Michael F. Greaney pp 7426–7427 DOI: 10.1021/ja0615526 Supporting Info

Enantioselective Total Synthesis of (+)- and (−)-Nigellamine A2 Jianwei Bian, Matthew Van Wingerden, and Joseph M. Ready pp 7428–7429 DOI: 10.1021/ja061559n Supporting Info

Palladium-Catalyzed Ring Enlargement of Aryl-Substituted Methylenecyclopropanes to Cyclobutenes Min Shi, Le-Ping Liu, and Jie Tang pp 7430–7431 DOI: 10.1021/ja061749y Supporting Info

Structure-Directing Role of Amines in the Ionothermal Synthesis Lei Wang, Yunpeng Xu, Ying Wei, Jicheng Duan, Aibing Chen, Bingchun Wang, Huaijun Ma, Zhijian Tian, and Liwu Lin pp 7432–7433 DOI: 10.1021/ja061882q Supporting Info

Alkali-Metal-Mediated Zincation of Anisole:  Synthesis and Structures of Three Instructive Ortho-Zincated Complexes William Clegg, Sophie H. Dale, Allison M. Drummond, Eva Hevia, Gordon W. Honeyman, and Robert E. Mulvey pp 7434–7435 DOI: 10.1021/ja061898g Supporting Info

Synthesis of Aromatic Ketones by a Transition Metal-Catalyzed Tandem Sequence Jing Zhao, Colin O. Hughes, and F. Dean Toste pp 7436–7437 DOI: 10.1021/ja061942s Supporting Info

Catalytic Asymmetric Assembly of Stereodefined Propionate Units:  An Enantioselective Total Synthesis of (−)-Pironetin Xiaoqiang Shen, Andrew S. Wasmuth, Junping Zhao, Cheng Zhu, and Scott G. Nelson pp 7438–7439 DOI: 10.1021/ja061938g Supporting Info

Highly Efficient Atom Transfer Radical Addition Reactions with a RuIII Complex as a Catalyst Precursor Laurent Quebatte, Katrin Thommes, and Kay Severin pp 7440–7441 DOI: 10.1021/ja0617542 Supporting Info

Organocatalytic Enantioselective Synthesis of α-Hydroxy Phosphonates Sampak Samanta and Cong-Gui Zhao pp 7442–7443 DOI: 10.1021/ja062091r Supporting Info

Synthesis of Colloidal Upconverting NaYF4 Nanocrystals Doped with Er3+, Yb3+ and Tm3+, Yb3+ via Thermal Decomposition of Lanthanide Trifluoroacetate Precursors John-Christopher Boyer, Fiorenzo Vetrone, Louis A. Cuccia, and John A. Capobianco pp 7444–7445 DOI: 10.1021/ja061848b Supporting Info

Supramolecular Binding of Cationic Porphyrins on a Filamentous Bacteriophage Template:  Toward a Noncovalent Antenna System Luigi Monsù Scolaro, Maria Angela Castriciano, Andrea Romeo, Norberto Micali, Nicola Angelini, Carla Lo Passo, and Franco Felici pp 7446–7447 DOI: 10.1021/ja061726j Supporting Info

Rapid and Reversible Reactions of [NiFe]-Hydrogenases with Sulfide Kylie A. Vincent, Natalie A. Belsey, Wolfgang Lubitz, and Fraser A. Armstrong pp 7448–7449 DOI: 10.1021/ja061732f

Mechanistic Implications of Pseudo Zero Order Kinetics in Kinetic Resolutions Donna G. Blackmond, Neil S. Hodnett, and Guy C. Lloyd-Jones pp 7450–7451 DOI: 10.1021/ja062173f Supporting Info

Photochemical Isomerization of N-Heterocyclic Carbene Ruthenium Hydride Complexes:  In situ Photolysis, Parahydrogen, and Computational Studies Kirsten A. M. Ampt, Suzanne Burling, Steven M. A. Donald, Susie Douglas, Simon B. Duckett, Stuart A. Macgregor, Robin N. Perutz, and Michael K. Whittlesey pp 7452–7453 DOI: 10.1021/ja0622397 Supporting Info

The Simplest Binary Fluorocarbon as a Ligand. Synthetic, Spectroscopic, Crystallographic, and Computational Studies of a Molybdenum Complex of Terminally Ligated Carbon Monofluoride (Fluoromethylidyne) Hui Huang, Russell P. Hughes, Clark R. Landis, and Arnold L. Rheingold pp 7454–7455 DOI: 10.1021/ja062510k Supporting Info

Coexistence of Liquid and Solid Phases of Bmim-PF6 Ionic Liquid on Mica Surfaces at Room Temperature Yaodong Liu, Yi Zhang, Guozhong Wu, and Jun Hu pp 7456–7457 DOI: 10.1021/ja062685u Supporting Info

Dioxygen Activation at Non-Heme Diiron Centers:  Characterization of Intermediates in a Mutant Form of Toluene/o-Xylene Monooxygenase Hydroxylase Leslie J. Murray, Ricardo García-Serres, Sunil Naik, Boi Hanh Huynh, and Stephen J. Lippard pp 7458–7459 DOI: 10.1021/ja062762l Supporting Info

Studies Related to the Relative Thermodynamic Stability of C-Terminal Peptidyl Esters of O-Hydroxy Thiophenol:  Emergence of a Doable Strategy for Non-Cysteine Ligation Applicable to the Chemical Synthesis of Glycopeptides Gong Chen, J. David Warren, Jiehao Chen, Bin Wu, Qian Wan, and Samuel J. Danishefsky pp 7460–7462 DOI: 10.1021/ja061588y Supporting Info

Unified Total Synthesis of Pteriatoxins and Their Diastereomers Fumiyoshi Matsuura, René Peters, Masahiro Anada, Scott S. Harried, Junliang Hao, and Yoshito Kishi pp 7463–7465 DOI: 10.1021/ja0618954 Supporting Info

Nickel Superoxide Dismutase Reaction Mechanism Studied by Hybrid Density Functional Methods Vladimir Pelmenschikov and Per E. M. Siegbahn pp 7466–7475 DOI: 10.1021/ja053665f Supporting Info

cis,cis-[(bpy)2RuVO]2O4+ Catalyzes Water Oxidation Formally via in Situ Generation of Radicaloid RuIV−O• Xiaofan Yang and Mu-Hyun Baik pp 7476–7485 DOI: 10.1021/ja053710j Supporting Info

Lariatins, Antimycobacterial Peptides Produced by Rhodococcus sp. K01−B0171, Have a Lasso Structure Masato Iwatsuki, Hiroshi Tomoda, Ryuji Uchida, Hiroaki Gouda, Shuichi Hirono, and Satoshi Ōmura pp 7486–7491 DOI: 10.1021/ja056780z Supporting Info

Chemical Engineering of the Single-Walled Carbon Nanotube−Nylon 6 Interface Junbo Gao, Bin Zhao, Mikhail E. Itkis, Elena Bekyarova, Hui Hu, Verina Kranak, Aiping Yu, and Robert C. Haddon pp 7492–7496 DOI: 10.1021/ja057484p Supporting Info

Quantitative Synthesis of Star-Shaped Poly(vinyl ether)s with a Narrow Molecular Weight Distribution by Living Cationic Polymerization Takaho Shibata, Shokyoku Kanaoka, and Sadahito Aoshima pp 7497–7504 DOI: 10.1021/ja057611h

Dendron-Tethered and Templated CdS Quantum Dots on Single-Walled Carbon Nanotubes Seok-Ho Hwang, Charles N. Moorefield, Pingshan Wang, Kwang-Un Jeong, Stephen Z. D. Cheng, Kishore K. Kotta, and George R. Newkome pp 7505–7509 DOI: 10.1021/ja057896y

Conformationally Gated Photoinduced Processes within PhotosensitizerAcceptor Dyads Based on Osmium(II) Complexes with Triarylpyridinio-Functionalized Terpyridyl Ligands:  Insights from Experimental Study Philippe P. Lainé, Fethi Bedioui, Frédérique Loiseau, Claudio Chiorboli, and Sebastiano Campagna pp 7510–7521 DOI: 10.1021/ja058357w Supporting Info

Insights on Charge Transfer Doping and Intrinsic Phonon Line Shape of Carbon Nanotubes by Simple Polymer Adsorption Moonsub Shim, Taner Ozel, Anshu Gaur, and Congjun Wang pp 7522–7530 DOI: 10.1021/ja058551i Supporting Info

Relative Strength of Cation-π vs Salt-Bridge Interactions:  The Gtα(340−350) Peptide/Rhodopsin System Matthew A. Anderson, Benhur Ogbay, Rieko Arimoto, Wei Sha, Oleg G. Kisselev, David P. Cistola, and Garland R. Marshall pp 7531–7541 DOI: 10.1021/ja058513z

Self-Assembled π-Nanotapes as Donor Scaffolds for Selective and Thermally Gated Fluorescence Resonance Energy Transfer (FRET) Vakayil K. Praveen, Subi J. George, Reji Varghese, Chakkooth Vijayakumar, and Ayyappanpillai Ajayaghosh pp 7542–7550 DOI: 10.1021/ja0587594 Supporting Info

Conformational Changes during Apoplastocyanin Folding Observed by Photocleavable Modification and Transient Grating Shun Hirota, Yukari Fujimoto, Jungkwon Choi, Naoki Baden, Noriko Katagiri, Masako Akiyama, Rinske Hulsker, Marcellus Ubbink, Toshihide Okajima, Teruhiro Takabe, Noriaki Funasaki, Yoshihito Watanabe, and Masahide Terazima pp 7551–7558 DOI: 10.1021/ja058788e

β-Turn Modified Gramicidin S Analogues Containing Arylated Sugar Amino Acids Display Antimicrobial and Hemolytic Activity Comparable to the Natural Product Gijsbert M. Grotenbreg, Annelies E. M. Buizert, Antonio L. Llamas-Saiz, Emile Spalburg, Peter A. V. van Hooft, Albert J. de Neeling, Daan Noort, Mark J. van Raaij, Gijsbert A. van der Marel, Herman S. Overkleeft, and Mark Overhand pp 7559–7565 DOI: 10.1021/ja0588510 Supporting Info

Direct Use of Unassigned Resonances in NMR Structure Calculations with Proxy Residues Eiso AB, David J. R. Pugh, Robert Kaptein, Rolf Boelens, and Alexandre M. J. J. Bonvin pp 7566–7571 DOI: 10.1021/ja058504q

Quenching of the Electrochemiluminescence of Tris(2,2‘-bipyridine)ruthenium(II) by Ferrocene and Its Potential Application to Quantitative DNA Detection Weidong Cao, Jerome P. Ferrance, James Demas, and James P. Landers pp 7572–7578 DOI: 10.1021/ja060162g

Kinetics of RNA Refolding in Dynamic Equilibrium by 1H-Detected 15N Exchange NMR Spectroscopy Philipp Wenter, Geoffrey Bodenhausen, Jens Dittmer, and Stefan Pitsch pp 7579–7587 DOI: 10.1021/ja060344a Supporting Info

A Generalized Two-Point H-Bonding Model for Catalytic Stereoselective Hydrogenation of Activated Ketones on Chirally Modified Platinum Stéphane Lavoie, Marc-André Laliberté, Israel Temprano, and Peter H. McBreen pp 7588–7593 DOI: 10.1021/ja060504i

Dynamic Effects on the Periselectivity, Rate, Isotope Effects, and Mechanism of Cycloadditions of Ketenes with Cyclopentadiene Bryson R. Ussing, Chao Hang, and Daniel A. Singleton pp 7594–7607 DOI: 10.1021/ja0606024 Supporting Info

How Nitrogenase Shakes − Initial Information about P−Cluster and FeMo-cofactor Normal Modes from Nuclear Resonance Vibrational Spectroscopy (NRVS) Yuming Xiao, Karl Fisher, Matt C. Smith, William E. Newton, David A. Case, Simon J. George, Hongxin Wang, Wolfgang Sturhahn, Ercan E. Alp, Jiyong Zhao, Yoshitaka Yoda, and Stephen P. Cramer pp 7608–7612 DOI: 10.1021/ja0603655 Supporting Info

XeCu Covalent Bonding in XeCuF and XeCuCl, Characterized by Fourier Transform Microwave Spectroscopy Supported by Quantum Chemical Calculations Julie M. Michaud and Michael C. L. Gerry pp 7613–7621 DOI: 10.1021/ja060745q Supporting Info

Defect-Free Nanoporous Thin Films from ABC Triblock Copolymers Joona Bang, Seung Hyun Kim, Eric Drockenmuller, Matthew J. Misner, Thomas P. Russell, and Craig J. Hawker pp 7622–7629 DOI: 10.1021/ja0608141

Chemically Controlled Self-Assembly of Protein Nanorings Jonathan C. T. Carlson, Sidhartha S. Jena, Michelle Flenniken, Tsui-fen Chou, Ronald A. Siegel, and Carston R. Wagner pp 7630–7638 DOI: 10.1021/ja060631e Supporting Info

Switching of Macromolecular Helicity of Optically Active Poly(phenylacetylene)s Bearing Cyclodextrin Pendants Induced by Various External Stimuli Katsuhiro Maeda, Hiroaki Mochizuki, Masaki Watanabe, and Eiji Yashima pp 7639–7650 DOI: 10.1021/ja060858+ Supporting Info

Conformational Stabilization of an Engineered Binding Protein Elisabet Wahlberg and Torleif Härd pp 7651–7660 DOI: 10.1021/ja060933g Supporting Info

Ultrafast Excited-State Dynamics of DNA Fluorescent Intercalators:  New Insight into the Fluorescence Enhancement Mechanism Alexandre Fürstenberg, Marc D. Julliard, Todor G. Deligeorgiev, Nikolai I. Gadjev, Aleksey A. Vasilev, and Eric Vauthey pp 7661–7669 DOI: 10.1021/ja0609001 Supporting Info

High Fidelity Self-Sorting Assembling of meso-Cinchomeronimide Appended meso-meso Linked Zn(II) Diporphyrins Taisuke Kamada, Naoki Aratani, Toshiaki Ikeda, Naoki Shibata, Yoshiki Higuchi, Atsushi Wakamiya, Shigehiro Yamaguchi, Kil Suk Kim, Zin Seok Yoon, Dongho Kim, and Atsuhiro Osuka pp 7670–7678 DOI: 10.1021/ja0611137 Supporting Info

Electrostatic-Gated Transport in Chemically Modified Glass Nanopore Electrodes Gangli Wang, Bo Zhang, Joshua R. Wayment, Joel M. Harris, and Henry S. White pp 7679–7686 DOI: 10.1021/ja061357r Supporting Info

Catalytic Enantioselective Allylation of Ketoimines Reiko Wada, Tomoyuki Shibuguchi, Sae Makino, Kounosuke Oisaki, Motomu Kanai, and Masakatsu Shibasaki pp 7687–7691 DOI: 10.1021/ja061510h Supporting Info

Reversible Thermal and Photochemical Switching of Liquid Crystalline Phases and Luminescence in Diphenylbutadiene-Based Mesogenic Dimers Shibu Abraham, V. Ajay Mallia, K. Vijayaraghavan Ratheesh, Nobuyuki Tamaoki, and Suresh Das pp 7692–7698 DOI: 10.1021/ja061575k Supporting Info

Superconductivity in Complex Systems. Structure and Bonding, 114 Edited by K. Alex Müller (Physik-Institut der Universität Zürich) and Annette Bussmann-Holder (Max-Planck-Institut für Festkörperforschung, Stuttgart). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2005. xii + 394 pp. $339. ISBN 3-540-23123-2. Thomas P. Devereaux p 7699 DOI: 10.1021/ja059826x

Frontiers in Crystal Engineering Edited by Edward R. T. Tiekink (The University of Texas at San Antonio) and Jagadese J. Vittal (National University of Singapore). John Wiley & Sons, Ltd:  Chichester. 2006. xiv + 332 pp. $195.00. ISBN 0-470-02258-2. Penelope W. Codding pp 7699–7700 DOI: 10.1021/ja069714l

Frontiers in Chemical Sensors:  Novel Principles and Techniques. Springer Series on Chemical Sensors and Biosensors, 03 Edited by Guillermo Orellana and Maria C. Moreno-Bondi (Universidad Complutense, Madrid, Spain). Series Edited by O. S. Wolfbeis. Springer:  Berlin, Heidelberg, New York. 2005. xii + 370 pp. $199.00. ISBN 3-540-27756-0. Benjamin L. Miller p 7700 DOI: 10.1021/ja0697018

Issue 24

Photoinduced Charge Transfer Mediated by DNA-Wrapped Carbon Nanotubes Ming Zheng and Vsevolod V. Rostovtsev pp 7702–7703 DOI: 10.1021/ja061464l

An Unprecedented α-Olefin Distribution Arising from a Homogeneous Ethylene Oligomerization Catalyst Atanas K. Tomov, Juan J. Chirinos, Richard J. Long, Vernon C. Gibson, and Mark R. J. Elsegood pp 7704–7705 DOI: 10.1021/ja0615369 Supporting Info

Nitrogen-14 NMR Spectroscopy Using Residual Dipolar Splittings in Solids Simone Cavadini, Adonis Lupulescu, Sasa Antonijevic, and Geoffrey Bodenhausen pp 7706–7707 DOI: 10.1021/ja0618898

Water-Soluble Salicylaldiminato Ni(II)−Methyl Complexes:  Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation Inigo Göttker-Schnetmann, Brigitte Korthals, and Stefan Mecking pp 7708–7709 DOI: 10.1021/ja0619962 Supporting Info

Indirect Cation Pool Method. Rapid Generation of Alkoxycarbenium Ion Pools from Thioacetals Seiji Suga, Kouichi Matsumoto, Koji Ueoka, and Jun-ichi Yoshida pp 7710–7711 DOI: 10.1021/ja0625778 Supporting Info

Selective 6-endo Cyclization of the Acyl Radicals onto the Nitrogen of Imine and Oxazoline C−N Bonds Mami Tojino, Noboru Otsuka, Takahide Fukuyama, Hiroshi Matsubara, and Ilhyong Ryu pp 7712–7713 DOI: 10.1021/ja0623865 Supporting Info

Reduced Fluorescence Quenching of Cyclodextrin−Acetylene Dye Rotaxanes Jong S. Park, James N. Wilson, Kenneth I. Hardcastle, Uwe H. F. Bunz, and Mohan Srinivasarao pp 7714–7715 DOI: 10.1021/ja0584121 Supporting Info

The α-Iminophospholide Ligands Joanna Grundy, Bruno Donnadieu, and François Mathey pp 7716–7717 DOI: 10.1021/ja060100q Supporting Info

Unique Crystal Morphologies of Glycine Grown from Octanoic Acid-in-Water Emulsions Catherine E. Nicholson, Sharon J. Cooper, and Matthew J. Jamieson pp 7718–7719 DOI: 10.1021/ja0603608 Supporting Info

Solution Properties of Graphite and Graphene Sandip Niyogi, Elena Bekyarova, Mikhail E. Itkis, Jared L. McWilliams, Mark A. Hamon, and Robert C. Haddon pp 7720–7721 DOI: 10.1021/ja060680r

Switch-Peptides to Trigger the Peptide Guided Assembly of Poly(ethylene oxide)−Peptide Conjugates into Tape Structures Jens Hentschel, Eberhard Krause, and Hans G. Börner pp 7722–7723 DOI: 10.1021/ja060759w Supporting Info

Characterization of the Transition State of Functional Enzyme Dynamics Evgenii L. Kovrigin and J. Patrick Loria pp 7724–7725 DOI: 10.1021/ja061435a Supporting Info

Photocatalytic Generation of Hydrogen from Water Using a Platinum(II) Terpyridyl Acetylide Chromophore Pingwu Du, Jacob Schneider, Paul Jarosz, and Richard Eisenberg pp 7726–7727 DOI: 10.1021/ja0610683 Supporting Info

Nickel-Mediated Regioselective [2 + 2 + 2] Cycloaddition of Carboryne with Alkynes Liang Deng, Hoi-Shan Chan, and Zuowei Xie pp 7728–7729 DOI: 10.1021/ja061605j Supporting Info

Topography Printing to Locally Control Wettability Zijian Zheng, Omar Azzaroni, Feng Zhou, and Wilhelm T. S. Huck pp 7730–7731 DOI: 10.1021/ja061636e Supporting Info

Stable Mesoscopic Dye-Sensitized Solar Cells Based on Tetracyanoborate Ionic Liquid Electrolyte Daibin Kuang, Peng Wang, Seigo Ito, Shaik. M. Zakeeruddin, and Michael Grätzel pp 7732–7733 DOI: 10.1021/ja061714y Supporting Info

Identification of Single-Strand DNA by in situ Scanning Tunneling Microscopy Mikala Grubb, Hainer Wackerbarth, and Jens Ulstrup pp 7734–7735 DOI: 10.1021/ja061747d

Thermodynamics of Interactions of Vancomycin and Synthetic Surrogates of Bacterial Cell Wall Mikhail Rekharsky, Dusan Hesek, Mijoon Lee, Samy O. Meroueh, Yoshihisa Inoue, and Shahriar Mobashery pp 7736–7737 DOI: 10.1021/ja061828+ Supporting Info

The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone Ryan M. McFadden and Brian M. Stoltz pp 7738–7739 DOI: 10.1021/ja061853f Supporting Info

Discovery of a TNF-α Antagonist Using Chondroitin Sulfate Microarrays Sarah E. Tully, Manish Rawat, and Linda C. Hsieh-Wilson pp 7740–7741 DOI: 10.1021/ja061906t Supporting Info

Stereochemistry of Pteriatoxins A, B, and C Junliang Hao, Fumiyoshi Matsuura, Yoshito Kishi, Masaki Kita, Daisuke Uemura, Naoki Asai, and Takashi Iwashita pp 7742–7743 DOI: 10.1021/ja061893j Supporting Info

New Limits for Solid-State 17O NMR Spectroscopy:  Complete Resolution of Multiple Oxygen Sites in a Simple Biomolecule Alan Wong, Andy P. Howes, Kevin J. Pike, Vincent Lemaître, Anthony Watts, Tiit Anupõld, Jaan Past, Ago Samoson, Ray Dupree, and Mark E. Smith pp 7744–7745 DOI: 10.1021/ja062031l Supporting Info

Bond Fluctuation of S/Se Anchoring Observed in Single-Molecule Conductance Measurements using the Point Contact Method with Scanning Tunneling Microscopy Satoshi Yasuda, Shoji Yoshida, Jiro Sasaki, Yoshitaka Okutsu, Tohru Nakamura, Atsushi Taninaka, Osamu Takeuchi, and Hidemi Shigekawa pp 7746–7747 DOI: 10.1021/ja062066l

Amineborane-Based Chemical Hydrogen Storage:  Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids Martin E. Bluhm, Mark G. Bradley, Robert Butterick III, Upal Kusari, and Larry G. Sneddon pp 7748–7749 DOI: 10.1021/ja062085v

Se2(B2O7):  A New Type of Second-Order NLO Material Fang Kong, Shu-Ping Huang, Zhong-Ming Sun, Jiang-Gao Mao, and Wen-Dan Cheng pp 7750–7751 DOI: 10.1021/ja0620991 Supporting Info

Formation of Linear Polymers with Pendant Vinyl Groups via Inclusion Complex Mediated Polymerization of Divinyl Monomers Sunita S. Satav, Rohini N. Karmalkar, Mohan G. Kulkarni, Nagaraju Mulpuri, and G. Narahari Sastry pp 7752–7753 DOI: 10.1021/ja062568z Supporting Info

Enantioselective Photocycloaddition Mediated by Chiral Brønsted Acids:  Asymmetric Synthesis of the Rocaglamides Baudouin Gerard, Sheharbano Sangji, Daniel J. O'Leary, and John A. Porco, Jr. pp 7754–7755 DOI: 10.1021/ja062621j Supporting Info

Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence Ya-Ping Sun, Bing Zhou, Yi Lin, Wei Wang, K. A. Shiral Fernando, Pankaj Pathak, Mohammed Jaouad Meziani, Barbara A. Harruff, Xin Wang, Haifang Wang, Pengju G. Luo, Hua Yang, Muhammet Erkan Kose, Bailin Chen, L. Monica Veca, and Su-Yuan Xie pp 7756–7757 DOI: 10.1021/ja062677d Supporting Info

Combined Hydrogen Production and Storage with Subsequent Carbon Crystallization Angela D. Lueking, Humberto R. Gutierrez, Dania A. Fonseca, Deepa L. Narayanan, Dirk Van Essendelft, Puja Jain, and Caroline E. B. Clifford pp 7758–7760 DOI: 10.1021/ja0604818 Supporting Info

Identification of a Quenching Species in Ruthenium Tris-Bipyridine Electroluminescent Devices Leonard J. Soltzberg, Jason D. Slinker, Samuel Flores-Torres, Daniel A. Bernards, George G. Malliaras, Hector D. Abruña, Ji-Seon Kim, Richard H. Friend, Michael D. Kaplan, and Velda Goldberg pp 7761–7764 DOI: 10.1021/ja055782g

Phosphate Activation in the Ground State of Purine Nucleoside Phosphorylase Hua Deng, Andrew S. Murkin, and Vern L. Schramm pp 7765–7771 DOI: 10.1021/ja0570281

Ligation-State Hydrogen Exchange:  Coupled Binding and Folding Equilibria in Ribonuclease P Protein Christopher H. Henkels and Terrence G. Oas pp 7772–7781 DOI: 10.1021/ja057279+ Supporting Info

Mechanism of the Diphenyldisulfone-Catalyzed Isomerization of Alkenes. Origin of the Chemoselectivity:  Experimental and Quantum Chemistry Studies Dean Marković, Adrián Varela-Álvarez, José Angel Sordo, and Pierre Vogel pp 7782–7795 DOI: 10.1021/ja0579210 Supporting Info

Direct Observation of Salt Effects on Molecular Interactions through Explicit-Solvent Molecular Dynamics Simulations:  Differential Effects on Electrostatic and Hydrophobic Interactions and Comparisons to Poisson−Boltzmann Theory Andrew S. Thomas and Adrian H. Elcock pp 7796–7806 DOI: 10.1021/ja058637b Supporting Info

A High-Frequency EPR Study of Frozen Solutions of GdIII Complexes:  Straightforward Determination of the Zero-Field Splitting Parameters and Simulation of the NMRD Profiles Meriem Benmelouka, Johan Van Tol, Alain Borel, Marc Port, Lothar Helm, Louis Claude Brunel, and André E. Merbach pp 7807–7816 DOI: 10.1021/ja0583261 Supporting Info

A Solid-State 95Mo NMR and Computational Investigation of Dodecahedral and Square Antiprismatic Octacyanomolybdate(IV) Anions:  Is the Point-Charge Approximation an Accurate Probe of Local Symmetry? Michelle A. M. Forgeron and Roderick E. Wasylishen pp 7817–7827 DOI: 10.1021/ja060124x Supporting Info

The Dewar Benzene Radical Cation and Its Ring-Opening Reaction Thomas Bally, Stephan Matzinger, and Pawel Bednarek pp 7828–7834 DOI: 10.1021/ja060176m Supporting Info

Theoretical Studies of Quantum Amplified Isomerizations for Imaging Systems Involving Hexamethyl Dewar Benzene and Related Systems Joseph E. Norton, Leif P. Olson, and K. N. Houk pp 7835–7845 DOI: 10.1021/ja060182i Supporting Info

A High-Throughput, High-Resolution Strategy for the Study of Site-Selective DNA Binding Agents:  Analysis of a “Highly Twisted” Benzimidazole-Diamidine Kristie D. Goodwin, Mark A. Lewis, Farial A. Tanious, Richard R. Tidwell, W. David Wilson, Millie M. Georgiadis, and Eric C. Long pp 7846–7854 DOI: 10.1021/ja0600936 Supporting Info

Variability of the 15N Chemical Shielding Tensors in the B3 Domain of Protein G from 15N Relaxation Measurements at Several Fields. Implications for Backbone Order Parameters Jennifer B. Hall and David Fushman pp 7855–7870 DOI: 10.1021/ja060406x Supporting Info

Quantitative Imaging of Protein Adsorption on Patterned Organic Thin-Film Arrays Using Secondary Electron Emission Nathan H. Mack, Rui Dong, and Ralph G. Nuzzo pp 7871–7881 DOI: 10.1021/ja060248+ Supporting Info

Long-Range Structural Order, Moiré Patterns, and Iridescence in Latex-Stabilized Foams Syuji Fujii, Anthony J. Ryan, and Steven P. Armes pp 7882–7886 DOI: 10.1021/ja060640n Supporting Info

Computational Simulations of HIV-1 ProteasesMulti-drug Resistance Due to Nonactive Site Mutation L90M Hirotaka Ode, Saburo Neya, Masayuki Hata, Wataru Sugiura, and Tyuji Hoshino pp 7887–7895 DOI: 10.1021/ja060682b Supporting Info

Antitumor Enediyne Chromoprotein C-1027:  Mechanistic Investigation of the Chromophore-Mediated Self-Decomposition Pathway Masayuki Inoue, Toyonobu Usuki, Nayoung Lee, Masahiro Hirama, Toshiyuki Tanaka, Fumihito Hosoi, Shinji Ohie, and Toshio Otani pp 7896–7903 DOI: 10.1021/ja060724w Supporting Info

Primary Reaction Steps of Al13- Clusters in an HCl Atmosphere:  Snapshots of the Dissolution of a Base Metal Ralf Burgert, Sarah T. Stokes, Kit H. Bowen, and Hansgeorg Schnöckel pp 7904–7908 DOI: 10.1021/ja060613x Supporting Info

Redox-Coupled Dynamics and Folding in Cytochrome c Laura B. Sagle, Jörg Zimmermann, Shigeo Matsuda, Philip E. Dawson, and Floyd E. Romesberg pp 7909–7915 DOI: 10.1021/ja060851s Supporting Info

Diproline Templates as Folding Nuclei in Designed Peptides. Conformational Analysis of Synthetic Peptide Helices Containing Amino Terminal Pro-Pro Segments Rajkishor Rai, Subrayashastry Aravinda, Karuppiah Kanagarajadurai, Srinivasarao Raghothama, Narayanaswamy Shamala, and Padmanabhan Balaram pp 7916–7928 DOI: 10.1021/ja060674v Supporting Info

Aptamers Selected for Higher-Affinity Binding Are Not More Specific for the Target Ligand James M. Carothers, Stephanie C. Oestreich, and Jack W. Szostak pp 7929–7937 DOI: 10.1021/ja060952q Supporting Info

Local Heating of Discrete Droplets Using Magnetic Porous Silicon-Based Photonic Crystals Ji-Ho Park, Austin M. Derfus, Ester Segal, Kenneth S. Vecchio, Sangeeta N. Bhatia, and Michael J. Sailor pp 7938–7946 DOI: 10.1021/ja0612854

A Family of Rare-Earth-Based Single Chain Magnets:  Playing with Anisotropy Kevin Bernot, Lapo Bogani, Andrea Caneschi, Dante Gatteschi, and Roberta Sessoli pp 7947–7956 DOI: 10.1021/ja061101l Supporting Info

Hydration Regulates Thermodynamics of G-Quadruplex Formation under Molecular Crowding Conditions Daisuke Miyoshi, Hisae Karimata, and Naoki Sugimoto pp 7957–7963 DOI: 10.1021/ja061267m Supporting Info

Sol−Gel Assembly of CdSe Nanoparticles to Form Porous Aerogel Networks Indika U. Arachchige and Stephanie L. Brock pp 7964–7971 DOI: 10.1021/ja061561e Supporting Info

Nuclear and Magnetic Structures and Magnetic Properties of the Layered Cobalt Hydroxysulfate Co5(OH)6(SO4)2(H2O)4 and Its Deuterated Analogue, Co5(OD)6(SO4)2(D2O)4 Mohsen Ben Salah, Serge Vilminot, Gilles André, Mireille Richard-Plouet, Tahar Mhiri, Seishi Takagi, and Mohamedally Kurmoo pp 7972–7981 DOI: 10.1021/ja061302p Supporting Info

Hydrogen−Deuterium Exchange between TpRu(PMe3)(L)X (L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and Deuterated Arene Solvents:  Evidence for Metal-Mediated Processes Yuee Feng, Marty Lail, Nicholas A. Foley, T. Brent Gunnoe, Khaldoon A. Barakat, Thomas R. Cundari, and Jeffrey L. Petersen pp 7982–7994 DOI: 10.1021/ja0615775 Supporting Info

Tunable Columnar Mesophases Utilizing C2 Symmetric Aromatic Donor−Acceptor Complexes Joseph J. Reczek, Karen R. Villazor, Vincent Lynch, Timothy M. Swager, and Brent L. Iverson pp 7995–8002 DOI: 10.1021/ja061649s Supporting Info

Configuration-Dependent Interface Charge Transfer at a Molecule−Metal Junction Li Wang, Lei Liu, Wei Chen, Yuanping Feng, and Andrew T. S. Wee pp 8003–8007 DOI: 10.1021/ja061741o

Experimental Probe for Hyperconjugative Resonance Contribution in Stabilizing the Singlet State of 2,2-Dialkoxy-1,3-diyls:  Regioselective 1,2-Oxygen Migration Manabu Abe, Masanori Hattori, Akinobu Takegami, Araki Masuyama, Takashi Hayashi, Shu Seki, and Seiichi Tagawa pp 8008–8014 DOI: 10.1021/ja0617688 Supporting Info

Hydride Transfer Reaction Catalyzed by Hyperthermophilic Dihydrofolate Reductase Is Dominated by Quantum Mechanical Tunneling and Is Promoted by Both Inter- and Intramonomeric Correlated Motions Jiayun Pang, Jingzhi Pu, Jiali Gao, Donald G. Truhlar, and Rudolf K. Allemann pp 8015–8023 DOI: 10.1021/ja061585l Supporting Info

Synthesis and Properties of Endohedral C60 Encapsulating Molecular Hydrogen Michihisa Murata, Yasujiro Murata, and Koichi Komatsu pp 8024–8033 DOI: 10.1021/ja061857k Supporting Info

Helix Triangle:  Unique Peptide-Based Molecular Architecture Kentaro Yoshida, Shin-ichi Kawamura, Tomoyuki Morita, and Shunsaku Kimura pp 8034–8041 DOI: 10.1021/ja061989d Supporting Info

Mechanistic Analysis of Reductive Nitrosylation on Water-Soluble Cobalt(III)-Porphyrins Federico Roncaroli and Rudi van Eldik pp 8042–8053 DOI: 10.1021/ja0549906 Supporting Info

Dynamics on the Microsecond Timescale in Microporous Aluminophosphate AlPO-14 as Evidenced by 27Al MQMAS and STMAS NMR Spectroscopy Sasa Antonijevic, Sharon E. Ashbrook, Silke Biedasek, Richard I. Walton, Stephen Wimperis, and Huaixin Yang pp 8054–8062 DOI: 10.1021/ja057682g

Site-Specific Cleavage of RNA by a Metal-Free Artificial Nuclease Attached to Antisense Oligonucleotides Claudio Gnaccarini, Sascha Peter, Ute Scheffer, Stefan Vonhoff, Sven Klussmann, and Michael W. Göbel pp 8063–8067 DOI: 10.1021/ja061036f Supporting Info

Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides:  A Complement to the Heck Reaction Walter Affo, Hirohisa Ohmiya, Takuma Fujioka, Yousuke Ikeda, Tomoaki Nakamura, Hideki Yorimitsu, Koichiro Oshima, Yuki Imamura, Tsutomu Mizuta, and Katsuhiko Miyoshi pp 8068–8077 DOI: 10.1021/ja061417t Supporting Info

Stereocontrolled Synthesis of the d- and l-glycero-β-d-manno-Heptopyranosides and Their 6-Deoxy Analogues. Synthesis of Methyl α-l-Rhamno-pyranosyl-(1→3)-d-glycero-β-d-manno-heptopyranosyl- (1→3)-6-deoxy-glycero-β-d-manno-heptopyranosyl-(1→4)-α-l- rhamno-pyranoside, a Tetrasaccharide Subunit of the Lipopolysaccharide from Plesimonas shigelloides David Crich and Abhisek Banerjee pp 8078–8086 DOI: 10.1021/ja061594u Supporting Info

Total Syntheses of the Telomerase Inhibitors Dictyodendrin B, C, and E Alois Fürstner, Mathias M. Domostoj, and Bodo Scheiper pp 8087–8094 DOI: 10.1021/ja0617800 Supporting Info

Quaternary Stereocenters:  Challenges and Solutions for Organic Synthesis Edited by Jens Christoffers and Angelika Baro (Universität Stuttgart). Wiley-VCH Verlag GmbH & Co. KGA:  Weinheim. 2005. xxiv + 336 pp. $170. ISBN 3-527-31107-6. Tomislav Rovis p 8095 DOI: 10.1021/ja0598917

Chromatographic Analysis of the Environment, 3rd Edition Edited by Leo M. L. Nollet (Hogeschool Gent, Ghent, Belgium). CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2006. xx + 1298 pp. $249.95. ISBN 0-8247-2629-4. p 8095 DOI: 10.1021/ja069720h

Dictionary of Carbohydrates with CD-ROM, 2nd Edition Edited by Peter M. Collins (University of London). Chapman and Hall/CRC/Taylor & Francis Group:  Boca Raton, FL. 2006. xxii + 1282 pp. $399.00. ISBN 0-8493-3829-8. pp 8095–8096 DOI: 10.1021/ja069718q

Organic Photochemistry and Photophysics. Molecular and Supramolecular Photochemistry, Volume 14 Edited by Vaidhyanathan Ramamurthy (University of Miami) and Kirk S. Schanze (University of Florida). CRC Press/Taylor & Francis:  Boca Raton, FL. 2006. xii + 300 pp. $169.95. ISBN 0-8493-7608-4. Anna D. Gudmundsdóttir p 8096 DOI: 10.1021/ja069719i

Modern Aspects of Main Group Chemistry. ACS Symposium Series 917 Edited by Michael Lattman (Southern Methodist University) and Richard Kemp (University of New Mexico and Sandia National Labs). American Chemical Society:  Washington, DC. 2006 (Distributed by Oxford University Press). xvi + 464 pp. $174.50. ISBN 0-84-123926-6. p 8096 DOI: 10.1021/ja0697323

Issue 25

The Organization of Aromatic Side Groups in an Amyloid Fibril Probed by Solid-State 2H and 19F NMR Spectroscopy Edward Jack, Matthew Newsome, Peter G. Stockley, Sheena E. Radford, and David A. Middleton pp 8098–8099 DOI: 10.1021/ja0581898 Supporting Info

Cooperative 4-Pyridone H-Bonds with Extraordinary Stability. A DFT Molecular Orbital Study Yung-fou Chen and J. J. Dannenberg pp 8100–8101 DOI: 10.1021/ja060494l Supporting Info

A Monolithiated and Its Related 1,3-Dilithiated Allylsilane:  Syntheses, Crystal Structures, and Reactivity Carsten Strohmann, Klaus Lehmen, and Stefan Dilsky pp 8102–8103 DOI: 10.1021/ja061286w Supporting Info

Determination of Lysine pK Values Using [5-13C]Lysine:  Application to the Lyase Domain of DNA Pol β Guanghua Gao, Rajendra Prasad, Siegfried N. Lodwig, Clifford J. Unkefer, William A. Beard, Samuel H. Wilson, and Robert E. London pp 8104–8105 DOI: 10.1021/ja061473u Supporting Info

To Patterned Binary Polymer Brushes via Capillary Force Lithography and Surface-Initiated Polymerization Yong Liu, Viktor Klep, and Igor Luzinov pp 8106–8107 DOI: 10.1021/ja061646f Supporting Info

Enhanced Open-Circuit Voltage in Subphthalocyanine/C60 Organic Photovoltaic Cells Kristin L. Mutolo, Elizabeth I. Mayo, Barry P. Rand, Stephen R. Forrest, and Mark E. Thompson pp 8108–8109 DOI: 10.1021/ja061655o Supporting Info

Off-Resonance TROSY-Selected R1ρ Experiment with Improved Sensitivity for Medium- and High-Molecular-Weight Proteins Tatyana I. Igumenova and Arthur G. Palmer, III pp 8110–8111 DOI: 10.1021/ja061692f Supporting Info

Reciprocity of Steric and Stereoelectronic Effects in the Collagen Triple Helix Matthew D. Shoulders, Jonathan A. Hodges, and Ronald T. Raines pp 8112–8113 DOI: 10.1021/ja061793d Supporting Info

Transition State Stabilization and α-Amino Carbon Acidity in Alanine Racemase Dan T. Major, Kwangho Nam, and Jiali Gao pp 8114–8115 DOI: 10.1021/ja062272t Supporting Info

Confinement and Controlled Release of Bisphosphonates on Ordered Mesoporous Silica-Based Materials Francisco Balas, Miguel Manzano, Patricia Horcajada, and María Vallet-Regí pp 8116–8117 DOI: 10.1021/ja062286z Supporting Info

Distance Distributions of Short Polypeptides Recovered by Fluorescence Resonance Energy Transfer in the 10 Å Domain Harekrushna Sahoo, Danilo Roccatano, Martin Zacharias, and Werner M. Nau pp 8118–8119 DOI: 10.1021/ja062293n Supporting Info

A Modular Approach to Ferroelectric Polymers with Chemically Tunable Curie Temperatures and Dielectric Constants Yingying Lu, Jason Claude, Bret Neese, Qiming Zhang, and Qing Wang pp 8120–8121 DOI: 10.1021/ja062306x Supporting Info

Self-Assembling Bisurea Macrocycles Used as an Organic Zeolite for a Highly Stereoselective Photodimerization of 2-Cyclohexenone Jun Yang, Mahender B. Dewal, and Linda S. Shimizu pp 8122–8123 DOI: 10.1021/ja062337s Supporting Info

Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters Takanori Shima and Zhaomin Hou pp 8124–8125 DOI: 10.1021/ja062348l Supporting Info

Total Synthesis and Absolute Stereochemical Assignment of (+)- and (−)-Galbulimima Alkaloid 13 Mohammad Movassaghi, Diana K. Hunt, and Meiliana Tjandra pp 8126–8127 DOI: 10.1021/ja0626180 Supporting Info

Geosmin Biosynthesis. Streptomyces coelicolor Germacradienol/Germacrene D Synthase Converts Farnesyl Diphosphate to Geosmin Jiaoyang Jiang, Xiaofei He, and David E. Cane pp 8128–8129 DOI: 10.1021/ja062669x Supporting Info

Chiral Permselectivity in Surface-Modified Nanoporous Opal Films Julie Cichelli and Ilya Zharov pp 8130–8131 DOI: 10.1021/ja062672g Supporting Info

Gold(I)-Catalyzed Synthesis of Dihydropyrans Benjamin D. Sherry, Lisa Maus, Brian Ngo Laforteza, and F. Dean Toste pp 8132–8133 DOI: 10.1021/ja061344d Supporting Info

Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene Norio Sakai, André Ridder, and John F. Hartwig pp 8134–8135 DOI: 10.1021/ja061349a Supporting Info

Hydrogen Storage in Metal−Organic Frameworks by Bridged Hydrogen Spillover Yingwei Li and Ralph T. Yang pp 8136–8137 DOI: 10.1021/ja061681m Supporting Info

Synthesis of Mixed Sequence Borane Phosphonate DNA Heather Brummel McCuen, Mary S. Noé, Agnieszka B. Sierzchala, Adrian P. Higson, and Marvin H. Caruthers pp 8138–8139 DOI: 10.1021/ja061757e Supporting Info

Most Stable Metallic Phase of the Mixed-Valence MMX-Chain, Pt2(dtp)4I (dtp = C2H5CS2-), in Purely d-Electronic Conductors Based on the Transition-Metal Complex Kazuya Otsubo, Atsushi Kobayashi, Hiroshi Kitagawa, Masato Hedo, Yoshiya Uwatoko, Hajime Sagayama, Yusuke Wakabayashi, and Hiroshi Sawa pp 8140–8141 DOI: 10.1021/ja061871x Supporting Info

Regiochemical Control in the Metal-Catalyzed Transposition of Allylic Silyl Ethers Eric C. Hansen and Daesung Lee pp 8142–8143 DOI: 10.1021/ja0620639 Supporting Info

Backbone-Thermoresponsive Hyperbranched Polyethers Zhifeng Jia, Hao Chen, Xinyuan Zhu, and Deyue Yan pp 8144–8145 DOI: 10.1021/ja062314d Supporting Info

Hydroheteroarylation of Alkynes under Mild Nickel Catalysis Yoshiaki Nakao, Kyalo Stephen Kanyiva, Shinichi Oda, and Tamejiro Hiyama pp 8146–8147 DOI: 10.1021/ja0623459 Supporting Info

Germanium Telluride Nanowires and Nanohelices with Memory-Switching Behavior Dong Yu, Junqiao Wu, Qian Gu, and Hongkun Park pp 8148–8149 DOI: 10.1021/ja0625071 Supporting Info

Palladium-Catalyzed Coupling of Allylboronic Acids with Iodobenzenes. Selective Formation of the Branched Allylic Product in the Absence of Directing Groups Sara Sebelius, Vilhelm J. Olsson, Olov A. Wallner, and Kálmán J. Szabó pp 8150–8151 DOI: 10.1021/ja062585o Supporting Info

Rh(I)-Catalyzed Silylation of Aryl and Alkenyl Cyanides Involving the Cleavage of C−C and Si−Si Bonds Mamoru Tobisu, Yusuke Kita, and Naoto Chatani pp 8152–8153 DOI: 10.1021/ja062745w Supporting Info

Potentiometry at Trace Levels in Confined Samples:  Ion-Selective Electrodes with Subfemtomole Detection Limits Adam Malon, Tamás Vigassy, Eric Bakker, and Ernö Pretsch pp 8154–8155 DOI: 10.1021/ja0625780 Supporting Info

Asymmetric Friedel−Crafts Reaction of Indoles with Imines by an Organic Catalyst Yong-Qiang Wang, Jun Song, Ran Hong, Hongming Li, and Li Deng pp 8156–8157 DOI: 10.1021/ja062700v Supporting Info

High Performance Poly(styrene-b-diene-b-styrene) Triblock Copolymers from a Hydrocarbon-Soluble and Additive-Free Dicarbanionic Initiator Rachid Matmour, Arvind S. More, Prakash P. Wadgaonkar, and Yves Gnanou pp 8158–8159 DOI: 10.1021/ja062695v Supporting Info

Enantioselective Synthesis of Bridged- or Fused-Ring Bicyclic Ketones by a Catalytic Asymmetric Michael Addition Pathway Duan Liu, Sungwoo Hong, and E. J. Corey pp 8160–8161 DOI: 10.1021/ja063332y Supporting Info

Nonchelated d0 Zirconium−Alkoxide−Alkene Complexes Edward J. Stoebenau, III and Richard F. Jordan pp 8162–8175 DOI: 10.1021/ja0575225 Supporting Info

Trehalose Click Polymers Inhibit Nanoparticle Aggregation and Promote pDNA Delivery in Serum Sathya Srinivasachari, Yemin Liu, Guodong Zhang, Lisa Prevette, and Theresa M. Reineke pp 8176–8184 DOI: 10.1021/ja0585580 Supporting Info

Two-State Reactivity, Electromerism, Tautomerism, and “Surprise” Isomers in the Formation of Compound II of the Enzyme Horseradish Peroxidase from the Principal Species, Compound I Etienne Derat and Sason Shaik pp 8185–8198 DOI: 10.1021/ja0600734 Supporting Info

Solid-State Acid−Base Interactions in Complexes of Heterocyclic Bases with Dicarboxylic Acids:  Crystallography, Hydrogen Bond Analysis, and 15N NMR Spectroscopy Z. Jane Li, Yuriy Abramov, Jon Bordner, Jason Leonard, Ales Medek, and Andrew V. Trask pp 8199–8210 DOI: 10.1021/ja0541332 Supporting Info

Perturbation of Conjugation in Internally Solvated Allylic Lithium Compounds:  Variation of Ligand Structure.  NMR and X-ray Crystallography Gideon Fraenkel, Judith Gallucci, and Hua Liu pp 8211–8216 DOI: 10.1021/ja060272n Supporting Info

Size- and Shape-Dependent Transformation of Nanosized Titanate into Analogous Anatase Titania Nanostructures Yuanbing Mao and Stanislaus S. Wong pp 8217–8226 DOI: 10.1021/ja0607483 Supporting Info

Temperature- and Length-Dependent Energetics of Formation for Polyalanine Helices in Water:  Assignment of wAla(n,T) and Temperature-Dependent CD Ellipticity Standards Gabriel E. Job, Robert J. Kennedy, Björn Heitmann, Justin S. Miller, Sharon M. Walker, and Daniel S. Kemp pp 8227–8233 DOI: 10.1021/ja060094y Supporting Info

Toward Exceeding the Shockley−Queisser Limit:  Photoinduced Interfacial Charge Transfer Processes that Store Energy in Excess of the Equilibrated Excited State Paul G. Hoertz, Aaron Staniszewski, Andras Marton, Gerard T. Higgins, Christopher D. Incarvito, Arnold L. Rheingold, and Gerald J. Meyer pp 8234–8245 DOI: 10.1021/ja060470e Supporting Info

Investigation of Dipolar-Mediated Water−Protein Interactions in Microcrystalline Crh by Solid-State NMR Spectroscopy Anne Lesage, Lyndon Emsley, François Penin, and Anja Böckmann pp 8246–8255 DOI: 10.1021/ja060866q

Topology of an Outer-Membrane Enzyme:  Measuring Oxygen and Water Contacts in Solution NMR Studies of PagP Ferenc Evanics, Peter M. Hwang, Yao Cheng, Lewis E. Kay, and R. Scott Prosser pp 8256–8264 DOI: 10.1021/ja0610075

Dendrimers as a Scaffold for Nitric Oxide Release Nathan A. Stasko and Mark H. Schoenfisch pp 8265–8271 DOI: 10.1021/ja060875z Supporting Info

An Approach to Helical Tubular Self-Aggregation Using C2-Symmetric Self-Complementary Hydrogen-Bonding Cavity Molecules Sigitas Stonius, Edvinas Orentas, Eugenius Butkus, Lars Öhrström, Ola F. Wendt, and Kenneth Wärnmark pp 8272–8285 DOI: 10.1021/ja061160z Supporting Info

X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO2 Species:  Superoxide−CuII versus Peroxide−CuIII Bonding Ritimukta Sarangi, Nermeen Aboelella, Kiyoshi Fujisawa, William B. Tolman, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 8286–8296 DOI: 10.1021/ja0615223 Supporting Info

Structures, Photoluminescence, and Reversible Vapoluminescence Properties of Neutral Platinum(II) Complexes Containing Extended π-Conjugated Cyclometalated Ligands Steven C. F. Kui, Stephen Sin-Yin Chui, Chi-Ming Che, and Nianyong Zhu pp 8297–8309 DOI: 10.1021/ja061422x Supporting Info

Structural Basis of the Inhibition of Golgi α-Mannosidase II by Mannostatin A and the Role of the Thiomethyl Moiety in Ligand−Protein Interactions Sameer P. Kawatkar, Douglas A. Kuntz, Robert J. Woods, David R. Rose, and Geert-Jan Boons pp 8310–8319 DOI: 10.1021/ja061216p Supporting Info

Artificial Transfer Hydrogenases Based on the Biotin−(Strept)avidin Technology:  Fine Tuning the Selectivity by Saturation Mutagenesis of the Host Protein Christophe Letondor, Anca Pordea, Nicolas Humbert, Anita Ivanova, Sylwester Mazurek, Marjana Novic, and Thomas R. Ward pp 8320–8328 DOI: 10.1021/ja061580o Supporting Info

Carbonic Anhydrase Inhibitors:  X-ray and Molecular Modeling Study for the Interaction of a Fluorescent Antitumor Sulfonamide with Isozyme II and IX Vincenzo Alterio, Rosa Maria Vitale, Simona Maria Monti, Carlo Pedone, Andrea Scozzafava, Alessandro Cecchi, Giuseppina De Simone, and Claudiu T. Supuran pp 8329–8335 DOI: 10.1021/ja061574s

Synthesis of Bicyclic p-Diiodobenzenes via Silver-Catalyzed Csp-H Iodination and Ruthenium-Catalyzed Cycloaddition Yoshihiko Yamamoto, Kozo Hattori, and Hisao Nishiyama pp 8336–8340 DOI: 10.1021/ja061619p Supporting Info

Divergent Growth of Coordination Dendrimers on Surfaces Meni Wanunu, Alexander Vaskevich, Abraham Shanzer, and Israel Rubinstein pp 8341–8349 DOI: 10.1021/ja061761q

Validation of the M−C/H−C Bond Enthalpy Relationship through Application of Density Functional Theory Eric Clot, Claire Mégret, Odile Eisenstein, and Robin N. Perutz pp 8350–8357 DOI: 10.1021/ja061803a Supporting Info

X-ray Illumination Induced Fe(II) Spin Crossover in the Prussian Blue Analogue Cesium Iron Hexacyanochromate Dionisis Papanikolaou, Serena Margadonna, Wataru Kosaka, Shin-ichi Ohkoshi, Michela Brunelli, and Kosmas Prassides pp 8358–8363 DOI: 10.1021/ja061650r

Diversity Synthesis via C−H Bond Functionalization:  Concept-Guided Development of New C-Arylation Methods for Imidazoles [J. Am. Chem. Soc. 2003, 125, 10580−10585]. Bengü Sezen and Dalibor Sames p 8364 DOI: 10.1021/ja0699642

Selective C-Arylation of Free (NH)-Heteroarenes via Catalytic C−H Bond Functionalization [J. Am. Chem. Soc. 2003, 125, 5274−5275]. Bengü Sezen and Dalibor Sames p 8364 DOI: 10.1021/ja069965u

C−C Bond Formation via C−H Bond Activation:  Catalytic Arylation and Alkenylation of Alkane Segments [J. Am. Chem. Soc. 2002, 124, 13372−13373]. Bengü Sezen, Roberto Franz, and Dalibor Sames p 8364 DOI: 10.1021/ja069966m

Environmental Catalysis Edited by Vicki H. Grassian (University of Iowa). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, FL. 2005. xx + 702 pp. $169.95. ISBN 1-57444-462-X. Israel E. Wachs p 8365 DOI: 10.1021/ja059877u

Combinatorial Chemistry and Technologies:  Methods and Applications, 2nd Edition Edited by Giorgio Fassina (XEPTAGEN S.p.A., Pozzuoli, Italy) and Stanislav Miertus (University of Trieste, Italy). CRC Press (an imprint of Taylor and Francis). 2005. xvi + 598 pp. $169.95. ISBN 0-8247-5837-4. Tobin J. Dickerson pp 8365–8366 DOI: 10.1021/ja059872x

Issue 26

Atomic-Scale Deformation in N-Doped Carbon Nanotubes Chia-Liang Sun, Houng-Wei Wang, Michitoshi Hayashi, Li-Chyong Chen, and Kuei-Hsien Chen pp 8368–8369 DOI: 10.1021/ja0587852 Supporting Info

Cycloaddition Reaction of 1,3-Butadiene with a Symmetric Si Adatom Pair on the Si(111)7×7 Surface Jaeyoon Baik, Minkook Kim, Chong-Yun Park, Yunsoo Kim, Joung Real Ahn, and Ki-Seok An pp 8370–8371 DOI: 10.1021/ja0600072

2‘-Hydroxyl Proton Positions in Helical RNA from Simultaneously Measured Heteronuclear Scalar Couplings and NOEs Jinfa Ying and Ad Bax pp 8372–8373 DOI: 10.1021/ja0606226 Supporting Info

Preparation, Characterization, and Substrate Metabolism of Gold-Immobilized Cytochrome P450 2C9 Peter M. Gannett, Jarod Kabulski, Felio A. Perez, Zhongyuan Liu, David Lederman, Charles W. Locuson, Robyn R. Ayscue, Nissa M. Thomsen, and Timothy S. Tracy pp 8374–8375 DOI: 10.1021/ja0608693 Supporting Info

Particle−Particle Interactions between Layered Double Hydroxide Nanoparticles Jennifer A. Gursky, Sandra D. Blough, Cesar Luna, Clarissa Gomez, Amber N. Luevano, and Elizabeth A. Gardner pp 8376–8377 DOI: 10.1021/ja0612100

Multiplexed Detection of Protein Cancer Markers with Biobarcoded Nanoparticle Probes Savka I. Stoeva, Jae-Seung Lee, Jennifer E. Smith, Steven T. Rosen, and Chad A. Mirkin pp 8378–8379 DOI: 10.1021/ja0613106 Supporting Info

Conjugated Chromophore Arrays with Unusually Large Hole Polaron Delocalization Lengths Kimihiro Susumu, Paul R. Frail, Paul J. Angiolillo, and Michael J. Therien pp 8380–8381 DOI: 10.1021/ja0614823 Supporting Info

Synthesis of Amphiphilic Superparamagnetic Ferrite/Block Copolymer Hollow Submicrospheres Xin-Hao Li, Dong-Hui Zhang, and Jie-Sheng Chen pp 8382–8383 DOI: 10.1021/ja061460g Supporting Info

Oxide Hemostatic Activity Todd A. Ostomel, Qihui Shi, and Galen D. Stucky pp 8384–8385 DOI: 10.1021/ja061717a Supporting Info

Model Compounds of Ruthenium−Alkene Intermediates in Olefin Metathesis Reactions Donde R. Anderson, Daniel D. Hickstein, Daniel J. O'Leary, and Robert H. Grubbs pp 8386–8387 DOI: 10.1021/ja0618090 Supporting Info

Radical Trapping by Gold Chlorides Forming Organogold Intermediates Carmela Aprile, Mercedes Boronat, Belén Ferrer, Avelino Corma, and Hermenegildo García pp 8388–8389 DOI: 10.1021/ja062000q Supporting Info

Sn122-:  Stannaspherene Li-Feng Cui, Xin Huang, Lei-Ming Wang, Dmitry Yu. Zubarev, Alexander I. Boldyrev, Jun Li, and Lai-Sheng Wang pp 8390–8391 DOI: 10.1021/ja062052f Supporting Info

Charge Flipping at Work:  A Case of Pseudosymmetry Gábor Oszlányi, András Sütő, Mátyás Czugler, and László Párkányi pp 8392–8393 DOI: 10.1021/ja062131r

New Mechanistic Insights Regarding Pd/Cu Catalysts for the Sonogashira Reaction:  HRMAS NMR Studies of Silica-Immobilized Systems Tobias Posset and Janet Blümel pp 8394–8395 DOI: 10.1021/ja062206r

Dielectrophoresis Field Flow Fractionation of Single-Walled Carbon Nanotubes Haiqing Peng, Noe T. Alvarez, Carter Kittrell, Robert H. Hauge, and Howard K. Schmidt pp 8396–8397 DOI: 10.1021/ja0621501 Supporting Info

Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal−Organic Great Rhombicuboctahedron Hiroyasu Furukawa, Jaheon Kim, Katherine E. Plass, and Omar M. Yaghi pp 8398–8399 DOI: 10.1021/ja062491e Supporting Info

Optical Sensing of Parts per Million Levels of Water in Organic Solvents Using Redox-Active Osmium Chromophore-Based Monolayers Tarkeshwar Gupta and Milko E. van der Boom pp 8400–8401 DOI: 10.1021/ja062538w Supporting Info

Accounting for Spin Relaxation in Quantitative Pulse Gradient Spin Echo NMR Mixture Analysis Brian Antalek pp 8402–8403 DOI: 10.1021/ja062592c Supporting Info

Toward a Protecting-Group-Free Halogen−Metal Exchange Reaction:  Practical, Chemoselective Metalation of Functionalized Aromatic Halides Using Dianion-type Zincate, tBu4ZnLi2 Masanobu Uchiyama, Taniyuki Furuyama, Minoru Kobayashi, Yotaro Matsumoto, and Kentaro Tanaka pp 8404–8405 DOI: 10.1021/ja058246x Supporting Info

Mapping Allostery through Equilibrium Perturbation NMR Spectroscopy Rahul Das, Mona Abu-Abed, and Giuseppe Melacini pp 8406–8407 DOI: 10.1021/ja060046d Supporting Info

Magnetic Field Effects and Radical Pair Mechanisms in Enzymes:  A Reappraisal of the Horseradish Peroxidase System Alex R. Jones, Nigel S. Scrutton, and Jonathan R. Woodward pp 8408–8409 DOI: 10.1021/ja060463q Supporting Info

C−C Bond-Forming Reductive Elimination from a Zirconium(IV) Redox-Active Ligand Complex Mason R. Haneline and Alan F. Heyduk pp 8410–8411 DOI: 10.1021/ja061107a Supporting Info

2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO:  Highly Efficient Organocatalysts for Oxidation of Alcohols Masatoshi Shibuya, Masaki Tomizawa, Iwao Suzuki, and Yoshiharu Iwabuchi pp 8412–8413 DOI: 10.1021/ja0620336 Supporting Info

A Highly Efficient Preparative Method of α-Ylidene-β-Diketones via AuIII-Catalyzed Acyl Migration of Propargylic Esters Shaozhong Wang and Liming Zhang pp 8414–8415 DOI: 10.1021/ja062777j Supporting Info

Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All-Carbon Quaternary Chiral Centers David Martin, Stefan Kehrli, Magali d'Augustin, Hervé Clavier, Marc Mauduit, and Alexandre Alexakis pp 8416–8417 DOI: 10.1021/ja0629920 Supporting Info

Highly Enantioselective Azadiene Diels−Alder Reactions Catalyzed by Chiral N-Heterocyclic Carbenes Ming He, Justin R. Struble, and Jeffrey W. Bode pp 8418–8420 DOI: 10.1021/ja062707c Supporting Info

Unveiling the “Booster Effect” of Fluorinated Alcohol Solvents:  Aggregation-Induced Conformational Changes and Cooperatively Enhanced H-Bonding Albrecht Berkessel, Jens A. Adrio, Daniel Hüttenhain, and Jörg M. Neudörfl pp 8421–8426 DOI: 10.1021/ja0545463 Supporting Info

Charging Behavior of Single-Stranded DNA Polyelectrolyte Brushes Gang Shen, Napoleon Tercero, Mariafrancis A. Gaspar, Bindhu Varughese, Kenneth Shepard, and Rastislav Levicky pp 8427–8433 DOI: 10.1021/ja0571500 Supporting Info

Electronic Properties of Furyl Substituents at Phosphorus and Their Influence on 31P NMR Chemical Shifts Marco Ackermann, Aurelia Pascariu, Thomas Höcher, Hans-Ullrich Siehl, and Stefan Berger pp 8434–8440 DOI: 10.1021/ja057085u Supporting Info

Abundant Polymorphism in a System with Multiple Hydrogen-Bonding Opportunities:  Oxalyl Dihydrazide Shinbyoung Ahn, Fang Guo, Benson M. Kariuki, and Kenneth D. M. Harris pp 8441–8452 DOI: 10.1021/ja0573155 Supporting Info

Tremendous Spin-Splitting Effects in Open Boron Nitride Nanotubes:  Application to Nanoscale Spintronic Devices Shaogang Hao, Gang Zhou, Wenhui Duan, Jian Wu, and Bing-Lin Gu pp 8453–8458 DOI: 10.1021/ja057420e

Discovery of Glutathione S-Transferase Inhibitors Using Dynamic Combinatorial Chemistry Baolu Shi, Ross Stevenson, Dominic J. Campopiano, and Michael F. Greaney pp 8459–8467 DOI: 10.1021/ja058049y Supporting Info

Unexpected Four-Membered over Six-Membered Ring Formation during the Synthesis of Azaheterocyclic Phosphonates: Experimental and Theoretical Evaluation Veronique Van Speybroeck, Kristof Moonen, Karen Hemelsoet, Christian V. Stevens, and Michel Waroquier pp 8468–8478 DOI: 10.1021/ja0584119 Supporting Info

Replacement of a Proline with Silaproline Causes a 20-Fold Increase in the Cellular Uptake of a Pro-Rich Peptide Sílvia Pujals, Jimena Fernández-Carneado, Marcelo J. Kogan, Jean Martinez, Florine Cavelier, and Ernest Giralt pp 8479–8483 DOI: 10.1021/ja060036c

PNA/dsDNA Complexes:  Site Specific Binding and dsDNA Biosensor Applications Erin Shammel Baker, Janice W. Hong, Brent S. Gaylord, Guillermo C. Bazan, and Michael T. Bowers pp 8484–8492 DOI: 10.1021/ja060069s Supporting Info

Coverage Dependent Supramolecular Structures:  C60:ACA Monolayers on Ag(111) Bo Xu, Chenggang Tao, Ellen D. Williams, and Janice E. Reutt-Robey pp 8493–8499 DOI: 10.1021/ja060227f Supporting Info

An Infrared νNH Scale for Weakly Basic Anions. Implications for Single-Molecule Acidity and Superacidity Evgenii S. Stoyanov, Kee-Chan Kim, and Christopher A. Reed pp 8500–8508 DOI: 10.1021/ja060714v Supporting Info

Cobalt-Mediated Cyclic and Linear 2:1 Cooligomerization of Alkynes with Alkenes:  A DFT Study Vincent Gandon, Nicolas Agenet, K. Peter C. Vollhardt, Max Malacria, and Corinne Aubert pp 8509–8520 DOI: 10.1021/ja060756j Supporting Info

pH-Induced Hysteretic Gating of Track-Etched Polycarbonate Membranes:  Swelling/Deswelling Behavior of Polyelectrolyte Multilayers in Confined Geometry Daeyeon Lee, Adam J. Nolte, Allison L. Kunz, Michael F. Rubner, and Robert E. Cohen pp 8521–8529 DOI: 10.1021/ja0608803 Supporting Info

Structural Chemistry and Metamagnetism of an Homologous Series of Layered Manganese Oxysulfides Zoltán A. Gál, Oliver J. Rutt, Catherine F. Smura, Timothy P. Overton, Nicolas Barrier, Simon J. Clarke, and Joke Hadermann pp 8530–8540 DOI: 10.1021/ja060892o Supporting Info

Mimicking cAMP-Dependent Allosteric Control of Protein Kinase A through Mechanical Tension Brian Choi and Giovanni Zocchi pp 8541–8548 DOI: 10.1021/ja060903d Supporting Info

High Triplet Energy Polymer as Host for Electrophosphorescence with High Efficiency Yen-Chun Chen, Guo-Sheng Huang, Chung-Chin Hsiao, and Show-An Chen pp 8549–8558 DOI: 10.1021/ja060936t Supporting Info

Regio- and Stereoselective Nickel-Catalyzed Homoallylation of Aldehydes with 1,3-Dienes Masanari Kimura, Akihiro Ezoe, Masahiko Mori, Keisuke Iwata, and Yoshinao Tamaru pp 8559–8568 DOI: 10.1021/ja0608904 Supporting Info

Structural Factors Controlling the Self-Assembly of Columnar Liquid Crystals E. Johan Foster, R. Bradley Jones, Christine Lavigueur, and Vance E. Williams pp 8569–8574 DOI: 10.1021/ja0613198 Supporting Info

Sequence-Specific Detection of Femtomolar DNA via a Chronocoulometric DNA Sensor (CDS):  Effects of Nanoparticle-Mediated Amplification and Nanoscale Control of DNA Assembly at Electrodes Jiong Zhang, Shiping Song, Lanyong Zhang, Lihua Wang, Haiping Wu, Dun Pan, and Chunhai Fan pp 8575–8580 DOI: 10.1021/ja061521a Supporting Info

Structure and Enhanced Reactivity Rates of the D5h Sc3N@C80 and Lu3N@C80 Metallofullerene Isomers:  The Importance of the Pyracylene Motif Ting Cai, Liaosa Xu, Mark R. Anderson, Zhongxin Ge, Tianming Zuo, Xuelei Wang, Marilyn M. Olmstead, Alan L. Balch, Harry W. Gibson, and Harry C. Dorn pp 8581–8589 DOI: 10.1021/ja0615573 Supporting Info

Two-State Reactivity in Alkane Hydroxylation by Non-Heme Iron−Oxo Complexes Hajime Hirao, Devesh Kumar, Lawrence Que, Jr., and Sason Shaik pp 8590–8606 DOI: 10.1021/ja061609o Supporting Info

Chloride Selective Calix[4]arene Optical Sensor Combining Urea Functionality with Pyrene Excimer Transduction Benjamin Schazmann, Nameer Alhashimy, and Dermot Diamond pp 8607–8614 DOI: 10.1021/ja061917m Supporting Info

Optimization of Bivalent Glutathione S-Transferase Inhibitors by Combinatorial Linker Design Sumit S. Mahajan, Liming Hou, Catalin Doneanu, Rajan Paranji, Dean Maeda, John Zebala, and William M. Atkins pp 8615–8625 DOI: 10.1021/ja061766n Supporting Info

Chemistry of Mangana- and Rhenatricarbadecaboranyl Tricarbonyl Complexes:  Evidence for an Associative Mechanism of Ligand Substitution Involving an η6−η4 Cage-Slippage Process Analagous to η5−η3-Cyclopentadienyl Ring-Slippage Robert Butterick III, Bhaskar M. Ramachandran, Patrick J. Carroll, and Larry G. Sneddon pp 8626–8637 DOI: 10.1021/ja062201u Supporting Info

Nonchelated Alkene and Alkyne Complexes of d0 Zirconocene Pentafluorophenyl Cations Edward J. Stoebenau, III and Richard F. Jordan pp 8638–8650 DOI: 10.1021/ja057524p Supporting Info

Magnetic Spin Effects in Enzymatic Reactions:  Radical Oxidation of NADH by Horseradish Peroxidase Maria S. Afanasyeva, Marc B. Taraban, Peter A. Purtov, Tatyana V. Leshina, and Charles B. Grissom pp 8651–8658 DOI: 10.1021/ja0585735

Counterion-Controlled Transition of a Cationic Gemini from Submicroscopic to Giant Vesicles Samppa J. Ryhänen, V. Matti J. Säily, Mikko J. Parry, Paola Luciani, Giovanna Mancini, Juha-Matti I. Alakoskela, and Paavo K. J. Kinnunen pp 8659–8663 DOI: 10.1021/ja060382u Supporting Info

Single Oligomer Spectra Probe Chromophore Nanoenvironments of Tetrameric Fluorescent Proteins Christian Blum, Alfred J. Meixner, and Vinod Subramaniam pp 8664–8670 DOI: 10.1021/ja060726g

Nucleophilic Additions of Trimethylsilyl Cyanide to Cyclic Oxocarbenium Ions:  Evidence for the Loss of Stereoselectivity at the Limits of Diffusion Control Siddhartha R. Shenoy, Deborah M. Smith, and K. A. Woerpel pp 8671–8677 DOI: 10.1021/ja061110u Supporting Info

Enantioselective Total Synthesis of Avrainvillamide and the Stephacidins Phil S. Baran, Benjamin D. Hafensteiner, Narendra B. Ambhaikar, Carlos A. Guerrero, and John D. Gallagher pp 8678–8693 DOI: 10.1021/ja061660s Supporting Info

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 A. Robert Armstrong, Michael Holzapfel, Petr Novák, Christopher S. Johnson, Sun-Ho Kang, Michael M. Thackeray, and Peter G. Bruce pp 8694–8698 DOI: 10.1021/ja062027+

Modulation of Luminescence Intensity of Lanthanide Complexes by Photoinduced Electron Transfer and Its Application to a Long-Lived Protease Probe  [J. Am. Chem. Soc. 2006, 128, 6938−6946].  Takuya Terai, Kazuya Kikuchi, Shin-ya Iwasawa, Takao Kawabe, Yasunobu Hirata, Yasuteru Urano, and Tetsuo Nagano pp 8699–8700 DOI: 10.1021/ja069963+

Issue 27

Amino Acid-Derived Enaminones:  A Study in Ring Formation Providing Valuable Asymmetric Synthons Brandon J. Turunen and Gunda I. Georg pp 8702–8703 DOI: 10.1021/ja0609046 Supporting Info

Highly anti-Selective Catalytic Aldol Reactions of Amides with Aldehydes Susumu Saito and Shu Kobayashi pp 8704–8705 DOI: 10.1021/ja061221t Supporting Info

Rhodium(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters with CO2 Kazutoshi Ukai, Masao Aoki, Jun Takaya, and Nobuharu Iwasawa pp 8706–8707 DOI: 10.1021/ja061232m Supporting Info

Formation of Alternating Copolymers via Spontaneous Copolymerization of 1,3-Dehydroadamantane with Electron-Deficient Vinyl Monomers Shin-ichi Matsuoka, Naoto Ogiwara, and Takashi Ishizone pp 8708–8709 DOI: 10.1021/ja062157i Supporting Info

Aryl-Halide versus Aryl−Aryl Reductive Elimination in Pt(IV)−Phosphine Complexes Anette Yahav-Levi, Israel Goldberg, and Arkadi Vigalok pp 8710–8711 DOI: 10.1021/ja062166r Supporting Info

Nonracemic 3°-Carbamines from the Asymmetric Allylboration of N-Trimethylsilyl Ketimines with B-Allyl-10-phenyl-9-borabicyclo[3.3.2]decanes Eda Canales, Eliud Hernandez, and John A. Soderquist pp 8712–8713 DOI: 10.1021/ja062242q Supporting Info

One-Step Conversion of Cellobiose to C6-Alcohols Using a Ruthenium Nanocluster Catalyst Ning Yan, Chen Zhao, Chen Luo, Paul J. Dyson, Haichao Liu, and Yuan Kou pp 8714–8715 DOI: 10.1021/ja062468t Supporting Info

Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin−Lions-type sp2N/sp3N Hybrid Ligands R-BINAN-R‘-Py Hanmin Huang, Tomoko Okuno, Kazuomi Tsuda, Masahiro Yoshimura, and Masato Kitamura pp 8716–8717 DOI: 10.1021/ja062451a Supporting Info

Mesoporous Materials with an Acidic Framework and Basic Pores. A Successful Cohabitation Johan Alauzun, Ahmad Mehdi, Catherine Reyé, and Robert J. P. Corriu pp 8718–8719 DOI: 10.1021/ja0622960 Supporting Info

Cheap and Environmentally Benign Electrochemical Energy Storage and Conversion Devices Based on AlI3 Electrolytes Bofei Xue, Zhengwen Fu, Hong Li, Xizhe Liu, Sunchao Cheng, Jia Yao, Dongmei Li, Liquan Chen, and Qingbo Meng pp 8720–8721 DOI: 10.1021/ja057791v Supporting Info

Microcoil High-Resolution Magic Angle Spinning NMR Spectroscopy Hans Janssen, Andreas Brinkmann, Ernst R. H. van Eck, P. Jan M. van Bentum, and Arno P. M. Kentgens pp 8722–8723 DOI: 10.1021/ja061350+ Supporting Info

The Hydrogenation/Transfer Hydrogenation Network:  Asymmetric Hydrogenation of Ketones with Chiral η6-Arene/N-Tosylethylenediamine−Ruthenium(II) Catalysts Takeshi Ohkuma, Noriyuki Utsumi, Kunihiko Tsutsumi, Kunihiko Murata, Christian Sandoval, and Ryoji Noyori pp 8724–8725 DOI: 10.1021/ja0620989 Supporting Info

Carboxylates as Proton-Accepting Groups in Concerted Proton−Electron Transfers. Electrochemistry of the 2,5-Dicarboxylate 1,4-Hydrobenzoquinone/2,5-Dicarboxy 1,4-Benzoquinone Couple Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 8726–8727 DOI: 10.1021/ja0621750 Supporting Info

Preparation and Properties of a Monomeric MnIV−Oxo Complex Trenton H. Parsell, Rachel K. Behan, Michael T. Green, Michael P. Hendrich, and A. S. Borovik pp 8728–8729 DOI: 10.1021/ja062332v Supporting Info

Lyotropic Liquid Crystals from Designed Helical β-Peptides William C. Pomerantz, Nicholas L. Abbott, and Samuel H. Gellman pp 8730–8731 DOI: 10.1021/ja062412z Supporting Info

Synthesis and Dynamic Random Access Memory Behavior of a Functional Polyimide Qi-Dan Ling, Feng-Chyuan Chang, Yan Song, Chun-Xiang Zhu, Der-Jang Liaw, Daniel Siu-Hhung Chan, En-Tang Kang, and Koon-Gee Neoh pp 8732–8733 DOI: 10.1021/ja062489n Supporting Info

Efficient Synthetic Access to the Hetisine C20-Diterpenoid Alkaloids. A Concise Synthesis of Nominine via Oxidoisoquinolinium-1,3-Dipolar and Dienamine-Diels−Alder Cycloadditions Kevin M. Peese and David Y. Gin pp 8734–8735 DOI: 10.1021/ja0625430 Supporting Info

N-Heterocyclic Carbene-Catalyzed Reaction of Chalcones and Enals via Homoenolate:  an Efficient Synthesis of 1,3,4-Trisubstituted Cyclopentenes Vijay Nair, Sreekumar Vellalath, Manojkumar Poonoth, and Eringathodi Suresh pp 8736–8737 DOI: 10.1021/ja0625677 Supporting Info

A Genetically Encoded Fluorescent Amino Acid Jiangyun Wang, Jianming Xie, and Peter G. Schultz pp 8738–8739 DOI: 10.1021/ja062666k Supporting Info

Self-Supported Organometallic Rhodium Quinonoid Nanocatalysts for Stereoselective Polymerization of Phenylacetylene Kang Hyun Park, Kwonho Jang, Seung Uk Son, and Dwight A. Sweigart pp 8740–8741 DOI: 10.1021/ja062907o Supporting Info

Highly Selective Room-Temperature Copper-Catalyzed C−N Coupling Reactions Alexandr Shafir and Stephen L. Buchwald pp 8742–8743 DOI: 10.1021/ja063063b Supporting Info

Olefin Metathesis of the Aligned Assemblies of Conjugated Polymers Constructed through Supramolecular Bundling Rie Wakabayashi, Yohei Kubo, Kenji Kaneko, Masayuki Takeuchi, and Seiji Shinkai pp 8744–8745 DOI: 10.1021/ja063040x Supporting Info

Photochemical Phase Transition versus Photochemical Phase Separation Xia Tong, Guang Wang, and Yue Zhao pp 8746–8747 DOI: 10.1021/ja063244d Supporting Info

Structure and Reaction Pathway of TMP-Zincate:  Amido Base or Alkyl Base? Masanobu Uchiyama, Yotaro Matsumoto, Daisuke Nobuto, Taniyuki Furuyama, Kentaro Yamaguchi, and Keiji Morokuma pp 8748–8750 DOI: 10.1021/ja060489h Supporting Info

Temperature-Driven Oxygenation Rate Control by Polymeric Photosensitizer Hisao Koizumi, Yasuhiro Shiraishi, Sachiko Tojo, Mamoru Fujitsuka, Tetsuro Majima, and Takayuki Hirai pp 8751–8753 DOI: 10.1021/ja062949c Supporting Info

Catalytic Intermolecular Direct Arylation of Perfluorobenzenes Marc Lafrance, Christopher N. Rowley, Tom K. Woo, and Keith Fagnou pp 8754–8756 DOI: 10.1021/ja062509l Supporting Info

NMR Determination of the Bioactive Conformation of Peloruside A Bound To Microtubules Jesús Jiménez-Barbero, Angeles Canales, Peter T. Northcote, Rubén M. Buey, José Manuel Andreu, and J. Fernando Díaz pp 8757–8765 DOI: 10.1021/ja0580237 Supporting Info

Discrimination of Hairpin Polyamides with an α-Substituted-γ-aminobutyric Acid as a 5‘-TG-3‘ Reader in DNA Minor Groove Wen Zhang, Toshikazu Bando, and Hiroshi Sugiyama pp 8766–8776 DOI: 10.1021/ja0580587 Supporting Info

Quantum Interference as the Source of Steric Asymmetry and Parity Propensity Rules in NO−Rare Gas Inelastic Scattering Arjan Gijsbertsen, Harold Linnartz, Craig A. Taatjes, and Steven Stolte pp 8777–8789 DOI: 10.1021/ja057828b Supporting Info

U(SMes*)n, (n = 3, 4) and Ln(SMes*)3 (Ln = La, Ce, Pr, Nd):  Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η3 Ligation Mode of the Arylthiolate Ligand, from X-ray Diffraction and DFT Analysis Mathieu Roger, Noémi Barros, Thérèse Arliguie, Pierre Thuéry, Laurent Maron, and Michel Ephritikhine pp 8790–8802 DOI: 10.1021/ja0584830 Supporting Info

Docking of Photosystem I Subunit C Using a Constrained Geometric Simulation Craig C. Jolley, Stephen A. Wells, Brandon M. Hespenheide, Michael F. Thorpe, and Petra Fromme pp 8803–8812 DOI: 10.1021/ja0587749 Supporting Info

Effect of Surface Composition on Electronic Structure, Stability, and Electrocatalytic Properties of Pt-Transition Metal Alloys:  Pt-Skin versus Pt-Skeleton Surfaces Vojislav R. Stamenkovic, Bongjin Simon Mun, Karl J. J. Mayrhofer, Philip N. Ross, and Nenad M. Markovic pp 8813–8819 DOI: 10.1021/ja0600476

Reaction Mechanism and Kinetics of the Traceless Staudinger Ligation Matthew B. Soellner, Bradley L. Nilsson, and Ronald T. Raines pp 8820–8828 DOI: 10.1021/ja060484k Supporting Info

Nonchromatographic “Stir and Filter Approach” (SAFA) for Isolating Sc3N@C80 Metallofullerenes Steven Stevenson, Kim Harich, Hua Yu, Ryan R. Stephen, David Heaps, Curtis Coumbe, and J. Paige Phillips pp 8829–8835 DOI: 10.1021/ja060752e Supporting Info

Phosphorus Copies of PPV:  π-Conjugated Polymers and Molecules Composed of Alternating Phenylene and Phosphaalkene Moieties Vincent A. Wright, Brian O. Patrick, Celine Schneider, and Derek P. Gates pp 8836–8844 DOI: 10.1021/ja060816l Supporting Info

Toward Chiral Sum-Frequency Spectroscopy Na Ji, Victor Ostroverkhov, Mikhail Belkin, Ying-Jen Shiu, and Yuen-Ron Shen pp 8845–8848 DOI: 10.1021/ja060888c

Experimental and Theoretical Electron Density Study of Estrone Elizabeth A. Zhurova, Chérif F. Matta, Nan Wu, Vladimir V. Zhurov, and A. Alan Pinkerton pp 8849–8861 DOI: 10.1021/ja061080v Supporting Info

P-Derived Organic Cations as Structure-Directing Agents:  Synthesis of a High-Silica Zeolite (ITQ-27) with a Two-Dimensional 12-Ring Channel System Douglas L. Dorset, Gordon J. Kennedy, Karl G. Strohmaier, Maria J. Diaz-Cabañas, Fernando Rey, and Avelino Corma pp 8862–8867 DOI: 10.1021/ja061206o Supporting Info

A Functionally Orthogonal Ligand−Receptor Pair Created by Targeting the Allosteric Mechanism of the Thyroid Hormone Receptor A. Quamrul Hassan and John T. Koh pp 8868–8874 DOI: 10.1021/ja060760v Supporting Info

Unique Pore Selectivity for Cs+ and Exceptionally High NH4+ Exchange Capacity of the Chalcogenide Material K6Sn[Zn4Sn4S17] Manolis J. Manos, Konstantinos Chrissafis, and Mercouri G. Kanatzidis pp 8875–8883 DOI: 10.1021/ja061342t Supporting Info

Preparation and Structure of CeSc2N@C80:  An Icosahedral Carbon Cage Enclosing an Acentric CeSc2N Unit with Buried f Electron Spin Xuelei Wang, Tianming Zuo, Marilyn M. Olmstead, James C. Duchamp, Thomas E. Glass, Frank Cromer, Alan L. Balch, and Harry C. Dorn pp 8884–8889 DOI: 10.1021/ja061434i Supporting Info

Chiral Templating of Surfaces:  Adsorption of (S)-2-Methylbutanoic Acid on Pt(111) Single-Crystal Surfaces Ilkeun Lee and Francisco Zaera pp 8890–8898 DOI: 10.1021/ja061654w

DNA-Induced Size-Selective Separation of Mixtures of Gold Nanoparticles Jae-Seung Lee, Savka I. Stoeva, and Chad A. Mirkin pp 8899–8903 DOI: 10.1021/ja061651j Supporting Info

Microporous Metal−Organic Frameworks Incorporating 1,4-Benzeneditetrazolate:  Syntheses, Structures, and Hydrogen Storage Properties Mircea Dinc, Anta F. Yu, and Jeffrey R. Long pp 8904–8913 DOI: 10.1021/ja061716i Supporting Info

One-Step, Regioselective Synthesis of up to 50-mers of RNA Oligomers by Montmorillonite Catalysis Wenhua Huang and James P. Ferris pp 8914–8919 DOI: 10.1021/ja061782k

Enterobactin Protonation and Iron Release:  Structural Characterization of the Salicylate Coordination Shift in Ferric Enterobactin1 Rebecca J. Abergel, Jeffrey A. Warner, David K. Shuh, and Kenneth N. Raymond pp 8920–8931 DOI: 10.1021/ja062046j Supporting Info

Enzyme Catalysis:  Tool to Make and Break Amygdalin Hydrogelators from Renewable Resources:  A Delivery Model for Hydrophobic Drugs Praveen Kumar Vemula, Jun Li, and George John pp 8932–8938 DOI: 10.1021/ja062650u Supporting Info

Control of Transcription Factor Activity and Osteoblast Differentiation in Mammalian Cells Using an Evolved Small-Molecule-Dependent Intein Courtney M. Yuen, Stephen J. Rodda, Steven A. Vokes, Andrew P. McMahon, and David R. Liu pp 8939–8946 DOI: 10.1021/ja062980e

Regioselectivity and Equilibrium Thermodynamics for Addition of Rh−OH to Olefins in Water Xuefeng Fu, Shan Li, and Bradford B. Wayland pp 8947–8954 DOI: 10.1021/ja0583416 Supporting Info

Vanadium Silicalite-1 Nanoparticles Deposition onto the Mesoporous Walls of SBA-15. Mechanistic Insights from a Combined EPR and Raman Study Mario Chiesa, Vera Meynen, Sabine Van Doorslaer, Pegie Cool, and Etienne F. Vansant pp 8955–8963 DOI: 10.1021/ja061630p Supporting Info

Designer Dendrimers:  Branched Oligosulfonimides with Controllable Molecular Architectures Oleg Lukin, Volker Gramlich, Ramchandra Kandre, Igor Zhun, Thorsten Felder, Christoph A. Schalley, and Grigoriy Dolgonos pp 8964–8974 DOI: 10.1021/ja061606b Supporting Info

Accurate Length Control of Supramolecular Oligomerization:  Vernier Assemblies Christopher A. Hunter and Salvador Tomas pp 8975–8979 DOI: 10.1021/ja061928f Supporting Info

Regioregular Copolymers of 3-Alkoxythiophene and Their Photovoltaic Application Chenjun Shi, Yan Yao, Yang Yang, and Qibing Pei pp 8980–8986 DOI: 10.1021/ja061664x Supporting Info

Polyynes:  Synthesis, Properties, and Applications Edited by Franco Cataldo (University of Rome “Tor Vergata”, Italy). CRC Press/Taylor and Francis Group. 2006. xviii + 506 pp. $125.96. ISBN 1-57444-512-X. Nancy S. Goroff p 8987 DOI: 10.1021/ja059897w

Electroorganic Reduction Synthesis, Volume 1−2 By Sigeru Torii (Okayama University, Japan). Kodansha, Ltd:  Tokyo, and Wiley-VCH Verlag GmbH & Co, KgaA:  Weinheim, 2006. xxvi + xxvi + 802 pp. $300.00. ISBN 3-527-31539-X. Albert J. Fry p 8987 DOI: 10.1021/ja0697370

Calculation of NMR and EPR Parameters:  Theory and Applications Edited by Martin Kaupp (University of Würzberg), Michael Bühl (Max-Planck-Institute for Coal Research, Mülheim an der Ruhr), and Vladimir G. Malkin (Slovak Academy of Sciences, Bratislava). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2004. xviii + 604 pp. $242.00. ISBN 3-527-30779-6. Anthony S. Serianni pp 8987–8988 DOI: 10.1021/ja0598098

Issue 28

Electrical Characteristics and Chemical Stability of Non-Oxidized, Methyl-Terminated Silicon Nanowires Hossam Haick, Patrick T. Hurley, Allon I. Hochbaum, Peidong Yang, and Nathan S. Lewis pp 8990–8991 DOI: 10.1021/ja056785w Supporting Info

Do Collective Atomic Fluctuations Account for Cooperative Effects? Molecular Dynamics Studies of the U1A−RNA Complex Bethany L. Kormos, Anne M. Baranger, and David L. Beveridge pp 8992–8993 DOI: 10.1021/ja0606071 Supporting Info

Self-Threading of a Poly(ethylene glycol) Chain in a Cyclodextrin-Ring:  Control of the Exchange Dynamics by Chain Length Youhei Inoue, Masahiko Miyauchi, Hiroki Nakajima, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 8994–8995 DOI: 10.1021/ja061095t Supporting Info

Adsorption of Benzene-1,4-dithiol on the Au(111) Surface and Its Possible Role in Molecular Conductance Renato B. Pontes, Frederico D. Novaes, Adalberto Fazzio, and Antônio J. R. da Silva pp 8996–8997 DOI: 10.1021/ja0612495 Supporting Info

Metal-Enhanced Fluorescence from CdTe Nanocrystals:  A Single-Molecule Fluorescence Study Krishanu Ray, Ramachandram Badugu, and Joseph R. Lakowicz pp 8998–8999 DOI: 10.1021/ja061762i Supporting Info

Exceptional Near-Infrared Fluorescence Quantum Yields and Excited-State Absorptivity of Highly Conjugated Porphyrin Arrays Timothy V. Duncan, Kimihiro Susumu, Louise E. Sinks, and Michael J. Therien pp 9000–9001 DOI: 10.1021/ja061897o Supporting Info

Kinetic Analysis for Formation of Cd1-xZnxSe Solid-Solution Nanocrystals Yun-Mo Sung, Yong-Ji Lee, and Kyung-Soo Park pp 9002–9003 DOI: 10.1021/ja061858c Supporting Info

Racemic Single-Walled Carbon Nanotubes Exhibit Circular Dichroism When Wrapped with DNA Gordana Dukovic, Milan Balaz, Peter Doak, Nina D. Berova, Ming Zheng, Robert S. Mclean, and Louis E. Brus pp 9004–9005 DOI: 10.1021/ja062095w Supporting Info

Current-Induced Metallic State in an Organic (EDT-TSF)2GaCl4 Conductor Hisataka Endo, Tadashi Kawamoto, Takehiko Mori, Ichiro Terasaki, Toru Kakiuchi, Hiroshi Sawa, Mie Kodani, Kazuo Takimiya, and Tetsuo Otsubo pp 9006–9007 DOI: 10.1021/ja062277q Supporting Info

A Binuclear Fe(III)Dy(III) Single Molecule Magnet. Quantum Effects and Models Marilena Ferbinteanu, Takashi Kajiwara, Kwang-Yong Choi, Hiroyuki Nojiri, Akio Nakamoto, Norimichi Kojima, Fanica Cimpoesu, Yuichi Fujimura, Shinya Takaishi, and Masahiro Yamashita pp 9008–9009 DOI: 10.1021/ja062399i Supporting Info

Diblock Copolymer Micellar Nanoparticles Decorated with Annexin-A5 Proteins Vanessa Schmidt, Cristiano Giacomelli, François Lecolley, Joséphine Lai-Kee-Him, Alain R. Brisson, and Redouane Borsali pp 9010–9011 DOI: 10.1021/ja062408n Supporting Info

Selective Catalytic Oxidation of Ammonia to Nitrogen on Atomic Oxygen Precovered Au(111) Jinlong Gong, Rotimi A. Ojifinni, Tae S. Kim, John M. White, and C. Buddie Mullins pp 9012–9013 DOI: 10.1021/ja062624w Supporting Info

Metabolic Coupling of Dehydration and Decarboxylation in the Curacin A Pathway:  Functional Identification of a Mechanistically Diverse Enzyme Pair Liangcai Gu, Junyong Jia, Haichuan Liu, Kristina Håkansson, William H. Gerwick, and David H. Sherman pp 9014–9015 DOI: 10.1021/ja0626382 Supporting Info

High-Speed Electroseparations Inside Silica Colloidal Crystals Suping Zheng, Eric Ross, Michael A. Legg, and Mary J. Wirth pp 9016–9017 DOI: 10.1021/ja062676l Supporting Info

Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer Brian L. Conley, Somesh K. Ganesh, Jason M. Gonzales, William J. Tenn, III, Kenneth J. H. Young, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana pp 9018–9019 DOI: 10.1021/ja062417w Supporting Info

A Highly Reduced Vanadium(III/IV) Polyoxovanadate Comprising an Octavanadyl Square-Prism Surrounding a Dimetallic Vanadium(III) Fragment Rebecca H. Laye, Qiang Wei, Pamela V. Mason, Maheswaran Shanmugam, Simon J. Teat, Euan K. Brechin, David Collison, and Eric J. L. McInnes pp 9020–9021 DOI: 10.1021/ja062723+ Supporting Info

Structure-Based Discovery of Glycolipids for CD1d-Mediated NKT Cell Activation:  Tuning the Adjuvant versus Immunosuppression Activity Masakazu Fujio, Douglass Wu, Raquel Garcia-Navarro, David D. Ho, Moriya Tsuji, and Chi-Huey Wong pp 9022–9023 DOI: 10.1021/ja062740z Supporting Info

Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents William J. Rieter, Kathryn M. L. Taylor, Hongyu An, Weili Lin, and Wenbin Lin pp 9024–9025 DOI: 10.1021/ja0627444 Supporting Info

Nanoparticle-Assisted Surface Immobilization of Phospholipid Liposomes Liangfang Zhang, Liang Hong, Yan Yu, Sung Chul Bae, and Steve Granick pp 9026–9027 DOI: 10.1021/ja062620r

Single-Molecule Spectroelectrochemistry (SMS-EC) Rodrigo E. Palacios, Fu-Ren F. Fan, Allen J. Bard, and Paul F. Barbara pp 9028–9029 DOI: 10.1021/ja062848e Supporting Info

Probing a Conjugated Polymer's Transfer of Organization-Dependent Properties from Solutions to Films Andrew Satrijo, Stefan C. J. Meskers, and Timothy M. Swager pp 9030–9031 DOI: 10.1021/ja063027c Supporting Info

Macrolactonization via Hydrocarbon Oxidation Kenneth J. Fraunhoffer, Narayanasamy Prabagaran, Lauren E. Sirois, and M. Christina White pp 9032–9033 DOI: 10.1021/ja063096r Supporting Info

Dithienosilole− and Dibenzosilole−Thiophene Copolymers as Semiconductors for Organic Thin-Film Transistors Hakan Usta, Gang Lu, Antonio Facchetti, and Tobin J. Marks pp 9034–9035 DOI: 10.1021/ja062908g Supporting Info

Self-Condensed Nanoparticles of Oligofluorenes with Water-Soluble Side Chains Yoshiko Koizumi, Shu Seki, Satoshi Tsukuda, Shingo Sakamoto, and Seiichi Tagawa pp 9036–9037 DOI: 10.1021/ja063056n Supporting Info

Intramolecular C−H Activation Reactions of Molybdenacyclobutanes Peter M. Graham, Miriam S. A. Buschhaus, and Peter Legzdins pp 9038–9039 DOI: 10.1021/ja063249a Supporting Info

Photochemical Route to the Synthesis of Thiolane 1-Oxides Jeffrey D. Winkler and Esther C. Y. Lee pp 9040–9041 DOI: 10.1021/ja060962r Supporting Info

Speeding Up Three-Dimensional Protein NMR Experiments to a Few Minutes Paul Schanda, Hélène Van Melckebeke, and Bernhard Brutscher pp 9042–9043 DOI: 10.1021/ja062025p Supporting Info

Organometallic Chemistry of Amidate Complexes. Accelerating Effect of Bidentate Ligands on the Reductive Elimination of N-Aryl Amidates from Palladium(II) Ken-ichi Fujita, Makoto Yamashita, Florian Puschmann, Miguel Martinez Alvarez-Falcon, Christopher D. Incarvito, and John F. Hartwig pp 9044–9045 DOI: 10.1021/ja062333n Supporting Info

Silver Technology for Stabilization of Simple (Z)-Enethiols:  Stereoselective Synthesis and Reaction of Silver (Z)-Enethiolates Masahito Ochiai, Masaya Hirobe, and Kazunori Miyamoto pp 9046–9047 DOI: 10.1021/ja0627747 Supporting Info

Intermolecular Amidation of Unactivated sp2 and sp3 C−H Bonds via Palladium-Catalyzed Cascade C−H Activation/Nitrene Insertion Hung-Yat Thu, Wing-Yiu Yu, and Chi-Ming Che pp 9048–9049 DOI: 10.1021/ja062856v Supporting Info

La3Ni2O6:  A New Double T‘-type Nickelate with Infinite Ni1+/2+O2 Layers Viktor V. Poltavets, Konstantin A. Lokshin, Sibel Dikmen, Mark Croft, Takeshi Egami, and Martha Greenblatt pp 9050–9051 DOI: 10.1021/ja063031o Supporting Info

A Perfectly Hydrophobic Surface (θA/θR = 180°/180°) Lichao Gao and Thomas J. McCarthy pp 9052–9053 DOI: 10.1021/ja062943n Supporting Info

Dynamic Processes in Silyl Palladium Complexes:  Evidence for Intermediate Si−H and Si−Si σ-Complexes Robert C. Boyle, Douglas Pool, Heiko Jacobsen, and Mark J. Fink pp 9054–9055 DOI: 10.1021/ja063344j Supporting Info

Rapid Growth of Polymer Brushes from Immobilized Initiators Zhiyi Bao, Merlin L. Bruening, and Gregory L. Baker pp 9056–9060 DOI: 10.1021/ja058743d Supporting Info

Self-Assembly of Organic Monolayers on Aerosolized Silicon Nanoparticles Ying-Chih Liao and Jeffrey T. Roberts pp 9061–9065 DOI: 10.1021/ja0611238

Highly Active Au(I) Catalyst for the Intramolecular exo-Hydrofunctionalization of Allenes with Carbon, Nitrogen, and Oxygen Nucleophiles Zhibin Zhang, Cong Liu, Robert E. Kinder, Xiaoqing Han, Hua Qian, and Ross A. Widenhoefer pp 9066–9073 DOI: 10.1021/ja062045r Supporting Info

Programmable Oligomers for Minor Groove DNA Recognition Raymond M. Doss, Michael A. Marques, Shane Foister, David M. Chenoweth, and Peter B. Dervan pp 9074–9079 DOI: 10.1021/ja0621795 Supporting Info

Effect on Kinetics by Deuterium in the 1,5-Hydrogen Shift of a Cisoid-Locked 1,3(Z)-Pentadiene, 2-Methyl-10-methylenebicyclo[4.4.0]dec-1-ene:  Evidence for Tunneling? William von E. Doering and Xin Zhao pp 9080–9085 DOI: 10.1021/ja057377v Supporting Info

Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen Bond, Stabilize the Transition State in Serine Protease Catalysis Cynthia N. Fuhrmann, Matthew D. Daugherty, and David A. Agard pp 9086–9102 DOI: 10.1021/ja057721o Supporting Info

On the Mechanism of the Copper-Catalyzed Enantioselective 1,4-Addition of Grignard Reagents to α,β-Unsaturated Carbonyl Compounds Syuzanna R. Harutyunyan, Fernando López, Wesley R. Browne, Arkaitz Correa, Diego Peña, Ramon Badorrey, Auke Meetsma, Adriaan J. Minnaard, and Ben L. Feringa pp 9103–9118 DOI: 10.1021/ja0585634 Supporting Info

Three-Dimensional 13C-Detected CH3-TOCSY Using Selectively Protonated Proteins:  Facile Methyl Resonance Assignment and Protein Structure Determination John B. Jordan, Helena Kovacs, Yuefeng Wang, Mehdi Mobli, Rensheng Luo, Clemens Anklin, Jeffrey C. Hoch, and Richard W. Kriwacki pp 9119–9128 DOI: 10.1021/ja058587a Supporting Info

Theoretical Evidence of PtSn Alloy Efficiency for CO Oxidation Céline Dupont, Yvette Jugnet, and David Loffreda pp 9129–9136 DOI: 10.1021/ja061303h

Sensitization of Cancer Cells to DNA Damaging Agents by Imidazolines Vasudha Sharma, Satyamaheshwar Peddibhotla, and Jetze J. Tepe pp 9137–9143 DOI: 10.1021/ja060273f Supporting Info

Spectroscopic and Computational Studies of Co1+Cobalamin:  Spectral and Electronic Properties of the “Superreduced” B12 Cofactor Mathew D. Liptak and Thomas C. Brunold pp 9144–9156 DOI: 10.1021/ja061433q Supporting Info

Molecular Understanding of Alumina Supported Single-Site Catalysts by a Combination of Experiment and Theory Jérôme Joubert, Françoise Delbecq, Philippe Sautet, Erwan Le Roux, Mostafa Taoufik, Chloé Thieuleux, Frédéric Blanc, Christophe Copéret, Jean Thivolle-Cazat, and Jean-Marie Basset pp 9157–9169 DOI: 10.1021/ja0616736 Supporting Info

Quantification of DNA BI/BII Backbone States in Solution. Implications for DNA Overall Structure and Recognition Brahim Heddi, Nicolas Foloppe, Nadia Bouchemal, Edith Hantz, and Brigitte Hartmann pp 9170–9177 DOI: 10.1021/ja061686j

The Pb122- and Pb102- Zintl Ions and the M@Pb122- and M@Pb102- Cluster Series Where M = Ni, Pd, Pt Emren N. Esenturk, James Fettinger, and Bryan Eichhorn pp 9178–9186 DOI: 10.1021/ja061842m Supporting Info

Designed High Affinity Cu2+-Binding α-Helical Foldamer Andrew J. Nicoll, David J. Miller, Klaus Fütterer, Raymond Ravelli, and Rudolf K. Allemann pp 9187–9193 DOI: 10.1021/ja061513u Supporting Info

Total Syntheses of Amphidinolide X and Y Alois Fürstner, Egmont Kattnig, and Olivier Lepage pp 9194–9204 DOI: 10.1021/ja061918e Supporting Info

Combined Magnetic and Single-Crystal X-ray Structural Study of the Linear Chain Antiferromagnet [(CH3)4N][MnCl3] under Varying Pressure Somchai Tancharakorn, Francesca P. A. Fabbiani, David R. Allan, Konstantin V. Kamenev, and Neil Robertson pp 9205–9210 DOI: 10.1021/ja061923i Supporting Info

Bolaamphiphiles Promote Phospholipid Translocation Across Vesicle Membranes Christopher C. Forbes, Kristy M. DiVittorio, and Bradley D. Smith pp 9211–9218 DOI: 10.1021/ja0619253 Supporting Info

Exploring the Limits of DNA Size:  Naphtho-Homologated DNA Bases and Pairs Alex H. F. Lee and Eric T. Kool pp 9219–9230 DOI: 10.1021/ja0619004 Supporting Info

Comparison of Facially Amphiphilic Biaryl Dendrimers with Classical Amphiphilic Ones Using Protein Surface Recognition as the Tool Akamol Klaikherd, Britto S. Sandanaraj, Dharma Rao Vutukuri, and S. Thayumanavan pp 9231–9237 DOI: 10.1021/ja0622406 Supporting Info

Role of the Metal Oxidation State in the SNS−Cr Catalyst for Ethylene Trimerization:  Isolation of Di- and Trivalent Cationic Intermediates Amir Jabri, Claire Temple, Patrick Crewdson, Sandro Gambarotta, Ilia Korobkov, and Robbert Duchateau pp 9238–9247 DOI: 10.1021/ja0623717 Supporting Info

Evaluation of Biologically Relevant Short α-Helices Stabilized by a Main-Chain Hydrogen-Bond Surrogate Deyun Wang, Kang Chen, John L. Kulp III, and Paramjit S. Arora pp 9248–9256 DOI: 10.1021/ja062710w Supporting Info

Time-Resolved X-ray Excited Optical Luminescence from Tris(2-phenyl bipyridine)iridium [J. Am. Chem. Soc. 2006, 128, 3906−3907]. Franziskus Heigl, Simone Lam, Tom Regier, Ian Coulthard, and Tsun-Kong Sham p 9257 DOI: 10.1021/ja069967e

Multiphase Homogeneous Catalysis:  Volumes 1−2 Edited by Boy Cornils (Hofheim, Germany), Wolfgang A. Herrmann (Universität München, Germany), Istvan T. Horvath (Eötvös University, Hungary), Walter Leitner (RWTH, Aachen, Germany), Stefan Mecking (Universität Konstanz, Germany), Hélène Olivier-Bourbigou (Institut Français du Pétrole, Vernaison, France), and Dieter Vogt (Eindhoven University of Technology, the Netherlands). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xxxiv + xxxiv + 872 pp. $385.00. ISBN 3-527-30721-4. Jim D. Atwood p 9258 DOI: 10.1021/ja0598762

Semiconductor Nanocrystals and Silicate Nano-particles. Structure and Bonding, 118 Edited by Xiaogang Peng (University of Arkansas, USA) and D. M. P. Mingos (Oxford University, UK). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2005. xii + 190 pp. $179.00. ISBN 3-540-27805-2. Jeffery L. Coffer p 9258 DOI: 10.1021/ja069705c

Issue 29

NMR Reveals Anomalous Copper(II) Binding to the Amyloid Aβ Peptide of Alzheimer's Disease Liming Hou and Michael G. Zagorski pp 9260–9261 DOI: 10.1021/ja046032u Supporting Info

A New Ru-Catalyzed Cascade Reaction Forming Polycyclic Cyclohexadienes from 1,6-Diynes and Alkenes Jesús A. Varela, Silvia G. Rubín, Carlos González-Rodríguez, Luis Castedo, and Carlos Saá pp 9262–9263 DOI: 10.1021/ja057306w Supporting Info

Liquid Crystalline Order from ortho-Phenylene Ethynylene Macrocycles Sang Hyuk Seo, Ticora V. Jones, Helga Seyler, Jack O. Peters, Tae Hyung Kim, Ji Young Chang, and Gregory N. Tew pp 9264–9265 DOI: 10.1021/ja060354b Supporting Info

Spectral Diffusion in the Tunneling Spectra of Ligand-Stabilized Undecagold Clusters Rachel K. Smith, Sanjini U. Nanayakkara, Gerd H. Woehrle, Thomas P. Pearl, Meaghan M. Blake, James E. Hutchison, and Paul S. Weiss pp 9266–9267 DOI: 10.1021/ja061040r Supporting Info

Reversible O−O Bond Cleavage in Copper−Dioxygen Isomers:  Impact of Anion Basicity Xavier Ottenwaelder, Deanne Jackson Rudd, Mary C. Corbett, Keith O. Hodgson, Britt Hedman, and T. Daniel P. Stack pp 9268–9269 DOI: 10.1021/ja061132g Supporting Info

Ruthenium-Catalyzed [1,n]-Metallotropic Shift (n = 3, 5) of Alkynyl Carbene Complex Intermediates Kouichi Ohe, Michinobu Fujita, Hideyuki Matsumoto, Yugo Tai, and Koji Miki pp 9270–9271 DOI: 10.1021/ja0612955 Supporting Info

Fe(III)-Templated Gd(III) Self-AssembliesA New Route toward Macromolecular MRI Contrast Agents1 Valérie C. Pierre, Mauro Botta, Silvio Aime, and Kenneth N. Raymond pp 9272–9273 DOI: 10.1021/ja061323j Supporting Info

Regio- and Chemoselective Covalent Immobilization of Proteins through Unnatural Amino Acids Cécile Gauchet, Guillermo R. Labadie, and C. Dale Poulter pp 9274–9275 DOI: 10.1021/ja061131o Supporting Info

Nanoporous Carbon Nanotubes Synthesized through Confined Hydrogen-Bonding Self-Assembly Adrian T. Rodriguez, Min Chen, Zhu Chen, C. Jeffrey Brinker, and Hongyou Fan pp 9276–9277 DOI: 10.1021/ja061380c Supporting Info

Origin of the Blue Shift of the CH Stretching Band for 2-Butoxyethanol in Water Yukiteru Katsumoto, Hiroyuki Komatsu, and Keiichi Ohno pp 9278–9279 DOI: 10.1021/ja061667+ Supporting Info

Folding of an Ala-Ala-Ala Tripeptide into a β-Turn via Hydrophobic Encapsulation Shohei Tashiro, Masahide Kobayashi, and Makoto Fujita pp 9280–9281 DOI: 10.1021/ja061722e Supporting Info

Atomic Structure and Bonding of Water Overlayer on Cu(110):  The Borderline for Intact and Dissociative Adsorption Jun Ren and Sheng Meng pp 9282–9283 DOI: 10.1021/ja061947p

Interfacial Synthesis of Dendritic Platinum Nanoshells Templated on Benzene Nanodroplets Stabilized in Water by a Photocatalytic Lipoporphyrin Haorong Wang, Yujiang Song, Craig J. Medforth, and John A. Shelnutt pp 9284–9285 DOI: 10.1021/ja0619859 Supporting Info

Asymmetric Functionalization of Gold Nanoparticles with Oligonucleotides Xiaoyang Xu, Nathaniel L. Rosi, Yuhuang Wang, Fengwei Huo, and Chad A. Mirkin pp 9286–9287 DOI: 10.1021/ja061980b Supporting Info

Control of the Optical Properties of Quantum Dots by Surface Coating with Calix[n]arene Carboxylic Acids Takashi Jin, Fumihiko Fujii, Eiji Yamada, Yoshinobu Nodasaka, and Masataka Kinjo pp 9288–9289 DOI: 10.1021/ja062021k Supporting Info

NMR Studies of Lysozyme Surface Accessibility by Using Different Paramagnetic Relaxation Probes Andrea Bernini, Ottavia Spiga, Vincenzo Venditti, Filippo Prischi, Luisa Bracci, Angela Pui-Ling Tong, Wing-Tak Wong, and Neri Niccolai pp 9290–9291 DOI: 10.1021/ja062109y Supporting Info

Negatively Charged π-(C60-)2 Dimer with Biradical State at Room Temperature Dmitri V. Konarev, Salavat S. Khasanov, Akihiro Otsuka, Gunzi Saito, and Rimma N. Lyubovskaya pp 9292–9293 DOI: 10.1021/ja062143c Supporting Info

Switchable Assembly of Ultra Narrow CdS Nanowires and Nanorods Somobrata Acharya, Israel Patla, Joseph Kost, Shlomo Efrima, and Yuval Golan pp 9294–9295 DOI: 10.1021/ja062404i Supporting Info

High-Speed Microcontact Printing Jo A. Helmuth, Heinz Schmid, Richard Stutz, Andreas Stemmer, and Heiko Wolf pp 9296–9297 DOI: 10.1021/ja062461b Supporting Info

“Ionic Carbenes”:  Synthesis, Structural Characterization, and Reactivity of Rare-Earth Metal Methylidene Complexes H. Martin Dietrich, Karl W. Törnroos, and Reiner Anwander pp 9298–9299 DOI: 10.1021/ja062523y Supporting Info

Azide Reactions for Controlling Clean Silicon Surface Chemistry:  Benzylazide on Si(100)-2 × 1 Semyon Bocharov, Olga Dmitrenko, Lucila P. Méndez De Leo, and Andrew V. Teplyakov pp 9300–9301 DOI: 10.1021/ja0623663 Supporting Info

Symbiotic Reagent Activation:  Oppenauer Oxidation of Magnesium Alkoxides by Silylglyoxylates Triggers Second-Stage Aldolization Xin Linghu, Andrew D. Satterfield, and Jeffrey S. Johnson pp 9302–9303 DOI: 10.1021/ja062637+ Supporting Info

2,6-Bis[2-(4-pentylphenyl)vinyl]anthracene:  A Stable and High Charge Mobility Organic Semiconductor with Densely Packed Crystal Structure Hong Meng, Fangping Sun, Marc B. Goldfinger, Feng Gao, David J. Londono, Will J. Marshal, Greg S. Blackman, Kerwin D. Dobbs, and Dalen E. Keys pp 9304–9305 DOI: 10.1021/ja062683+ Supporting Info

Direct Measurement of the Thermodynamics of Vinylarene Hydroamination Adam M. Johns, Norio Sakai, André Ridder, and John F. Hartwig pp 9306–9307 DOI: 10.1021/ja062773e Supporting Info

A Reversible Reaction Inside a Self-Assembled Capsule Tetsuo Iwasawa, Enrique Mann, and Julius Rebek, Jr. pp 9308–9309 DOI: 10.1021/ja062768a Supporting Info

Multiple Alignment Tensors from a Denatured Protein Erika B. Gebel, Ke Ruan, Joel R. Tolman, and David Shortle pp 9310–9311 DOI: 10.1021/ja0627693 Supporting Info

Efficient Transfer of a VA-SWNT Film by a Flip-Over Technique Myung Jong Kim, Nolan Nicholas, Carter Kittrell, Erik Haroz, Hongwei Shan, T. J. Wainerdi, Sungbae Lee, Howard K. Schmidt, Richard E. Smalley, and Robert H. Hauge pp 9312–9313 DOI: 10.1021/ja062872s Supporting Info

Biomimetic Fabrication of 3D Structures by Spontaneous Folding of Tapes Derek A. Bruzewicz, Mila Boncheva, Adam Winkleman, Jason M. St. Clair, Gregory S. Engel, and George M. Whitesides pp 9314–9315 DOI: 10.1021/ja062973q Supporting Info

A Selective Fluorescent Sensor for Detecting Lead in Living Cells Qiwen He, Evan W. Miller, Audrey P. Wong, and Christopher J. Chang pp 9316–9317 DOI: 10.1021/ja063029x Supporting Info

Assembly of Ultrathin Polymer Multilayer Films by Click Chemistry Georgina K. Such, John F. Quinn, Anthony Quinn, Elvira Tjipto, and Frank Caruso pp 9318–9319 DOI: 10.1021/ja063043+ Supporting Info

Laser Spectroscopy of a Halocarbocation in the Gas Phase:  CH2I+ Chong Tao, Calvin Mukarakate, and Scott A. Reid pp 9320–9321 DOI: 10.1021/ja0631293 Supporting Info

Electron Attachment-Induced DNA Single Strand Breaks:  C3‘−O3‘ σ-Bond Breaking of Pyrimidine Nucleotides Predominates Jiande Gu, Jing Wang, and Jerzy Leszczynski pp 9322–9323 DOI: 10.1021/ja063309c Supporting Info

Bromoenterobactins as Potent Inhibitors of a Pathogen-Associated, Siderophore-Modifying C-Glycosyltransferase Hening Lin, Michael A. Fischbach, Gregory J. Gatto, Jr., David R. Liu, and Christopher T. Walsh pp 9324–9325 DOI: 10.1021/ja063236x Supporting Info

Ambient Pressure Syntheses of Size-Controlled Corundum-type In2O3 Nanocubes Chang Hoon Lee, Minsik Kim, Taekhoon Kim, Ansoon Kim, Jungsun Paek, Ju Wook Lee, Sung-Yool Choi, Kyuwon Kim, Jong-Bong Park, and Kwangyeol Lee pp 9326–9327 DOI: 10.1021/ja063227o Supporting Info

Enantioselective Organocatalytic Amine Conjugate Addition Young K. Chen, Masanori Yoshida, and David W. C. MacMillan pp 9328–9329 DOI: 10.1021/ja063267s Supporting Info

Controlled Synthesis and Self-Assembly of CeO2 Nanocubes Songwang Yang and Lian Gao pp 9330–9331 DOI: 10.1021/ja063359h Supporting Info

Synthesis of the Phenoxonium Cation of an α-Tocopherol Model Compound Crystallized with Non-Nucleophilic [B(C6F5)4]- and (CB11H6Br6)- Anions Stephen B. Lee, Anthony C. Willis, and Richard D. Webster pp 9332–9333 DOI: 10.1021/ja0634268 Supporting Info

A Ni2+ (S = 1) Kagome Compound Templated by 1,8-Diazacubane J. N. Behera and C. N. R. Rao pp 9334–9335 DOI: 10.1021/ja063385f Supporting Info

Catalytic Asymmetric Synthesis of Ferrocenes and P-Stereogenic Bisphosphines Cédric Genet, Steven J. Canipa, Peter O'Brien, and Sven Taylor pp 9336–9337 DOI: 10.1021/ja062616f Supporting Info

Exposure of Self-Assembly Interiors to External Elements. A Kinetic Approach Fredric M. Menger and Lei Shi pp 9338–9339 DOI: 10.1021/ja062807i Supporting Info

Metal-Catalyzed Cycloisomerization of Enyne Functionalities via a 1,3-Alkylidene Migration Ming-Yuan Lin, Arindam Das, and Rai-Shung Liu pp 9340–9341 DOI: 10.1021/ja062515h Supporting Info

Popular Theoretical Methods Predict Benzene and Arenes To Be Nonplanar Damian Moran, Andrew C. Simmonett, Franklin E. Leach III, Wesley D. Allen, Paul v. R. Schleyer, and Henry F. Schaefer III pp 9342–9343 DOI: 10.1021/ja0630285 Supporting Info

Synthesis of Secondary Amines by Titanium-Mediated Transfer of Alkenyl Groups from Alcohols Balasubramanian Ramanathan and Aaron L. Odom pp 9344–9345 DOI: 10.1021/ja0628811 Supporting Info

New RNA Labeling Methods Offer Dramatic Sensitivity Enhancements in 2H NMR Relaxation Spectra Pramodh Vallurupalli, Lincoln Scott, Mirko Hennig, James R. Williamson, and Lewis E. Kay pp 9346–9347 DOI: 10.1021/ja0632512 Supporting Info

A New Approach to the Nazarov Reaction via Sequential Electrocyclic Ring Opening and Ring Closure Tina N. Grant and F. G. West pp 9348–9349 DOI: 10.1021/ja063421a Supporting Info

Unique σ-Bond Metathesis of Silylalkynes Promoted by an ansa-Dimethylsilyl and Oxo-Bridged Uranium Metallocene Jiaxi Wang, Ylia Gurevich, Mark Botoshansky, and Moris S. Eisen pp 9350–9351 DOI: 10.1021/ja063443x Supporting Info

Total Synthesis of Ciguatoxin and 51-HydroxyCTX3C Masayuki Inoue, Keisuke Miyazaki, Yuuki Ishihara, Atsushi Tatami, Yuyu Ohnuma, Yuuya Kawada, Kazuo Komano, Shuji Yamashita, Nayoung Lee, and Masahiro Hirama pp 9352–9354 DOI: 10.1021/ja063041p Supporting Info

Structure of n-Butyllithium in Mixtures of Ethers and Diamines:  Influence of Mixed Solvation on 1,2-Additions to Imines Bo Qu and David B. Collum pp 9355–9360 DOI: 10.1021/ja0609654 Supporting Info

Synthesis, Characterization, and Activity in Ethylene Polymerization of Silica Supported Cationic Cyclopentadienyl Zirconium Complexes Nicolas Millot, Sophie Soignier, Catherine C. Santini, Anne Baudouin, and Jean-Marie Basset pp 9361–9370 DOI: 10.1021/ja060420+

Stamping Patterns of Insulated Gold Nanowires with Self-Organized Ultrathin Polymer Films James M. Helt, Charles Michael Drain, and Giorgio Bazzan pp 9371–9377 DOI: 10.1021/ja056809z Supporting Info

Spectroscopic Characterization of Copper(II) Binding to the Immunosuppressive Drug Mycophenolic Acid Christopher E. Jones, Paul J. Taylor, Alastair G. McEwan, and Graeme R. Hanson pp 9378–9386 DOI: 10.1021/ja057651l Supporting Info

Direct Detection of the Formation of V-Amylose Helix by Single Molecule Force Spectroscopy Qingmin Zhang, Zhenyu Lu, Hao Hu, Weitao Yang, and Piotr E. Marszalek pp 9387–9393 DOI: 10.1021/ja057693+ Supporting Info

Very Fast Electron Migrations within p-Doped Aromatic Cofacial Arrays Leading to Three-Dimensional (Toroidal) π-Delocalization Sergiy V. Rosokha, Ivan S. Neretin, Duoli Sun, and Jay K. Kochi pp 9394–9407 DOI: 10.1021/ja060393n Supporting Info

Janus and Ternary Particles Generated by Microfluidic Synthesis:  Design, Synthesis, and Self-Assembly Zhihong Nie, Wei Li, Minseok Seo, Shengqing Xu, and Eugenia Kumacheva pp 9408–9412 DOI: 10.1021/ja060882n Supporting Info

Thiourea-Catalyzed Asymmetric Michael Addition of Activated Methylene Compounds to α,β-Unsaturated Imides:  Dual Activation of Imide by Intra- and Intermolecular Hydrogen Bonding Tsubasa Inokuma, Yasutaka Hoashi, and Yoshiji Takemoto pp 9413–9419 DOI: 10.1021/ja061364f Supporting Info

Sharing Orbitals:  Ultrafast Excited State Deactivations with Different Outcomes in Bucky Ferrocenes and Ruthenocenes Dirk M. Guldi, G. M. Aminur Rahman, Renata Marczak, Yutaka Matsuo, Masahiro Yamanaka, and Eiichi Nakamura pp 9420–9427 DOI: 10.1021/ja061120v Supporting Info

In Situ Temperature Jump High-Frequency Dynamic Nuclear Polarization Experiments:  Enhanced Sensitivity in Liquid-State NMR Spectroscopy Chan-Gyu Joo, Kan-Nian Hu, Jeffrey A. Bryant, and Robert G. Griffin pp 9428–9432 DOI: 10.1021/ja0611947

Asymmetric Induction in Methyl Ketone Aldol Additions to α-Alkoxy and α,β-Bisalkoxy Aldehydes:  A Model for Acyclic Stereocontrol David A. Evans, Victor J. Cee, and Sarah J. Siska pp 9433–9441 DOI: 10.1021/ja061010o Supporting Info

Rapid Self-Assembly of Core−Shell Organosilicon Microcapsules within a Microfluidic Device Jeremy L. Steinbacher, Rebecca W. Y. Moy, Kristin E. Price, Meredith A. Cummings, Chandrani Roychowdhury, Jarrod J. Buffy, William L. Olbricht, Michael Haaf, and D. Tyler McQuade pp 9442–9447 DOI: 10.1021/ja0612403 Supporting Info

Spinel-to-CaFe2O4-Type Structural Transformation in LiMn2O4 under High Pressure Kazunari Yamaura, Qingzhen Huang, Lianqi Zhang, Kazunori Takada, Yuji Baba, Takuro Nagai, Yoshio Matsui, Kosuke Kosuda, and Eiji Takayama-Muromachi pp 9448–9456 DOI: 10.1021/ja0612302 Supporting Info

Determination of μ-Oxo Exchange Rates in Di-μ-Oxo Dimanganese Complexes by Electrospray Ionization Mass Spectrometry Ranitendranath Tagore, Hongyu Chen, Robert H. Crabtree, and Gary W. Brudvig pp 9457–9465 DOI: 10.1021/ja061348i Supporting Info

Hydration and Hydrogen Bonding of Carbonyls in Dimyristoyl-Phosphatidylcholine Bilayer Victor V. Volkov, Francesca Nuti, Yuji Takaoka, Riccardo Chelli, Anna Maria Papini, and Roberto Righini pp 9466–9471 DOI: 10.1021/ja0614621 Supporting Info

Substituent Effects in the Hydrosilylation of Coordinated Dinitrogen in a Ditantalum Complex:  Cleavage and Functionalization of N2 Bruce A. MacKay, Rui F. Munha, and Michael D. Fryzuk pp 9472–9483 DOI: 10.1021/ja061508q Supporting Info

d-Orbital Effects on Stereochemical Non-Rigidity:  Twisted TiIV Intramolecular Dynamics Anna V. Davis, Timothy K. Firman, Benjamin P. Hay, and Kenneth N. Raymond pp 9484–9496 DOI: 10.1021/ja0617946 Supporting Info

Toward the Control of the Magnetic Anisotropy of FeII Cubes:  A DFT Study Jordi Ribas-Arino, Tunna Baruah, and Mark R. Pederson pp 9497–9505 DOI: 10.1021/ja061518r

Effects of Temperature and Salt Concentration on the Structural Stability of Human Lymphotactin:  Insights from Molecular Simulations Mark S. Formaneck, Liang Ma, and Qiang Cui pp 9506–9517 DOI: 10.1021/ja061620o Supporting Info

A Non-Oxidative Approach toward Chemically and Electrochemically Functionalizing Si(111) Rosemary D. Rohde, Heather D. Agnew, Woon-Seok Yeo, Ryan C. Bailey, and James R. Heath pp 9518–9525 DOI: 10.1021/ja062012b

From Armchair to Zigzag Peripheries in Nanographenes Marcel Kastler, Jochen Schmidt, Wojciech Pisula, Daniel Sebastiani, and Klaus Müllen pp 9526–9534 DOI: 10.1021/ja062026h Supporting Info

Control of Ambipolar Thin Film Architectures by Co-Self-Assembling Oligo(p-phenylenevinylene)s and Perylene Bisimides Pascal Jonkheijm, Natalie Stutzmann, Zhijian Chen, Dago M. de Leeuw, E. W. Meijer, Albertus P. H. J. Schenning, and Frank Würthner pp 9535–9540 DOI: 10.1021/ja061966z Supporting Info

Columnar Self-Assembled Ureido Crown Ethers:  An Example of Ion-Channel Organization in Lipid Bilayers Adinela Cazacu, Christine Tong, Arie van der Lee, Thomas M. Fyles, and Mihail Barboiu pp 9541–9548 DOI: 10.1021/ja061861w Supporting Info

Determining the Topology of Integral Membrane Peptides Using EPR Spectroscopy Johnson J. Inbaraj, Thomas B. Cardon, Mikhail Laryukhin, Stuart M. Grosser, and Gary A. Lorigan pp 9549–9554 DOI: 10.1021/ja0622204 Supporting Info

Molecular Structure Determination in Powders by NMR Crystallography from Proton Spin Diffusion Bénédicte Elena, Guido Pintacuda, Nicolas Mifsud, and Lyndon Emsley pp 9555–9560 DOI: 10.1021/ja062353p Supporting Info

Total Synthesis of a 28-Member Stereoisomer Library of Murisolins Dennis P. Curran, Qisheng Zhang, Cyrille Richard, Hejun Lu, Venugopal Gudipati, and Craig S. Wilcox pp 9561–9573 DOI: 10.1021/ja061801q Supporting Info

Palladium in Organic Synthesis. Topics in Organometallic Chemistry, 14 Edited by Jiro Tsuji (Kamakura, Japan). Springer:  Berlin, Heidelberg, New York. 2005. x + 332 pp. $299. ISBN 3-540-23982-0. Eric Fillion p 9574 DOI: 10.1021/ja059836y

Chiral Diazaligands for Asymmetric Synthesis. Topics in Organometallic Chemistry, 15 Edited by Marc Lemaire (Unviersité Claude Bernard Lyon 1) and Pierre Mangeney (Université P. et M. Curie, Paris). Springer:  Berlin, Heidelberg, New York. 2005. x + 302 pp. $299.00. ISBN 3-540-26064-1. Marisa C. Kozlowski p 9574 DOI: 10.1021/ja0599420

Issue 30

Ru-Catalyzed Cyclization of Terminal Alkynals to Cycloalkenes Jesús A. Varela, Carlos González-Rodríguez, Silvia G. Rubín, Luis Castedo, and Carlos Saá pp 9576–9577 DOI: 10.1021/ja0610434 Supporting Info

Direct Observation of Surface-Mediated Thioacetyl Deprotection:  Covalent Tethering of a Thiol-Terminated Porphyrin to the Ag(100) Surface Owain P. H. Vaughan, Mark Turner, Federico J. Williams, Andreas Hille, Jeremy K. M. Sanders, and Richard M. Lambert pp 9578–9579 DOI: 10.1021/ja061247k Supporting Info

Fast Local Backbone Dynamics of Encapsulated Ubiquitin Alana K. Simorellis and Peter F. Flynn pp 9580–9581 DOI: 10.1021/ja061705p Supporting Info

Homogeneous, Titanocene-Catalyzed Dehydrocoupling of Amine−Borane Adducts Timothy J. Clark, Christopher A. Russell, and Ian Manners pp 9582–9583 DOI: 10.1021/ja062217k Supporting Info

Reversible Extrusion and Uptake of HCl Molecules by Crystalline Solids Involving Coordination Bond Cleavage and Formation Guillermo Mínguez Espallargas, Lee Brammer, Jacco van de Streek, Kenneth Shankland, Alastair J. Florence, and Harry Adams pp 9584–9585 DOI: 10.1021/ja0625733 Supporting Info

Synthesis and Structural, Electrochemical, and Stacking Properties of Conical Molecules Possessing Buckyferrocene on the Apex Yutaka Matsuo, Ayako Muramatsu, Yuko Kamikawa, Takashi Kato, and Eiichi Nakamura pp 9586–9587 DOI: 10.1021/ja062757h Supporting Info

Reacting the Unreactive:  A Toolbox of Low-Temperature Solution-Mediated Reactions for the Facile Interconversion of Nanocrystalline Intermetallic Compounds Robert E. Cable and Raymond E. Schaak pp 9588–9589 DOI: 10.1021/ja0627996 Supporting Info

Surface Plasmon Resonance Imaging Analysis of Protein-Receptor Binding in Supported Membrane Arrays on Gold Substrates with Calcinated Silicate Films K. Scott Phillips, Thomas Wilkop, Jiing-Jong Wu, Rabih O. Al-Kaysi, and Quan Cheng pp 9590–9591 DOI: 10.1021/ja0628102 Supporting Info

Hierarchical Luminescence Patterning Based on Multiscaled Self-Assembly Xiaodong Chen, Andrey L. Rogach, Dmitri V. Talapin, Harald Fuchs, and Lifeng Chi pp 9592–9593 DOI: 10.1021/ja062863j Supporting Info

Dynamics of Vibrational Overtone Excitations of H2SO4, H2SO4−H2O:  Hydrogen−Hopping and Photodissociation Processes Yifat Miller and R. Benny Gerber pp 9594–9595 DOI: 10.1021/ja062890+

Palladium-Catalyzed Hydrogenation:  Detection of Palladium Hydrides. A Joint Study Using Para-Hydrogen-Enhanced NMR Spectroscopy and Density Functional Theory Joaquín López-Serrano, Simon B. Duckett, and Agustí Lledós pp 9596–9597 DOI: 10.1021/ja0630137 Supporting Info

High Performance n- and p-Type Field-Effect Transistors Based on Tetrathiafulvalene Derivatives Naraso, Jun-ichi Nishida, Daisuke Kumaki, Shizuo Tokito, and Yoshiro Yamashita pp 9598–9599 DOI: 10.1021/ja0630083 Supporting Info

Solid State Structural Evidence of Chloroform−Benzene−Chloroform Adduct Trapped in Hexaanthryl Octaaminocryptand Channels P. S. Lakshminarayanan, D. Krishna Kumar, and Pradyut Ghosh pp 9600–9601 DOI: 10.1021/ja063228g Supporting Info

Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex:  The X-ray Crystal Structure of [(U (η-C8H6{SiiPr3-1,4}2)(η-C5Me4H)]2(μ-η2: η2-C4O4) Owen T. Summerscales, F. Geoffrey N. Cloke, Peter B. Hitchcock, Jennifer C. Green, and Nilay Hazari pp 9602–9603 DOI: 10.1021/ja063222r Supporting Info

Oxo-, Hydroxo-, and Peroxo-Bridged Fe(III) Phosphonate Cages Sanjit Konar, Nattamai Bhuvanesh, and Abraham Clearfield pp 9604–9605 DOI: 10.1021/ja063388s Supporting Info

Parallel Acquisition of Two-Dimensional NMR Spectra of Several Nuclear Species Ēriks Kupe, Ray Freeman, and Boban K. John pp 9606–9607 DOI: 10.1021/ja0634876 Supporting Info

Synthesis and Characterization of Bromonium Ylides and Their Unusual Ligand Transfer Reactions with N-Heterocycles Masahito Ochiai, Norihiro Tada, Kentaro Murai, Satoru Goto, and Motoo Shiro pp 9608–9609 DOI: 10.1021/ja063492+ Supporting Info

Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations Polly L. Arnold, Dipti Patel, Alexander J. Blake, Claire Wilson, and Jason B. Love pp 9610–9611 DOI: 10.1021/ja0634167 Supporting Info

Photogeneration of Heptacene in a Polymer Matrix Rajib Mondal, Bipin K. Shah, and Douglas C. Neckers pp 9612–9613 DOI: 10.1021/ja063823i Supporting Info

Highly Active Molybdenum−Alkylidyne Catalysts for Alkyne Metathesis:  Synthesis from the Nitrides by Metathesis with Alkynes Robyn L. Gdula and Marc J. A. Johnson pp 9614–9615 DOI: 10.1021/ja058036k Supporting Info

Mechanistic Evidence for Intermolecular Radical Carbonyl Additions Promoted by Samarium Diiodide Anna Mette Hansen, Karl B. Lindsay, P. K. Sudhadevi Antharjanam, Jakob Karaffa, Kim Daasbjerg, Robert A. Flowers II, and Troels Skrydstrup pp 9616–9617 DOI: 10.1021/ja060553v Supporting Info

Direct, Stereospecific Generation of (Z)-Disubstituted Allylic Alcohols Sang-Jin Jeon, Ethan L. Fisher, Patrick J. Carroll, and Patrick J. Walsh pp 9618–9619 DOI: 10.1021/ja061973n Supporting Info

Propargyl Glycosides as Stable Glycosyl Donors:  Anomeric Activation and Glycoside Syntheses Srinivas Hotha and Sudhir Kashyap pp 9620–9621 DOI: 10.1021/ja062425c Supporting Info

Generation of Dimethylsilylene and Allylidene Holmium Complexes from Trimethylsilylated Allyl Ligands Rosemary E. White, Timothy P. Hanusa, and Benjamin E. Kucera pp 9622–9623 DOI: 10.1021/ja062646i Supporting Info

Simple Diamine- and Triamine-Protonic Acid Catalysts for the Enantioselective Michael Addition of Cyclic Ketones to Nitroalkenes Sunil V. Pansare and Keyur Pandya pp 9624–9625 DOI: 10.1021/ja062701n Supporting Info

Design of Chiral N-Triflyl Phosphoramide as a Strong Chiral Brønsted Acid and Its Application to Asymmetric Diels−Alder Reaction Daisuke Nakashima and Hisashi Yamamoto pp 9626–9627 DOI: 10.1021/ja062508t Supporting Info

A New Type of N-Heterocyclic Silylene with Ambivalent Reactivity Matthias Driess, Shenglai Yao, Markus Brym, Christoph van Wüllen, and Dieter Lentz pp 9628–9629 DOI: 10.1021/ja062928i Supporting Info

3-Pyrrolidinecarboxylic Acid for Direct Catalytic Asymmetric anti-Mannich-Type Reactions of Unmodified Ketones Haile Zhang, Maria Mifsud, Fujie Tanaka, and Carlos F. Barbas, III pp 9630–9631 DOI: 10.1021/ja062950b Supporting Info

Acyclic catena-Diphosphinodiphosphonium Dications [R3P-PR‘-PR‘-PR3]2+ or Bisphosphine−Diphosphenium Complexes [R3P→PR‘-PR‘←PR3]2+:  Synthesis by Reductive P−P Coupling of [R3P-PR‘Cl]+ and Phosphine Ligand Exchange C. Adam Dyker, Neil Burford, Michael D. Lumsden, and Andreas Decken pp 9632–9633 DOI: 10.1021/ja062972y Supporting Info

Oxidation of Hydroxyl-Substituted Organotrifluoroborates Gary A. Molander and Daniel E. Petrillo pp 9634–9635 DOI: 10.1021/ja062974i Supporting Info

Organocatalytic Mitsunobu Reactions Tracy Yuen Sze But and Patrick H. Toy pp 9636–9637 DOI: 10.1021/ja063141v Supporting Info

Atomic Layer Deposition of Tungsten(III) Oxide Thin Films from W2(NMe2)6 and Water:  Precursor-Based Control of Oxidation State in the Thin Film Material Charles L. Dezelah IV, Oussama M. El-Kadri, Imre M. Szilágyi, Joseph M. Campbell, Kai Arstila, Lauri Niinistö, and Charles H. Winter pp 9638–9639 DOI: 10.1021/ja063272w Supporting Info

A FRET-Based Approach to Ratiometric Fluorescence Detection of Hydrogen Peroxide Aaron E. Albers, Voytek S. Okreglak, and Christopher J. Chang pp 9640–9641 DOI: 10.1021/ja063308k Supporting Info

Carbon−Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium Alkoxide Pinjing Zhao, Christopher D. Incarvito, and John F. Hartwig pp 9642–9643 DOI: 10.1021/ja063347w Supporting Info

A General Process for the Haloamidation of Olefins. Scope and Mechanism Ying-Yeung Yeung, Xuri Gao, and E. J. Corey pp 9644–9645 DOI: 10.1021/ja063675w Supporting Info

Asymmetric Allylboration of Cyclic Imines and Applications to Alkaloid Synthesis T. Robert Wu and J. Michael Chong pp 9646–9647 DOI: 10.1021/ja0636791 Supporting Info

Total Synthesis of the Proposed Structure of Brevenal Haruhiko Fuwa, Makoto Ebine, and Makoto Sasaki pp 9648–9650 DOI: 10.1021/ja062524q Supporting Info

Mechanism of the Aerobic Oxidation of Alcohols by Palladium Complexes of N-Heterocyclic Carbenes Robert J. Nielsen and William A. Goddard III pp 9651–9660 DOI: 10.1021/ja060915z Supporting Info

Thermal and Metal-Catalyzed Cyclization of 1-Substituted 3,5-Dien-1-ynes via a [1,7]-Hydrogen Shift:  Development of a Tandem Aldol Condensation−Dehydration and Aromatization Catalysis between 3-En-1-yn-5-al Units and Cyclic Ketones Jian-Jou Lian, Chung-Chang Lin, Hsu-Kai Chang, Po-Chiang Chen, and Rai-Shung Liu pp 9661–9667 DOI: 10.1021/ja061203b Supporting Info

Chiral α-Branched Benzylic Carbocations:  Diastereoselective Intermolecular Reactions with Arene Nucleophiles and NMR Spectroscopic Studies Friedrich Mühlthau, Daniel Stadler, Alain Goeppert, George A. Olah, G. K. Surya Prakash, and Thorsten Bach pp 9668–9675 DOI: 10.1021/ja062102g Supporting Info

Hydrogen- and Fluorine-Bridged Disilyl Cations and Their Use in Catalytic C−F Activation Robin Panisch, Michael Bolte, and Thomas Müller pp 9676–9682 DOI: 10.1021/ja061800y Supporting Info

2H Natural-Abundance MAS NMR Spectroscopy:  An Alternative Approach to Obtain 1H Chemical Shifts in Solids Takashi Mizuno, Takahiro Nemoto, Masataka Tansho, Tadashi Shimizu, Hiroki Ishii, and K. Takegoshi pp 9683–9686 DOI: 10.1021/ja062280+

Hydrolysis of Acyloxy Nitroso Compounds Yields Nitroxyl (HNO) Xin Sha, T. Scott Isbell, Rakesh P. Patel, Cynthia S. Day, and S. Bruce King pp 9687–9692 DOI: 10.1021/ja062365a Supporting Info

Photoelectrochemical Immunosensor for Label-Free Detection and Quantification of Anti-cholera Toxin Antibody Naoufel Haddour, Jérôme Chauvin, Chantal Gondran, and Serge Cosnier pp 9693–9698 DOI: 10.1021/ja062729z

The Putative Endocannabinoid Transport Blocker LY2183240 Is a Potent Inhibitor of FAAH and Several Other Brain Serine Hydrolases Jessica P. Alexander and Benjamin F. Cravatt pp 9699–9704 DOI: 10.1021/ja062999h Supporting Info

Au- and Pt-Catalyzed Cycloisomerizations of 1,5-Enynes to Cyclohexadienes with a Broad Alkyne Scope Jianwei Sun, Matthew P. Conley, Liming Zhang, and Sergey A. Kozmin pp 9705–9710 DOI: 10.1021/ja063384n Supporting Info

Biscyclization Reactions in Butadiyne- and Ethyne-Linked Triazenes and Diazenes:  Concerted versus Stepwise Coarctate Cyclizations Laura D. Shirtcliff, Austin G. Hayes, Michael M. Haley, Felix Köhler, Kirsten Hess, and Rainer Herges pp 9711–9721 DOI: 10.1021/ja054547v Supporting Info

Highly Stereoselective Asymmetric Pummerer Reactions That Incorporate Intermolecular and Intramolecular Nonbonded S···O Interactions Yoshimitsu Nagao, Satoshi Miyamoto, Motoyuki Miyamoto, Hiroe Takeshige, Kazuhiko Hayashi, Shigeki Sano, Motoo Shiro, Kentaro Yamaguchi, and Yoshihisa Sei pp 9722–9729 DOI: 10.1021/ja056649r Supporting Info

Enantioselective Synthesis of Vinylcyclopropanes and Vinylepoxides Mediated by Camphor-Derived Sulfur Ylides:  Rationale of Enantioselectivity, Scope, and Limitation Xian-Ming Deng, Ping Cai, Song Ye, Xiu-Li Sun, Wei-Wei Liao, Kai Li, Yong Tang, Yun-Dong Wu, and Li-Xin Dai pp 9730–9740 DOI: 10.1021/ja056751o Supporting Info

First-Principles Study of Hydrogen Storage on Li12C60 Qiang Sun, Puru Jena, Qian Wang, and Manuel Marquez pp 9741–9745 DOI: 10.1021/ja058330c

Rhodium-Mediated Stereoselective Polymerization of “Carbenes” Dennis G. H. Hetterscheid, Coen Hendriksen, Wojciech I. Dzik, Jan M. M. Smits, Ernst R. H. van Eck, Alan E. Rowan, Vincenzo Busico, Michele Vacatello, Valeria Van Axel Castelli, Annalaura Segre, Erica Jellema, Tom G. Bloemberg, and Bas de Bruin pp 9746–9752 DOI: 10.1021/ja058722j Supporting Info

Synthesis, Characterization, and Self-Assembly of Pencil-Shaped CoO Nanorods Kwangjin An, Nohyun Lee, Jongnam Park, Sung Chul Kim, Yosun Hwang, Je-Geun Park, Jae-Young Kim, Jae-Hoon Park, Myung Joon Han, Jaejun Yu, and Taeghwan Hyeon pp 9753–9760 DOI: 10.1021/ja0608702 Supporting Info

Site-Specific Detection of DNA Methylation Utilizing mCpG-SEER Cliff I. Stains, Jennifer L. Furman, David J. Segal, and Indraneel Ghosh pp 9761–9765 DOI: 10.1021/ja060681j Supporting Info

Convergent Dynamics in the Protease Enzymatic Superfamily Vincenzo Carnevale, Simone Raugei, Cristian Micheletti, and Paolo Carloni pp 9766–9772 DOI: 10.1021/ja060896t Supporting Info

Biphasic Hydrosilylation in Ionic Liquids:  A Process Set for Industrial Implementation Tilmann J. Geldbach, Dongbin Zhao, Nikola C. Castillo, Gabor Laurenczy, Bernd Weyershausen, and Paul J. Dyson pp 9773–9780 DOI: 10.1021/ja0612293 Supporting Info

Scope and Mechanism of the C−H Bond Activation Reactivity within a Supramolecular Host by an Iridium Guest:  A Stepwise Ion Pair Guest Dissociation Mechanism Dennis H. Leung, Robert G. Bergman, and Kenneth N. Raymond pp 9781–9797 DOI: 10.1021/ja061412w Supporting Info

Silver Bromide Nanoparticle/Polymer Composites:  Dual Action Tunable Antimicrobial Materials Varun Sambhy, Megan M. MacBride, Blake R. Peterson, and Ayusman Sen pp 9798–9808 DOI: 10.1021/ja061442z

Investigating a Quadruplex−Ligand Interaction by Unfolding Kinetics Jeremy J. Green, Sylvain Ladame, Liming Ying, David Klenerman, and Shankar Balasubramanian pp 9809–9812 DOI: 10.1021/ja0615425 Supporting Info

Propene Activation by the Oxo-Iron Active Species of Taurine/α-Ketoglutarate Dioxygenase (TauD) Enzyme. How Does the Catalysis Compare to Heme-Enzymes? Sam P. de Visser pp 9813–9824 DOI: 10.1021/ja061581g Supporting Info

X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-):  Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes Abhishek Dey, Rosalie K. Hocking, Peter Larsen, Andrew S. Borovik, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 9825–9833 DOI: 10.1021/ja061618x Supporting Info

Synthetic, Structural, Mechanistic, and Computational Studies on Single-Site β-Diketiminate Tin(II) Initiators for the Polymerization of rac-Lactide Andrew P. Dove, Vernon C. Gibson, Edward L. Marshall, Henry S. Rzepa, Andrew J. P. White, and David J. Williams pp 9834–9843 DOI: 10.1021/ja061400a Supporting Info

Retinol Modulates Site-Specific Mobility of Apo-Cellular Retinol-Binding Protein to Promote Ligand Binding Tanja Mittag, Lorella Franzoni, Davide Cavazzini, Brian Schaffhausen, Gian Luigi Rossi, and Ulrich L. Günther pp 9844–9848 DOI: 10.1021/ja0616128 Supporting Info

Ion-Binding Study by 17O Solid-State NMR Spectroscopy in the Model Peptide Gly-Gly-Gly at 19.6 T Eduard Y. Chekmenev, Kevin W. Waddell, Jun Hu, Zhehong Gan, Richard J. Wittebort, and Timothy A. Cross pp 9849–9855 DOI: 10.1021/ja060191r Supporting Info

SHARP-TACSY:  Triple-Band Tailored Correlated Spectroscopy for Base-to-Sugar Transfer in Nucleic Acid Residues with Intermediate Time Scale Motions Christophe Farès and Teresa Carlomagno pp 9856–9862 DOI: 10.1021/ja061424h Supporting Info

Cooperative Hydrogen Bonding Effects Are Key Determinants of Backbone Amide Proton Chemical Shifts in Proteins Laura L. Parker, Andrew R. Houk, and Jan H. Jensen pp 9863–9872 DOI: 10.1021/ja0617901

Conversion of Methane to Methanol at the Mononuclear and Dinuclear Copper Sites of Particulate Methane Monooxygenase (pMMO):  A DFT and QM/MM Study Kazunari Yoshizawa and Yoshihito Shiota pp 9873–9881 DOI: 10.1021/ja061604r Supporting Info

Effect of Electronic Polarization on Charge-Transport Parameters in Molecular Organic Semiconductors Edward F. Valeev, Veaceslav Coropceanu, Demetrio A. da Silva Filho, Seyhan Salman, and Jean-Luc Brédas pp 9882–9886 DOI: 10.1021/ja061827h Supporting Info

Designing Multistep Transformations Using the Hammett Equation:  Imine Exchange on a Copper(I) Template David Schultz and Jonathan R. Nitschke pp 9887–9892 DOI: 10.1021/ja061841u Supporting Info

Interaction of α-Synuclein with Divalent Metal Ions Reveals Key Differences:  A Link between Structure, Binding Specificity and Fibrillation Enhancement Andrés Binolfi, Rodolfo M. Rasia, Carlos W. Bertoncini, Marcelo Ceolin, Markus Zweckstetter, Christian Griesinger, Thomas M. Jovin, and Claudio O. Fernández pp 9893–9901 DOI: 10.1021/ja0618649 Supporting Info

Application of Centrifugation to the Large-Scale Purification of Electric Arc-Produced Single-Walled Carbon Nanotubes Aiping Yu, Elena Bekyarova, Mikhail E. Itkis, Danylo Fakhrutdinov, Robert Webster, and Robert C. Haddon pp 9902–9908 DOI: 10.1021/ja062041m

Synthesis, Oxidation Behavior, Crystallization and Structure of 2‘-Methylseleno Guanosine Containing RNAs Holger Moroder, Christoph Kreutz, Kathrin Lang, Alexander Serganov, and Ronald Micura pp 9909–9918 DOI: 10.1021/ja0621400 Supporting Info

Characterization of the Bis-Silylated Endofullerene Sc3N@C80 Takatsugu Wakahara, Yuko Iiduka, Ozora Ikenaga, Tsukasa Nakahodo, Akihiro Sakuraba, Takahiro Tsuchiya, Yutaka Maeda, Masahiro Kako, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Naomi Mizorogi, and Shigeru Nagase pp 9919–9925 DOI: 10.1021/ja062233h Supporting Info

Layer-by-Layer Enzyme/Polyelectrolyte Films as a Functional Protective Barrier in Oxidizing Media Tatsiana G. Shutava, Dinesh S. Kommireddy, and Yuri M. Lvov pp 9926–9934 DOI: 10.1021/ja062318i

Nanoporous Block Copolymer Micelle/Micelle Multilayer Films with Dual Optical Properties Jinhan Cho, Jinkee Hong, Kookheon Char, and Frank Caruso pp 9935–9942 DOI: 10.1021/ja062437y Supporting Info

On the Proof and Disproof of Natural Product Stereostructures:  Characterization and Analysis of a Twenty-Eight Member Stereoisomer Library of Murisolins and Their Mosher Ester Derivatives Dennis P. Curran, Qisheng Zhang, Hejun Lu, and Venugopal Gudipati pp 9943–9956 DOI: 10.1021/ja062469l Supporting Info

Chiral Three-Dimensional Microporous Nickel Aspartate with Extended Ni−O−Ni Bonding Ekaterina V. Anokhina, Yong Bok Go, Yongjae Lee, Thomas Vogt, and Allan J. Jacobson pp 9957–9962 DOI: 10.1021/ja062743b Supporting Info

Structure of the Human Telomere in K+ Solution:  An Intramolecular (3 + 1) G-Quadruplex Scaffold Kim Ngoc Luu, Anh Tuân Phan, Vitaly Kuryavyi, Laurent Lacroix, and Dinshaw J. Patel pp 9963–9970 DOI: 10.1021/ja062791w

Genetically Engineered Synthesis and Structural Characterization of Cobalt−Precorrin 5A and −5B, Two New Intermediates on the Anaerobic Pathway to Vitamin B12:  Definition of the Roles of the CbiF and CbiG Enzymes Yasuhiro Kajiwara, Patricio J. Santander, Charles A. Roessner, Lisa M. Pérez, and A. Ian Scott pp 9971–9978 DOI: 10.1021/ja062940a Supporting Info

A Highly Efficient Preparative Method of α-Ylidene-β-Diketones via AuIII-Catalyzed Acyl Migration of Propargylic Esters  [J. Am. Chem. Soc. 2006, 128, 8414−8415].  Shaozhong Wang and Liming Zhang p 9979 DOI: 10.1021/ja0699687

Bioorganometallics:  Biomolecules, Labeling, Medicine Edited by Gérard Jaouen (Ecole Nationale Supérieure de Chimie de Paris). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xxiii + 444 pp. $170.00. ISBN 3-527-30990-X. Joseph M. O'Connor p 9980 DOI: 10.1021/ja0697119

Magnetic Functions beyond the Spin-Hamiltonian. Structure and Bonding, 117 Volume and Series Edited by D. M. P. Mingos (Oxford University, UK). Springer:  Berlin, Heidelberg, New York. 2006. x + 276 pp. $325.00. ISBN 3-540-26079-X. Aurora Clark p 9980 DOI: 10.1021/ja069727z

Block Copolymers I and II. Advances in Polymer Science 189 and 190 Edited by Volker Abetz (Institut für Polymerforschung, Geesthacht, Germany). Springer:  Berlin, Heidelberg, New York. 2005. xx + 238 pp. $199.00. ISBN 3-540-26580-5 (Volume I). xii + 252 pp. $219.00. ISBN 3-540-26902-9 (Volume II). C. Geraldine Bazuin pp 9980–9981 DOI: 10.1021/ja069709h

Intermolecular Forces and Clusters I. Structure and Bonding, 115 Edited by D. J. Wales (University of Cambridge, UK). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2005. xvi + 206 pp. $199.00. ISBN 3-540-28194-0. Peter E. Siska pp 9981–9982 DOI: 10.1021/ja059870c

Intermolecular Forces and Clusters II. Structure and Bonding, 116 Edited by D. J. Wales (University of Cambridge, UK). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2005. xvi + 158 pp. $175.00. ISBN 3-540-28191-6. Ajit J. Thakkar p 9982 DOI: 10.1021/ja069729j

Issue 31

Photoinduced Charge Transfer between CdSe Nanocrystal Quantum Dots and Ru−Polypyridine Complexes Milan Sykora, Melissa A. Petruska, James Alstrum-Acevedo, Ilya Bezel, Thomas J. Meyer, and Victor I. Klimov pp 9984–9985 DOI: 10.1021/ja061556a Supporting Info

Hybrid Molecular Probe for Nucleic Acid Analysis in Biological Samples Chaoyong James Yang, Karen Martinez, Hui Lin, and Weihong Tan pp 9986–9987 DOI: 10.1021/ja0618346 Supporting Info

Tuning the Sensitivity of a Foldamer-Based Mercury Sensor by Its Folding Energy Yan Zhao and Zhenqi Zhong pp 9988–9989 DOI: 10.1021/ja062001i Supporting Info

Covalent Attachment of Acetylene and Methylacetylene Functionality to Si(111) Surfaces: Scaffolds for Organic Surface Functionalization while Retaining Si−C Passivation of Si(111) Surface Sites Patrick T. Hurley, E. Joseph Nemanick, Bruce S. Brunschwig, and Nathan S. Lewis pp 9990–9991 DOI: 10.1021/ja061969b

Constant-Time Through-Bond 13C Correlation Spectroscopy for Assigning Protein Resonances with Solid-State NMR Spectroscopy Lingling Chen, Ryan A. Olsen, Douglas W. Elliott, John M. Boettcher, Donghua H. Zhou, Chad M. Rienstra, and Leonard J. Mueller pp 9992–9993 DOI: 10.1021/ja062347t Supporting Info

Redox Ionic Liquid Phases:  Ferrocenated Imidazoliums Ramjee Balasubramanian, Wei Wang, and Royce W. Murray pp 9994–9995 DOI: 10.1021/ja0625327 Supporting Info

Efficient Non-corrosive Electron-Transfer Mediator Mixtures for Dye-Sensitized Solar Cells Silvia Cazzanti, Stefano Caramori, Roberto Argazzi, C. Michael Elliott, and Carlo Alberto Bignozzi pp 9996–9997 DOI: 10.1021/ja062087f Supporting Info

Highly Efficient Alkylation to Ketones and Aldimines with Grignard Reagents Catalyzed by Zinc(II) Chloride Manabu Hatano, Shinji Suzuki, and Kazuaki Ishihara pp 9998–9999 DOI: 10.1021/ja0628405 Supporting Info

Detection and Structural Characterization of Clusters with Ultrashort-Lived Electronically Excited States:  IR Absorption Detected by Femtosecond Multiphoton Ionization Yevgeniy Nosenko, Maksim Kunitski, Randolph P. Thummel, Alexander Kyrychenko, Jerzy Herbich, Jacek Waluk, Christoph Riehn, and Bernhard Brutschy pp 10000–10001 DOI: 10.1021/ja063093e Supporting Info

Synthesis of Homoallylic Amines via the Palladium-Catalyzed Decarboxylative Coupling of Amino Acid Derivatives Erin C. Burger and Jon A. Tunge pp 10002–10003 DOI: 10.1021/ja063115x Supporting Info

Inter-Helix Distances in Lysophospholipid Micelle-Bound α-Synuclein from Pulsed ESR Measurements Peter Borbat, Trudy F. Ramlall, Jack H. Freed, and David Eliezer pp 10004–10005 DOI: 10.1021/ja063122l Supporting Info

Directed Self-Assembly of Gold-Tipped CdSe Nanorods Asaf Salant, Ella Amitay-Sadovsky, and Uri Banin pp 10006–10007 DOI: 10.1021/ja063192s Supporting Info

Distinct Dynamic Behaviors of Water Molecules in Hydrated Pores Martín Febles, Natalia Pérez-Hernández, Cirilo Pérez, Matías L. Rodríguez, Concepción Foces-Foces, María Victoria Roux, Ezequiel Q. Morales, Gerd Buntkowsky, Hans-Heinrich Limbach, and Julio D. Martín pp 10008–10009 DOI: 10.1021/ja063223j Supporting Info

Pseudo-CSA Restraints for NMR Refinement of Nucleic Acid Structure Alexander Grishaev, Jinfa Ying, and Ad Bax pp 10010–10011 DOI: 10.1021/ja0633058 Supporting Info

Iron-Based Layered Superconductor:  LaOFeP Yoichi Kamihara, Hidenori Hiramatsu, Masahiro Hirano, Ryuto Kawamura, Hiroshi Yanagi, Toshio Kamiya, and Hideo Hosono pp 10012–10013 DOI: 10.1021/ja063355c Supporting Info

Molecular Architecture via Coordination:  Self-Assembly of Nanoscale Hexagonal Metallodendrimers with Designed Building Blocks Hai-Bo Yang, Neeladri Das, Feihe Huang, Adam M. Hawkridge, David C. Muddiman, and Peter J. Stang pp 10014–10015 DOI: 10.1021/ja063377z Supporting Info

Two Pressure-Induced Superconducting Anion Radical Salts Exhibiting Different Spin States at Ambient Pressure Reizo Kato, Akiko Tajima, Akiko Nakao, and Masafumi Tamura pp 10016–10017 DOI: 10.1021/ja063525l Supporting Info

Nanoparticle-Based Sensing of Glycan−Lectin Interactions Zong Dai, Abdel-Nasser Kawde, Yun Xiang, Jeffrey T. La Belle, Jared Gerlach, Veer P. Bhavanandan, Lokesh Joshi, and Joseph Wang pp 10018–10019 DOI: 10.1021/ja063565p Supporting Info

Thermal Reactions of 7-d- and 8-d-Bicyclo[4.2.0]oct-2-enes John E. Baldwin, Phyllis A. Leber, and David C. Powers pp 10020–10021 DOI: 10.1021/ja0636035 Supporting Info

Sensitive and Selective Detection of Nitric Oxide Using an H−NOX Domain Elizabeth M. Boon and Michael A. Marletta pp 10022–10023 DOI: 10.1021/ja0632714

Nanoscale Spherical Architectures Fabricated by Metal Coordination of Multiple Dipyrrin Moieties Hiromitsu Maeda, Masahiro Hasegawa, Takashi Hashimoto, Takuya Kakimoto, Satoru Nishio, and Takashi Nakanishi pp 10024–10025 DOI: 10.1021/ja0637301 Supporting Info

Carbons with Extremely Large Volume of Uniform Mesopores Synthesized by Carbonization of Phenolic Resin Film Formed on Colloidal Silica Template Kamil P. Gierszal and Mietek Jaroniec pp 10026–10027 DOI: 10.1021/ja0634831 Supporting Info

Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides Qilong Shen and John F. Hartwig pp 10028–10029 DOI: 10.1021/ja064005t Supporting Info

Hydration and Dynamic Behavior of Poly(N-isopropylacrylamide)s in Aqueous Solution:  A Sharp Phase Transition at the Lower Critical Solution Temperature Yousuke Ono and Toshiyuki Shikata pp 10030–10031 DOI: 10.1021/ja063990i Supporting Info

Dodecamethoxy- and Hexaoxotricyclobutabenzene:  Synthesis and Characterization Toshiyuki Hamura, Yousuke Ibusuki, Hidehiro Uekusa, Takashi Matsumoto, Jay S. Siegel, Kim K. Baldridge, and Keisuke Suzuki pp 10032–10033 DOI: 10.1021/ja064063e Supporting Info

Revealing Two-State Protein−Protein Interactions of Calmodulin by Single-Molecule Spectroscopy Ruchuan Liu, Dehong Hu, Xin Tan, and H. Peter Lu pp 10034–10042 DOI: 10.1021/ja057005m Supporting Info

Chemical Control of Electronic Structure and Superconductivity in Layered Borides and Borocarbides:  Understanding the Absence of Superconductivity in LixBC Andrew M. Fogg, James Meldrum, George R. Darling, John B. Claridge, and Matthew J. Rosseinsky pp 10043–10053 DOI: 10.1021/ja0578449 Supporting Info

Structural Characterization of Ultrasmall Superparamagnetic Iron Oxide (USPIO) Particles in Aqueous Suspension by Energy Dispersive X-ray Diffraction (EDXD) Mariagrazia Di Marco, Marc Port, Patrick Couvreur, Catherine Dubernet, Paolo Ballirano, and Claudia Sadun pp 10054–10059 DOI: 10.1021/ja061674y Supporting Info

Zero-Point Corrections and Temperature Dependence of HD Spin−Spin Coupling Constants of Heavy Metal Hydride and Dihydrogen Complexes Calculated by Vibrational Averaging Brendan C. Mort and Jochen Autschbach pp 10060–10072 DOI: 10.1021/ja0586236 Supporting Info

Layering at an Ionic Liquid−Vapor Interface:  A Molecular Dynamics Simulation Study of [bmim][PF6] B. L. Bhargava and S. Balasubramanian pp 10073–10078 DOI: 10.1021/ja060035k

Facile Interstrand Migration of the Hydrocarbon Moiety of a Dibenzo[a,l]pyrene 11,12-Diol 13,14-Epoxide Adduct at N 2 of Deoxyguanosine in a Duplex Oligonucleotide Ben Wang, Jane M. Sayer, Haruhiko Yagi, Heinrich Frank, Albrecht Seidel, and Donald M. Jerina pp 10079–10084 DOI: 10.1021/ja0608038

Base-Displaced Intercalated Structure of the Food Mutagen 2-Amino-3-methylimidazo[4,5-f]quinoline in the Recognition Sequence of the NarI Restriction Enzyme, a Hotspot for −2 bp Deletions Feng Wang, Nicholas E. DeMuro, C. Eric Elmquist, James S. Stover, Carmelo J. Rizzo, and Michael P. Stone pp 10085–10095 DOI: 10.1021/ja062004v Supporting Info

A Comparative QM/MM Simulation Study of the Reaction Mechanisms of Human and Plasmodium falciparum HG(X)PRTases Aline Thomas and Martin J. Field pp 10096–10102 DOI: 10.1021/ja060823+

Wheel-Shaped Polyoxotungstate [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- Macroanions Form Supramolecular “Blackberry” Structure in Aqueous Solution Guang Liu, Tianbo Liu, Sib Sankar Mal, and Ulrich Kortz pp 10103–10110 DOI: 10.1021/ja0610840

Self-Assembly of Peptide Scaffolds in Biosilica Formation:  Computer Simulations of a Coarse-Grained Model Leonardo Lenoci and Philip J. Camp pp 10111–10117 DOI: 10.1021/ja061211s

Two-Phase Synthesis of Shape-Controlled Colloidal Zirconia Nanocrystals and Their Characterization Nana Zhao, Daocheng Pan, Wei Nie, and Xiangling Ji pp 10118–10124 DOI: 10.1021/ja0612145 Supporting Info

The Mechanism of Epoxide Carbonylation by [Lewis Acid]+[Co(CO)4]- Catalysts Tamara L. Church, Yutan D. Y. L. Getzler, and Geoffrey W. Coates pp 10125–10133 DOI: 10.1021/ja061503t Supporting Info

Exploration of Ground and Excited Electronic States of Aromatic and Quinoid S,S-Dioxide Terthiophenes. Complementary Systems for Enhanced Electronic Organic Materials Juan Casado, Marek Z. Zgierski, Paul C. Ewbank, Michael W. Burand, Daron E. Janzen, Kent R. Mann, Ted M. Pappenfus, Anna Berlin, Ezequiel Pérez-Inestrosa, Rocío Ponce Ortiz, and Juan T. López Navarrete pp 10134–10144 DOI: 10.1021/ja061372w Supporting Info

How an Enzyme Tames Reactive Intermediates:  Positioning of the Active-Site Components of Lysine 2,3-Aminomutase during Enzymatic Turnover As Determined by ENDOR Spectroscopy Nicholas S. Lees, Dawei Chen, Charles J. Walsby, Elham Behshad, Perry A. Frey, and Brian M. Hoffman pp 10145–10154 DOI: 10.1021/ja061282r Supporting Info

Europium(III) Macrocyclic Complexes with Alcohol Pendant Groups as Chemical Exchange Saturation Transfer Agents Mark Woods, Donald E. Woessner, Piyu Zhao, Azhar Pasha, Meng-Yin Yang, Ching-Hui Huang, Olga Vasalitiy, Janet R. Morrow, and A. Dean Sherry pp 10155–10162 DOI: 10.1021/ja061498t Supporting Info

Electrochemistry, Spectroscopy, and Electrogenerated Chemiluminescence of Silole-Based Chromophores Matthew M. Sartin, Andrew J. Boydston, Brian L. Pagenkopf, and Allen J. Bard pp 10163–10170 DOI: 10.1021/ja0618494 Supporting Info

Manipulation of Aqueous Growth of CdTe Nanocrystals To Fabricate Colloidally Stable One-Dimensional Nanostructures Hao Zhang, Dayang Wang, Bai Yang, and Helmuth Möhwald pp 10171–10180 DOI: 10.1021/ja061787h Supporting Info

Mössbauer and Computational Study of an N2-Bridged Diiron Diketiminate Complex:  Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen Sebastian A. Stoian, Javier Vela, Jeremy M. Smith, Azwana R. Sadique, Patrick L. Holland, Eckard Münck, and Emile L. Bominaar pp 10181–10192 DOI: 10.1021/ja062051n Supporting Info

Ferromagnetic Coupling in Hexanuclear Gadolinium Clusters Lucas E. Sweet, Lindsay E. Roy, Fanqin Meng, and Timothy Hughbanks pp 10193–10201 DOI: 10.1021/ja0617690 Supporting Info

Evidence for Increased Exchange Interactions with 5d Compared to 4d Metal Ions. Experimental and Theoretical Insights into the Ferromagnetic Interactions of a Series of Trinuclear [{M(CN)8}3-/NiII] Compounds (M = MoV or WV) Diana Visinescu, Cédric Desplanches, Inhar Imaz, Vincent Bahers, Rabindranath Pradhan, Frederick A. Villamena, Philippe Guionneau, and Jean-Pascal Sutter pp 10202–10212 DOI: 10.1021/ja061911x Supporting Info

Importance of Direct Spin−Spin Coupling and Spin-Flip Excitations for the Zero-Field Splittings of Transition Metal Complexes:  A Case Study Frank Neese pp 10213–10222 DOI: 10.1021/ja061798a Supporting Info

MIL-96, a Porous Aluminum Trimesate 3D Structure Constructed from a Hexagonal Network of 18-Membered Rings and μ3-Oxo-Centered Trinuclear Units Thierry Loiseau, Ludovic Lecroq, Christophe Volkringer, Jérôme Marrot, Gérard Férey, Mohamed Haouas, Francis Taulelle, Sandrine Bourrelly, Philip L. Llewellyn, and Michel Latroche pp 10223–10230 DOI: 10.1021/ja0621086 Supporting Info

Synthesis and Photophysical Properties of Borondipyrromethene Dyes Bearing Aryl Substituents at the Boron Center Christine Goze, Gilles Ulrich, Laura J. Mallon, Ben D. Allen, Anthony Harriman, and Raymond Ziessel pp 10231–10239 DOI: 10.1021/ja062405a Supporting Info

Supramolecular Catalysis of Unimolecular Rearrangements:  Substrate Scope and Mechanistic Insights Dorothea Fiedler, Herman van Halbeek, Robert G. Bergman, and Kenneth N. Raymond pp 10240–10252 DOI: 10.1021/ja062329b Supporting Info

Controlling the Biological Effects of Spermine Using a Synthetic Receptor Laurent Vial, R. Frederick Ludlow, Julien Leclaire, Ruth Pérez-Fernández, and Sijbren Otto pp 10253–10257 DOI: 10.1021/ja062536b Supporting Info

A Simple γ-Backbone Modification Preorganizes Peptide Nucleic Acid into a Helical Structure Anca Dragulescu-Andrasi, Srinivas Rapireddy, Brian M. Frezza, Chakicherla Gayathri, Roberto R. Gil, and Danith H. Ly pp 10258–10267 DOI: 10.1021/ja0625576 Supporting Info

Theoretical Characterization of Cyclic Thiolated Gold Clusters Henrik Grönbeck, Michael Walter, and Hannu Häkkinen pp 10268–10275 DOI: 10.1021/ja062584w

Kinetically Controlled Catalytic Formation of Zinc Oxide Thin Films at Low Temperature David Kisailus, Birgit Schwenzer, John Gomm, James C. Weaver, and Daniel E. Morse pp 10276–10280 DOI: 10.1021/ja062434l

Shape-Specific Detection Based on Fluorescence Resonance Energy Transfer Using a Flexible Water-Soluble Conjugated Polymer Wei Lv, Na Li, Yuliang Li, Ye Li, and Andong Xia pp 10281–10287 DOI: 10.1021/ja063004y

Biocatalytic Synthesis of a Nanostructured and Crystalline Bimetallic Perovskite-like Barium Oxofluorotitanate at Low Temperature Richard L. Brutchey, Edward S. Yoo, and Daniel E. Morse pp 10288–10294 DOI: 10.1021/ja063107g Supporting Info

Comparison of Thermodynamic and Kinetic Aspects of Oxidative Addition of PhE−EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 Complexes. The Role of Oxidation State and Ancillary Ligands in Metal Complex Induced Chalcogenyl Radical Generation James E. McDonough, John J. Weir, Kengkaj Sukcharoenphon, Carl D. Hoff, Olga P. Kryatova, Elena V. Rybak-Akimova, Brian L. Scott, Gregory J. Kubas, Arjun Mendiratta, and Christopher C. Cummins pp 10295–10303 DOI: 10.1021/ja063250+ Supporting Info

Ultrastable Substrates for Surface-Enhanced Raman Spectroscopy:  Al2O3 Overlayers Fabricated by Atomic Layer Deposition Yield Improved Anthrax Biomarker Detection Xiaoyu Zhang, Jing Zhao, Alyson V. Whitney, Jeffrey W. Elam, and Richard P. Van Duyne pp 10304–10309 DOI: 10.1021/ja0638760

Formation of Nearly Monodisperse In2O3 Nanodots and Oriented-Attached Nanoflowers:  Hydrolysis and Alcoholysis vs Pyrolysis Arun Narayanaswamy, Huifang Xu, Narayan Pradhan, Myeongseob Kim, and Xiaogang Peng pp 10310–10319 DOI: 10.1021/ja0627601 Supporting Info

Spectroscopy and Electrochemistry of Cytochrome P450 BM3-Surfactant Film Assemblies Andrew K. Udit, Katharine D. Hagen, Peter J. Goldman, Andrew Star, James M. Gillan, Harry B. Gray, and Michael G. Hill pp 10320–10325 DOI: 10.1021/ja061896w Supporting Info

Lithium Diisopropylamide-Mediated Enolization:  Catalysis by Hemilabile Ligands Antonio Ramirez, Xiufeng Sun, and David B. Collum pp 10326–10336 DOI: 10.1021/ja062147h Supporting Info

Size-Dependent Extinction Coefficients of PbS Quantum Dots Ludovico Cademartiri, Erica Montanari, Gianluca Calestani, Andrea Migliori, Antonietta Guagliardi, and Geoffrey A. Ozin pp 10337–10346 DOI: 10.1021/ja063166u Supporting Info

Issue 32

Pressure-Induced Infiltration of Aqueous Solutions of Multiple Promoters in a Nanoporous Silica Aijie Han and Yu Qiao pp 10348–10349 DOI: 10.1021/ja062037a Supporting Info

Superoxo, Peroxo, and Hydroperoxo Complexes Formed from Reactions of Rhodium Porphyrins with Dioxygen:  Thermodynamics and Kinetics Weihong Cui and Bradford B. Wayland pp 10350–10351 DOI: 10.1021/ja0628755 Supporting Info

Au(I)-Catalyzed Annulation of Enantioenriched Allenes in the Enantioselective Total Synthesis of (−)-Rhazinilam Zuosheng Liu, Andrew S. Wasmuth, and Scott G. Nelson pp 10352–10353 DOI: 10.1021/ja0629110 Supporting Info

Enantioselective Organocatalytic Tandem Michael−Aldol Reactions:  One-Pot Synthesis of Chiral Thiochromenes Wei Wang, Hao Li, Jian Wang, and Liansuo Zu pp 10354–10355 DOI: 10.1021/ja063328m Supporting Info

Elucidating the Effect of Additives on the Growth and Stability of Cu2O Surfaces via Shape Transformation of Pre-Grown Crystals Matthew J. Siegfried and Kyoung-Shin Choi pp 10356–10357 DOI: 10.1021/ja063574y Supporting Info

Vanadium-Catalyzed Addition of Propargyl Alcohols and Imines Barry M. Trost and Cheol K. Chung pp 10358–10359 DOI: 10.1021/ja064011p Supporting Info

Enantioselective Carbolithiation Initiated Cascade Reactions Anne-Marie L. Hogan and Donal F. O'Shea pp 10360–10361 DOI: 10.1021/ja060076g Supporting Info

Isotope-Coded and Affinity-Tagged Cross-Linking (ICATXL):  An Efficient Strategy to Probe Protein Interaction Surfaces Feixia Chu, Sami Mahrus, Charles S. Craik, and Alma L. Burlingame pp 10362–10363 DOI: 10.1021/ja0614159 Supporting Info

Scrambling of Sequence Information in Collision-Induced Dissociation of Peptides Alex G. Harrison, Alex B. Young, Christian Bleiholder, Sándor Suhai, and Béla Paizs pp 10364–10365 DOI: 10.1021/ja062440h Supporting Info

What Nonlinear−IR Experiments Can Tell You about Water that the IR Spectrum Cannot Ivan R. Piletic, David E. Moilanen, Nancy E. Levinger, and M. D. Fayer pp 10366–10367 DOI: 10.1021/ja062549p Supporting Info

Molecular Mechanism for the Cross-Nucleation between Polymorphs Caroline Desgranges and Jerome Delhommelle pp 10368–10369 DOI: 10.1021/ja063218f Supporting Info

Strain-Release Rearrangement of N-Vinyl-2-Arylaziridines. Total Synthesis of the Anti-Leukemia Alkaloid (−)-Deoxyharringtonine Joseph D. Eckelbarger, Jeremy T. Wilmot, and David Y. Gin pp 10370–10371 DOI: 10.1021/ja063304f Supporting Info

The Dark Side of Crystal Engineering:  Creating Glasses from Small Symmetric Molecules that Form Multiple Hydrogen Bonds Olivier Lebel, Thierry Maris, Marie-Ève Perron, Eric Demers, and James D. Wuest pp 10372–10373 DOI: 10.1021/ja063353s Supporting Info

Demonstration by 2H ENDOR Spectroscopy that myo-Inositol Binds via an Alkoxide Bridge to the Mixed-Valent Diiron Center of myo-Inositol Oxygenase Sun Hee Kim, Gang Xing, J. Martin Bollinger, Jr., Carsten Krebs, and Brian M. Hoffman pp 10374–10375 DOI: 10.1021/ja063602c Supporting Info

Microencapsulated Linear Polymers:  “Soluble” Heterogeneous Catalysts Kristin E. Price, Brian P. Mason, Andrew R. Bogdan, Steven J. Broadwater, Jeremy L. Steinbacher, and D. Tyler McQuade pp 10376–10377 DOI: 10.1021/ja063688+ Supporting Info

Synthesis and Application of Quantum Dots FRET-Based Protease Sensors Lifang Shi, Vania De Paoli, Nitsa Rosenzweig, and Zeev Rosenzweig pp 10378–10379 DOI: 10.1021/ja063509o Supporting Info

Combinatorial Synthesis of Benzimidazolium Dyes and Its Diversity Directed Application toward GTP-Selective Fluorescent Chemosensors Shenliang Wang and Young-Tae Chang pp 10380–10381 DOI: 10.1021/ja063733d Supporting Info

Bridged Dihydroxypyridine Ligands for the Synthesis of Expanded Helicates Zacharias Grote, Simone Bonazzi, Rosario Scopelliti, and Kay Severin pp 10382–10383 DOI: 10.1021/ja0637806 Supporting Info

Room Temperature Liquid Fullerenes:  An Uncommon Morphology of C60 Derivatives Tsuyoshi Michinobu, Takashi Nakanishi, Jonathan P. Hill, Masahiro Funahashi, and Katsuhiko Ariga pp 10384–10385 DOI: 10.1021/ja063866z Supporting Info

The Bifunctional Glyceryl Transferase/Phosphatase OzmB Belonging to the HAD Superfamily That Diverts 1,3-Bisphosphoglycerate into Polyketide Biosynthesis Pieter C. Dorrestein, Steven G. Van Lanen, Wenli Li, Chunhua Zhao, Zixin Deng, Ben Shen, and Neil L. Kelleher pp 10386–10387 DOI: 10.1021/ja0639362 Supporting Info

Efficient Templated Synthesis of Donor−Acceptor Rotaxanes Using Click Chemistry William R. Dichtel, Ognjen Š. Miljanić, Jason M. Spruell, James R. Heath, and J. Fraser Stoddart pp 10388–10390 DOI: 10.1021/ja063127i Supporting Info

Experimental and Theoretical Studies of 45Sc NMR Interactions in Solids Aaron J. Rossini and Robert W. Schurko pp 10391–10402 DOI: 10.1021/ja060477w Supporting Info

Microporous Metal−Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks Brett D. Chandler, David T. Cramb, and George K. H. Shimizu pp 10403–10412 DOI: 10.1021/ja060666e Supporting Info

A Fluorescent Lectin Array Using Supramolecular Hydrogel for Simple Detection and Pattern Profiling for Various Glycoconjugates Yoichiro Koshi, Eiji Nakata, Hiroki Yamane, and Itaru Hamachi pp 10413–10422 DOI: 10.1021/ja0613963 Supporting Info

Ethyne-Bridged (Porphinato)Zinc(II)−(Porphinato)Iron(III) Complexes:  Phenomenological Dependence of Excited-State Dynamics upon (Porphinato)Iron Electronic Structure Timothy V. Duncan, Sophia P. Wu, and Michael J. Therien pp 10423–10435 DOI: 10.1021/ja061388m Supporting Info

Electronic Coupling and Exciton Energy Transfer in CdTe Quantum-Dot Molecules Rolf Koole, Peter Liljeroth, Celso de Mello Donegá, Daniël Vanmaekelbergh, and Andries Meijerink pp 10436–10441 DOI: 10.1021/ja061608w Supporting Info

Fe L-Edge XAS Studies of K4[Fe(CN)6] and K3[Fe(CN)6]:  A Direct Probe of Back-Bonding Rosalie K. Hocking, Erik C. Wasinger, Frank M. F. de Groot, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 10442–10451 DOI: 10.1021/ja061802i Supporting Info

Oligo-Asp Tag/Zn(II) Complex Probe as a New Pair for Labeling and Fluorescence Imaging of Proteins Akio Ojida, Kei Honda, Daisuke Shinmi, Shigeki Kiyonaka, Yasuo Mori, and Itaru Hamachi pp 10452–10459 DOI: 10.1021/ja0618604 Supporting Info

On the Origin of Helical Mesostructures Sui Yang, Lingzhi Zhao, Chengzhong Yu, Xufeng Zhou, Jiawei Tang, Pei Yuan, Daoyong Chen, and Dongyuan Zhao pp 10460–10466 DOI: 10.1021/ja0619049 Supporting Info

Conformational Flexibility in Hydrated Sugars:  the Glycolaldehyde−Water Complex Juan-Ramon Aviles-Moreno, Jean Demaison, and Thérèse R. Huet pp 10467–10473 DOI: 10.1021/ja062312t Supporting Info

Spectroscopic Determination of Proton Position in the Proton-Coupled Electron Transfer Pathways of Donor−Acceptor Supramolecule Assemblies Joel Rosenthal, Justin M. Hodgkiss, Elizabeth R. Young, and Daniel G. Nocera pp 10474–10483 DOI: 10.1021/ja062430g Supporting Info

Extreme Conformational Constraints in π-Extended Tetrathiafulvalenes:  Unusual Topologies and Redox Behavior of Doubly and Triply Bridged Cyclophanes Christian A. Christensen, Andrei S. Batsanov, and Martin R. Bryce pp 10484–10490 DOI: 10.1021/ja062358m Supporting Info

Total Synthesis and Structural Confirmation of Chlorodysinosin A Stephen Hanessian, Juan R. Del Valle, Yafeng Xue, and Niklas Blomberg pp 10491–10495 DOI: 10.1021/ja0625834 Supporting Info

Electron Self-Exchange between Au140+/0 Nanoparticles Is Faster Than That between Au38+/0 in Solid-State, Mixed-Valent Films Jai-Pil Choi and Royce W. Murray pp 10496–10502 DOI: 10.1021/ja062736n Supporting Info

Modulating Rhodopsin Receptor Activation by Altering the pKa of the Retinal Schiff Base Reiner Vogel, Friedrich Siebert, Elsa C. Y. Yan, Thomas P. Sakmar, Amiram Hirshfeld, and Mordechai Sheves pp 10503–10512 DOI: 10.1021/ja0627848

Rational Design of Bacitracin A Derivatives by Incorporating Natural Product Derived Heterocycles Björn Wagner, Dirk Schumann, Uwe Linne, Ulrich Koert, and Mohamed A. Marahiel pp 10513–10520 DOI: 10.1021/ja062906w Supporting Info

Development of an ab Initio Emulsion Atom Transfer Radical Polymerization:  From Microemulsion to Emulsion Ke Min, Haifeng Gao, and Krzysztof Matyjaszewski pp 10521–10526 DOI: 10.1021/ja0629054

Construction of Segregated Arrays of Multiple Donor and Acceptor Units Using a Dendritic Scaffold:  Remarkable Dendrimer Effects on Photoinduced Charge Separation Wei-Shi Li, Kil Suk Kim, Dong-Lin Jiang, Hiroyuki Tanaka, Tomoji Kawai, Jung Ho Kwon, Dongho Kim, and Takuzo Aida pp 10527–10532 DOI: 10.1021/ja063081t Supporting Info

Photochemical Reactivity of 2-Vinylbiphenyl and 2-Vinyl-1,3-terphenyl:  The Balance between Nonadiabatic and Adiabatic Photocyclization Martial Boggio-Pasqua, Michael J. Bearpark, François Ogliaro, and Michael A. Robb pp 10533–10540 DOI: 10.1021/ja062901z Supporting Info

Competition between Protein Ligands and Cytoplasmic Inorganic Anions for the Metal Cation:  A DFT/CDM Study Todor Dudev and Carmay Lim pp 10541–10548 DOI: 10.1021/ja063111s Supporting Info

Synthesis and Reactivity of the Imido Analogues of the Uranyl Ion Trevor W. Hayton, James M. Boncella, Brian L. Scott, Enrique R. Batista, and P. Jeffrey Hay pp 10549–10559 DOI: 10.1021/ja0629155 Supporting Info

Nanosphere and Nanonetwork Formations of [60]Fullerene-End-Capped Stereoregular Poly(methyl methacrylate)s through Stereocomplex Formation Combined with Self-Assembly of the Fullerenes Takehiro Kawauchi, Jiro Kumaki, and Eiji Yashima pp 10560–10567 DOI: 10.1021/ja063252u Supporting Info

Soluble Ultra-Short Single-Walled Carbon Nanotubes Zheyi Chen, Kazufumi Kobashi, Urs Rauwald, Richard Booker, Hua Fan, Wen-Fang Hwang, and James M. Tour pp 10568–10571 DOI: 10.1021/ja063283p Supporting Info

Toward the Development of a General Chiral Auxiliary. A Total Synthesis of (+)-Tetronolide via a Tandem Ketene-Trapping [4 + 2] Cycloaddition Strategy Robert K. Boeckman, Jr., Pengcheng Shao, Stephen T. Wrobleski, Debra J. Boehmler, Geoffrey R. Heintzelman, and Antonio. J. Barbosa pp 10572–10588 DOI: 10.1021/ja0581346 Supporting Info

Intramolecular Diels−Alder/1,3-Dipolar Cycloaddition Cascade of 1,3,4-Oxadiazoles Gregory I. Elliott, James R. Fuchs, Brian S. J. Blagg, Hayato Ishikawa, Houchao Tao, Z.-Q. Yuan, and Dale L. Boger pp 10589–10595 DOI: 10.1021/ja0612549 Supporting Info

Total Synthesis of (−)- and ent-(+)-Vindoline and Related Alkaloids Hayato Ishikawa, Gregory I. Elliott, Juraj Velcicky, Younggi Choi, and Dale L. Boger pp 10596–10612 DOI: 10.1021/ja061256t Supporting Info

Gold Metal-Catalyzed Reactions of Isocyanides with Primary Amines and Oxygen:  Analogies with Reactions of Isocyanides in Transition Metal Complexes Mihaela Lazar and Robert J. Angelici pp 10613–10620 DOI: 10.1021/ja0618907 Supporting Info

Cooperative Hydration of Pyruvic Acid in Ice Marcelo I. Guzmán, Lea Hildebrandt, Agustín J. Colussi, and Michael R. Hoffmann pp 10621–10624 DOI: 10.1021/ja062039v Supporting Info

A Binary DNA Probe for Highly Specific Nucleic Acid Recognition Dmitry M. Kolpashchikov pp 10625–10628 DOI: 10.1021/ja0628093

Rhodium-Catalyzed Cycloisomerization of N-Propargyl Enamine Derivatives [J. Am. Chem. Soc. 2006, 128, 6336−6337]. Hahn Kim and Chulbom Lee p 10629 DOI: 10.1021/ja063381a Supporting Info

Surfactant-Induced Modulation of Fluorosensor Activity:  A Simple Way to Maximize the Sensor Efficiency [J. Am. Chem. Soc. 2006, 128, 3126−3127]. Arabinda Mallick, Malay C. Mandal, Basudeb Haldar, Alok Chakrabarty, Paramita Das, and Nitin Chattopadhyay p 10629 DOI: 10.1021/ja064646o

Activated Carbon Adsorption By Roop Chand Bansal and Meenakshi Goyal (Panjab University, Chandigarh, India). CRC Press (an imprint of Taylor and Francis Group):  Boca Raton, FL. 2005. xxii + 498 pp. $189.95. ISBN 0-8247-5344-5. Douglas K. Ludlow p 10630 DOI: 10.1021/ja059874h

Nuclear Spin Relaxation in Liquids:  Theory, Experiments, and Applications By Jozef Kowalewski and Lena Mäler (Stockholm University, Sweden). from the Series in Chemical Physics. Edited by J. H. Moore and N. D. Spencer. CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2006. xii + 426 pp. $129.95. ISBN 0-7503-0964-4. Cecil Dybowski pp 10630–10631 DOI: 10.1021/ja069760l

Isotope Effects in Chemistry and Biology Edited by Amnon Kohen (University of Iowa) and Hans-Heinrich Limbach (Freie Universität Berlin). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. xiv + 1074 pp. $229.95. ISBN 0-9247-2449-6. W. Phillip Huskey p 10631 DOI: 10.1021/ja069717y

The Jahn−Teller Effect By Isaac B. Bersuker (University of Texas at Austin). Cambridge University Press:  Cambridge. 2006. xvi + 616 pp. $185.00. ISBN 0-521-82212-2. Michael D. Kaplan pp 10631–10632 DOI: 10.1021/ja069734n

Molecular Machines. Topics in Current Chemistry, 262 Edited by T. Ross Kelly (Boston College). Springer:  Berlin, Heidelberg, New York. 2005. xii + 236 pp. $229.00. ISBN 3-540-28501-6. Stefan H. Bossmann pp 10632–10633 DOI: 10.1021/ja069730i

Enzyme-Catalyzed Synthesis of Polymers. Advances in Polymer Science, 194 Edited by Shiro Kobayashi (Kyoto Institute of Technology, Japan), Helmut Ritter (Heinrich Heine University, Dusseldorf, Germany), and David Kaplan (Tufts University, Medford, MA). Springer:  Berlin, Heidelberg, New York. 2006. xii + 256 pp. $239.00. ISBN 3-540-29212-8. Jonathan S. Dordick p 10633 DOI: 10.1021/ja069728r

Layered Double Hydroxides. Structure & Bonding, 119 Edited by Xue Duan and David G. Evans (Beijing University of Chemical Technology). Series. Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2006. xii + 234 pp. $219. ISBN 3-540-28279-3. Elizabeth Gardner pp 10633–10634 DOI: 10.1021/ja069733v

Issue 33

An Ordered Mesoporous Aluminosilicate with Completely Crystalline Zeolite Wall Structure Yunming Fang and Haoquan Hu pp 10636–10637 DOI: 10.1021/ja061182l Supporting Info

Glycosylated Foldamers To Probe the Carbohydrate−Carbohydrate Interaction Graham L. Simpson, Andrew H. Gordon, David M. Lindsay, Netnepa Promsawan, Matthew P. Crump, Keith Mulholland, Barry R. Hayter, and Timothy Gallagher pp 10638–10639 DOI: 10.1021/ja0614565 Supporting Info

Mechanism-Based Molecular Design of Highly Selective Fluorescence Probes for Nitrative Stress Tasuku Ueno, Yasuteru Urano, Hirotatsu Kojima, and Tetsuo Nagano pp 10640–10641 DOI: 10.1021/ja061972v Supporting Info

Propagation of Conformation in the Surface-Aligned Dissociation of Single CH3SSCH3 Molecules on Au(111) Peter Maksymovych and John T. Yates Jr. pp 10642–10643 DOI: 10.1021/ja062006f

d8 Rhodium and Iridium Complexes of Corannulene Jay S. Siegel, Kim K. Baldridge, Anthony Linden, and Reto Dorta pp 10644–10645 DOI: 10.1021/ja062110x Supporting Info

A Single CH/π Weak Hydrogen Bond Governs Stability and the Photocycle of the Photoactive Yellow Protein Miki Harigai, Mikio Kataoka, and Yasushi Imamoto pp 10646–10647 DOI: 10.1021/ja062125v Supporting Info

“Cymothoe sangaris”:  An Extremely Stable and Highly Luminescent 1,2-Hydroxypyridinonate Chelate of Eu(III) Evan G. Moore, Jide Xu, Christoph J. Jocher, Eric J. Werner, and Kenneth N. Raymond pp 10648–10649 DOI: 10.1021/ja062597+ Supporting Info

Cyclic Peptide Helices:  A Hybrid β-Hairpin/β-Helical Supersecondary Structure Mallika Sastry, Christopher Brown, Gerhard Wagner, and Thomas D. Clark pp 10650–10651 DOI: 10.1021/ja062737f Supporting Info

Cold Denaturation of Encapsulated Ubiquitin Maxim S. Pometun, Ronald W. Peterson, Charles R. Babu, and A. Joshua Wand pp 10652–10653 DOI: 10.1021/ja0628654

Detection of Peptide−Phospholipid Interaction Sites in Bilayer Membranes by 13C NMR Spectroscopy:  Observation of 2H/31P-Selective 1H-Depolarization under Magic-Angle Spinning Erisa Harada, Yasuto Todokoro, Hideo Akutsu, and Toshimichi Fujiwara pp 10654–10655 DOI: 10.1021/ja062811u Supporting Info

Contrasting Solvent and Capping Ligand Effects Directing the Photochemistry of Uranyl(VI) Schiff Base Complexes Anthony E. Vaughn, Daniel B. Bassil, Charles L. Barnes, Sheryl A. Tucker, and Paul B. Duval pp 10656–10657 DOI: 10.1021/ja062735v Supporting Info

Ni/NiO Core/Shell Nanoparticles for Selective Binding and Magnetic Separation of Histidine-Tagged Proteins In Su Lee, Nohyun Lee, Jongnam Park, Byung Hyo Kim, Yong-Weon Yi, Taeuk Kim, Tae Kook Kim, In Hwan Lee, Seung R. Paik, and Taeghwan Hyeon pp 10658–10659 DOI: 10.1021/ja063177n Supporting Info

A Biosynthetic Gene Cluster for the Acetyl-CoA Carboxylase Inhibitor Andrimid Mi Jin, Michael A. Fischbach, and Jon Clardy pp 10660–10661 DOI: 10.1021/ja063194c Supporting Info

Synthesis of Imidazoles through the Copper-Catalyzed Cross-Cycloaddition between Two Different Isocyanides Chikashi Kanazawa, Shin Kamijo, and Yoshinori Yamamoto pp 10662–10663 DOI: 10.1021/ja0617439 Supporting Info

Gold-Catalyzed Intramolecular Allylation of Silyl Alkynes Induced by Silane Alcoholysis Sangho Park and Daesung Lee pp 10664–10665 DOI: 10.1021/ja062560p Supporting Info

N-Benzyl-2,3-oxazolidinone as a Glycosyl Donor for Selective α-Glycosylation and One-Pot Oligosaccharide Synthesis Involving 1,2-cis-Glycosylation Shino Manabe, Kazuyuki Ishii, and Yukishige Ito pp 10666–10667 DOI: 10.1021/ja062531e Supporting Info

Visible Light-Driven Water Oxidation by Ir Oxide Clusters Coupled to Single Cr Centers in Mesoporous Silica Ryuhei Nakamura and Heinz Frei pp 10668–10669 DOI: 10.1021/ja0625632 Supporting Info

Benzyl (Phenyl) γ- and δ-lactones via Photoinduced Tandem Ar−C, C−O Bond Formation Stefano Protti, Maurizio Fagnoni, and Angelo Albini pp 10670–10671 DOI: 10.1021/ja0627287 Supporting Info

Rieske Protein from Thermus thermophilus:  15N NMR Titration Study Demonstrates the Role of Iron-Ligated Histidines in the pH Dependence of the Reduction Potential I-Jin Lin, Ying Chen, James A. Fee, Jikui Song, William M. Westler, and John L. Markley pp 10672–10673 DOI: 10.1021/ja0627388 Supporting Info

Highly Enantioselective Reductive Cyclization of Acetylenic Aldehydes via Rhodium Catalyzed Asymmetric Hydrogenation Jong Uk Rhee and Michael J. Krische pp 10674–10675 DOI: 10.1021/ja0637954 Supporting Info

Synthesis and Stabilization of Monodisperse Fe Nanoparticles Sheng Peng, Chao Wang, Jin Xie, and Shouheng Sun pp 10676–10677 DOI: 10.1021/ja063969h Supporting Info

The Interaction of Water with MOF-5 Simulated by Molecular Dynamics Jeffery A. Greathouse and Mark D. Allendorf pp 10678–10679 DOI: 10.1021/ja063506b Supporting Info

Photoinduced Charge-Transfer States in Subphthalocyanine−Ferrocene Dyads David González-Rodríguez, Tomás Torres, Marilyn M. Olmstead, José Rivera, Maria Ángeles Herranz, Luis Echegoyen, Carmen Atienza Castellanos, and Dirk M. Guldi pp 10680–10681 DOI: 10.1021/ja0632409 Supporting Info

Observation of Intramolecular Paramagnetic T1 Spin Decoupling in the 13C NMR Spectra of Triazacyclohexane Complexes of Ni(II) Randolf D. Köhn, Matthias Haufe, and Gabriele Kociok-Köhn pp 10682–10683 DOI: 10.1021/ja063357x Supporting Info

Stochastic Detection of Enantiomers Xiao-feng Kang, Stephen Cheley, Xiyun Guan, and Hagan Bayley pp 10684–10685 DOI: 10.1021/ja063485l Supporting Info

Selective Sensing of Metalloproteins from Nonselective Binding Using a Fluorogenic Amphiphilic Polymer Britto S. Sandanaraj, Robert Demont, Sivakumar V. Aathimanikandan, Elamprakash N. Savariar, and S. Thayumanavan pp 10686–10687 DOI: 10.1021/ja063544v Supporting Info

Water-Soluble Through-Bond Energy Transfer Cassettes for Intracellular Imaging Rakeshwar Bandichhor, Anca D. Petrescu, Aude Vespa, Ann B. Kier, Friedhelm Schroeder, and Kevin Burgess pp 10688–10689 DOI: 10.1021/ja063784a Supporting Info

Sensing of Chiral Fullerenes by a Cyclic Host with an Asymmetrically Distorted π-Electronic Component Yoshiaki Shoji, Kentaro Tashiro, and Takuzo Aida pp 10690–10691 DOI: 10.1021/ja063828f Supporting Info

Clamshell Structure of Sc(biphenyl) from High Resolution Photoelectron Spectroscopy Bradford R. Sohnlein, Jason F. Fuller, and Dong-Sheng Yang pp 10692–10693 DOI: 10.1021/ja0638253 Supporting Info

The Selective Reaction of Aryl Halides with KOH:  Synthesis of Phenols, Aromatic Ethers, and Benzofurans Kevin W. Anderson, Takashi Ikawa, Rachel E. Tundel, and Stephen L. Buchwald pp 10694–10695 DOI: 10.1021/ja0639719 Supporting Info

N−C Bond Formation Promoted by a Hafnocene Dinitrogen Complex:  Comparison of Zirconium and Hafnium Congeners Wesley H. Bernskoetter, Andrea V. Olmos, Jaime A. Pool, Emil Lobkovsky, and Paul J. Chirik pp 10696–10697 DOI: 10.1021/ja064163k Supporting Info

Characterization of the Cereulide NRPS α-Hydroxy Acid Specifying Modules:  Activation of α-Keto Acids and Chiral Reduction on the Assembly Line Nathan A. Magarvey, Monika Ehling-Schulz, and Christopher T. Walsh pp 10698–10699 DOI: 10.1021/ja0640187 Supporting Info

Transferring Self-Assembled, Nanoscale Cables into Electrical Devices Shengxiong Xiao, Jinyao Tang, Tobias Beetz, Xuefeng Guo, Noah Tremblay, Theo Siegrist, Yimei Zhu, Michael Steigerwald, and Colin Nuckolls pp 10700–10701 DOI: 10.1021/ja0642360 Supporting Info

Can Ring Strain Be Realized in Momentum Space? P. Balanarayan and Shridhar R. Gadre pp 10702–10706 DOI: 10.1021/ja056883h Supporting Info

Supramolecular Self-Assembly of Dendronized Polymers:  Reversible Control of the Polymer Architectures through Acid−Base Reactions Ken C.-F. Leung, Paula M. Mendes, Sergei N. Magonov, Brian H. Northrop, Sangcheol Kim, Kaushik Patel, Amar H. Flood, Hsian-Rong Tseng, and J. Fraser Stoddart pp 10707–10715 DOI: 10.1021/ja058151v Supporting Info

Simultaneous Interaction with Base and Phosphate Moieties Modulates the Phosphodiester Cleavage of Dinucleoside 3‘,5‘-Monophosphates by Dinuclear Zn2+ Complexes of Di(azacrown) Ligands Qi Wang and Harri Lönnberg pp 10716–10728 DOI: 10.1021/ja058806s

19F NMR Studies of the Native and Denatured States of Green Fluorescent Protein Farid Khan, Ilya Kuprov, Timothy D. Craggs, P. J. Hore, and Sophie E. Jackson pp 10729–10737 DOI: 10.1021/ja060618u Supporting Info

Nucleophilic Substitution at Phosphorus (SN2@P):  Disappearance and Reappearance of Reaction Barriers Marc A. van Bochove, Marcel Swart, and F. Matthias Bickelhaupt pp 10738–10744 DOI: 10.1021/ja0606529 Supporting Info

A Porous Framework Polymer Based on a Zinc(II) 4,4‘-Bipyridine-2,6,2‘,6‘-tetracarboxylate:  Synthesis, Structure, and “Zeolite-Like” Behaviors Xiang Lin, Alexander J. Blake, Claire Wilson, Xue Zhong Sun, Neil R. Champness, Michael W. George, Peter Hubberstey, Robert Mokaya, and Martin Schröder pp 10745–10753 DOI: 10.1021/ja060946u Supporting Info

Ratiometric Fluorescent Sensor Proteins with Subnanomolar Affinity for Zn(II) Based on Copper Chaperone Domains Elisabeth M. W. M. van Dongen, Linda M. Dekkers, Kristie Spijker, E. W. Meijer, Leo W. J. Klomp, and Maarten Merkx pp 10754–10762 DOI: 10.1021/ja0610030 Supporting Info

Cationic Oligonucleotide−Peptide Conjugates with Aggregating Properties Enter Efficiently into Cells while Maintaining Hybridization Properties and Enzymatic Recognition Andrew W. Fraley, Bénédicte Pons, Deniz Dalkara, Gérard Nullans, Jean-Paul Behr, and Guy Zuber pp 10763–10771 DOI: 10.1021/ja060873e Supporting Info

A Combined Experimental and Theoretical Study of the Kinetics and Mechanism of the Addition of Alcohols to Electronically Stabilized Silenes:  A New Mechanism for the Addition of Alcohols to the SiC Bond William J. Leigh, Thomas R. Owens, Michael Bendikov, Sanjio S. Zade, and Yitzhak Apeloig pp 10772–10783 DOI: 10.1021/ja0613557 Supporting Info

A Fluoro Analogue of the Menadione Derivative 6-[2‘-(3‘-Methyl)-1‘,4‘-naphthoquinolyl]hexanoic Acid Is a Suicide Substrate of Glutathione Reductase. Crystal Structure of the Alkylated Human Enzyme Holger Bauer, Karin Fritz-Wolf, Andreas Winzer, Sebastian Kühner, Susan Little, Vanessa Yardley, Hervé Vezin, Bruce Palfey, R. Heiner Schirmer, and Elisabeth Davioud-Charvet pp 10784–10794 DOI: 10.1021/ja061155v Supporting Info

Oxidative Damage to DNA:  Counterion-Assisted Addition of Water to Ionized DNA Robert N. Barnett, Angelo Bongiorno, Charles L. Cleveland, Abraham Joy, Uzi Landman, and Gary B. Schuster pp 10795–10800 DOI: 10.1021/ja061795y Supporting Info

Physical Controls on Directed Virus Assembly at Nanoscale Chemical Templates Chin Li Cheung, Sung-Wook Chung, Anju Chatterji, Tianwei Lin, John E. Johnson, Saphon Hok, Julie Perkins, and James J. De Yoreo pp 10801–10807 DOI: 10.1021/ja0616884 Supporting Info

Color Tuning in Rhodopsins:  The Mechanism for the Spectral Shift between Bacteriorhodopsin and Sensory Rhodopsin II Michael Hoffmann, Marius Wanko, Paul Strodel, Peter H. König, Thomas Frauenheim, Klaus Schulten, Walter Thiel, Emad Tajkhorshid, and Marcus Elstner pp 10808–10818 DOI: 10.1021/ja062082i Supporting Info

Electrochemical, Spectroelectrochemical, and Molecular Quadratic and Cubic Nonlinear Optical Properties of Alkynylruthenium Dendrimers1 Marie P. Cifuentes, Clem E. Powell, Joseph P. Morrall, Andrew M. McDonagh, Nigel T. Lucas, Mark G. Humphrey, Marek Samoc, Stephan Houbrechts, Inge Asselberghs, Koen Clays, André Persoons, and Takashi Isoshima pp 10819–10832 DOI: 10.1021/ja062246v

Chirally Directed Formation of Nanometer-Scale Proline Clusters Sunnie Myung, Marco Fioroni, Ryan R. Julian, Stormy L. Koeniger, Mu-Hyun Baik, and David E. Clemmer pp 10833–10839 DOI: 10.1021/ja0622711 Supporting Info

Dynamic Nuclear Polarization of Amyloidogenic Peptide Nanocrystals:  GNNQQNY, a Core Segment of the Yeast Prion Protein Sup35p Patrick C. A. van der Wel, Kan-Nian Hu, Józef Lewandowski, and Robert G. Griffin pp 10840–10846 DOI: 10.1021/ja0626685 Supporting Info

Crystal Structure of Homo-DNA and Nature's Choice of Pentose over Hexose in the Genetic System Martin Egli, Pradeep S. Pallan, Rekha Pattanayek, Christopher J. Wilds, Paolo Lubini, George Minasov, Max Dobler, Christian J. Leumann, and Albert Eschenmoser pp 10847–10856 DOI: 10.1021/ja062548x Supporting Info

Structural Features of the Modulated BiCu2(P1-xVx)O6 Solid Solution; 4-D Treatment of x = 0.87 Compound and Magnetic Spin-Gap to Gapless Transition in New Cu2+ Two-Leg Ladder Systems Olivier Mentré, El Mostafa Ketatni, Marie Colmont, Marielle Huvé, Francis Abraham, and Vaclav Petricek pp 10857–10867 DOI: 10.1021/ja0631091 Supporting Info

Rapid Energy Transfer in Cascade-Type Bodipy Dyes Anthony Harriman, Guillaume Izzet, and Raymond Ziessel pp 10868–10875 DOI: 10.1021/ja0631448 Supporting Info

Molecular Dynamics Simulations on the Escherichia coli Ammonia Channel Protein AmtB:  Mechanism of Ammonia/Ammonium Transport Yuchun Lin, Zexing Cao, and Yirong Mo pp 10876–10884 DOI: 10.1021/ja0631549 Supporting Info

Triphenylene Analogues with B2N2C2 Cores:  Synthesis, Structure, Redox Behavior, and Photophysical Properties Cory A. Jaska, David J. H. Emslie, Michael J. D. Bosdet, Warren E. Piers, Ted S. Sorensen, and Masood Parvez pp 10885–10896 DOI: 10.1021/ja063519p Supporting Info

Microwave-Assisted Self-Organization of Colloidal Particles in Confining Aqueous Droplets Shin-Hyun Kim, Su Yeon Lee, Gi-Ra Yi, David J. Pine, and Seung-Man Yang pp 10897–10904 DOI: 10.1021/ja063528y Supporting Info

Localized Surface Plasmon Resonance Spectroscopy near Molecular Resonances Amanda J. Haes, Shengli Zou, Jing Zhao, George C. Schatz, and Richard P. Van Duyne pp 10905–10914 DOI: 10.1021/ja063575q

Reversal of Stability on Metalation of Pentagonal-Bipyramidal (1-MB6H72-, 1-M-2-CB5H71-, and 1-M-2,4-C2B4H7) and Icosahedral (1-MB11H122-, 1-M-2-CB10H121-, and 1-M-2,4-C2B9H12) Boranes (M = Al, Ga, In, and Tl): Energetics of Condensation and Relationship to Binuclear Metallocenes Biswarup Pathak, Shanthi Pandian, Narayan Hosmane, and Eluvathingal D. Jemmis pp 10915–10922 DOI: 10.1021/ja061399f Supporting Info

Creation of a Broad-Range and Highly Stereoselective d-Amino Acid Dehydrogenase for the One-Step Synthesis of d-Amino Acids Kavitha Vedha-Peters, Manjula Gunawardana, J. David Rozzell, and Scott J. Novick pp 10923–10929 DOI: 10.1021/ja0603960 Supporting Info

Palladium-Catalyzed C−H Homocoupling of Bromothiophene Derivatives and Synthetic Application to Well-Defined Oligothiophenes Masabumi Takahashi, Kentaro Masui, Hiroki Sekiguchi, Nobuhiko Kobayashi, Atsunori Mori, Masahiro Funahashi, and Nobuyuki Tamaoki pp 10930–10933 DOI: 10.1021/ja060749v Supporting Info

Photoinduced Reductive Repair of Thymine Glycol:  Implications for Excess Electron Transfer through DNA Containing Modified Bases Takeo Ito, Akiko Kondo, Satoru Terada, and Sei-ichi Nishimoto pp 10934–10942 DOI: 10.1021/ja061304+ Supporting Info

Dynamic Thermodynamic and Dynamic Kinetic Resolution of 2-Lithiopyrrolidines Iain Coldham, Samuel Dufour, Thomas F. N. Haxell, Jignesh J. Patel, and Graciela Sanchez-Jimenez pp 10943–10951 DOI: 10.1021/ja061963m Supporting Info

Dynamic Properties of Metallocenium Ion Pairs in Solution by Atomistic Simulations Andrea Correa and Luigi Cavallo pp 10952–10959 DOI: 10.1021/ja062407v Supporting Info

Site-Specific Nucleation and Growth Kinetics in Hierarchical Nanosyntheses of Branched ZnO Crystallites Tierui Zhang, Wenjun Dong, Mary Keeter-Brewer, Sanjit Konar, Roland N. Njabon, and Z. Ryan Tian pp 10960–10968 DOI: 10.1021/ja0631596

Synthesis and Characterization of the Octahydrotriborate Complexes Cp*V(B3H8)2 and Cp*Cr(B3H8)2 and the Unusual Cobaltaborane Cluster Cp*2Co2(B6H14) Do Young Kim and Gregory S. Girolami pp 10969–10977 DOI: 10.1021/ja063285+ Supporting Info

Photocontrolled Magnetization of CdS-Modified Prussian Blue Nanoparticles Minori Taguchi, Ichizo Yagi, Masaru Nakagawa, Tomokazu Iyoda, and Yasuaki Einaga pp 10978–10982 DOI: 10.1021/ja063461e Supporting Info

Issue 34

Tuning Interactions between Ligands in Self-Assembled Double-Decker Phthalocyanine Arrays Tao Ye, Tomohide Takami, Rongming Wang, Jianzhuang Jiang, and Paul S. Weiss pp 10984–10985 DOI: 10.1021/ja060029o Supporting Info

Schiff Base Route to Stackable Pseudo-Triphenylenes:  Stereoelectronic Control of Assembly and Luminescence Justin A. Riddle, Stephen P. Lathrop, John C. Bollinger, and Dongwhan Lee pp 10986–10987 DOI: 10.1021/ja061307m Supporting Info

Ultrafast Energy Migration in Chromophore Shell−Metal Nanoparticle Assemblies Oleg P. Varnavski, Mahinda Ranasinghe, Xingzhong Yan, Christina A. Bauer, Sung-Jae Chung, Joseph W. Perry, Seth R. Marder, and Theodore Goodson, III pp 10988–10989 DOI: 10.1021/ja061378l Supporting Info

Simultaneous Two-Photon Excited Fluorescence and One-Photon Excited Phosphorescence from Single Molecules of an Organometallic Complex Ir(ppy)3 Yohei Koide, Susumu Takahashi, and Martin Vacha pp 10990–10991 DOI: 10.1021/ja0616635 Supporting Info

Doubly Ortho-Linked Quinoxaline/Diphenylfluorene Hybrids as Bipolar, Fluorescent Chameleons for Optoelectronic Applications Chien-Tien Chen, Yi Wei, Jin-Sheng Lin, Murthy V. R. K. Moturu, Wei-San Chao, Yu-Tai Tao, and Chin-Hsiung Chien pp 10992–10993 DOI: 10.1021/ja062660v Supporting Info

Mechanism of the Chiral SHG Activity of Bacteriorhodopsin Films Ronald D. Wampler, Mingkang Zhou, David H. Thompson, and Garth J. Simpson pp 10994–10995 DOI: 10.1021/ja062671o Supporting Info

Bisoxazolidine-Catalyzed Enantioselective Alkynylation of Aldehydes Christian Wolf and Shuanglong Liu pp 10996–10997 DOI: 10.1021/ja062711o Supporting Info

Microbial Evasion of the Immune System:  Structural Modifications of Enterobactin Impair Siderocalin Recognition1 Rebecca J. Abergel, Evan G. Moore, Roland K. Strong, and Kenneth N. Raymond pp 10998–10999 DOI: 10.1021/ja062476+ Supporting Info

Crystallographic Analysis of an 8-mer p53 Peptide Analogue Complexed with MDM2 Kaori Sakurai, Carsten Schubert, and Daniel Kahne pp 11000–11001 DOI: 10.1021/ja063102j Supporting Info

Localized Protein Interaction Surfaces on the EntB Carrier Protein Revealed by Combinatorial Mutagenesis and Selection Jonathan R. Lai, Michael A. Fischbach, David R. Liu, and Christopher T. Walsh pp 11002–11003 DOI: 10.1021/ja063238h Supporting Info

Resonance Surface Plasmon Spectroscopy:  Low Molecular Weight Substrate Binding to Cytochrome P450 Jing Zhao, Aditi Das, Xiaoyu Zhang, George C. Schatz, Stephen G. Sligar, and Richard P. Van Duyne pp 11004–11005 DOI: 10.1021/ja0636082 Supporting Info

Chirality of Silver Nanoparticles Synthesized on DNA Gabriel Shemer, Olga Krichevski, Gil Markovich, Tatiana Molotsky, Irit Lubitz, and Alexander B. Kotlyar pp 11006–11007 DOI: 10.1021/ja063702i

Encapsulation of Single Enzyme in Nanogel with Enhanced Biocatalytic Activity and Stability Ming Yan, Jun Ge, Zheng Liu, and Pingkai Ouyang pp 11008–11009 DOI: 10.1021/ja064126t Supporting Info

Photoinduced Alignment of Nanocylinders by Supramolecular Cooperative Motions Haifeng Yu, Tomokazu Iyoda, and Tomiki Ikeda pp 11010–11011 DOI: 10.1021/ja064148f Supporting Info

Rapid Long-Distance Hole Transfer through Consecutive Adenine Sequence Tadao Takada, Kiyohiko Kawai, Mamoru Fujitsuka, and Tetsuro Majima pp 11012–11013 DOI: 10.1021/ja0641554

In Situ Hydrogenation of Terminal Halogen in Poly(methyl methacrylate) by Ruthenium-Catalyzed Living Radical Polymerization:  Direct Transformation of “Polymerization Catalyst” into “Hydrogenation Catalyst” Takaya Terashima, Makoto Ouchi, Tsuyoshi Ando, and Mitsuo Sawamoto pp 11014–11015 DOI: 10.1021/ja0641507 Supporting Info

Low-Temperature Solution Route to Macroscopic Amounts of Hydrogen Terminated Silicon Nanoparticles Doinita Neiner, Hsiang Wei Chiu, and Susan M. Kauzlarich pp 11016–11017 DOI: 10.1021/ja064177q Supporting Info

Nanometer-Thick Conformal Pore Sealing of Self-Assembled Mesoporous Silica by Plasma-Assisted Atomic Layer Deposition Ying-Bing Jiang, Nanguo Liu, Henry Gerung, Joseph L. Cecchi, and C. Jeffrey Brinker pp 11018–11019 DOI: 10.1021/ja061097d Supporting Info

Electrocatalytic Oxidation of Tyrosine by Parallel Rate-Limiting Proton Transfer and Multisite Electron−Proton Transfer Christine J. Fecenko, Thomas J. Meyer, and H. Holden Thorp pp 11020–11021 DOI: 10.1021/ja061931z Supporting Info

Synthesis of Taiwaniaquinoids via Nazarov Triflation Guangxin Liang, Yue Xu, Ian B. Seiple, and Dirk Trauner pp 11022–11023 DOI: 10.1021/ja062505g Supporting Info

Structural−Mechanical Phase Diagram of Isotactic Polypropylene Claudio De Rosa and Finizia Auriemma pp 11024–11025 DOI: 10.1021/ja063464r Supporting Info

New Insight into Reactions of Ni(S2C2(CF3)2)2 with Simple Alkenes:  Alkene Adduct versus Dihydrodithiin Product Selectivity Is Controlled by [Ni(S2C2(CF3)2)2]- Anion Daniel J. Harrison, Neilson Nguyen, Alan J. Lough, and Ulrich Fekl pp 11026–11027 DOI: 10.1021/ja063030w Supporting Info

Does Substrate Oxidation Determine the Regioselectivity of Cyclohexene and Propene Oxidation by Cytochrome P450? Shimrit Cohen, Sebastian Kozuch, Carina Hazan, and Sason Shaik pp 11028–11029 DOI: 10.1021/ja063269c Supporting Info

Unique Contrast Patterns from Resonance-Enhanced Chiral SHG of Cell Membranes Ping Yan, Andrew C. Millard, Meide Wei, and Leslie M. Loew pp 11030–11031 DOI: 10.1021/ja0635534 Supporting Info

Toward the Development of a General Chiral Auxiliary. Enantioselective Alkylation and a New Catalytic Asymmetric Addition of Silyloxyfurans:  Application to a Total Synthesis of (−)-Rasfonin Robert K. Boeckman, Jr., Joseph E. Pero, and Debra J. Boehmler pp 11032–11033 DOI: 10.1021/ja063532+ Supporting Info

Enantioselective Scandium-Catalyzed Vinylsilane Additions:  A New Approach to the Synthesis of Enantiopure β,γ-Unsaturated α-Hydroxy Acid Derivatives David A. Evans and Yimon Aye pp 11034–11035 DOI: 10.1021/ja063878k Supporting Info

Catalytic Diboration of Aldehydes via Insertion into the Copper−Boron Bond David S. Laitar, Emily Y. Tsui, and Joseph P. Sadighi pp 11036–11037 DOI: 10.1021/ja064019z Supporting Info

Enantioselective Transfer Aminoallylation:  Synthesis of Optically Active Homoallylic Primary Amines Masaharu Sugiura, Chieko Mori, and Shū Kobayashi pp 11038–11039 DOI: 10.1021/ja064106r Supporting Info

CO2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone Hiroto Yoshida, Hiroyuki Fukushima, Joji Ohshita, and Atsutaka Kunai pp 11040–11041 DOI: 10.1021/ja064157o Supporting Info

Colloids Seeded Deposition:  Growth of Titania Nanotubes in Solution Lin Yue, Wei Gao, Danyu Zhang, Xuefeng Guo, Weiping Ding, and Yi Chen pp 11042–11043 DOI: 10.1021/ja064198k Supporting Info

Chromene Chromium Carbene Complexes in the Syntheses of Naphthopyran and Naphthopyrandione Units Present in Photochromic Materials and Biologically Active Natural Products Manish Rawat, Victor Prutyanov, and William D. Wulff pp 11044–11053 DOI: 10.1021/ja0568852 Supporting Info

Semiconductor Surface-Induced 1,3-Hydrogen Shift:  The Role of Covalent vs Zwitterionic Character Michael P. Schwartz, Daniel E. Barlow, John N. Russell, Jr., Kevin P. Weidkamp, James E. Butler, Mark P. D'Evelyn, and Robert J. Hamers pp 11054–11061 DOI: 10.1021/ja060598w

Self-Assembled FePt Nanocrystals with Large Coercivity:  Reduction of the fcc-to-L10 Ordering Temperature Laudemir Carlos Varanda and Miguel Jafelicci, Jr. pp 11062–11066 DOI: 10.1021/ja060711i

Solid-State 2H NMR Structure of Retinal in Metarhodopsin I Gilmar F. J. Salgado, Andrey V. Struts, Katsunori Tanaka, Sonja Krane, Koji Nakanishi, and Michael F. Brown pp 11067–11071 DOI: 10.1021/ja058738+ Supporting Info

Protein Backbone Dynamics through 13C‘−13Cα Cross-Relaxation in NMR Spectroscopy Fabien Ferrage, Philippe Pelupessy, David Cowburn, and Geoffrey Bodenhausen pp 11072–11078 DOI: 10.1021/ja0600577 Supporting Info

Chiral N-Isobutyryl-cysteine Protected Gold Nanoparticles:  Preparation, Size Selection, and Optical Activity in the UV−vis and Infrared Cyrille Gautier and Thomas Bürgi pp 11079–11087 DOI: 10.1021/ja058717f Supporting Info

van der Waals Interactions and Decrease of the Rotational Barrier of Methyl-Sized Rotators:  A Theoretical Study Jerome Baudry pp 11088–11093 DOI: 10.1021/ja060731k Supporting Info

Quadruplex-Based Molecular Beacons as Tunable DNA Probes A. Bourdoncle, A. Estévez Torres, C. Gosse, L. Lacroix, P. Vekhoff, T. Le Saux, L. Jullien, and J.-L. Mergny pp 11094–11105 DOI: 10.1021/ja0608040 Supporting Info

Theoretical Investigation of the Stereoselective Stepwise Cope Rearrangement of a 3-Vinylmethylenecyclobutane Yi-Lei Zhao, Christopher P. Suhrada, Michael E. Jung, and K. N. Houk pp 11106–11113 DOI: 10.1021/ja060913e Supporting Info

Periodic Density Functional Theory Study of Propane Oxidative Dehydrogenation over V2O5(001) Surface Hui Fu, Zhi-Pan Liu, Zhen-Hua Li, Wen-Ning Wang, and Kang-Nian Fan pp 11114–11123 DOI: 10.1021/ja0611745

Improving Nature's Enzyme Active Site with Genetically Encoded Unnatural Amino Acids Jennifer C. Jackson, Sean P. Duffy, Kenneth R. Hess, and Ryan A. Mehl pp 11124–11127 DOI: 10.1021/ja061099y Supporting Info

Donor Stabilized Borylnitrene:  A Highly Reactive BN Analogue of Vinylidene Holger F. Bettinger and Holger Bornemann pp 11128–11134 DOI: 10.1021/ja061346y Supporting Info

From Homoligand- to Mixed-Ligand- Monolayer-Protected Metal Nanoparticles:  A Scanning Tunneling Microscopy Investigation Alicia M. Jackson, Ying Hu, Paulo Jacob Silva, and Francesco Stellacci pp 11135–11149 DOI: 10.1021/ja061545h

Cyclization and Catenation Directed by Molecular Self-Assembly Wei Wang, LiQiong Wang, Bruce J. Palmer, Gregory J. Exarhos, and Alexander D. Q. Li pp 11150–11159 DOI: 10.1021/ja061826p Supporting Info

Synthetic, Electrochemical, and Theoretical Studies of Tetrairidium Clusters Bearing Mono- and Bis[60]fullerene Ligands Bo Keun Park, Gaehang Lee, Kyoung Hoon Kim, Hongkyu Kang, Chang Yeon Lee, Md. Arzu Miah, Jaehoon Jung, Young-Kyu Han, and Joon T. Park pp 11160–11172 DOI: 10.1021/ja0616027 Supporting Info

Magnetic Properties of Lanthanide Chalcogenide Semiconducting Nanoparticles Michelle D. Regulacio, Konrad Bussmann, Brad Lewis, and Sarah L. Stoll pp 11173–11179 DOI: 10.1021/ja0620080 Supporting Info

Assignment of Absolute Configuration of Natural Abundance Deuterium Signals Associated with (R)- and (S)-Enantioisotopomers in a Fatty Acid Aligned in a Chiral Liquid Crystal:  Enantioselective Synthesis and NMR Analysis Vincent Baillif, Richard J. Robins, Isabelle Billault, and Philippe Lesot pp 11180–11187 DOI: 10.1021/ja0617892 Supporting Info

Manganese Oxides:  Parallels between Abiotic and Biotic Structures Ian Saratovsky, Peter G. Wightman, Pablo A. Pastén, Jean-François Gaillard, and Kenneth R. Poeppelmeier pp 11188–11198 DOI: 10.1021/ja062097g Supporting Info

Carbon Nanotube Amplification Strategies for Highly Sensitive Immunodetection of Cancer Biomarkers Xin Yu, Bernard Munge, Vyomesh Patel, Gary Jensen, Ashwin Bhirde, Joseph D. Gong, Sang N. Kim, John Gillespie, J. Silvio Gutkind, Fotios Papadimitrakopoulos, and James F. Rusling pp 11199–11205 DOI: 10.1021/ja062117e Supporting Info

Noncovalent Interactions within a Synthetic Receptor Can Reinforce Guest Binding Zaida Rodriguez-Docampo, Sofia I. Pascu, Stefan Kubik, and Sijbren Otto pp 11206–11210 DOI: 10.1021/ja062389h Supporting Info

How Does Single Oxygen Atom Addition Affect the Properties of an Fe−Nitrile Hydratase Analogue? The Compensatory Role of the Unmodified Thiolate Priscilla Lugo-Mas, Abhishek Dey, Liang Xu, Steven D. Davin, Jason Benedict, Werner Kaminsky, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and Julie A. Kovacs pp 11211–11221 DOI: 10.1021/ja062706k Supporting Info

Interactions in Single Wall Carbon Nanotubes/Pyrene/Porphyrin Nanohybrids Christian Ehli, G. M. Aminur Rahman, Norbert Jux, Domenico Balbinot, Dirk M. Guldi, Francesco Paolucci, Massimo Marcaccio, Demis Paolucci, Manuel Melle-Franco, Francesco Zerbetto, Stéphane Campidelli, and Maurizio Prato pp 11222–11231 DOI: 10.1021/ja0624974 Supporting Info

Remarkably Stable Chiral Zirconium Complexes for Asymmetric Mannich-Type Reactions Kowichiro Saruhashi and Shū Kobayashi pp 11232–11235 DOI: 10.1021/ja062776r Supporting Info

Solid Memory:  Structural Preferences in Group 2 Dihalide Monomers, Dimers, and Solids Kelling J. Donald and Roald Hoffmann pp 11236–11249 DOI: 10.1021/ja062817j Supporting Info

Biosynthesis of the (2S,3R)-3-Methyl Glutamate Residue of Nonribosomal Lipopeptides Claire Milne, Amanda Powell, John Jim, Majid Al Nakeeb, Colin P. Smith, and Jason Micklefield pp 11250–11259 DOI: 10.1021/ja062960c Supporting Info

Single-Molecule Charge-Transport Measurements that Reveal Technique-Dependent Perturbations Dwight S. Seferos, Amy Szuchmacher Blum, James G. Kushmerick, and Guillermo C. Bazan pp 11260–11267 DOI: 10.1021/ja062898j Supporting Info

The True Nature of the Di-iron(III) γ-Keggin Structure in Water:  Catalytic Aerobic Oxidation and Chemistry of an Unsymmetrical Trimer Bogdan Botar, Yurii V. Geletii, Paul Kögerler, Djamaladdin G. Musaev, Keiji Morokuma, Ira A. Weinstock, and Craig L. Hill pp 11268–11277 DOI: 10.1021/ja063157l Supporting Info

Lithium Cation as Radical-Polymerization Catalyst Timothy Clark pp 11278–11285 DOI: 10.1021/ja063204+ Supporting Info

Directed Assembly of Mesoscopic Metallocycles with Controllable Size, Chirality, and Functionality Based on the Robust Pt−Alkynyl Linkage Hua Jiang and Wenbin Lin pp 11286–11297 DOI: 10.1021/ja0633013 Supporting Info

Binding and Stability Determinants of the PPARγ Nuclear Receptor−Coactivator Interface As Revealed by Shotgun Alanine Scanning and in Vivo Selection Kevin J. Phillips, Daniel M. Rosenbaum, and David R. Liu pp 11298–11306 DOI: 10.1021/ja0635985

Catalytic Polymerization and Facile Grafting of Poly(furfuryl alcohol) to Single-Wall Carbon Nanotube:  Preparation of Nanocomposite Carbon Bo Yi, Ramakrishnan Rajagopalan, Henry C. Foley, Un Jeong Kim, Xiaoming Liu, and Peter C. Eklund pp 11307–11313 DOI: 10.1021/ja063518x Supporting Info

Kinetics and Thermodynamics of H• Transfer from (η5-C5R5)Cr(CO)3H (R = Ph, Me, H) to Methyl Methacrylate and Styrene [J. Am. Chem. Soc. 2003, 125, 10093−10102]. Lihao Tang, Elizabeth T. Papish, Graham P. Abramo, Jack R. Norton, Mu-Hyun Baik, Richard A. Friesner, and Anthony Rappé p 11314 DOI: 10.1021/ja069969z

Nanoparticle Assemblies and Superstructures Edited by Nicholas A. Kotov (University of Michigan, Ann Arbor). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. xx + 626 pp. $199.95. ISBN 0-824-2524-7. Miguel E. Castro p 11315 DOI: 10.1021/ja059899g

Metal Oxides:  Chemistry and Applications Edited by J. L. G. Fierro (National Council for Scientific Research (CSIC), Madrid, Spain). CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2006. xxii + 783 pp. $179.95. ISBN 0-8247-2371-6. Douglas J. Buttrey pp 11315–11316 DOI: 10.1021/ja0598964

Carbon Nanotubes Edited by Valentin N. Popov (University of Sofia, Bulgaria) and Philippe Lambin (Facultes Universitaires Notre-Dame de la Paix, Namur, Belgium). Springer:  Dordrecht. 2006. xvi + 254 pp. $139.00. ISBN 1-4020-4572-7. p 11316 DOI: 10.1021/ja069740j

Organic Reaction Mechanisms 2002 Edited by A. C. Knipe (University of Ulster). John Wiley and Sons, Ltd:  Chichester. 2006. x + 654 pp. $525.00. ISBN 0-470-02203-5. p 11316 DOI: 10.1021/ja069753x

Issue 35

Dissociation Mechanism of Acetic Acid in Water Jung Mee Park, Alessandro Laio, Marcella Iannuzzi, and Michele Parrinello pp 11318–11319 DOI: 10.1021/ja060454h Supporting Info

Generation of Cations from Alkoxides:  Allylation of Propargyl Alcohols George W. Kabalka, Min-Liang Yao, and Scott Borella pp 11320–11321 DOI: 10.1021/ja061379d Supporting Info

Epoxidation and Deoxygenation of Single-Walled Carbon Nanotubes:  Quantification of Epoxide Defects Douglas Ogrin, Jayanta Chattopadhyay, Anil K. Sadana, W. Edward Billups, and Andrew R. Barron pp 11322–11323 DOI: 10.1021/ja061680u Supporting Info

The Interpretation of Compliance Constants and Their Suitability for Characterizing Hydrogen Bonds and Other Weak Interactions Jon Baker and Peter Pulay pp 11324–11325 DOI: 10.1021/ja0618503

A R2/R1 Ratiometric Procedure for a Concentration-Independent, pH-Responsive, Gd(III)-Based MRI Agent Silvio Aime, Franco Fedeli, Alberto Sanino, and Enzo Terreno pp 11326–11327 DOI: 10.1021/ja062387x

Subnanometer Actuation of a Tethered Lipid Bilayer Monitored with Fluorescence Resonance Energy Transfer Andreas Kunding and Dimitrios Stamou pp 11328–11329 DOI: 10.1021/ja062545k Supporting Info

Thermodynamic and Kinetic Aspects of Metal Binding to the Histidine-rich Protein, Hpn Ruiguang Ge, Yi Zhang, Xuesong Sun, Rory M. Watt, Qing-Yu He, Jian-Dong Huang, Dean E. Wilcox, and Hongzhe Sun pp 11330–11331 DOI: 10.1021/ja062589t Supporting Info

Cleavage of a Carbon−Carbon Triple Bond via Gold-Catalyzed Cascade Cyclization/Oxidative Cleavage Reactions of (Z)-Enynols with Molecular Oxygen Yuanhong Liu, Feijie Song, and Shenghai Guo pp 11332–11333 DOI: 10.1021/ja062610q Supporting Info

A Supramolecular ON−OFF−ON Fluorescence Assay for Selective Recognition of GTP Prakash P. Neelakandan, Mahesh Hariharan, and Danaboyina Ramaiah pp 11334–11335 DOI: 10.1021/ja062651m Supporting Info

Spatially Controlled Chemistry Using Remotely Guided Nanoliter Scale Containers Timothy Leong, Zhiyong Gu, Travis Koh, and David H. Gracias pp 11336–11337 DOI: 10.1021/ja063100z Supporting Info

Toward β-Amino Acid Proteins:  A Cooperatively Folded β-Peptide Quaternary Structure Jade X. Qiu, E. James Petersson, Erin E. Matthews, and Alanna Schepartz pp 11338–11339 DOI: 10.1021/ja063164+ Supporting Info

Peierls Instability in One-Dimensional Borine Wire on Si(001) Jin-Ho Choi and Jun-Hyung Cho pp 11340–11341 DOI: 10.1021/ja063226w Supporting Info

Nanocompatible Chemistry toward Fabrication of Target-Specific Gold Nanoparticles Raghuraman Kannan, Valerie Rahing, Cathy Cutler, Ravi Pandrapragada, Kavita K. Katti, Vijaya Kattumuri, J. David Robertson, Stan J. Casteel, Silvia Jurisson, Charles Smith, Evan Boote, and Kattesh V. Katti pp 11342–11343 DOI: 10.1021/ja063280c Supporting Info

High-Precision Catalysts:  Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes Mark Kuil, Theresa Soltner, Piet W. N. M. van Leeuwen, and Joost N. H. Reek pp 11344–11345 DOI: 10.1021/ja063294i Supporting Info

Label-Free “Digital Detection” of Single-Molecule DNA Hybridization with a Single Electron Transistor Louis C. Brousseau, III pp 11346–11347 DOI: 10.1021/ja063022f Supporting Info

Catalytic Enantioselective Decarboxylative Protonation Justin T. Mohr, Toyoki Nishimata, Douglas C. Behenna, and Brian M. Stoltz pp 11348–11349 DOI: 10.1021/ja063335a Supporting Info

Unexpected Intermolecular Pd-Catalyzed Cross-Coupling Reaction Employing Heteroaromatic Carboxylic Acids as Coupling Partners Pat Forgione, Marie-Christine Brochu, Miguel St-Onge, Kris H. Thesen, Murray D. Bailey, and François Bilodeau pp 11350–11351 DOI: 10.1021/ja063511f Supporting Info

Tb3N@C84:  An Improbable, Egg-Shaped Endohedral Fullerene that Violates the Isolated Pentagon Rule Christine M. Beavers, Tianming Zuo, James C. Duchamp, Kim Harich, Harry C. Dorn, Marilyn M. Olmstead, and Alan L. Balch pp 11352–11353 DOI: 10.1021/ja063636k Supporting Info

Controlling Carbon Surface Chemistry by Alloying:  Carbon Tolerant Reforming Catalyst Eranda Nikolla, Adam Holewinski, Johannes Schwank, and Suljo Linic pp 11354–11355 DOI: 10.1021/ja0638298 Supporting Info

Toward the Syntheses of Universal Ligands for Metal Oxide Surfaces:  Controlling Surface Functionality through Click Chemistry Meghann A. White, Jeremiah A. Johnson, Jeffrey T. Koberstein, and Nicholas J. Turro pp 11356–11357 DOI: 10.1021/ja064041s Supporting Info

Long-Range Ordered Magnet of a Charge-Transfer Ru24+/TCNQ Two-Dimensional Network Compound Hitoshi Miyasaka, Toru Izawa, Nao Takahashi, Masahiro Yamashita, and Kim R. Dunbar pp 11358–11359 DOI: 10.1021/ja063963s Supporting Info

Synthesis of 3-Miktoarm Stars and 1st Generation Mikto Dendritic Copolymers by “Living” Radical Polymerization and “Click” Chemistry Michael R. Whittaker, Carl N. Urbani, and Michael J. Monteiro pp 11360–11361 DOI: 10.1021/ja0645990 Supporting Info

Bisdioxaborine Polymethines with Large Third-Order Nonlinearities for All-Optical Signal Processing Joel M. Hales, Shijun Zheng, Stephen Barlow, Seth R. Marder, and Joseph W. Perry pp 11362–11363 DOI: 10.1021/ja063535m Supporting Info

Stereoselective Synthesis of Vinylsilanes by a Gold(I)-Catalyzed Acetylenic Sila-Cope Rearrangement Yoshikazu Horino, Michael R. Luzung, and F. Dean Toste pp 11364–11365 DOI: 10.1021/ja0636800 Supporting Info

Very Large Changes in Bond Length and Bond Angle in a Heavy Group 14 Element Alkyne Analogue by Modification of a Remote Ligand Substituent Roland C. Fischer, Lihung Pu, James C. Fettinger, Marcin A. Brynda, and Philip P. Power pp 11366–11367 DOI: 10.1021/ja0637090 Supporting Info

Efficient Catalytic Insertion of Acetylenes into a Carbon−Carbon Single Bond of Nonstrained Cyclic Compounds under Mild Conditions Yoichiro Kuninobu, Atsushi Kawata, and Kazuhiko Takai pp 11368–11369 DOI: 10.1021/ja064022i Supporting Info

A Sensitized Europium Complex Generated by Micromolar Concentrations of Copper(I):  Toward the Detection of Copper(I) in Biology Romain F. H. Viguier and Alison N. Hulme pp 11370–11371 DOI: 10.1021/ja064232v Supporting Info

Gold-Catalyzed Intramolecular [3 + 2]-Cycloaddition of Arenyne-Yne Functionalities Jian-Jou Lian, Po-Chiang Chen, Yau-Ping Lin, Hao-Chun Ting, and Rai-Shung Liu pp 11372–11373 DOI: 10.1021/ja0643826 Supporting Info

The Enantioselective Step in the Nickel-Catalyzed Hydrocyanation of 1,3-Cyclohexadiene Jos Wilting, Michèle Janssen, Christian Müller, and Dieter Vogt pp 11374–11375 DOI: 10.1021/ja064378u Supporting Info

Remarkable Aspects of Unsaturation in Trinuclear Metal Carbonyl Clusters:  The Triiron Species Fe3(CO)n (n = 12, 11, 10, 9) Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer, III pp 11376–11384 DOI: 10.1021/ja055223+ Supporting Info

TOTAPOL: A Biradical Polarizing Agent for Dynamic Nuclear Polarization Experiments in Aqueous Media Changsik Song, Kan-Nian Hu, Chan-Gyu Joo, Timothy M. Swager, and Robert G. Griffin, pp 11385–11390 DOI: 10.1021/ja061284b

Does Dinitrogen Hydrogenation Follow Different Mechanisms for [(η5-C5Me4H)2Zr]2(μ2,η2,η2-N2) and {[PhP(CH2SiMe2NSiMe2CH2)PPh]Zr}2(μ2,η2,η2-N2) Complexes? A Computational Study Petia Bobadova-Parvanova, Qingfang Wang, David Quinonero-Santiago, Keiji Morokuma, and Djamaladdin G. Musaev pp 11391–11403 DOI: 10.1021/ja057937q Supporting Info

Understanding the Role of Ti in Reversible Hydrogen Storage as Sodium Alanate:  A Combined Experimental and Density Functional Theoretical Approach Santanu Chaudhuri, Jason Graetz, Alex Ignatov, James J. Reilly, and James T. Muckerman pp 11404–11415 DOI: 10.1021/ja060437s Supporting Info

Small Polaron Hopping in LixFePO4 Solid Solutions:  Coupled Lithium-Ion and Electron Mobility Brian Ellis, Laura K. Perry, Dominic H. Ryan, and L. F. Nazar pp 11416–11422 DOI: 10.1021/ja0614114

Characterization of a Single Molecule DNA Switch in Free Solution Samuel S. White, Haitao Li, Richard J. Marsh, Joe D. Piper, Nicholas D. Leonczek, Nick Nicolaou, Angus J. Bain, Liming Ying, and David Klenerman pp 11423–11432 DOI: 10.1021/ja0614870

Mass Measurements of Increased Accuracy Resolve Heterogeneous Populations of Intact Ribosomes Adam R. McKay, Brandon T. Ruotolo, Leopold L. Ilag, and Carol V. Robinson pp 11433–11442 DOI: 10.1021/ja061468q Supporting Info

Chemical Shift Tensors of Protonated Base Carbons in Helical RNA and DNA from NMR Relaxation and Liquid Crystal Measurements Jinfa Ying, Alexander Grishaev, David L. Bryce, and Ad Bax pp 11443–11454 DOI: 10.1021/ja061984g Supporting Info

Production of Highly Homogeneous Si(100) Surfaces by H2O Etching:  Surface Morphology and the Role of Strain Marc F. Faggin, Sara K. Green, Ian T. Clark, K. T. Queeney, and Melissa A. Hines pp 11455–11462 DOI: 10.1021/ja062172n

A Synthetic Mimic of Human Fc Receptors:  Defined Chemical Modification of Cell Surfaces Enables Efficient Endocytic Uptake of Human Immunoglobulin-G Siwarutt Boonyarattanakalin, Scott E. Martin, Qi Sun, and Blake R. Peterson pp 11463–11470 DOI: 10.1021/ja062377w

Evidence for Basic Ferryls in Cytochromes P450 Rachel K. Behan, Lee M. Hoffart, Kari L. Stone, Carsten Krebs, and Michael T. Green pp 11471–11474 DOI: 10.1021/ja062428p Supporting Info

Multistep Solution-Mediated Formation of AuCuSn2:  Mechanistic Insights for the Guided Design of Intermetallic Solid-State Materials and Complex Multimetal Nanocrystals Brian M. Leonard and Raymond E. Schaak pp 11475–11482 DOI: 10.1021/ja062475h Supporting Info

Origin of Syn/Anti Diastereoselectivity in Aldehyde and Ketone Crotylation Reactions:  A Combined Theoretical and Experimental Study Lutz F. Tietze, Tom Kinzel, and Stefan Schmatz pp 11483–11495 DOI: 10.1021/ja062528v Supporting Info

Synthesis, Structure, Anion Binding, and Sensing by Calix[4]pyrrole Isomers Ryuhei Nishiyabu, Manuel A. Palacios, Wim Dehaen, and Pavel Anzenbacher, Jr. pp 11496–11504 DOI: 10.1021/ja0622150 Supporting Info

Conformational Flexibility of a Microcrystalline Globular Protein: Order Parameters by Solid-State NMR Spectroscopy Justin L. Lorieau and Ann E. McDermott pp 11505–11512 DOI: 10.1021/ja062443u Supporting Info

Nickel-Catalyzed Coupling of Alkenes, Aldehydes, and Silyl Triflates Sze-Sze Ng, Chun-Yu Ho, and Timothy F. Jamison pp 11513–11528 DOI: 10.1021/ja062866w Supporting Info

Antimitotic Rhizoxin Derivatives from a Cultured Bacterial Endosymbiont of the Rice Pathogenic Fungus Rhizopus microsporus Kirstin Scherlach, Laila P. Partida-Martinez, Hans-Martin Dahse, and Christian Hertweck pp 11529–11536 DOI: 10.1021/ja062953o

Permanganate Oxidation of Alkenes. Substituent and Solvent Effects. Difficulties with MP2 Calculations Kenneth B. Wiberg, Yi-gui Wang, Stepan Sklenak, Carol Deutsch, and Gary Trucks pp 11537–11544 DOI: 10.1021/ja0630184 Supporting Info

Escherichia coli Type I Isopentenyl Diphosphate Isomerase:  Structural and Catalytic Roles for Divalent Metals Sungwon Lee and C. Dale Poulter pp 11545–11550 DOI: 10.1021/ja063073c

pH Responsiveness of Dendrimer-like Poly(ethylene oxide)s Xiaoshuang Feng, Daniel Taton, Redouane Borsali, Elliot L. Chaikof, and Yves Gnanou pp 11551–11562 DOI: 10.1021/ja0631605 Supporting Info

Nanografting:  Modeling and Simulation Seol Ryu and George C. Schatz pp 11563–11573 DOI: 10.1021/ja063138b Supporting Info

A Nanoengineering Approach to Regulate the Lateral Heterogeneity of Self-Assembled Monolayers Jing-jiang Yu, Yih Horng Tan, Xue Li, Pao-Kuang Kuo, and Gang-yu Liu pp 11574–11581 DOI: 10.1021/ja0631403 Supporting Info

Formation of a Miscible Supramolecular Polymer Blend through Self-Assembly Mediated by a Quadruply Hydrogen-Bonded Heterocomplex Taiho Park and Steven C. Zimmerman pp 11582–11590 DOI: 10.1021/ja0631854

Structural and Functional Consequences of an Amide-to-Ester Substitution in the Selectivity Filter of a Potassium Channel Francis I. Valiyaveetil, Matthew Sekedat, Roderick MacKinnon, and Tom W. Muir pp 11591–11599 DOI: 10.1021/ja0631955

A Self-Locking Molecule Operative with a Photoresponsive Key Takahiro Muraoka, Kazushi Kinbara, and Takuzo Aida pp 11600–11605 DOI: 10.1021/ja0632308 Supporting Info

Water-Dissolvable Sodium Sulfate Nanowires as a Versatile Template for the Fabrication of Polyelectrolyte- and Metal-Based Nanotubes Ying-Chih Pu, Jih Ru Hwu, Wu-Chou Su, Dar-Bin Shieh, Yonhua Tzeng, and Chen-Sheng Yeh pp 11606–11611 DOI: 10.1021/ja063221z Supporting Info

Mechanistic Studies and Methods To Prevent Aglycon Transfer of Thioglycosides Zhitao Li and Jeffrey C. Gildersleeve pp 11612–11619 DOI: 10.1021/ja063247q Supporting Info

Synthesis, X-ray Crystallography, and Computational Analysis of 1-Azafenestranes Scott E. Denmark, Justin I. Montgomery, and Laurenz A. Kramps pp 11620–11630 DOI: 10.1021/ja0632759 Supporting Info

Synthesis, Crystal Structure, and Nonlinear Optical Properties of Li6CuB4O10:  a Congruently Melting Compound with Isolated [CuB4O10]6- Units Shilie Pan, Jared P. Smit, Byron Watkins, Michael R. Marvel, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 11631–11634 DOI: 10.1021/ja0633114 Supporting Info

Control of sp2/sp3 Carbon Ratio and Surface Chemistry of Nanodiamond Powders by Selective Oxidation in Air Sebastian Osswald, Gleb Yushin, Vadym Mochalin, Sergei O. Kucheyev, and Yury Gogotsi pp 11635–11642 DOI: 10.1021/ja063303n

(tBu2MeSi)2SnSn(SiMetBu2)2:  A Distannene with a >SnSn< Double Bond That Is Stable Both in the Solid State and in Solution Vladimir Ya. Lee, Tomohide Fukawa, Masaaki Nakamoto, Akira Sekiguchi, Boris L. Tumanskii, Miriam Karni, and Yitzhak Apeloig pp 11643–11651 DOI: 10.1021/ja063322x Supporting Info

Triconstituent Co-assembly to Ordered Mesostructured Polymer−Silica and Carbon−Silica Nanocomposites and Large-Pore Mesoporous Carbons with High Surface Areas Ruili Liu, Yifeng Shi, Ying Wan, Yan Meng, Fuqiang Zhang, Dong Gu, Zhenxia Chen, Bo Tu, and Dongyuan Zhao pp 11652–11662 DOI: 10.1021/ja0633518 Supporting Info

Understanding the Mechanism of Gelation and Stimuli-Responsive Nature of a Class of Metallo-Supramolecular Gels Wengui Weng, J. Benjamin Beck, Alex M. Jamieson, and Stuart J. Rowan pp 11663–11672 DOI: 10.1021/ja063408q Supporting Info

Early Intermediate in Human Prion Protein Folding As Evidenced by Ultrarapid Mixing Experiments Adrian C. Apetri, Kosuke Maki, Heinrich Roder, and Witold K. Surewicz pp 11673–11678 DOI: 10.1021/ja063880b

On the Reactivity of Surface Methoxy Species in Acidic Zeolites Yijiao Jiang, Michael Hunger, and Wei Wang pp 11679–11692 DOI: 10.1021/ja061018y

Hydrazines and Azides via the Metal-Catalyzed Hydrohydrazination and Hydroazidation of Olefins Jérôme Waser, Boris Gaspar, Hisanori Nambu, and Erick M. Carreira pp 11693–11712 DOI: 10.1021/ja062355+ Supporting Info

Transfer of Structural Elements from Compact to Extended States in Unsolvated Ubiquitin Stormy L. Koeniger, Samuel I. Merenbloom, Sundarapandian Sevugarajan, and David E. Clemmer pp 11713–11719 DOI: 10.1021/ja062137g

Visible Light Excitation of CdSe Nanocrystals Triggers the Release of Coumarin from Cinnamate Surface Ligands Maikel Wijtmans, Sandra J. Rosenthal, Binne Zwanenburg, and Ned A. Porter pp 11720–11726 DOI: 10.1021/ja063562c Supporting Info

Total Synthesis and Structural Confirmation of Chlorodysinosin A  [J. Am. Chem. Soc. 2006, 128, 10491−10495].  Stephen Hanessian, Juan R. Del Valle, Yafeng Xue, and Niklas Blomberg pp 11727–11728 DOI: 10.1021/ja069971q

Issue 36

Interaction Energy Contributions of H-Bonded and Stacked Structures of the AT and GC DNA Base Pairs from the Combined Density Functional Theory and Intermolecular Perturbation Theory Approach Andreas Hesselmann, Georg Jansen, and Martin Schütz pp 11730–11731 DOI: 10.1021/ja0633363 Supporting Info

Two-Dimensional Electronic Conjugation:  Cooperative Folding and Fluorescence Switching Xuan Jiang, John C. Bollinger, and Dongwhan Lee pp 11732–11733 DOI: 10.1021/ja063413u Supporting Info

A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity Shengqian Ma and Hong-Cai Zhou pp 11734–11735 DOI: 10.1021/ja063538z Supporting Info

Imaging Farnesyl Protein Transferase Using a Topologically Activated Probe Wellington Pham, Pamela Pantazopoulos, and Anna Moore pp 11736–11737 DOI: 10.1021/ja063599x Supporting Info

X-ray Scattering Study of the Effect of Hydration on the Cross-β Structure of Amyloid Fibrils Adam M. Squires, Glyn L. Devlin, Sally L. Gras, Anna K. Tickler, Cait E. MacPhee, and Christopher M. Dobson pp 11738–11739 DOI: 10.1021/ja063751v Supporting Info

Hydrogen Storage in Chemically Reducible Mesoporous and Microporous Ti Oxides Xin Hu, Boris O. Skadtchenko, Michel Trudeau, and David M. Antonelli pp 11740–11741 DOI: 10.1021/ja0639766 Supporting Info

Simulated Unfolded-State Ensemble and the Experimental NMR Structures of Villin Headpiece Yield Similar Wide-Angle Solution X-ray Scattering Profiles Bojan Zagrovic and Vijay S. Pande pp 11742–11743 DOI: 10.1021/ja0640694

Unique Organic−Inorganic Interactions Leading to a Structure-Directed Microporous Aluminophosphate Crystallization as Observed with in situ Raman Spectroscopy Matthew G. O'Brien, Andrew M. Beale, C. Richard A. Catlow, and Bert M. Weckhuysen pp 11744–11745 DOI: 10.1021/ja064230a Supporting Info

A Metallic (EDT-DSDTFVSDS)2·FeBr4 Salt:  Antiferromagnetic Ordering of d Spins of FeBr4- Ions and Anomalous Magnetoresistance Due to Preferential π−d Interaction Toshiki Hayashi, Xunwen Xiao, Hideki Fujiwara, Toyonari Sugimoto, Hiroyuki Nakazumi, Satoru Noguchi, Tsutomu Fujimoto, Syuma Yasuzuka, Harukazu Yoshino, Keizo Murata, Takehiko Mori, and Hiroko Aruga-Katori pp 11746–11747 DOI: 10.1021/ja064307v Supporting Info

Direct C−H Arylation of (Hetero)arenes with Aryl Iodides via Rhodium Catalysis Shuichi Yanagisawa, Tomoko Sudo, Ryoji Noyori, and Kenichiro Itami pp 11748–11749 DOI: 10.1021/ja064500p Supporting Info

Externally Tunable Dynamic Confinement Effect in Organosilica Sol−Gels Marci C. Burt and Bakul C. Dave pp 11750–11751 DOI: 10.1021/ja064928o

A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions Uttam K. Tambar, David C. Ebner, and Brian M. Stoltz pp 11752–11753 DOI: 10.1021/ja0651815 Supporting Info

Rhodium-Catalyzed Stereoselective Formation of Z-Enamines from Allylaziridines France-Aimée Alphonse and Andrei K. Yudin pp 11754–11755 DOI: 10.1021/ja0632557 Supporting Info

Removal of a Single Minor-Groove Functional Group Eliminates A-Tract Curvature Meena, Zhenhua Sun, Christine Mulligan, and Larry W. McLaughlin pp 11756–11757 DOI: 10.1021/ja0632310 Supporting Info

Monodisperse Lanthanide Oxysulfide Nanocrystals Fei Zhao, Mei Yuan, Wen Zhang, and Song Gao pp 11758–11759 DOI: 10.1021/ja0638410 Supporting Info

Phosphorus-Containing Hybrid Calixphyrins:  Promising Mixed-Donor Ligands for Visible and Efficient Palladium Catalysts Yoshihiro Matano, Tooru Miyajima, Takashi Nakabuchi, Hiroshi Imahori, Noriaki Ochi, and Shigeyoshi Sakaki pp 11760–11761 DOI: 10.1021/ja0640039 Supporting Info

Self-Coiling of Ag2V4O11 Nanobelts into Perfect Nanorings and Microloops Guozhen Shen and Di Chen pp 11762–11763 DOI: 10.1021/ja064123g Supporting Info

Progressive−Convergent Elucidation of Stereochemistry in Complex Polyols. The Absolute Configuration of (−)-Sagittamide A Sarah C. Lievens and Tadeusz F. Molinski pp 11764–11765 DOI: 10.1021/ja063735y Supporting Info

Enantioselective Intramolecular [2 + 2 + 2] Cycloaddition of 1,4-Diene-ynes:  A New Approach to the Construction of Quaternary Carbon Stereocenters Takanori Shibata and Yu-ki Tahara pp 11766–11767 DOI: 10.1021/ja0639160 Supporting Info

Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction Tobias Ritter, Michael W. Day, and Robert H. Grubbs pp 11768–11769 DOI: 10.1021/ja064091x Supporting Info

Sequential Catalytic Isomerization and Allylic Substitution. Conversion of Racemic Branched Allylic Carbonates to Enantioenriched Allylic Substitution Products Shashank Shekhar, Brian Trantow, Andreas Leitner, and John F. Hartwig pp 11770–11771 DOI: 10.1021/ja0644273 Supporting Info

Versatile, Fragrant, Convertible Isonitriles Michael C. Pirrung and Subir Ghorai pp 11772–11773 DOI: 10.1021/ja0644374 Supporting Info

Highly Efficient Rh(I)-Catalyzed Asymmetric Hydrogenation of Enamines Using Monodente Spiro Phosphonite Ligands Guo-Hua Hou, Jian-Hua Xie, Li-Xin Wang, and Qi-Lin Zhou pp 11774–11775 DOI: 10.1021/ja0644778 Supporting Info

Mixed La−Li Heterobimetallic Complexes for Tertiary Nitroaldol Resolution Shin-ya Tosaki, Keiichi Hara, Vijay Gnanadesikan, Hiroyuki Morimoto, Shinji Harada, Mari Sugita, Noriyuki Yamagiwa, Shigeki Matsunaga, and Masakatsu Shibasaki pp 11776–11777 DOI: 10.1021/ja064858l Supporting Info

Design of a Bacterial Host for Site-Specific Incorporation of p-Bromophenylalanine into Recombinant Proteins Inchan Kwon, Pin Wang, and David A. Tirrell pp 11778–11783 DOI: 10.1021/ja0626281

Facile Amine Formation by Intermolecular Catalytic Amidation of Carbon−Hydrogen Bonds Manuel R. Fructos, Swiatoslaw Trofimenko, M. Mar Díaz-Requejo, and Pedro J. Pérez pp 11784–11791 DOI: 10.1021/ja0627850 Supporting Info

Ion/Molecule Reactions of Cation Radicals Formed from Protonated Polypeptides via Gas-Phase Ion/Ion Electron Transfer Yu Xia, Paul A. Chrisman, Sharon J. Pitteri, David E. Erickson, and Scott A. McLuckey pp 11792–11798 DOI: 10.1021/ja063248i

Total Synthesis of Piericidin A1 and B1 and Key Analogues Martin J. Schnermann, F. Anthony Romero, Inkyu Hwang, Eiko Nakamaru-Ogiso, Takao Yagi, and Dale L. Boger pp 11799–11807 DOI: 10.1021/ja0632862 Supporting Info

Metallosupramolecular Chemistry with Bis(benzene-o-dithiolato) Ligands Thorsten Kreickmann, Christian Diedrich, Tania Pape, Han Vinh Huynh, Stefan Grimme, and F. Ekkehardt Hahn pp 11808–11819 DOI: 10.1021/ja063655u Supporting Info

Hydrogen-Bond Symmetry in Zwitterionic Phthalate Anions:  Symmetry Breaking by Solvation Charles L. Perrin and Jonathan S. Lau pp 11820–11824 DOI: 10.1021/ja063797o Supporting Info

Separation of Tricomponent Protein Mixtures with Triblock Nanorods Byung-Keun Oh, Sungho Park, Jill E. Millstone, Seung Woo Lee, Ki-Bum Lee, and Chad A. Mirkin pp 11825–11829 DOI: 10.1021/ja057525h

Binding Free Energy Contributions of Interfacial Waters in HIV-1 Protease/Inhibitor Complexes Yipin Lu, Chao-Yie Yang, and Shaomeng Wang pp 11830–11839 DOI: 10.1021/ja058042g Supporting Info

Investigation of Two-Photon Absorption Properties in Branched Alkene and Alkyne Chromophores Ajit Bhaskar, Guda Ramakrishna, Zhikuan Lu, Robert Twieg, Joel M. Hales, David J. Hagan, Eric Van Stryland, and Theodore Goodson III pp 11840–11849 DOI: 10.1021/ja060630m Supporting Info

Resonance Bonding Patterns of Peroxide Chemistry:  Cyclic Three-Center Hyperbonding in “Phosphadioxirane” Intermediates Jeremiah J. Wilke and Frank Weinhold pp 11850–11859 DOI: 10.1021/ja060676f Supporting Info

Optimization, Standardization, and Testing of a New NMR Method for the Determination of Zeolite Host−Organic Guest Crystal Structures Colin A. Fyfe and Darren H. Brouwer pp 11860–11871 DOI: 10.1021/ja060744y Supporting Info

Cruciforms as Functional Fluorophores:  Response to Protons and Selected Metal Ions Anthony J. Zucchero, James N. Wilson, and Uwe H. F. Bunz pp 11872–11881 DOI: 10.1021/ja061112e Supporting Info

Phage Display Affords Peptides that Modulate β-Amyloid Aggregation Brendan P. Orner, Lin Liu, Regina M. Murphy, and Laura L. Kiessling pp 11882–11889 DOI: 10.1021/ja0619861 Supporting Info

FRET Templated by G-Quadruplex DNA:  A Specific Ternary Interaction Using an Original Pair of Donor/Acceptor Partners Clémence Allain, David Monchaud, and Marie-Paule Teulade-Fichou pp 11890–11893 DOI: 10.1021/ja062193h Supporting Info

Femtosecond Time- and Wavelength-Resolved Fluorescence and Absorption Spectroscopic Study of the Excited States of Adenosine and an Adenine Oligomer Wai-Ming Kwok, Chensheng Ma, and David Lee Phillips pp 11894–11905 DOI: 10.1021/ja0622002 Supporting Info

Synthetic Studies of Complex Immunostimulants from Quillaja saponaria:  Synthesis of the Potent Clinical Immunoadjuvant QS-21Aapi Yong-Jae Kim, Pengfei Wang, Mauricio Navarro-Villalobos, Bridget D. Rohde, JohnMark DerryBerry, and David Y. Gin pp 11906–11915 DOI: 10.1021/ja062364i Supporting Info

Isolation, Structure, and Absolute Stereochemistry of Platensimycin, A Broad Spectrum Antibiotic Discovered Using an Antisense Differential Sensitivity Strategy Sheo B. Singh, Hiranthi Jayasuriya, John G. Ondeyka, Kithsiri B. Herath, Chaowei Zhang, Deborah L. Zink, Nancy N. Tsou, Richard G. Ball, Angela Basilio, Olga Genilloud, Maria Teresa Diez, Francisca Vicente, Fernando Pelaez, Katherine Young, and Jun Wang pp 11916–11920 DOI: 10.1021/ja062232p Supporting Info

Rational Synthesis, Self-Assembly, and Optical Properties of PbS−Au Heterogeneous Nanostructures via Preferential Deposition Jian Yang, Hendry Izaac Elim, QingBo Zhang, Jim Yang Lee, and Wei Ji pp 11921–11926 DOI: 10.1021/ja062494r Supporting Info

Silapropargyl/Silaallenyl and Silylene Acetylide Complexes of [Cp(CO)2W]+. Theoretical Study of Their Interesting Bonding Nature and Formation Reaction Mausumi Ray, Yoshihide Nakao, Hirofumi Sato, Hiroyuki Sakaba, and Shigeyoshi Sakaki pp 11927–11939 DOI: 10.1021/ja0625374 Supporting Info

Substituents on Quinone Methides Strongly Modulate Formation and Stability of Their Nucleophilic Adducts Emily E. Weinert, Ruggero Dondi, Stefano Colloredo-Melz, Kristen N. Frankenfield, Charles H. Mitchell, Mauro Freccero, and Steven E. Rokita pp 11940–11947 DOI: 10.1021/ja062948k Supporting Info

Practical Approach for the Stereoselective Introduction of β-Arabinofuranosides Xiangming Zhu, Sameer Kawatkar, Yu Rao, and Geert-Jan Boons pp 11948–11957 DOI: 10.1021/ja0629817 Supporting Info

Room-Temperature Biosynthesis of Ferroelectric Barium Titanate Nanoparticles Vipul Bansal, Pankaj Poddar, Absar Ahmad, and Murali Sastry pp 11958–11963 DOI: 10.1021/ja063011m Supporting Info

Comparison of the Specificity of Interaction of Cellular and Viral Zinc-Binding Domains with 2-Mercaptobenzamide Thioesters Lisa M. Miller Jenkins, Stewart R. Durell, Andrew T. Maynard, Stephen J. Stahl, John K. Inman, Ettore Appella, Pascale Legault, and James G. Omichinski pp 11964–11976 DOI: 10.1021/ja063329e Supporting Info

Large Molecular Assembly of Amphotericin B Formed in Ergosterol-Containing Membrane Evidenced by Solid-State NMR of Intramolecular Bridged Derivative Nobuaki Matsumori, Yuri Sawada, and Michio Murata pp 11977–11984 DOI: 10.1021/ja063433w Supporting Info

Discovery of a Solid Solution of Enantiomers in a Racemate-Forming System by Seeding Jun Huang, Shuang Chen, Ilia A. Guzei, and Lian Yu pp 11985–11992 DOI: 10.1021/ja063450l Supporting Info

Edge-Bridged Mo2Fe6S8 to PN-Type Mo2Fe6S9 Cluster Conversion:  Structural Fate of the Attacking Sulfide/Selenide Nucleophile Curtis P. Berlinguette and R. H. Holm pp 11993–12000 DOI: 10.1021/ja063604x Supporting Info

Chemical Functionalization of Boron−Nitride Nanotubes with NH3 and Amino Functional Groups Xiaojun Wu, Wei An, and Xiao Cheng Zeng pp 12001–12006 DOI: 10.1021/ja063653+

Molecular Structure and Dynamics at the Interfaces within Bulk Heterojunction Materials for Solar Cells Cuiying Yang, Jerry G. Hu, and Alan J. Heeger pp 12007–12013 DOI: 10.1021/ja063707f

Micelle Density Regulated by a Reversible Switch of Protein Secondary Structure Rory E. Sallach, Min Wei, Nilanjana Biswas, Vincent P. Conticello, Sébastien Lecommandoux, Richard A. Dluhy, and Elliot L. Chaikof pp 12014–12019 DOI: 10.1021/ja0638509 Supporting Info

Why Does Perfluorination Render Bicyclo[2.2.0]hex-1(4)-ene Stable toward Dimerization? Calculations Provide the Answers G. Robert Shelton, David A. Hrovat, Haiyan Wei, and Weston Thatcher Borden pp 12020–12027 DOI: 10.1021/ja063848h Supporting Info

Molybdenum-Catalyzed Asymmetric Allylation of 3-Alkyloxindoles:  Application to the Formal Total Synthesis of (−)-Physostigmine [J. Am. Chem. Soc. 2006, 128, 4590−4591]. Barry M. Trost and Yong Zhang p 12028 DOI: 10.1021/ja069970y Supporting Info

Medicinal Chemistry of Bioactive Natural Products Edited by Xiao-Tian Liang and Wei-Shuo Fang (Chinese Academy of Medical Sciences, Beijing, China). John Wiley & Sons, Inc.:  Hoboken, NJ, 2006. xx + 460 pp. $89.95. ISBN 0-471-66007-8. George A. O'Doherty p 12029 DOI: 10.1021/ja069731a

Organometallics. Third, Completely Revised and Extended Edition By Christoph Elschenbroich (Philipps-Universität Marburg). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2006. xvi + 804 pp. $95.00. ISBN 3-527-29390-6. Christopher W. Bielawski pp 12029–12030 DOI: 10.1021/ja069735f

Polymer Analysis, Polymer Theory. Advances in Polymer Science, 182 With Contributions By S. Anantawaraskul, H. Aoki, A. Blumen, A. A. Gurtovenko, H. Hillborg, S. Ito, H. Schönherr, J. B. P. Soares, G. J. Vancso, and P. M. Wood-Adams. Springer:  Berlin, Heidelberg, New York. 2005. x + 308 pp. $269.00. ISBN 3-540-25548-6. Bob A. Howell p 12030 DOI: 10.1021/ja0598863

Vibrational Spectroscopy of Biological and Polymeric Materials Edited by Vasilis G. Gregoriou (Foundation of Research and Technology, Hellas, Greece) and Mark S. Braiman (Syracuse University, New York, USA). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. xvi + 430 pp. $139.95. ISBN 1-57444-539-1. Garth J. Simpson pp 12030–12031 DOI: 10.1021/ja069721+

Recent Advances in the Theory of Chemical and Physical Systems. Progress in Theoretical Chemistry and Physics, Volume 15 Edited by Jean-Pierre Julien (CNRS and UJF, Grenoble, France), Jean Maruani (CNRS and UPMC, Paris, France), Didier Mayou (CNRS and UJF, Grenoble), Stephen Wilson (Rutherford Appleton Laboratory, Oxfordshire, UK), and Gerardo Delgado-Barrio (CSIC, Madrid, Spain). Springer:  Dordrecht. 2006. xii + 592 pp. $179.00. ISBN 1-4020-4527-1. p 12031 DOI: 10.1021/ja069765i

Radiative Decay Engineering. Topics in Fluorescence Spectroscopy, Volume 8 Edited by Chris D. Geddes (University of Maryland Biotechnology Institute, Baltimore, MD) and Joseph R. Lakowicz (University of Maryland School of Medicine, Baltimore, MD). Springer:  New York. 2005. xviii + 458 pp. $149.00. ISBN 0-387-22662-1. Gary A. Baker pp 12031–12032 DOI: 10.1021/ja0597552

Issue 37

X-ray Magnetic Circular Dichroism of Size-Selected, Thiolated Gold Clusters Yuichi Negishi, Hironori Tsunoyama, Motohiro Suzuki, Naomi Kawamura, Michio M. Matsushita, Koichi Maruyama, Tadashi Sugawara, Toshihiko Yokoyama, and Tatsuya Tsukuda pp 12034–12035 DOI: 10.1021/ja062815z Supporting Info

Ionic Conductivity in Crystalline PEO6:Li(AsF6)1-x(SbF6)x Scott J. Lilley, Yuri G. Andreev, and Peter G. Bruce pp 12036–12037 DOI: 10.1021/ja063091u Supporting Info

Solvatochromism of the Green Fluorescence Protein Chromophore and Its Derivatives Jian Dong, Kyril M. Solntsev, and Laren M. Tolbert pp 12038–12039 DOI: 10.1021/ja063128a Supporting Info

Improved Photostable FRET-Competent Biarsenical−Tetracysteine Probes Based on Fluorinated Fluoresceins Carla C. Spagnuolo, Rudolf J. Vermeij, and Elizabeth A. Jares-Erijman pp 12040–12041 DOI: 10.1021/ja063212q Supporting Info

Selective Ion-Binding by Protein Probed with the 3D-RISM Theory Norio Yoshida, Saree Phongphanphanee, Yutaka Maruyama, Takashi Imai, and Fumio Hirata pp 12042–12043 DOI: 10.1021/ja0633262 Supporting Info

Conductive Wiring of Immobilized Photosynthetic Reaction Center to Electrode by Cytochrome c Nikolai Lebedev, Scott A. Trammell, Anthony Spano, Evgeny Lukashev, Igor Griva, and Joel Schnur pp 12044–12045 DOI: 10.1021/ja063367y Supporting Info

Multiple Deprotonations and Deaminations of Phenethylamines to Synthesize Pyrroles Xiaobing Wan, Dong Xing, Zhao Fang, Bijie Li, Fei Zhao, Keya Zhang, Liping Yang, and Zhangjie Shi pp 12046–12047 DOI: 10.1021/ja061176p Supporting Info

Efficient Catalysis of Ammonia Borane Dehydrogenation Melanie C. Denney, Vincent Pons, Travis J. Hebden, D. Michael Heinekey, and Karen I. Goldberg pp 12048–12049 DOI: 10.1021/ja062419g Supporting Info

Gold-Catalyzed 1,2-Migration of Silicon, Tin, and Germanium en Route to C-2 Substituted Fused Pyrrole-Containing Heterocycles Ilya V. Seregin and Vladimir Gevorgyan pp 12050–12051 DOI: 10.1021/ja063278l Supporting Info

Dynamic Electronic Structure of a Au/TiO2 Catalyst under Reaction Conditions Elizabeth A. Willneff, Simon Braun, Dirk Rosenthal, Hendrik Bluhm, Michael Hävecker, Evgenyi Kleimenov, Axel Knop-Gericke, Robert Schlögl, and Sven L. M. Schroeder pp 12052–12053 DOI: 10.1021/ja062792o Supporting Info

A Re(CO)5 Fragment Bonded to a Polyhedral Oligomeric Hydroxysilsesquioxane as a Model which Gives Further Evidence to the Existence of an Unexpected Re(CO)5 Surface Species Elena Lucenti, Giuseppe D'Alfonso, Piero Macchi, Mario Maranesi, Dominique Roberto, Angelo Sironi, and Renato Ugo pp 12054–12055 DOI: 10.1021/ja0630588 Supporting Info

On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR‘2 Sébastien Bontemps, Ghenwa Bouhadir, Karinne Miqueu, and Didier Bourissou pp 12056–12057 DOI: 10.1021/ja0637494 Supporting Info

Total Degradation of Fenitrothion and Other Organophosphorus Pesticides by Catalytic Oxidation Employing Fe-TAML Peroxide Activators Arani Chanda, Sushil K. Khetan, Deboshri Banerjee, Anindya Ghosh, and Terrence J. Collins pp 12058–12059 DOI: 10.1021/ja064017e Supporting Info

cis−trans Formic Acid Dimer:  Experimental Observation and Improved Stability against Proton Tunneling Kseniya Marushkevich, Leonid Khriachtchev, Jan Lundell, and Markku Räsänen pp 12060–12061 DOI: 10.1021/ja064154b Supporting Info

Synthesis of Indenyl Ethers by Gold(I)-Catalyzed Intramolecular Carboalkoxylation of Alkynes Pascal Dubé and F. Dean Toste pp 12062–12063 DOI: 10.1021/ja064209+ Supporting Info

In Situ Fabrication of A Water-Soluble, Self-Doped Polyaniline Nanocomposite:  The Unique Role of DNA Functionalized Single-Walled Carbon Nanotubes Yufeng Ma, Shah R. Ali, Ling Wang, Pui Lam Chiu, Richard Mendelsohn, and Huixin He pp 12064–12065 DOI: 10.1021/ja063375e Supporting Info

Mixed-Valence Two-Legged MX-Ladder Complex with a Pair of Out-of-Phase Charge-Density Waves Atsushi Kobayashi and Hiroshi Kitagawa pp 12066–12067 DOI: 10.1021/ja064082o Supporting Info

Unusual Non-Bulk Properties in Nanoscale Materials:  Thermal Metal−Metal Bond Contraction of γ-Alumina-Supported Pt Catalysts Joo H. Kang, Laurent D. Menard, Ralph G. Nuzzo, and Anatoly I. Frenkel pp 12068–12069 DOI: 10.1021/ja064207p Supporting Info

Electron Paramagnetic Resonance Studies of an Integral Membrane Peptide Inserted into Aligned Phospholipid Bilayer Nanotube Arrays Ethan S. Karp, Johnson J. Inbaraj, Mikhail Laryukhin, and Gary A. Lorigan pp 12070–12071 DOI: 10.1021/ja064077k

Copolymerization of Silyl Vinyl Ethers with Olefins by (α-diimine)PdR+ Shuji Luo and Richard F. Jordan pp 12072–12073 DOI: 10.1021/ja064398w Supporting Info

Generalized Route to Metal Nanoparticles with Liquid Behavior Scott C. Warren, Matthew J. Banholzer, Liane S. Slaughter, Emmanuel P. Giannelis, Francis J. DiSalvo, and Ulrich B. Wiesner pp 12074–12075 DOI: 10.1021/ja064469r Supporting Info

Transfer of Surface Polymerase Reaction Products to a Secondary Platform with Conservation of Spatial Registration Joohoon Kim and Richard M. Crooks pp 12076–12077 DOI: 10.1021/ja0646139 Supporting Info

A Chemical Reporter Strategy to Probe Glycoprotein Fucosylation David Rabuka, Sarah C. Hubbard, Scott T. Laughlin, Sulabha P. Argade, and Carolyn R. Bertozzi pp 12078–12079 DOI: 10.1021/ja064619y Supporting Info

Force-Controlled Inorganic Crystallization Lithography Chao-Min Cheng and Philip R. LeDuc pp 12080–12081 DOI: 10.1021/ja064653c

Direct Electrochemistry of Endonuclease III in the Presence and Absence of DNA Alon A. Gorodetsky, Amie K. Boal, and Jacqueline K. Barton pp 12082–12083 DOI: 10.1021/ja064784d Supporting Info

A Versatile New Monomer Family:  Functionalized 4-Vinyl-1,2,3-Triazoles via Click Chemistry Raymond J. Thibault, Kenichi Takizawa, Peter Lowenheilm, Brett Helms, Justin L. Mynar, Jean M. J. Fréchet, and Craig J. Hawker pp 12084–12085 DOI: 10.1021/ja0648209 Supporting Info

Constrained-Geometry Aluminum Complexes with η5;η1-Coordination:  Syntheses, Structures, and Theoretical Studies of Dicarbollylamino Aluminum(III) Complexes Ki-Chul Son, Young-Joo Lee, Minserk Cheong, Jaejung Ko, and Sang Ook Kang pp 12086–12087 DOI: 10.1021/ja064696t Supporting Info

Reversible Alkene Extrusion from Platinaoxetanes Endre Szuromi, Jianguo Wu, and Paul R. Sharp pp 12088–12089 DOI: 10.1021/ja065207s Supporting Info

Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes Oleg Byl, Jin-Chen Liu, Yang Wang, Wai-Leung Yim, J. Karl Johnson, and John T. Yates, Jr. pp 12090–12097 DOI: 10.1021/ja057856u Supporting Info

Atomically Detailed Simulations of Concentrated Protein Solutions:  The Effects of Salt, pH, Point Mutations, and Protein Concentration in Simulations of 1000-Molecule Systems Sean R. McGuffee and Adrian H. Elcock pp 12098–12110 DOI: 10.1021/ja0614058 Supporting Info

Microsolvation of Formamide:  A Rotational Study Susana Blanco, Juan C. López, Alberto Lesarri, and José L. Alonso pp 12111–12121 DOI: 10.1021/ja0618393 Supporting Info

Solvent-Induced Effects:  Self-Association of Positively Charged π Systems Eric Buisine, Katherine de Villiers, Timothy J. Egan, and Christophe Biot pp 12122–12128 DOI: 10.1021/ja061755u Supporting Info

Influence of the Membrane Potential on the Protonation of Bacteriorhodopsin:  Insights from Electrostatic Calculations into the Regulation of Proton Pumping Elisa Bombarda, Torsten Becker, and G. Matthias Ullmann pp 12129–12139 DOI: 10.1021/ja0619657 Supporting Info

Automated Search for New Thermoelectric Materials: The Case of LiZnSb Georg K. H. Madsen pp 12140–12146 DOI: 10.1021/ja062526a

X-ray Diffraction Area Mapping of Preferred Orientation and Phase Change in TiO2 Thin Films Deposited by Chemical Vapor Deposition Geoffrey Hyett, Mark Green, and Ivan P. Parkin pp 12147–12155 DOI: 10.1021/ja062766q Supporting Info

Antimicrobial Peptides in Action Hari Leontiadou, Alan E. Mark, and Siewert J. Marrink pp 12156–12161 DOI: 10.1021/ja062927q

Sequence-Specific Alkylation of Double-Strand Human Telomere Repeat Sequence by Pyrrole-Imidazole Polyamides with Indole Linkers Shunta Sasaki, Toshikazu Bando, Masafumi Minoshima, Tatsuhiko Shimizu, Ken-ichi Shinohara, Toshiyasu Takaoka, and Hiroshi Sugiyama pp 12162–12168 DOI: 10.1021/ja0626584 Supporting Info

Circumambulatory Rearrangement with Characteristics of a 2:1 Covalent Molecular Bevel Gear Rosa E. Bulo, Florian Allaart, Andreas W. Ehlers, Franciscus J. J. de Kanter, Marius Schakel, Martin Lutz, Anthony L. Spek, and Koop Lammertsma pp 12169–12173 DOI: 10.1021/ja0627895 Supporting Info

Synthesis and Evaluation of Bioorthogonal Pantetheine Analogues for in Vivo Protein Modification Jordan L. Meier, Andrew C. Mercer, Heriberto Rivera, Jr., and Michael D. Burkart pp 12174–12184 DOI: 10.1021/ja063217n Supporting Info

Serendipity and Four Polymorphic Structures of Benzidine, C12H12N2 Michal Rafilovich and Joel Bernstein pp 12185–12191 DOI: 10.1021/ja063224b Supporting Info

Pentacyanoiron(II) as an Electron Donor Group for Nonlinear Optics:  Medium-Responsive Properties and Comparisons with Related Pentaammineruthenium(II) Complexes Benjamin J. Coe, Josephine L. Harries, Madeleine Helliwell, Lathe A. Jones, Inge Asselberghs, Koen Clays, Bruce S. Brunschwig, James A. Harris, Javier Garín, and Jesús Orduna pp 12192–12204 DOI: 10.1021/ja063449m Supporting Info

Microfluidic Production of Biopolymer Microcapsules with Controlled Morphology Hong Zhang, Ethan Tumarkin, Raheem Peerani, Zhihong Nie, Ruby May A. Sullan, Gilbert C. Walker, and Eugenia Kumacheva pp 12205–12210 DOI: 10.1021/ja0635682 Supporting Info

Catalyzed Relaxation of a Metastable DNA Fuel Georg Seelig, Bernard Yurke, and Erik Winfree pp 12211–12220 DOI: 10.1021/ja0635635

Stereochemical and Regiochemical Trends in the Selective Detection of Saccharides Shan Jiang, Jorge O. Escobedo, Kyu Kwang Kim, Onur Alptürk, George K. Samoei, Sayo O. Fakayode, Isiah M. Warner, Oleksandr Rusin, and Robert M. Strongin pp 12221–12228 DOI: 10.1021/ja063651p Supporting Info

Determining the Intracellular Transport Mechanism of a Cleft−[2]Rotaxane Xiaofeng Bao, Idit Isaacsohn, Angela F. Drew, and David B. Smithrud pp 12229–12238 DOI: 10.1021/ja063667f Supporting Info

Dispersion and Separation of Small-Diameter Single-Walled Carbon Nanotubes Yutaka Maeda, Makoto Kanda, Masahiro Hashimoto, Tadashi Hasegawa, Shin-ichi Kimura, Yongfu Lian, Takatsugu Wakahara, Takeshi Akasaka, Said Kazaoui, Nobutsugu Minami, Toshiya Okazaki, Yuhei Hayamizu, Kenji Hata, Jing Lu, and Shigeru Nagase pp 12239–12242 DOI: 10.1021/ja063776u Supporting Info

Synthesis, Structural Studies, Theoretical Calculations, and Linear and Nonlinear Optical Properties of Terpyridyl Lanthanide Complexes:  New Evidence for the Contribution of f Electrons to the NLO Activity Katell Sénéchal-David, Anne Hemeryck, Nicolas Tancrez, Loïc Toupet, J. A. Gareth Williams, Isabelle Ledoux, Joseph Zyss, Abdou Boucekkine, Jean-Paul Guégan, Hubert Le Bozec, and Olivier Maury pp 12243–12255 DOI: 10.1021/ja063586j Supporting Info

Structure Determination of a Membrane Protein with Two Trans-membrane Helices in Aligned Phospholipid Bicelles by Solid-State NMR Spectroscopy Anna A. De Angelis, Stanley C. Howell, Alexander A. Nevzorov, and Stanley J. Opella pp 12256–12267 DOI: 10.1021/ja063640w

Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern:  C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6 Ivan E. Kareev, Natalia B. Shustova, Igor V. Kuvychko, Sergey F. Lebedkin, Susie M. Miller, Oren P. Anderson, Alexey A. Popov, Steven H. Strauss, and Olga V. Boltalina pp 12268–12280 DOI: 10.1021/ja063907r Supporting Info

Calix[4]pyrrole as a Chloride Anion Receptor:  Solvent and Countercation Effects Jonathan L. Sessler, Dustin E. Gross, Won-Seob Cho, Vincent M. Lynch, Franz P. Schmidtchen, Gareth W. Bates, Mark E. Light, and Philip A. Gale pp 12281–12288 DOI: 10.1021/ja064012h Supporting Info

Staurosporine and Rebeccamycin Aglycones Are Assembled by the Oxidative Action of StaP, StaC, and RebC on Chromopyrrolic Acid Annaleise R. Howard-Jones and Christopher T. Walsh pp 12289–12298 DOI: 10.1021/ja063898m Supporting Info

Homogeneously Alloyed CdSxSe1-x Nanocrystals:  Synthesis, Characterization, and Composition/Size-Dependent Band Gap Laura A. Swafford, Lauren A. Weigand, Michael J. Bowers II, James R. McBride, Jason L. Rapaport, Tony L. Watt, Sriram K. Dixit, Leonard C. Feldman, and Sandra J. Rosenthal pp 12299–12306 DOI: 10.1021/ja063939e

Hydrogen-Bonding-Mediated Anthranilamide Homoduplexes. Increasing Stability through Preorganization and Iterative Arrangement of a Simple Amide Binding Site Jiang Zhu, Jian-Bin Lin, Yun-Xiang Xu, Xue-Bin Shao, Xi-Kui Jiang, and Zhan-Ting Li pp 12307–12313 DOI: 10.1021/ja064218i Supporting Info

Born−Haber−Fajans Cycle Generalized:  Linear Energy Relation between Molecules, Crystals, and Metals Leslie Glasser and László von Szentpály pp 12314–12321 DOI: 10.1021/ja063812p

Catalysis of Diribonucleoside Monophosphate Cleavage by Water Soluble Copper(II) Complexes of Calix[4]arene Based Nitrogen Ligands Roberta Cacciapaglia, Alessandro Casnati, Luigi Mandolini, David N. Reinhoudt, Riccardo Salvio, Andrea Sartori, and Rocco Ungaro pp 12322–12330 DOI: 10.1021/ja0632106 Supporting Info

Kinetics of CO Insertion and Acetyl Group Transfer Steps, and a Model of the Acetyl-CoA Synthase Catalytic Mechanism Xiangshi Tan, Ivan V. Surovtsev, and Paul A. Lindahl pp 12331–12338 DOI: 10.1021/ja0627702

Studies of the Generation and Pericyclic Behavior of Cyclic Pentadienyl Carbanions. Alkylation Reactions as an Efficient Route to Functionalized cis-Bicyclo[3.3.0]octenes David R. Williams, Jonathan T. Reeves, Partha P. Nag, William H. Pitcock, Jr., and Mu-Hyun Baik pp 12339–12348 DOI: 10.1021/ja063243l Supporting Info

Computational Chemistry of Solid State Materials:  A Guide for Materials Scientists, Chemists, Physicists and Others By Richard Dronskowski (RWTH Aachen, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. vi + 294 pp. $125.00. ISBN 3-527-31410-5. Stephen P. Kelty p 12349 DOI: 10.1021/ja069725e

Annual Review of Physical Chemistry, Volume 57, 2006 Edited by Stephen R. Leone (University of California, Berkeley), Paul Alivisatos (University of California, Berkeley), and Ann E. McDermott (Columbia University, New York). Annual Reviews:  Palo Alto, CA. 2006. xvi + 692 pp. $188.00. ISBN 0-8243-1057-8. pp 12349–12350 DOI: 10.1021/ja069769n

Optical Chemical Sensors Edited by F. Baldini (IFAC-CNR, Florence, Italy), A. N. Chester (Hughes Research Labs, Inc., Malibu, CA), J. Homola (IREE-Academy of Sciences, Prague, Czech Republic), and S. Martellucci (The University of Rome “Tor Vergata”, Italy). Springer:  Dordrecht. 2006. xxxii + 536 pp. $99.00. ISBN 1-4020-4609-X. p 12350 DOI: 10.1021/ja0697572

Anion Receptor Chemistry By Jonathan L. Sessler (University of Texas, Austin, USA), Philip A. Gale (University of Southampton, UK), and Won-Seob Cho (University of Texas, Austin, USA). From the Series:  Monographs in Supramolecular Chemistry. Edited by J. F. Stoddart. Royal Society of Chemistry:  Cambridge. 2006. xvi + 414 pp. $219. ISBN 0-85404-974-6. Dennis H. Burns p 12350 DOI: 10.1021/ja069759m

Issue 38

New Application of AAO Template:  A Mold for Nanoring and Nanocone Arrays Shiyong Zhao, Helene Roberge, Arthur Yelon, and Teodor Veres pp 12352–12353 DOI: 10.1021/ja062148+ Supporting Info

Protein Side-Chain Dynamics Observed by Solution- and Solid-State NMR:  Comparative Analysis of Methyl 2H Relaxation Data Bernd Reif, Yi Xue, Vipin Agarwal, Maria S. Pavlova, Maggy Hologne, Anne Diehl, Yaroslav E. Ryabov, and Nikolai R. Skrynnikov pp 12354–12355 DOI: 10.1021/ja062808a Supporting Info

Synthesis of RNA Using 2‘-O-DTM Protection Andrey Semenyuk, Andras Földesi, Tommy Johansson, Camilla Estmer-Nilsson, Peter Blomgren, Mathias Brännvall, Leif A. Kirsebom, and Marek Kwiatkowski pp 12356–12357 DOI: 10.1021/ja0636587 Supporting Info

Preparation and Characterization of Conducting Trimetallic Nickel−Dithiolene Complexes with Bridging Tetrathiooxalate Ligands Kazuya Kubo, Akiko Nakao, Hiroshi M. Yamamoto, and Reizo Kato pp 12358–12359 DOI: 10.1021/ja0638004 Supporting Info

DFTMP, an NMR Reagent for Assessing the Near-Neutral pH of Biological Samples Michael D. Reily, Lora C. Robosky, Matthew L. Manning, Andrew Butler, John David Baker, and R. Thomas Winters pp 12360–12361 DOI: 10.1021/ja063773h Supporting Info

From Carbon Dioxide to Methane:  Homogeneous Reduction of Carbon Dioxide with Hydrosilanes Catalyzed by Zirconium−Borane Complexes Tsukasa Matsuo and Hiroyuki Kawaguchi pp 12362–12363 DOI: 10.1021/ja0647250 Supporting Info

Chemical Tuning of Positive and Negative Magnetoresistances, and Superconductivity in 1222-Type Ruthenocuprates Abbie C. Mclaughlin, Laura Begg, Catriona Harrow, Simon A. J. Kimber, Falak Sher, and J. Paul Attfield pp 12364–12365 DOI: 10.1021/ja064778h Supporting Info

Catalytic One-Pot Synthesis of Cyclic Amidines by Virtue of Tandem Reactions Involving Intramolecular Hydroamination under Mild Conditions Sukbok Chang, Minjae Lee, Doo Young Jung, Eun Jeong Yoo, Seung Hwan Cho, and Sun Kyu Han pp 12366–12367 DOI: 10.1021/ja064788i Supporting Info

The [1,5]-Brook Rearrangement:  An Initial Application in Anion Relay Chemistry Amos B. Smith, III, Ming Xian, Won-Suk Kim and Dae-Shik Kim pp 12368–12369 DOI: 10.1021/ja065033e Supporting Info

Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes:  Application to the Total Synthesis of (+)-Lasubine II Robert T. Yu and Tomislav Rovis pp 12370–12371 DOI: 10.1021/ja064868m Supporting Info

Reductive DNA Cleavage Induced by UVA Photoirradiation of NADH without Oxygen Makiko Tanaka, Kei Ohkubo, and Shunichi Fukuzumi pp 12372–12373 DOI: 10.1021/ja065073i Supporting Info

Hydroxylamine as an Oxygen Nucleophile. Structure and Reactivity of Ammonia Oxide Anthony J. Kirby, John E. Davies, Tiago A. S. Brandão, Pedro F. da Silva, Willian R. Rocha, and Faruk Nome pp 12374–12375 DOI: 10.1021/ja065147q Supporting Info

Rhenium-Catalyzed Insertion of Aldehyde into a C−H Bond:  Synthesis of Isobenzofuran Derivatives Yoichiro Kuninobu, Yuta Nishina, Chie Nakagawa, and Kazuhiko Takai pp 12376–12377 DOI: 10.1021/ja065643e Supporting Info

Self-Healing of Surfactant Surface Micelles on Millisecond Time Scales Hannes C. Schniepp, Dudley A. Saville, and Ilhan A. Aksay pp 12378–12379 DOI: 10.1021/ja0624826 Supporting Info

Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers Satoru Hiroto, Ko Furukawa, Hiroshi Shinokubo, and Atsuhiro Osuka pp 12380–12381 DOI: 10.1021/ja062654z Supporting Info

Electrochemical Proteolytic Beacon for Detection of Matrix Metalloproteinase Activities Guodong Liu, Jun Wang, David S Wunschel, and Yuehe Lin pp 12382–12383 DOI: 10.1021/ja0626638 Supporting Info

Controllable Distribution of Single Molecules and Peptides within Oligomer Template Investigated by STM Jian-Ru Gong, Hui-Juan Yan, Qun-Hui Yuan, Li-Ping Xu, Zhi-Shan Bo, and Li-Jun Wan pp 12384–12385 DOI: 10.1021/ja062533z Supporting Info

A Combined SAXS/WAXS/XAFS Setup Capable of Observing Concurrent Changes Across the Nano-to-Micrometer Size Range in Inorganic Solid Crystallization Processes Andrew M. Beale, Ad M. J. van der Eerden, Simon D. M. Jacques, Olivier Leynaud, Matthew G. O'Brien, Florian Meneau, Sergei Nikitenko, Wim Bras, and Bert M. Weckhuysen pp 12386–12387 DOI: 10.1021/ja062580r Supporting Info

Structure Transition and Swapping Pattern of Clathrate Hydrates Driven by External Guest Molecules Sun-Hwa Yeon, Jiwoong Seol, and Huen Lee pp 12388–12389 DOI: 10.1021/ja062937r Supporting Info

Rotational Polymorphism in 2-Naphthalenethiol SAMs on Au(111) Peng Jiang, Aymeric Nion, Alexandr Marchenko, Luc Piot, and Denis Fichou pp 12390–12391 DOI: 10.1021/ja063060z Supporting Info

Intermetallic Compounds with 1D Infinite Tunnels. Syntheses and Structures of AAu4In2 (A = K, Rb) Bin Li and John D. Corbett pp 12392–12393 DOI: 10.1021/ja063503z Supporting Info

Rapid Production of Metal−Organic Frameworks via Microwave-Assisted Solvothermal Synthesis Zheng Ni and Richard I. Masel pp 12394–12395 DOI: 10.1021/ja0635231

Organic Azide Inhibitors of Cysteine Proteases Giang Thanh Le, Giovanni Abbenante, Praveen K. Madala, Huy N. Hoang, and David P. Fairlie pp 12396–12397 DOI: 10.1021/ja0637649 Supporting Info

Observation of Heteronuclear Overhauser Effects Confirms the 15N−1H Dipolar Relaxation Mechanism in a Crystalline Protein Nicolas Giraud, Julien Sein, Guido Pintacuda, Anja Böckmann, Anne Lesage, Martin Blackledge, and Lyndon Emsley pp 12398–12399 DOI: 10.1021/ja064037g Supporting Info

Selective sp3 C−H Activation of Ketones at the β Position by Ir(I). Origin of Regioselectivity and Water Effect Moran Feller, Amir Karton, Gregory Leitus, Jan M. L. Martin, and David Milstein pp 12400–12401 DOI: 10.1021/ja0641352 Supporting Info

Synthesis and Electric Field Actuation of an Ionic Liquid Polymer Holly L. Ricks-Laskoski and Arthur W. Snow pp 12402–12403 DOI: 10.1021/ja064264i Supporting Info

Photoisomerization of an Individual Azobenzene Molecule in Water: An On−Off Switch Triggered by Light at a Fixed Wavelength Sandra Loudwig and Hagan Bayley pp 12404–12405 DOI: 10.1021/ja0642818 Supporting Info

Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core Zhi Yang, Xiaoli Ma, Rainer B. Oswald, Herbert W. Roesky, and Mathias Noltemeyer pp 12406–12407 DOI: 10.1021/ja064035w Supporting Info

Polymerization of Ionized Acetylene Clusters into Covalent Bonded Ions:  Evidence for the Formation of Benzene Radical Cation Paul O. Momoh, Samuel A. Abrash, Ridha Mabrouki, and M. Samy El-Shall pp 12408–12409 DOI: 10.1021/ja064405g Supporting Info

Design of a Highly Sensitive and Specific Nucleotide Sensor Based on Photon Upconverting Particles Peng Zhang, Snezna Rogelj, Khoi Nguyen, and Damon Wheeler pp 12410–12411 DOI: 10.1021/ja0644024

Reversible Three-State Switching of Luminescence:  A New Twist to Electro- and Photochromic Behavior Wesley R. Browne, Michael M. Pollard, Ben de Lange, Auke Meetsma, and Ben L. Feringa pp 12412–12413 DOI: 10.1021/ja064423y Supporting Info

Charge-Transfer Transitions in Protein Circular Dichroism Calculations Mark T. Oakley and Jonathan D. Hirst pp 12414–12415 DOI: 10.1021/ja0644125 Supporting Info

Isotope Labeling Studies Reveal the Order of Oxygen Incorporation into the Tryptophan Tryptophylquinone Cofactor of Methylamine Dehydrogenase Arwen R. Pearson, Sudha Marimanikkuppam, Xianghui Li, Victor L. Davidson, and Carrie M. Wilmot pp 12416–12417 DOI: 10.1021/ja064466e

Increasing Molecular Weight Parameters of a Helical Polymer through Polymerization in a Chiral Solvent Simon J. Holder, Mariliz Achilleos, and Richard G. Jones pp 12418–12419 DOI: 10.1021/ja064587e Supporting Info

A Cost-Effective Method for the Optical Transduction of Chemical Reactions. Application to Hyaluronidase Inhibitor Screening with Polyarginine−Counteranion Complexes in Lipid Bilayers Tomohiro Miyatake, Masamichi Nishihara, and Stefan Matile pp 12420–12421 DOI: 10.1021/ja064732o Supporting Info

The Discovery of an Enantioselective Receptor for (−)-Adenosine from a Racemic Dynamic Combinatorial Library Sharon M. Voshell, Stephen J. Lee, and Michel R. Gagné pp 12422–12423 DOI: 10.1021/ja0647699 Supporting Info

A Pro-Chelator Triggered by Hydrogen Peroxide Inhibits Iron-Promoted Hydroxyl Radical Formation Louise K. Charkoudian, David M. Pham, and Katherine J. Franz pp 12424–12425 DOI: 10.1021/ja064806w Supporting Info

Conjugated Polymers in an Arene Sandwich Anne J. McNeil, Peter Müller, James E. Whitten, and Timothy M. Swager pp 12426–12427 DOI: 10.1021/ja0648099 Supporting Info

Radial-Position-Controlled Doping in CdS/ZnS Core/Shell Nanocrystals Yongan Yang, Ou Chen, Alexander Angerhofer, and Y. Charles Cao pp 12428–12429 DOI: 10.1021/ja064818h Supporting Info

Stereoelectronic Tuning of the Structure and Stability of the Trp Cage Miniprotein Devan Naduthambi and Neal J. Zondlo pp 12430–12431 DOI: 10.1021/ja0648458 Supporting Info

Strong Cooperative Enhancement of Two-Photon Absorption in Double-Strand Conjugated Porphyrin Ladder Arrays Mikhail Drobizhev, Yuriy Stepanenko, Aleksander Rebane, Craig J. Wilson, Thomas E. O. Screen, and Harry L. Anderson pp 12432–12433 DOI: 10.1021/ja0649623 Supporting Info

Direct Observation of Reductive Elimination of Methyl Iodide from a Rhodium(III) Pincer Complex:  The Importance of Sterics Christian M. Frech and David Milstein pp 12434–12435 DOI: 10.1021/ja064945d Supporting Info

Molecular-Wire Behavior of OLED Materials:  Exciton Dynamics in Multichromophoric Alq3-Oligofluorene-Pt(II)porphyrin Triads Victor A. Montes, César Pérez-Bolívar, Neeraj Agarwal, Joseph Shinar, and Pavel Anzenbacher, Jr. pp 12436–12438 DOI: 10.1021/ja064471i Supporting Info

Hydration and Dewetting near Fluorinated Superhydrophobic Plates Xin Li, Jingyuan Li, Maria Eleftheriou, and Ruhong Zhou pp 12439–12447 DOI: 10.1021/ja057944e

Methane Dehydrogenation on Rh@Cu(111):  A First-Principles Study of a Model Catalyst Anton Kokalj, Nicola Bonini, Stefano de Gironcoli, Carlo Sbraccia, Guido Fratesi, and Stefano Baroni pp 12448–12454 DOI: 10.1021/ja060114w Supporting Info

Heme Protein Oxygen Affinity Regulation Exerted by Proximal Effects Luciana Capece, Marcelo A. Marti, Alejandro Crespo, Fabio Doctorovich, and Darío A. Estrin pp 12455–12461 DOI: 10.1021/ja0620033 Supporting Info

Lipids Out of Equilibrium:  Energetics of Desorption and Pore Mediated Flip-Flop D. Peter Tieleman and Siewert-Jan Marrink pp 12462–12467 DOI: 10.1021/ja0624321

Elasticity of Crystalline β-Sheet Monolayers Hila Isenberg, Kristian Kjaer, and Hanna Rapaport pp 12468–12472 DOI: 10.1021/ja062363q Supporting Info

Arsenic Binding to Human Metallothionein Thanh T. Ngu and Martin J. Stillman pp 12473–12483 DOI: 10.1021/ja062914c Supporting Info

A 2H NMR Relaxation Experiment for the Measurement of the Time Scale of Methyl Side-Chain Dynamics in Large Proteins Vitali Tugarinov and Lewis E. Kay pp 12484–12489 DOI: 10.1021/ja063071s Supporting Info

Synthesis and Structural Characterization of 1-Mesityl-1,3-dihydro-imidazole-2-selone and Bis(1-mesitylimidazol-2-yl)diselenide:  Experimental Evidence That the Selone Is More Stable Than the Selenol Tautomer Victoria K. Landry, Mao Minoura, Keliang Pang, Daniela Buccella, Bryte V. Kelly, and Gerard Parkin pp 12490–12497 DOI: 10.1021/ja063168e Supporting Info

Quasi-Isomeric Gallium Amides and Imides GaNR2 and RGaNR (R = Organic Group):  Reactions of the Digallene, Ar‘GaGaAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) with Unsaturated Nitrogen Compounds Robert J. Wright, Marcin Brynda, James C. Fettinger, Audra R. Betzer, and Philip P. Power pp 12498–12509 DOI: 10.1021/ja063072k Supporting Info

Specificity of Human Thymine DNA Glycosylase Depends on N-Glycosidic Bond Stability Matthew T. Bennett, M. T. Rodgers, Alexander S. Hebert, Lindsay E. Ruslander, Leslie Eisele, and Alexander C. Drohat pp 12510–12519 DOI: 10.1021/ja0634829 Supporting Info

The Arginine Anomaly:  Arginine Radicals Are Poor Hydrogen Atom Donors in Electron Transfer Induced Dissociations Xiaohong Chen and František Tureek pp 12520–12530 DOI: 10.1021/ja063676o Supporting Info

Synthesis, Reactivity, and DFT Studies of Tantalum Complexes Incorporating Diamido-N-heterocyclic Carbene Ligands. Facile Endocyclic C−H Bond Activation Liam P. Spencer, Chad Beddie, Michael B. Hall, and Michael D. Fryzuk pp 12531–12543 DOI: 10.1021/ja063282x Supporting Info

Dendrimer-Functionalized Single-Wall Carbon Nanotubes:  Synthesis, Characterization, and Photoinduced Electron Transfer Stéphane Campidelli, Chloé Sooambar, Enrique Lozano Diz, Christian Ehli, Dirk M. Guldi, and Maurizio Prato pp 12544–12552 DOI: 10.1021/ja063697i

π-Complex Structure of Gaseous Benzene−NO Cations Assayed by IR Multiple Photon Dissociation Spectroscopy Barbara Chiavarino, Maria Elisa Crestoni, Simonetta Fornarini, Joel Lemaire, Philippe Maître, and Luke MacAleese pp 12553–12561 DOI: 10.1021/ja0637548

Studies on the Mechanism of Action of Prekinamycin, a Member of the Diazoparaquinone Family of Natural Products:  Evidence for Both sp2 Radical and Orthoquinonemethide Intermediates Ken S. Feldman and Kyle J. Eastman pp 12562–12573 DOI: 10.1021/ja0642616 Supporting Info

Sequence-Specific Recognition and Cooperative Dimerization of N-Terminal Aromatic Peptides in Aqueous Solution by a Synthetic Host Lisa M. Heitmann, Alexander B. Taylor, P. John Hart, and Adam R. Urbach pp 12574–12581 DOI: 10.1021/ja064323s Supporting Info

One-Electron Reduction of Kinetically Stabilized Dipnictenes:  Synthesis of Dipnictene Anion Radicals Takahiro Sasamori, Eiko Mieda, Noriyoshi Nagahora, Kazunobu Sato, Daisuke Shiomi, Takeji Takui, Yoshinobu Hosoi, Yukio Furukawa, Nozomi Takagi, Shigeru Nagase, and Norihiro Tokitoh pp 12582–12588 DOI: 10.1021/ja064062m Supporting Info

Issue 39

Synthesis of CdSe/CdTe Nanobarbells Jonathan E. Halpert, Venda J. Porter, John P. Zimmer, and Moungi G. Bawendi pp 12590–12591 DOI: 10.1021/ja0616534 Supporting Info

A New Class of Mixed-Valence Systems with Orbitally Degenerate Organic Redox Centers. Examples Based on Hexa-Rhenium Molecular Prisms Peter H. Dinolfo, Veaceslav Coropceanu, Jean-Luc Brédas, and Joseph T. Hupp pp 12592–12593 DOI: 10.1021/ja0623764 Supporting Info

A Blind Structure Prediction of Ice XIV Gareth A. Tribello, Ben Slater, and Christoph G. Salzmann pp 12594–12595 DOI: 10.1021/ja0630902 Supporting Info

Efficient and Selective Al-Catalyzed Alcohol Oxidation via Oppenauer Chemistry Christopher R. Graves, Bi-Shun Zeng, and SonBinh T. Nguyen pp 12596–12597 DOI: 10.1021/ja063842s Supporting Info

RNA-Templated Semiconductor Nanocrystals Nan Ma, Chad J. Dooley, and Shana O. Kelley pp 12598–12599 DOI: 10.1021/ja0638962 Supporting Info

Protein Assembly Line Components in Prodigiosin Biosynthesis:  Characterization of PigA,G,H,I,J Sylvie Garneau-Tsodikova, Pieter C. Dorrestein, Neil L. Kelleher, and Christopher T. Walsh pp 12600–12601 DOI: 10.1021/ja063611l Supporting Info

Noncovalent Control for Bottom-Up Assembly of Functional Supramolecular Wires Josep Puigmartí-Luis, Andrea Minoia, Hiroshi Uji-i, Concepció Rovira, Jérôme Cornil, Steven De Feyter, Roberto Lazzaroni, and David B. Amabilino pp 12602–12603 DOI: 10.1021/ja0640288 Supporting Info

2,7-Diphenyl[1]benzothieno[3,2-b]benzothiophene, A New Organic Semiconductor for Air-Stable Organic Field-Effect Transistors with Mobilities up to 2.0 cm2 V-1 s-1 Kazuo Takimiya, Hideaki Ebata, Katsuhiro Sakamoto, Takafumi Izawa, Tetsuo Otsubo, and Yoshihito Kunugi pp 12604–12605 DOI: 10.1021/ja064052l Supporting Info

Three-Coordinate Metal Centers in Extended Transition Metal Oxides Amy Bowman, Mathieu Allix, Denis Pelloquin, and Matthew J. Rosseinsky pp 12606–12607 DOI: 10.1021/ja064083g Supporting Info

Room-Temperature Decay and Light Reactivation of High-Tc Ferromagnetism in an Oxide-Diluted Magnetic Semiconductor Dengyu Pan, Jianguo Wan, Guoliang Xu, Liya Lv, Yujie Wu, Han Min, Junming Liu, and Guanghou Wang pp 12608–12609 DOI: 10.1021/ja064094+ Supporting Info

Sensing Vase-to-Kite Switching of Cavitands by Sum-Frequency Vibrational Spectroscopy Pasquale Pagliusi, François Lagugné-Labarthet, Devanand K. Shenoy, Enrico Dalcanale, and Y. Ron Shen pp 12610–12611 DOI: 10.1021/ja064158g Supporting Info

Divergence in the Behavior of the Charge Density Wave in RETe3 (RE = Rare-Earth Element) with Temperature and RE Element Christos D. Malliakas and Mercouri G. Kanatzidis pp 12612–12613 DOI: 10.1021/ja0641608 Supporting Info

Gold(I) Catalyzed Isomerization of 5-en-2-yn-1-yl Acetates:  An Efficient Access to Acetoxy Bicyclo[3.1.0]hexenes and 2-Cycloalken-1-ones Andrea Buzas and Fabien Gagosz pp 12614–12615 DOI: 10.1021/ja064223m Supporting Info

A 3.0 μs Room Temperature Excited State Lifetime of a Bistridentate RuII−Polypyridine Complex for Rod-like Molecular Arrays Maria Abrahamsson, Michael Jäger, Tomas Österman, Lars Eriksson, Petter Persson, Hans-Christian Becker, Olof Johansson, and Leif Hammarström pp 12616–12617 DOI: 10.1021/ja064262y Supporting Info

Monitoring DPA Release from a Single Germinating Bacillus subtilis Endospore via Surface-Enhanced Raman Scattering Microscopy David D. Evanoff, Jr., John Heckel, Thomas P. Caldwell, Kenneth A. Christensen, and George Chumanov pp 12618–12619 DOI: 10.1021/ja0642717

High Resolution 1H Detected 1H,13C Correlation Spectra in MAS Solid-State NMR using Deuterated Proteins with Selective 1H,2H Isotopic Labeling of Methyl Groups Vipin Agarwal, Anne Diehl, Nikolai Skrynnikov, and Bernd Reif pp 12620–12621 DOI: 10.1021/ja064379m Supporting Info

Exchange of an Imido Ligand in Bis(imido) Complexes of Uranium Trevor W. Hayton, James M. Boncella, Brian L. Scott, and Enrique R. Batista pp 12622–12623 DOI: 10.1021/ja064400j Supporting Info

Extending the Series:  Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue Jason L. Dutton, Heikki M. Tuononen, Michael C. Jennings, and Paul J. Ragogna pp 12624–12625 DOI: 10.1021/ja064381d Supporting Info

Chemically Selective Sensing through Layer-by-Layer Incorporation of Biorecognition into Thin Film Substrates for Surface-Enhanced Resonance Raman Scattering Nicholas P. W. Pieczonka, Paul J. G. Goulet, and Ricardo F. Aroca pp 12626–12627 DOI: 10.1021/ja0644327 Supporting Info

Sequence-Specific Association in Aqueous Media by Integrating Hydrogen Bonding and Dynamic Covalent Interactions Minfeng Li, Kazuhiro Yamato, Joseph S. Ferguson, and Bing Gong pp 12628–12629 DOI: 10.1021/ja064515n Supporting Info

Antifungal Activity from 14-Helical β-Peptides Amy J. Karlsson, William C. Pomerantz, Bernard Weisblum, Samuel H. Gellman, and Sean P. Palecek pp 12630–12631 DOI: 10.1021/ja064630y Supporting Info

TEM-Induced Structural Evolution in Amorphous Fe Oxide Nanoparticles Andrew H. Latham, Mark J. Wilson, Peter Schiffer, and Mary Elizabeth Williams pp 12632–12633 DOI: 10.1021/ja064666q Supporting Info

Palladium-Catalyzed Alkylation of sp2 and sp3 C−H Bonds with Methylboroxine and Alkylboronic Acids:  Two Distinct C−H Activation Pathways Xiao Chen, Charles E. Goodhue, and Jin-Quan Yu pp 12634–12635 DOI: 10.1021/ja0646747 Supporting Info

Efficient H2 Adsorption by Nanopores of High-Purity Double-Walled Carbon Nanotubes Junichi Miyamoto, Yoshiyuki Hattori, Daisuke Noguchi, Hideki Tanaka, Tomonori Ohba, Shigenori Utsumi, Hirofumi Kanoh, Yoong Ahm Kim, Hiroyuki Muramatsu, Takuya Hayashi, Morinobu Endo, and Katsumi Kaneko pp 12636–12637 DOI: 10.1021/ja064744+ Supporting Info

Solid-State 139La and 15N NMR Spectroscopy of Lanthanum-Containing Metallocenes Hiyam Hamaed, Andy Y. H. Lo, David S. Lee, William J. Evans, and Robert W. Schurko pp 12638–12639 DOI: 10.1021/ja0645180 Supporting Info

Inverted Sapphyrin:  A New Family of Doubly N-Confused Expanded Porphyrins Jonathan L. Sessler, Dong-Gyu Cho, Marcin Stpień, Vincent Lynch, Jacek Waluk, Zin Seok Yoon, and Dongho Kim pp 12640–12641 DOI: 10.1021/ja064675z Supporting Info

Porous Carbon Powders Prepared by Ultrasonic Spray Pyrolysis Sara E. Skrabalak and Kenneth S. Suslick pp 12642–12643 DOI: 10.1021/ja064899h Supporting Info

Facile Ar−CF3 Bond Formation at Pd. Strikingly Different Outcomes of Reductive Elimination from [(Ph3P)2Pd(CF3)Ph] and [(Xantphos)Pd(CF3)Ph] Vladimir V. Grushin and William J. Marshall pp 12644–12645 DOI: 10.1021/ja064935c Supporting Info

Stereoselective Synthesis of Functionalized Pyrrolidines via a [3 + 2]-Annulation of N-Ts-α-Amino Aldehydes and 1,3-Bis(silyl)propenes Per Restorp, Andreas Fischer, and Peter Somfai pp 12646–12647 DOI: 10.1021/ja0647102 Supporting Info

Asymmetric Synergy between Chiral Dienes and Diphosphines in Cationic Rh(I)-Catalyzed Intramolecular [4 + 2] Cycloaddition Kohsuke Aikawa, Susumu Akutagawa, and Koichi Mikami pp 12648–12649 DOI: 10.1021/ja0650100 Supporting Info

Generation of Carbamoyl- and Thiocarbamoyllithium Synthons Having a Hydrogen(s) or an Aryl Group on the Nitrogen and Their Trapping with Carbonyl Electrophiles Nobuaki Kambe, Toru Inoue, Takanobu Takeda, Shin-ichi Fujiwara, and Noboru Sonoda pp 12650–12651 DOI: 10.1021/ja065078f Supporting Info

Organocatalytic Enantioselective Conjugate Additions to Enones Jian Wang, Hao Li, Liansuo Zu, Wei Jiang, Hexin Xie, Wenhu Duan, and Wei Wang pp 12652–12653 DOI: 10.1021/ja065187u Supporting Info

Total Synthesis of (−)-Himgaline Unmesh Shah, Samuel Chackalamannil, Ashit K. Ganguly, Mariappan Chelliah, Sergei Kolotuchin, Alexei Buevich, and Andrew McPhail pp 12654–12655 DOI: 10.1021/ja065198n Supporting Info

A Concise Total Synthesis of dl-Histrionicotoxin Maheswaran S. Karatholuvhu, Alex Sinclair, Annabella F. Newton, Marie-Lyne Alcaraz, Robert A. Stockman, and Philip L. Fuchs pp 12656–12657 DOI: 10.1021/ja065015x Supporting Info

Enantioselective Synthesis of γ-Hydroxyenones by Chiral Base-Catalyzed Kornblum DeLaMare Rearrangement Steven T. Staben, Xin Linghu, and F. Dean Toste pp 12658–12659 DOI: 10.1021/ja065464x Supporting Info

Asymmetric Allylboration of Ketones Catalyzed by Chiral Diols Sha Lou, Philip N. Moquist, and Scott E. Schaus pp 12660–12661 DOI: 10.1021/ja0651308 Supporting Info

Organocatalytic Transfer Hydrogenation of Cyclic Enones Jamison B. Tuttle, Stéphane G. Ouellet, and David W. C. MacMillan pp 12662–12663 DOI: 10.1021/ja0653066 Supporting Info

Antibody Nanoarrays with a Pitch of 20 Nanometers Yu He, Ye Tian, Alexander E. Ribbe, and Chengde Mao pp 12664–12665 DOI: 10.1021/ja065467+ Supporting Info

The Micellar Shuttle:  Thermoreversible, Intact Transfer of Block Copolymer Micelles between an Ionic Liquid and Water Yiyong He and Timothy P. Lodge pp 12666–12667 DOI: 10.1021/ja0655587 Supporting Info

Synthesis and Solution- and Solid-State Characterization of Gold(I) Rings with Short Au···Au Interactions. Spontaneous Resolution of a Gold(I) Complex Andrea Deák, Tünde Megyes, Gábor Tárkányi, Péter Király, László Biczók, Gábor Pálinkás, and Peter J. Stang pp 12668–12670 DOI: 10.1021/ja064609x Supporting Info

Faceting of Nanocrystals during Chemical Transformation:  From Solid Silver Spheres to Hollow Gold Octahedra Yadong Yin, Can Erdonmez, Shaul Aloni, and A. Paul Alivisatos pp 12671–12673 DOI: 10.1021/ja0646038 Supporting Info

Control Over Charge Separation in Phthalocyanine−Anthraquinone Conjugates as a Function of the Aggregation Status Andreas Gouloumis, David González-Rodríguez, Purificación Vázquez, Tomás Torres, Shenggao Liu, Luis Echegoyen, Jeff Ramey, Gordon L. Hug, and Dirk M. Guldi pp 12674–12684 DOI: 10.1021/ja055344+ Supporting Info

The Si−Si Effect on Ionization of β-Disilanyl Sulfides and Selenides Richard S. Glass, Eric Block, Edward Lorance, Uzma I. Zakai, Nadine E. Gruhn, Jin Jin, and Shao-Zhong Zhang pp 12685–12692 DOI: 10.1021/ja0573514 Supporting Info

Behavior of Polycatalytic Assemblies in a Substrate-Displaying Matrix Renjun Pei, Steven K. Taylor, Darko Stefanovic, Sergei Rudchenko, Tiffany E. Mitchell, and Milan N. Stojanovic pp 12693–12699 DOI: 10.1021/ja058394n Supporting Info

Ionic Core−Shell Dendrimers with an Octacationic Core as Noncovalent Supports for Homogeneous Catalysts Rob van de Coevering, Alfred P. Alfers, Johannes D. Meeldijk, Eloísa Martínez-Viviente, Paul S. Pregosin, Robertus J. M. Klein Gebbink, and Gerard van Koten pp 12700–12713 DOI: 10.1021/ja060079t Supporting Info

Soluble Narrow Band Gap and Blue Propylenedioxythiophene-Cyanovinylene Polymers as Multifunctional Materials for Photovoltaic and Electrochromic Applications Barry C. Thompson, Young-Gi Kim, Tracy D. McCarley, and John R. Reynolds pp 12714–12725 DOI: 10.1021/ja061274a Supporting Info

Synthesis of Poly(β-amino ester)s with Thiol-Reactive Side Chains for DNA Delivery Gregory T. Zugates, Daniel G. Anderson, Steven R. Little, Ingrid E. B. Lawhorn, and Robert Langer pp 12726–12734 DOI: 10.1021/ja061570n Supporting Info

Arginine Methylation in a β-Hairpin Peptide:  Implications for Arg−π Interactions, ΔCp°, and the Cold Denatured State Robert M. Hughes and Marcey L. Waters pp 12735–12742 DOI: 10.1021/ja061656g Supporting Info

Conical Intersection Control of Heterocyclic Photochemical Bond Scission1,2 Howard E. Zimmerman and Oleg D. Mitkin pp 12743–12749 DOI: 10.1021/ja061851v Supporting Info

Binding of a Designed Substrate Analogue to Diisopropyl Fluorophosphatase:  Implications for the Phosphotriesterase Mechanism Marc-Michael Blum, Frank Löhr, Andre Richardt, Heinz Rüterjans, and Julian C.-H. Chen pp 12750–12757 DOI: 10.1021/ja061887n Supporting Info

When Is Water Not Water? Exploring Water Confined in Large Reverse Micelles Using a Highly Charged Inorganic Molecular Probe Bharat Baruah, Jennifer M. Roden, Myles Sedgwick, N. Mariano Correa, Debbie C. Crans, and Nancy E. Levinger pp 12758–12765 DOI: 10.1021/ja0624319 Supporting Info

Thermodynamic Basis for Promiscuity and Selectivity in Protein−Protein Interactions:  PDZ Domains, a Case Study Nathalie Basdevant, Harel Weinstein, and Marco Ceruso pp 12766–12777 DOI: 10.1021/ja060830y

Synthesis and Characterization of Iron Silicon Boron (Fe5Si2B) and Iron Boride (Fe3B) Nanowires Yan Li and R. P. H. Chang pp 12778–12784 DOI: 10.1021/ja0610378 Supporting Info

The Mechanism of the Phosphine-Free Palladium-Catalyzed Hydroarylation of Alkynes Mårten Ahlquist, Giancarlo Fabrizi, Sandro Cacchi, and Per-Ola Norrby pp 12785–12793 DOI: 10.1021/ja061543x Supporting Info

Photo-CIDNP MAS NMR in Intact Cells of Rhodobacter sphaeroides R26:  Molecular and Atomic Resolution at Nanomolar Concentration Shipra Prakash, Alia, Peter Gast, Huub J. M. de Groot, Jörg Matysik, and Gunnar Jeschke pp 12794–12799 DOI: 10.1021/ja0623616

Lanthanides to Quantum Dots Resonance Energy Transfer in Time-Resolved Fluoro-Immunoassays and Luminescence Microscopy Loïc J. Charbonnière, Niko Hildebrandt, Raymond F. Ziessel, and Hans-Gerd Löhmannsröben pp 12800–12809 DOI: 10.1021/ja062693a Supporting Info

Sum Frequency Generation Vibrational Spectroscopic and High-Pressure Scanning Tunneling Microscopic Studies of Benzene Hydrogenation on Pt(111) Kaitlin M. Bratlie, Max O. Montano, Lucio D. Flores, Matti Paajanen, and Gabor A. Somorjai pp 12810–12816 DOI: 10.1021/ja0626032

The Catalytic Mechanism of Peptidylglycine α-Hydroxylating Monooxygenase Investigated by Computer Simulation Alejandro Crespo, Marcelo A. Martí, Adrian E. Roitberg, L. Mario Amzel, and Darío A. Estrin pp 12817–12828 DOI: 10.1021/ja062876x Supporting Info

To Achieve Stable Spherical Clusters:  General Principles and Experimental Confirmations Zhongfang Chen, Sven Neukermans, Xin Wang, Ewald Janssens, Zhen Zhou, Roger E. Silverans, R. Bruce King, Paul von Ragué Schleyer, and Peter Lievens pp 12829–12834 DOI: 10.1021/ja062868g Supporting Info

Incremental Solvation of Nonionized and Zwitterionic Glycine Christine M. Aikens and Mark S. Gordon pp 12835–12850 DOI: 10.1021/ja062842p Supporting Info

Gate Dielectric Chemical Structure−Organic Field-Effect Transistor Performance Correlations for Electron, Hole, and Ambipolar Organic Semiconductors Myung-Han Yoon, Choongik Kim, Antonio Facchetti, and Tobin J. Marks pp 12851–12869 DOI: 10.1021/ja063290d Supporting Info

Reversible pH-Driven Conformational Switching of Tethered Superoxide Dismutase with Gold Nanoparticle Enhanced Surface Plasmon Resonance Spectroscopy Taewook Kang, Surin Hong, Inhee Choi, Jung Jun Sung, Younjung Kim, Ji-Sook Hahn, and Jongheop Yi pp 12870–12878 DOI: 10.1021/ja0632198 Supporting Info

Luminescent Triarylborane-Functionalized Polystyrene:  Synthesis, Photophysical Characterization, and Anion-Binding Studies Kshitij Parab, Krishnan Venkatasubbaiah, and Frieder Jäkle pp 12879–12885 DOI: 10.1021/ja063302v Supporting Info

Well-Defined Chiral Spiro Iridium/Phosphine−Oxazoline Cationic Complexes for Highly Enantioselective Hydrogenation of Imines at Ambient Pressure Shou-Fei Zhu, Jian-Bo Xie, Yong-Zhen Zhang, Shen Li, and Qi-Lin Zhou pp 12886–12891 DOI: 10.1021/ja063444p Supporting Info

Raman Thermometry Measurements of Free Evaporation from Liquid Water Droplets Jared D. Smith, Christopher D. Cappa, Walter S. Drisdell, Ronald C. Cohen, and Richard J. Saykally pp 12892–12898 DOI: 10.1021/ja063579v

Functionalization of Single-Walled Carbon Nanotubes “On Water” B. Katherine Price and James M. Tour pp 12899–12904 DOI: 10.1021/ja063609u Supporting Info

Synthesis of Ordered Mesoporous Fe3O4 and γ-Fe2O3 with Crystalline Walls Using Post-Template Reduction/Oxidation Feng Jiao, Jean-Claude Jumas, Manfred Womes, Alan V. Chadwick, Andrew Harrison, and Peter G. Bruce pp 12905–12909 DOI: 10.1021/ja063662i

Structure Determination of Protein−Ligand Complexes by Transferred Paramagnetic Shifts Michael John, Guido Pintacuda, Ah Young Park, Nicholas E. Dixon, and Gottfried Otting pp 12910–12916 DOI: 10.1021/ja063584z Supporting Info

Controlling the Growth of Single Crystalline Nanoribbons of Copper Tetracyanoquinodimethane for the Fabrication of Devices and Device Arrays Yaling Liu, Hongxiang Li, Deyu Tu, Zhuoyu Ji, Congshun Wang, Qingxin Tang, Ming Liu, Wenping Hu, Yunqi Liu, and Daoben Zhu pp 12917–12922 DOI: 10.1021/ja0636183 Supporting Info

Highly Enantioselective Synthesis of Atropisomeric Anilide Derivatives through Catalytic Asymmetric N-Arylation:  Conformational Analysis and Application to Asymmetric Enolate Chemistry Osamu Kitagawa, Masatoshi Yoshikawa, Hajime Tanabe, Tomofumi Morita, Masashi Takahashi, Yasuo Dobashi, and Takeo Taguchi pp 12923–12931 DOI: 10.1021/ja064026n Supporting Info

A Modular Strategy for Tailoring Fluorescent Biosensors from Ribonucleopeptide Complexes Masaki Hagihara, Masatora Fukuda, Tetsuya Hasegawa, and Takashi Morii pp 12932–12940 DOI: 10.1021/ja063965c Supporting Info

Mechanism for Catechol Ring Cleavage by Non-Heme Iron Intradiol Dioxygenases:  A Hybrid DFT Study Tomasz Borowski and Per E. M. Siegbahn pp 12941–12953 DOI: 10.1021/ja0641251 Supporting Info

Hydrogen-Bond-Directed Highly Stereoselective Synthesis of Z-Enamides via Pd-Catalyzed Oxidative Amidation of Conjugated Olefins Ji Min Lee, Doo-Sik Ahn, Doo Young Jung, Junseung Lee, Youngkyu Do, Sang Kyu Kim, and Sukbok Chang pp 12954–12962 DOI: 10.1021/ja0639315 Supporting Info

Molded, High Surface Area Polymer Electrolyte Membranes from Cured Liquid Precursors Zhilian Zhou, Raymond N. Dominey, Jason P. Rolland, Benjamin W. Maynor, Ashish A. Pandya, and Joseph M. DeSimone pp 12963–12972 DOI: 10.1021/ja064391e

Dienamine Catalysis:  Organocatalytic Asymmetric γ-Amination of α,β-Unsaturated Aldehydes Søren Bertelsen, Mauro Marigo, Sebastian Brandes, Peter Dinér, and Karl Anker Jørgensen pp 12973–12980 DOI: 10.1021/ja064637f Supporting Info

A Multistep Oriented Attachment Kinetics:  Coarsening of ZnS Nanoparticle in Concentrated NaOH Jing Zhang, Zhang Lin, Youzhao Lan, Guoqiang Ren, Dagui Chen, Feng Huang, and Maochun Hong pp 12981–12987 DOI: 10.1021/ja062572a

Solution 1H NMR Characterization of the Axial Bonding of the Two His in Oxidized Human Cytoglobin Vasyl Bondarenko, Sylvia Dewilde, Luc Moens, and Gerd N. La Mar pp 12988–12999 DOI: 10.1021/ja063330d Supporting Info

High-Throughput Sequence Determination of Cyclic Peptide Library Members by Partial Edman Degradation/Mass Spectrometry Sang Hoon Joo, Qing Xiao, Yun Ling, Bhaskar Gopishetty, and Dehua Pei pp 13000–13009 DOI: 10.1021/ja063722k Supporting Info

DFT Studies on the Mechanism of Allylative Dearomatization Catalyzed by Palladium Alireza Ariafard and Zhenyang Lin pp 13010–13016 DOI: 10.1021/ja063944i Supporting Info

Hafnocene Catalysts for Selective Propylene Oligomerization:  Efficient Synthesis of 4-Methyl-1-pentene by β-Methyl Transfer Yasuhiko Suzuki, Takahiro Yasumoto, Kazushi Mashima, and Jun Okuda pp 13017–13025 DOI: 10.1021/ja063717g Supporting Info

Five-Order-of-Magnitude Reduction of the Triplet Lifetimes of N-Heterocycles by Complexation to a Trinuclear Mercury Complex [J. Am. Chem. Soc. 2005, 127, 12166−12167]. Charlotte Burress, Oussama Elbjeirami, Mohammad A. Omary, François P. Gabbaï p 13026 DOI: 10.1021/ja066053j

Conformation-Dependent Design of Sequences in Copolymers I and II. Advances in Polymer Science 195 and 196 Edited by Alexei R. Khokhlov (Moscow State University). Springer:  Berlin, Heidelberg, New York. 2006. xiv + 238 pp. $239.00. ISBN 3-540-29513-5 (for I). xiv + 238 pp. $219. ISBN 3-540-29151-1 (for II). Eric Fossum p 13027 DOI: 10.1021/ja0697368

Topics in Stereochemistry, Volume 25 Edited by Scott E. Denmark (University of Illinois, Urbana-Champaign, USA) and Jay S. Siegel (University of Zürich, Switzerland). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xiv + 404 pp. $150.00. ISBN 0-471-68244-6. Bart Kahr pp 13027–13028 DOI: 10.1021/ja069756+

Issue 40

Using Unnatural Protein Fusions to Engineer Resveratrol Biosynthesis in Yeast and Mammalian Cells Yansheng Zhang, Song-Zhe Li, Jia Li, Xiangqing Pan, Rebecca E. Cahoon, Jan G. Jaworski, Xuemin Wang, Joseph M. Jez, Feng Chen, and Oliver Yu pp 13030–13031 DOI: 10.1021/ja0622094 Supporting Info

On the Mechanism of Lead Chalcogenide Nanocrystal Formation Jonathan S. Steckel, Brian K. H. Yen, David C. Oertel, and Moungi G. Bawendi pp 13032–13033 DOI: 10.1021/ja062626g Supporting Info

The Catalytic Power of Uracil DNA Glycosylase in the Opening of Thymine Base Pairs Chunyang Cao, Yu Lin Jiang, Daniel J. Krosky, and James T. Stivers pp 13034–13035 DOI: 10.1021/ja062978n Supporting Info

Pentalenolactone Biosynthesis. Molecular Cloning and Assignment of Biochemical Function to PtlI, a Cytochrome P450 of Streptomyces avermitilis Richard Quaderer, Satoshi Omura, Haruo Ikeda, and David E. Cane pp 13036–13037 DOI: 10.1021/ja0639214 Supporting Info

Electrostatically Controlled Hierarchical Arrangement of Monocationic Silver(I) and Dicationic Mercury(II) Ions between Disk-Shaped Template Ligands Shuichi Hiraoka, Takaaki Tanaka, and Mitsuhiko Shionoya pp 13038–13039 DOI: 10.1021/ja064194f Supporting Info

A Simple Technique To Grow Polymer Brushes Using in Situ Surface Ligation of an Organometallic Initiator Krishna D. Dronavajjala, Ramakrishnan Rajagopalan, Sundararajan Uppili, Ayusman Sen, David L. Allara, and Henry C. Foley pp 13040–13041 DOI: 10.1021/ja064549v Supporting Info

Patterning of Robust Self-Assembled n-type Hexaazatrinaphthylene-Based Nanorods and Nanowires by Microcontact Printing Hin-Lap Yip, Jingyu Zou, Hong Ma, Yanqing Tian, Neil M. Tucker, and Alex K.-Y. Jen pp 13042–13043 DOI: 10.1021/ja064934k Supporting Info

Stabilization of NH Tautomers of Quinolines by Osmium and Ruthenium Miguel A. Esteruelas, Francisco J. Fernández-Alvarez, and Enrique Oñate pp 13044–13045 DOI: 10.1021/ja064979l Supporting Info

Point by Point Comparison of Two Thermosensitive Polymers Exhibiting a Similar LCST:  Is the Age of Poly(NIPAM) Over? Jean-François Lutz, Özgür Akdemir, and Ann Hoth pp 13046–13047 DOI: 10.1021/ja065324n Supporting Info

Proton-Induced Lewis Acidity of Unsaturated Iridium Amides Zachariah M. Heiden and Thomas B. Rauchfuss pp 13048–13049 DOI: 10.1021/ja0653831 Supporting Info

Probing the Reaction Mechanism of the d-ala-d-ala Dipeptidase, VanX, by Using Stopped-Flow Kinetic and Rapid-Freeze Quench EPR Studies on the Co(II)-Substituted Enzyme Megan L. Matthews, Gopalraj Periyannan, Christine Hajdin, Tara K. Sidgel, Brian Bennett, and Michael W. Crowder pp 13050–13051 DOI: 10.1021/ja0627343

Chemoselective Nucleophilic Arylation and Single-Step Oxidative Esterification of Aldehydes Using Siloxanes and a Palladium−Phosphinous Acid as a Reaction Switch Rachel Lerebours and Christian Wolf pp 13052–13053 DOI: 10.1021/ja063476c Supporting Info

Facile Arene C−H Bond Activation and Alkane Dehydrogenation with Anionic LPtIIMe2- in Hydrocarbon−Water Systems (L = Dimethyldi(2-pyridyl)borate) Eugene Khaskin, Peter Y. Zavalij, and Andrei N. Vedernikov pp 13054–13055 DOI: 10.1021/ja0643570 Supporting Info

Soluble Molecular Compounds with the Mg−O−Al Structural Motif:  A Model Approach for the Fixation of Organometallics on a MgO Surface Sharanappa Nembenna, Herbert W. Roesky, Swadhin K. Mandal, Rainer B. Oswald, Aritra Pal, Regine Herbst-Irmer, Mathias Noltemeyer, and Hans-Georg Schmidt pp 13056–13057 DOI: 10.1021/ja064460p Supporting Info

1-Imino Nitroxide Pyrene for High Performance Organic Field-Effect Transistors with Low Operating Voltage Ying Wang, Hongmei Wang, Yunqi Liu, Chong-an Di, Yanming Sun, Weiping Wu, Gui Yu, Deqing Zhang, and Daoben Zhu pp 13058–13059 DOI: 10.1021/ja064580x Supporting Info

Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes Eleuterio Alvarez, Salvador Conejero, Margarita Paneque, Ana Petronilho, Manuel L. Poveda, Oracio Serrano, and Ernesto Carmona pp 13060–13061 DOI: 10.1021/ja0646592 Supporting Info

Diastereomerically-Specific Zirconium Complexes of Chiral Salan Ligands:  Isospecific Polymerization of 1-Hexene and 4-Methyl-1-pentene and Cyclopolymerization of 1,5-Hexadiene Adi Yeori, Israel Goldberg, Michael Shuster, and Moshe Kol pp 13062–13063 DOI: 10.1021/ja0647654 Supporting Info

Highly Efficient Oxidative Amidation of Aldehydes with Amine Hydrochloride Salts Woo-Jin Yoo and Chao-Jun Li pp 13064–13065 DOI: 10.1021/ja064315b Supporting Info

Stereocontrolled Synthesis of β-d-Mannuronic Acid Esters:  Synthesis of an Alginate Trisaccharide Leendert J. van den Bos, Jasper Dinkelaar, Herman S. Overkleeft, and Gijsbert A. van der Marel pp 13066–13067 DOI: 10.1021/ja064787q Supporting Info

Switching of Structural Order in a Cross-Linked Polymer Triggered by the Desorption/Adsorption of Guest Molecules Yasuhiro Ishida, Sayaka Amano, Nobutaka Iwahashi, and Kazuhiko Saigo pp 13068–13069 DOI: 10.1021/ja064969k Supporting Info

Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction Takahiko Akiyama, Hisashi Morita, and Kohei Fuchibe pp 13070–13071 DOI: 10.1021/ja064676r Supporting Info

Facile Transformation of Benzocyclobutenones into 2,3-Benzodiazepines via 4π−8π Tandem Electrocyclic Reactions Involving Net Insertion of Diazomethylene Compounds Yuji Matsuya, Noriko Ohsawa, and Hideo Nemoto pp 13072–13073 DOI: 10.1021/ja065277z Supporting Info

Catalytic Asymmetric Reductive Amination of Aldehydes via Dynamic Kinetic Resolution Sebastian Hoffmann, Marcello Nicoletti, and Benjamin List pp 13074–13075 DOI: 10.1021/ja065404r Supporting Info

Kinetic Effects of Hydrogen Bonds on Proton-Coupled Electron Transfer from Phenols Martin Sjödin, Tania Irebo, Josefin E. Utas, Johan Lind, Gabor Merényi, Björn Åkermark, and Leif Hammarström pp 13076–13083 DOI: 10.1021/ja063264f

Self-Assembly of Small Gold Nanoparticles through Interligand Interaction Masayuki Kanehara, Etsushi Kodzuka, and Toshiharu Teranishi pp 13084–13094 DOI: 10.1021/ja064510q Supporting Info

Enantioselective Total Synthesis of Guanacastepene N Using an Uncommon 7-Endo Heck Cyclization as a Pivotal Step Shin Iimura, Larry E. Overman, Ralph Paulini, and Armen Zakarian pp 13095–13101 DOI: 10.1021/ja0650504 Supporting Info

EPR−ENDOR of the Cu(I)NO Complex of Nitrite Reductase Oleg M. Usov, Yan Sun, Vladimir M. Grigoryants, James P. Shapleigh, and Charles P. Scholes pp 13102–13111 DOI: 10.1021/ja056166n Supporting Info

Automated Protein Structure Determination from NMR Spectra Blanca López-Méndez and Peter Güntert pp 13112–13122 DOI: 10.1021/ja061136l Supporting Info

Amphiphilic Poly(phenyleneethynylene)s Can Mimic Antimicrobial Peptide Membrane Disordering Effect by Membrane Insertion Yuji Ishitsuka, Lachelle Arnt, Jaroslaw Majewski, Shelli Frey, Maria Ratajczek, Kristian Kjaer, Gregory N. Tew, and Ka Yee C. Lee pp 13123–13129 DOI: 10.1021/ja061186q

Interplay of Structure and Reactivity in a Most Unusual Furan Diels-Alder Reaction Gerry A. Griffith, Ian H. Hillier, Andrew C. Moralee, Jonathan M. Percy, Ricard Roig, and Mark A. Vincent pp 13130–13141 DOI: 10.1021/ja061458p Supporting Info

Generation of Oxynitrenes and Confirmation of Their Triplet Ground States Walter A. Wasylenko, Naod Kebede, Brett M. Showalter, Nikita Matsunaga, Alexander P. Miceli, Yonglin Liu, Lev R. Ryzhkov, Christopher M. Hadad, and John P. Toscano pp 13142–13150 DOI: 10.1021/ja062712g Supporting Info

Theoretical Studies on the Bifunctionality of Chiral Thiourea-Based Organocatalysts:  Competing Routes to C−C Bond Formation Andrea Hamza, Gábor Schubert, Tibor Soós, and Imre Pápai pp 13151–13160 DOI: 10.1021/ja063201x Supporting Info

Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy Ronan Le Toquin, Werner Paulus, Alain Cousson, Carmelo Prestipino, and Carlo Lamberti pp 13161–13174 DOI: 10.1021/ja063207m Supporting Info

Ligand Redox Effects in the Synthesis, Electronic Structure, and Reactivity of an Alkyl−Alkyl Cross-Coupling Catalyst Gavin D. Jones, Jason L. Martin, Chris McFarland, Olivia R. Allen, Ryan E. Hall, Aireal D. Haley, R. Jacob Brandon, Tatyana Konovalova, Patrick J. Desrochers, Peter Pulay, and David A. Vicic pp 13175–13183 DOI: 10.1021/ja063334i Supporting Info

Cation−π Interaction in the Polyolefin Cyclization Cascade Uncovered by Incorporating Unnatural Amino Acids into the Catalytic Sites of Squalene Cyclase Noriko Morikubo, Yoriyuki Fukuda, Kazumasa Ohtake, Naoko Shinya, Daisuke Kiga, Kensaku Sakamoto, Miwako Asanuma, Hiroshi Hirota, Shigeyuki Yokoyama, and Tsutomu Hoshino pp 13184–13194 DOI: 10.1021/ja063358p Supporting Info

Giant Excitonic Zeeman Splittings in Colloidal Co2+-Doped ZnSe Quantum Dots Nick S. Norberg, Gregory L. Parks, G. Mackay Salley, and Daniel R. Gamelin pp 13195–13203 DOI: 10.1021/ja063425f

QM/MM Study of Mechanisms for Compound I Formation in the Catalytic Cycle of Cytochrome P450cam Jingjing Zheng, Dongqi Wang, Walter Thiel, and Sason Shaik pp 13204–13215 DOI: 10.1021/ja063439l Supporting Info

A Point Mutation Converts Dihydroneopterin Aldolase to a Cofactor-Independent Oxygenase Yi Wang, Gwynyth Scherperel, Kade D. Roberts, A. Daniel Jones, Gavin E. Reid, and Honggao Yan pp 13216–13223 DOI: 10.1021/ja063455i Supporting Info

Observation of Highly Flexible Residues in Amyloid Fibrils of the HET-s Prion Ansgar B. Siemer, Alexandre A. Arnold, Christiane Ritter, Thomas Westfeld, Matthias Ernst, Roland Riek, and Beat H. Meier pp 13224–13228 DOI: 10.1021/ja063639x Supporting Info

Hydrogen and Deuterium Exchange on Pt(111) and Its Poisoning by Carbon Monoxide Studied by Surface Sensitive High-Pressure Techniques Max Montano, Kaitlin Bratlie, Miquel Salmeron, and Gabor A. Somorjai pp 13229–13234 DOI: 10.1021/ja063703a

Rational Design of a β-Lactamase Inhibitor Achieved via Stabilization of the trans-Enamine Intermediate:  1.28 Å Crystal Structure of wt SHV-1 Complex with a Penam Sulfone Pius S. Padayatti, Anjaneyulu Sheri, Monica A. Totir, Marion S. Helfand, Marianne P. Carey, Vernon E. Anderson, Paul R. Carey, Christopher R. Bethel, Robert A. Bonomo, John D. Buynak, and Focco van den Akker pp 13235–13242 DOI: 10.1021/ja063715w Supporting Info

Distance-Dependent Emission from Dye-Labeled Oligonucleotides on Striped Au/Ag Nanowires:  Effect of Secondary Structure and Hybridization Efficiency Rebecca L. Stoermer and Christine D. Keating pp 13243–13254 DOI: 10.1021/ja0637200

Total Synthesis of (+)-Batzelladine A and (−)-Batzelladine D via [4 + 2]-Annulation of Vinyl Carbodiimides with N-Alkyl Imines Michael A. Arnold, Kenneth A. Day, Sergio G. Durón, and David Y. Gin pp 13255–13260 DOI: 10.1021/ja063860+ Supporting Info

A New Concept for the Noncovalent Binding of a Ruthenium-Based Olefin Metathesis Catalyst to Polymeric Phases:  Preparation of a Catalyst on Raschig Rings Anna Michrowska, Klaas Mennecke, Ulrich Kunz, Andreas Kirschning, and Karol Grela pp 13261–13267 DOI: 10.1021/ja063561k Supporting Info

The 1/1 and 2/1 Approximants in the Sc−Mg−Zn Quasicrystal System:  Triacontahedral Clusters as Fundamental Building Blocks Qisheng Lin and John D. Corbett pp 13268–13273 DOI: 10.1021/ja063897u Supporting Info

Designing 129Xe NMR Biosensors for Matrix Metalloproteinase Detection Qian Wei, Garry K. Seward, P. Aru Hill, Brian Patton, Ivan E. Dimitrov, Nicholas N. Kuzma, and Ivan J. Dmochowski pp 13274–13283 DOI: 10.1021/ja0640501 Supporting Info

Modular α-Helical Mimetics with Antiviral Activity against Respiratory Syncitial Virus Nicholas E. Shepherd, Huy N. Hoang, Vishal S. Desai, Eric Letouze, Paul R. Young, and David P. Fairlie pp 13284–13289 DOI: 10.1021/ja064058a Supporting Info

Modular Catalysts for Diene Cycloisomerization:  Rapid and Enantioselective Variants for Bicyclopropane Synthesis Jeremy A. Feducia, Alison N. Campbell, Michael Q. Doherty, and Michel R. Gagné pp 13290–13297 DOI: 10.1021/ja064335d Supporting Info

Molecular-Level Helical Stack of a Nucleotide-Appended Oligo(p-phenylenevinylene) Directed by Supramolecular Self-Assembly with a Complementary Oligonucleotide as a Template Rika Iwaura, Freek J. M. Hoeben, Mitsutoshi Masuda, Albertus P. H. J. Schenning, E. W. Meijer, and Toshimi Shimizu pp 13298–13304 DOI: 10.1021/ja064560v Supporting Info

Supramolecular Nanopatterns Self-Assembled by Adenine−Thymine Quartets at the Liquid/Solid Interface Wael Mamdouh, Mingdong Dong, Sailong Xu, Eva Rauls, and Flemming Besenbacher pp 13305–13311 DOI: 10.1021/ja064988u Supporting Info

Phosphine−Substrate Recognition through the CH···O Hydrogen Bond:  Application to the Asymmetric Pauson−Khand Reaction [J. Am. Chem. Soc. 2005, 127, 13629−13633]. Jordi Solà, Antoni Riera, Xavier Verdaguer, and Miguel A. Maestro p 13312 DOI: 10.1021/ja066395p

The Interaction of Water with MOF-5 Simulated by Molecular Dynamics [J. Am. Chem. Soc. 2006, 128, 10678−10679]. Jeffery A. Greathouse and Mark D. Allendorf p 13312 DOI: 10.1021/ja069972i Supporting Info

NMRPredict Modgraph Consultants, Ltd, 1348 Graham Place, Escondido, CA 92129. http://www.modgraph-usa.com. Contact company for pricing information. Anita J. Brandolini p 13313 DOI: 10.1021/ja059832t

Chemical Genomics:  Small Molecule Probes to Study Cellular Function. Ernst Schering Research Foundation Workshop 58 Edited by Stefan Jaroch and Hilmar Weinmann (Schering AG, Berlin). Springer:  Berlin, Heidelberg, New York. 2006. xiv + 180 pp. $79.95. ISBN 3-540-27865-6. p 13314 DOI: 10.1021/ja0697727

Carbohydrate Drug Design Edited by Anatole A. Klyosov (Pro-Pharmaceuticals, Inc., Newton, MA), Zbigniew J. Witczak (Wilkes University, Wilkes-Barre, PA), and David Platt (Pro-Pharmaceuticals, Inc.). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2006. xii + 324 pp. $189.50. ISBN 0-8412-3946-0. p 13314 DOI: 10.1021/ja069773z

Progress in Colloid and Polymer Science:  Characterization of Polymer Surfaces and Thin Films, Volume 132, 2006 Edited by Karina Grundke, Manfred Stamm (Leibniz Institute of Polymer Research, Dresden, Germany), and Hans-Jürgen P. Adler (Technische Universität). Series Edited by K. Kremer and W. Richtering. Springer:  Berlin, Heidelberg. 2006. viii + 172 pp. $189. ISBN 3-540-31241-2. p 13314 DOI: 10.1021/ja0697828

Combinatorial Chemistry:  From Theory to Application, Second Revised Edition, Volume 26 Edited by Willi Bannwarth (Universität Freiburg, Germany) and Berthold Hinzen (Bayer AG, Wuppertal, Germany). Series Edited by R. Mannhold, H. Kubinyi, and G. Folkers. Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xxii + 672 pp. $205. ISBN 3-527-30693-5. p 13314 DOI: 10.1021/ja069784s

Microwave Assisted Organic Synthesis Edited by Jason P. Tierney (GlaxoSmithKline, Harlow, UK) and Pelle Lidström (Biotage AB, Uppsala, Sweden). Blackwell Publishing and CRC Press:  Oxford, UK and Boca Raton, FL, USA. 2005. xii + 280 pp. $149.95. ISBN 0-8493-2371-1. George Majetich pp 13314–13315 DOI: 10.1021/ja059817o

Radicals in Synthesis II:  Complex Molecules. Topics in Current Chemistry, 264 Edited by Andreas Gansäuer (Universität Bonn, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xii + 250 pp. $249.00. ISBN 3-540-31325-7. Rebecca Braslau pp 13315–13316 DOI: 10.1021/ja069761d

Issue 41

A Large Protonated Water Cluster H+(H2O)27 in a 3D Metal−Organic Framework Meilin Wei, Cheng He, Weijie Hua, Chunying Duan, Shuhua Li, and Qingjin Meng pp 13318–13319 DOI: 10.1021/ja0611184 Supporting Info

A Ratiometric CdSe/ZnS Nanocrystal pH Sensor Preston T. Snee, Rebecca C. Somers, Gautham Nair, John P. Zimmer, Moungi G. Bawendi, and Daniel G. Nocera pp 13320–13321 DOI: 10.1021/ja0618999 Supporting Info

Enantioselectivity of Redox Reaction of DOPA at the Gold Electrode Modified with a Self-Assembled Monolayer of Homocysteine Takuya Nakanishi, Mariko Matsunaga, Makoto Nagasaka, Toru Asahi, and Tetsuya Osaka pp 13322–13323 DOI: 10.1021/ja062380f Supporting Info

Aggregation of the Amphipathic Peptides (AAKA)n into Antiparallel β-Sheets Thomas J. Measey and Reinhard Schweitzer-Stenner pp 13324–13325 DOI: 10.1021/ja0632411 Supporting Info

Determination of Enantiomeric Excess and Concentration of Unprotected Amino Acids, Amines, Amino Alcohols, and Carboxylic Acids by Competitive Binding Assays with a Chiral Scandium Complex Xuefeng Mei and Christian Wolf pp 13326–13327 DOI: 10.1021/ja0636486 Supporting Info

Palladium-Catalyzed Asymmetric [3 + 2] Trimethylenemethane Cycloaddition Reactions Barry M. Trost, James P. Stambuli, Steven M. Silverman, and Ulrike Schwörer pp 13328–13329 DOI: 10.1021/ja0640750 Supporting Info

Gold Nanoparticles Propulsion from Surface Fueled by Absorption of Femtosecond Laser Pulse at Their Surface Plasmon Resonance Wenyu Huang, Wei Qian, and Mostafa A. El-Sayed pp 13330–13331 DOI: 10.1021/ja064328p Supporting Info

At Least Three Contiguous Atoms Are Necessary for CO Formation during Methanol Electrooxidation on Platinum Angel Cuesta pp 13332–13333 DOI: 10.1021/ja0644172 Supporting Info

Infrared Line Shape of an α-Carbon Deuterium-Labeled Amino Acid Carrie S. Kinnaman, Matthew E. Cremeens, Floyd E. Romesberg, and Steven A. Corcelli pp 13334–13335 DOI: 10.1021/ja064468z Supporting Info

An Easy Way to Sugar-Containing Polymer Vesicles or Glycosomes Liangchen You and Helmut Schlaad pp 13336–13337 DOI: 10.1021/ja064569x Supporting Info

Synthesis of Single- and Double-Walled Carbon Nanotube Forests on Conducting Metal Foils Tatsuki Hiraoka, Takeo Yamada, Kenji Hata, Don N. Futaba, Hiroyuki Kurachi, Sashirou Uemura, Motoo Yumura, and Sumio Iijima pp 13338–13339 DOI: 10.1021/ja0643772 Supporting Info

Iron-Catalyzed [2π + 2π] Cycloaddition of α,ω-Dienes:  The Importance of Redox-Active Supporting Ligands Marco W. Bouwkamp, Amanda C. Bowman, Emil Lobkovsky, and Paul J. Chirik pp 13340–13341 DOI: 10.1021/ja064711u Supporting Info

Patterned Metal Nanowire Arrays from Photolithographically-Modified Templates Feng Li, Mo Zhu, Changgeng Liu, Weilie L. Zhou, and John B. Wiley pp 13342–13343 DOI: 10.1021/ja0647856 Supporting Info

Complementary Segmental Labeling of Large RNAs:  Economic Preparation and Simplified NMR Spectra for Measurement of More RDCs Andreas G. Tzakos, Laura E. Easton, and Peter J. Lukavsky pp 13344–13345 DOI: 10.1021/ja064807o Supporting Info

Pyrones to Pyrans:  Enantioselective Radical Additions to Acyloxy Pyrones Mukund P. Sibi and Jake Zimmerman pp 13346–13347 DOI: 10.1021/ja0648108 Supporting Info

Lipid Encapsulation of Arsenic Trioxide Attenuates Cytotoxicity and Allows for Controlled Anticancer Drug Release Haimei Chen, Robert C. MacDonald, Shuyou Li, Nancy L. Krett, Steven T. Rosen, and Thomas V. O'Halloran pp 13348–13349 DOI: 10.1021/ja064864h Supporting Info

Base and Phosphate Electron Detachment Energies of Deoxyribonucleotide Anions Viatcheslav V. Zakjevskii, Samuel J. King, Olga Dolgounitcheva, Viatcheslav G. Zakrzewski, and Joseph Vincent Ortiz pp 13350–13351 DOI: 10.1021/ja064621p Supporting Info

The Elusive Mechanism of Olefin Metathesis Promoted by (NHC)Ru-Based Catalysts:  A Trade between Steric, Electronic, and Solvent Effects Andrea Correa and Luigi Cavallo pp 13352–13353 DOI: 10.1021/ja064924j Supporting Info

Layered Oxysulfides Sr2MnO2Cu2m-0.5Sm+1 (m = 1, 2, and 3) as Insertion Hosts for Li Ion Batteries Sylvio Indris, Jordi Cabana, Oliver J. Rutt, Simon J. Clarke, and Clare P. Grey pp 13354–13355 DOI: 10.1021/ja064961a Supporting Info

Site-Specific Conversion of Cysteine Thiols into Thiocyanate Creates an IR Probe for Electric Fields in Proteins Aaron T. Fafarman, Lauren J. Webb, Jessica I. Chuang, and Steven G. Boxer pp 13356–13357 DOI: 10.1021/ja0650403 Supporting Info

A Biocompatible Method of Decorporation:  Bisphosphonate-Modified Magnetite Nanoparticles to Remove Uranyl Ions from Blood Ling Wang, Zhimou Yang, Jinhao Gao, Keming Xu, Hongwei Gu, Bei Zhang, Xixiang Zhang, and Bing Xu pp 13358–13359 DOI: 10.1021/ja0651355 Supporting Info

The Open Structure of a Multi-Drug-Resistant HIV-1 Protease is Stabilized by Crystal Packing Contacts Melinda Layten, Viktor Hornak, and Carlos Simmerling pp 13360–13361 DOI: 10.1021/ja065133k Supporting Info

Dipolar Control of Monolayer Morphology:  Spontaneous SAM Patterning Yanhu Wei, Wenjun Tong, Cynthia Wise, Xiaoliang Wei, Kurt Armbrust, and Matthew Zimmt pp 13362–13363 DOI: 10.1021/ja065338t Supporting Info

Unique Aggregation of Anthrax (Bacillus anthracis) Spores by Sugar-Coated Single-Walled Carbon Nanotubes Haifang Wang, Lingrong Gu, Yi Lin, Fushen Lu, Mohammed J. Meziani, Pengju G. Luo, Wei Wang, Li Cao, and Ya-Ping Sun pp 13364–13365 DOI: 10.1021/ja065455o

Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes Toshimichi Ohmura, Hideki Furukawa, and Michinori Suginome pp 13366–13367 DOI: 10.1021/ja065588+ Supporting Info

Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones Nolwenn J. A. Martin and Benjamin List pp 13368–13369 DOI: 10.1021/ja065708d Supporting Info

Catalytic, Enantioselective Bifunctional Inverse Electron Demand Hetero-Diels−Alder Reactions of Ketene Enolates and o-Benzoquinone Diimides Ciby J. Abraham, Daniel H. Paull, Michael T. Scerba, James W. Grebinski, and Thomas Lectka pp 13370–13371 DOI: 10.1021/ja065754d Supporting Info

Multicolor Microwave-Triggered Metal-Enhanced Chemiluminescence Kadir Aslan, Stuart N. Malyn, and Chris D. Geddes pp 13372–13373 DOI: 10.1021/ja065571r Supporting Info

Electrochemical Real-Time Polymerase Chain Reaction Stephen S. W. Yeung, Thomas M. H. Lee, and I-Ming Hsing pp 13374–13375 DOI: 10.1021/ja065733j Supporting Info

The Design and Investigation of Room Temperature Thermotropic Nematic Gold Nanoparticles Liliana Cseh and Georg H. Mehl pp 13376–13377 DOI: 10.1021/ja066099c Supporting Info

Organic−Organic Epitaxy of Incommensurate Systems:  Quaterthiophene on Potassium Hydrogen Phthalate Single Crystals Marcello Campione, Adele Sassella, Massimo Moret, Antonio Papagni, Silvia Trabattoni, Roland Resel, Ondrej Lengyel, Valentina Marcon, and Guido Raos pp 13378–13387 DOI: 10.1021/ja058771w

Thermal Denaturing of Mutant Lysozyme with Both the OPLSAA and the CHARMM Force Fields Maria Eleftheriou, Robert S. Germain, Ajay K. Royyuru, and Ruhong Zhou pp 13388–13395 DOI: 10.1021/ja060972s Supporting Info

Time-Dependent Photoluminescence Blue Shift of the Quantum Dots in Living Cells:  Effect of Oxidation by Singlet Oxygen Yu Zhang, Jia He, Pei-Nan Wang, Ji-Yao Chen, Zhou-Jun Lu, Da-Ru Lu, Jia Guo, Chang-Chun Wang, and Wu-Li Yang pp 13396–13401 DOI: 10.1021/ja061225y

Early Events in the Photochemistry of Aryl Azides from Femtosecond UV/Vis Spectroscopy and Quantum Chemical Calculations Gotard Burdzinski, John C Hackett, Jin Wang, Terry L. Gustafson, Christopher M. Hadad, and Matthew S. Platz pp 13402–13411 DOI: 10.1021/ja061520i Supporting Info

Dramatic Acceleration of Olefin Epoxidation in Fluorinated Alcohols:  Activation of Hydrogen Peroxide by Multiple H-Bond Networks Albrecht Berkessel and Jens A. Adrio pp 13412–13420 DOI: 10.1021/ja0620181 Supporting Info

Targeted Acquisition for Real-Time NMR Spectroscopy Victor A. Jaravine and Vladislav Yu. Orekhov pp 13421–13426 DOI: 10.1021/ja062146p

Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies Ingo Krossing, John M. Slattery, Corinne Daguenet, Paul J. Dyson, Alla Oleinikova, and Hermann Weingärtner pp 13427–13434 DOI: 10.1021/ja0619612 Supporting Info

Free-Energy Landscape for β Hairpin Folding from Combined Parallel Tempering and Metadynamics Giovanni Bussi, Francesco Luigi Gervasio, Alessandro Laio, and Michele Parrinello pp 13435–13441 DOI: 10.1021/ja062463w

A Europium(III) Complex as an Efficient Singlet Oxygen Luminescence Probe Bo Song, Guilan Wang, Mingqian Tan, and Jingli Yuan pp 13442–13450 DOI: 10.1021/ja062990f Supporting Info

Proline Zwitterion Dynamics in Solution, Glass, and Crystalline State Josef Kapitán, Vladimír Baumruk, Vladimír Kopecký, Jr., Radek Pohl, and Petr Bouř pp 13451–13462 DOI: 10.1021/ja062958l Supporting Info

Sorptive Reconstruction of CuMCl4 (M = Al and Ga) upon Small-Molecule Binding and the Competitive Binding of CO and Ethylene Michael D. Capracotta, Roger M. Sullivan, and James D. Martin pp 13463–13473 DOI: 10.1021/ja063172q Supporting Info

Sensitivity Enhancement of Multidimensional NMR Experiments by Paramagnetic Relaxation Effects Sheng Cai, Candace Seu, Zoltan Kovacs, A. Dean Sherry, and Yuan Chen pp 13474–13478 DOI: 10.1021/ja0634526

Characterization of Self-Assembled Monolayers of Fullerene Derivatives on Gold Surfaces:  Implications for Device Evaluations Yasuhiro Shirai, Long Cheng, Bo Chen, and James M. Tour pp 13479–13489 DOI: 10.1021/ja063451d Supporting Info

Hydrophobic and Ionic Interactions in Nanosized Water Droplets S. Vaitheeswaran and D. Thirumalai pp 13490–13496 DOI: 10.1021/ja063445h Supporting Info

Exchange Coupling Mediated Through-Bonds and Through-Space in Conformationally Constrained Polyradical Scaffolds:  Calix[4]arene Nitroxide Tetraradicals and Diradical Andrzej Rajca, Sumit Mukherjee, Maren Pink, and Suchada Rajca pp 13497–13507 DOI: 10.1021/ja063567+ Supporting Info

Residual Dipolar Couplings in Short Peptides Reveal Systematic Conformational Preferences of Individual Amino Acids Sonja Alexandra Dames, Regula Aregger, Navratna Vajpai, Pau Bernado, Martin Blackledge, and Stephan Grzesiek pp 13508–13514 DOI: 10.1021/ja063606h

Octahedral Non-Heme Oxo and Non-Oxo Fe(IV) Complexes:  An Experimental/Theoretical Comparison John F. Berry, Eckhard Bill, Eberhard Bothe, Frank Neese, and Karl Wieghardt pp 13515–13528 DOI: 10.1021/ja063590v Supporting Info

Blood Group B Galactosyltransferase:  Insights into Substrate Binding from NMR Experiments Jesus Angulo, Brigitte Langpap, Astrid Blume, Thorsten Biet, Bernd Meyer, N. Rama Krishna, Hannelore Peters, Monica M. Palcic, and Thomas Peters pp 13529–13538 DOI: 10.1021/ja063550r Supporting Info

Effects of the Alternating Backbone Configuration on the Secondary Structure and Self-Assembly of β-Peptides Tamás A. Martinek, István M. Mándity, Lívia Fülöp, Gábor K. Tóth, Elemér Vass, Miklós Hollósi, Eniko Forró, and Ferenc Fülöp pp 13539–13544 DOI: 10.1021/ja063890c Supporting Info

Solid-State NMR of a Paramagnetic DIAD-FeII Catalyst:  Sensitivity, Resolution Enhancement, and Structure-Based Assignments Gwendal Kervern, Guido Pintacuda, Yong Zhang, Eric Oldfield, Charbel Roukoss, Emile Kuntz, Eberhardt Herdtweck, Jean-Marie Basset, Sylvian Cadars, Anne Lesage, Christophe Copéret, and Lyndon Emsley pp 13545–13552 DOI: 10.1021/ja063510n Supporting Info

Photon Gated Transport at the Glass Nanopore Electrode Gangli Wang, Andrew K. Bohaty, Ilya Zharov, and Henry S. White pp 13553–13558 DOI: 10.1021/ja064274j Supporting Info

Energy-Resolved Photoionization of Alkylperoxy Radicals and the Stability of Their Cations Giovanni Meloni, Peng Zou, Stephen J. Klippenstein, Musahid Ahmed, Stephen R. Leone, Craig A. Taatjes, and David L. Osborn pp 13559–13567 DOI: 10.1021/ja064556j Supporting Info

Assisted Desolvation as a Key Kinetic Step for Crystal Growth Stefano Piana, Franca Jones, and Julian D Gale pp 13568–13574 DOI: 10.1021/ja064706q Supporting Info

Neutral and Zwitterionic Low-Coordinate Titanium Complexes Bearing the Terminal Phosphinidene Functionality. Structural, Spectroscopic, Theoretical, and Catalytic Studies Addressing the Ti−P Multiple Bond Guangyu Zhao, Falguni Basuli, Uriah J. Kilgore, Hongjun Fan, Halikhedkar Aneetha, John C. Huffman, Gang Wu, and Daniel J. Mindiola pp 13575–13585 DOI: 10.1021/ja064853o Supporting Info

Effects of Lysine Acetylation in a β-Hairpin Peptide:  Comparison of an Amide−π and a Cation−π Interaction Robert M. Hughes and Marcey L. Waters pp 13586–13591 DOI: 10.1021/ja0648460 Supporting Info

Color Fingerprinting of Proteins by Calixarenes Embedded in Lipid/Polydiacetylene Vesicles Sofiya Kolusheva, Reza Zadmard, Thomas Schrader, and Raz Jelinek pp 13592–13598 DOI: 10.1021/ja064957z Supporting Info

Kinetics and Mechanism of Ketone Enolization Mediated by Magnesium Bis(hexamethyldisilazide) Xuyang He, J. Jacob Morris, Bruce C. Noll, Seth N. Brown, and Kenneth W. Henderson pp 13599–13610 DOI: 10.1021/ja064927w Supporting Info

Thermodynamic and Kinetic Studies on the Binding of Nitric Oxide to a New Enzyme Mimic of Cytochrome P450 Alicja Franke, Natalya Hessenauer-Ilicheva, Dominik Meyer, Grażyna Stochel, Wolf-D. Woggon, and Rudi van Eldik pp 13611–13624 DOI: 10.1021/ja060650o Supporting Info

Amorphous Linear Aliphatic Polyesters for the Facile Preparation of Tunable Rapidly Degrading Elastomeric Devices and Delivery Vectors David A. Olson, Stephanie E. A. Gratton, Joseph M. DeSimone, and Valerie V. Sheares pp 13625–13633 DOI: 10.1021/ja063092m Supporting Info

Electronic Structure and Stability of Pentaorganosilicates Erik P. A. Couzijn, Andreas W. Ehlers, Marius Schakel, and Koop Lammertsma pp 13634–13639 DOI: 10.1021/ja0645887 Supporting Info

Racemization in Prins Cyclization Reactions Ramesh Jasti and Scott D. Rychnovsky pp 13640–13648 DOI: 10.1021/ja064783l Supporting Info

ChemDraw Ultra 10.0 CambridgeSoft, 100 CambridgePark Drive, Cambridge, MA 02140. www.cambridgesoft.com. Commercial Price:  $1910 for download, $2150 for CD-ROM; Academic Price:  $710 for download, $800 for CD-ROM. Nancy Mills pp 13649–13650 DOI: 10.1021/ja0697875

Issue 42

Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts:  A Further Step toward an Optimum Balance between Antinomic Properties Michał Bieniek, Robert Bujok, Maciej Cabaj, Noël Lugan, Guy Lavigne, Dieter Arlt, and Karol Grela pp 13652–13653 DOI: 10.1021/ja063186w Supporting Info

Electron Transfer Reactions of Fluorotyrosyl Radicals Steven Y. Reece, Mohammad R. Seyedsayamdost, JoAnne Stubbe, and Daniel G. Nocera pp 13654–13655 DOI: 10.1021/ja0636688 Supporting Info

Lipid-Carbon Nanotube Self-Assembly in Aqueous Solution Rui Qiao and Pu Chun Ke pp 13656–13657 DOI: 10.1021/ja063977y Supporting Info

Anionic Rare-Earth Thiocyanate Complexes as Building Blocks for Low-Melting Metal-Containing Ionic Liquids Peter Nockemann, Ben Thijs, Niels Postelmans, Kristof Van Hecke, Luc Van Meervelt, and Koen Binnemans pp 13658–13659 DOI: 10.1021/ja0640391 Supporting Info

Fluxional Additives:  A Second Generation Control in Enantioselective Catalysis Mukund P. Sibi, Shankar Manyem, and Hector Palencia pp 13660–13661 DOI: 10.1021/ja064472a Supporting Info

Oxazole-Based Peptide Macrocycles:  A New Class of G-Quadruplex Binding Ligands Katja Jantos, Raphaël Rodriguez, Sylvain Ladame, Pravin S. Shirude, and Shankar Balasubramanian pp 13662–13663 DOI: 10.1021/ja064713e Supporting Info

Periodic Arrangement of Silica Nanospheres Assisted by Amino Acids Toshiyuki Yokoi, Yasuhiro Sakamoto, Osamu Terasaki, Yoshihiro Kubota, Tatsuya Okubo, and Takashi Tatsumi pp 13664–13665 DOI: 10.1021/ja065071y Supporting Info

Label-Free and Reagentless Aptamer-Based Sensors for Small Molecules Maya Zayats, Ye Huang, Ron Gill, Chun-an Ma, and Itamar Willner pp 13666–13667 DOI: 10.1021/ja0651456

Circumventing the Problems Caused by Protein Diversity in Microarrays:  Implications for Protein Interaction Networks Andrew Gordus and Gavin MacBeath pp 13668–13669 DOI: 10.1021/ja065381g Supporting Info

Surface-Mediated Growth of Transparent, Oriented, and Well-Defined Nanocrystalline Anatase Titania Films Donghai Wang, Jun Liu, Qisheng Huo, Zimin Nie, Weigang Lu, Rick E. Williford, and Ying-Bing Jiang pp 13670–13671 DOI: 10.1021/ja0655993 Supporting Info

Platinum Promoted Insertion of an Alkyne into a Metal−Hydrogen Bond Richard D. Adams, Burjor Captain, and Lei Zhu pp 13672–13673 DOI: 10.1021/ja0657152 Supporting Info

High Yield Syntheses of Stable, Singly Bonded Pd26+ Compounds F. Albert Cotton, Igor O. Koshevoy, Pascual Lahuerta, Carlos A. Murillo, Mercedes Sanaú, M. Angeles Ubeda, and Qinliang Zhao pp 13674–13675 DOI: 10.1021/ja0656595 Supporting Info

Potentiometric Biosensing of Proteins with Ultrasensitive Ion-Selective Microelectrodes and Nanoparticle Labels Karin Y. Chumbimuni-Torres, Zong Dai, Nastassia Rubinova, Yun Xiang, Ernö Pretsch, Joseph Wang, and Eric Bakker pp 13676–13677 DOI: 10.1021/ja065899k Supporting Info

Cellular Immobilization within Microfluidic Microenvironments:  Dielectrophoresis with Polyelectrolyte Multilayers Samuel P. Forry, Darwin R. Reyes, Michael Gaitan, and Laurie E. Locascio pp 13678–13679 DOI: 10.1021/ja0627951 Supporting Info

Stacked Conjugated Oligomers as Molecular Models to Examine Interchain Interactions in Conjugated Materials Kurt M. Knoblock, Catherine J. Silvestri, and David M. Collard pp 13680–13681 DOI: 10.1021/ja063312w Supporting Info

Palladium-Catalyzed Asymmetric Silaboration of Allenes Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome pp 13682–13683 DOI: 10.1021/ja063934h Supporting Info

Ruthenium-Catalyzed Regiospecific Borylation of Methyl C−H Bonds Jaclyn M. Murphy, Joshua D. Lawrence, Kazumori Kawamura, Christopher Incarvito, and John F. Hartwig pp 13684–13685 DOI: 10.1021/ja064092p Supporting Info

Highly Enantioselective Construction of a Chiral Spirocyclic Structure by the [2 + 2 + 2] Cycloaddition of Diynes and exo-Methylene Cyclic Compounds Kyoji Tsuchikama, Yusuke Kuwata, and Takanori Shibata pp 13686–13687 DOI: 10.1021/ja064257u Supporting Info

Production of C6O6- from Oligomerization of CO on Molybdenum Anions Richard B. Wyrwas and Caroline Chick Jarrold pp 13688–13689 DOI: 10.1021/ja0643927

Ideal Mixing in Polyelectrolyte Complexes and Multilayers:  Entropy Driven Assembly Claudiu B. Bucur, Zhijie Sui, and Joseph B. Schlenoff pp 13690–13691 DOI: 10.1021/ja064532c Supporting Info

Chiral Bicyclic Guanidine-Catalyzed Enantioselective Reactions of Anthrones Juan Shen, Thanh Truc Nguyen, Yong-Peng Goh, Weiping Ye, Xiao Fu, Junye Xu, and Choon-Hong Tan pp 13692–13693 DOI: 10.1021/ja064636n Supporting Info

Glycopeptide Biosynthesis:  Dbv21/Orf2* from dbv/tcp Gene Clusters Are N-Ac-Glm Teicoplanin Pseudoaglycone Deacetylases and Orf15 from cep Gene Cluster Is a Glc-1-P Thymidyltransferase Jin-Yuan Ho, Yu-Ting Huang, Chang-Jer Wu, Yi-Shan Li, Ming-Daw Tsai, and Tsung-Lin Li pp 13694–13695 DOI: 10.1021/ja0644834 Supporting Info

C-Aryl Glycosides via Tandem Intramolecular Benzyne−Furan Cycloadditions. Total Synthesis of Vineomycinone B2 Methyl Ester Chi-Li Chen, Steven M. Sparks, and Stephen F. Martin pp 13696–13697 DOI: 10.1021/ja0652619 Supporting Info

Selective Homo- and Heterodehydrocouplings of Phosphines Catalyzed by Rhodium Phosphido Complexes Li-Biao Han and T. Don Tilley pp 13698–13699 DOI: 10.1021/ja065346+ Supporting Info

An Unexpected Possible Role of Base in Asymmetric Catalytic Hydrogenations of Ketones. Synthesis and Characterization of Several Key Catalytic Intermediates Robin J. Hamilton and Steven H. Bergens pp 13700–13701 DOI: 10.1021/ja065460s Supporting Info

Ruthenium Induced C−N Bond Activation of an N-Heterocyclic Carbene:  Isolation of C- and N-Bound Tautomers Suzanne Burling, Mary F. Mahon, Rachael E. Powell, Michael K. Whittlesey, and Jonathan M. J. Williams pp 13702–13703 DOI: 10.1021/ja065582k Supporting Info

Total Synthesis of (+)-cis-Sylvaticin:  Double Oxidative Cyclization Reactions Catalyzed by Osmium Timothy J. Donohoe, Robert M. Harris, Jeremy Burrows, and Jeremy Parker pp 13704–13705 DOI: 10.1021/ja0660148 Supporting Info

Radical Additions of Aryl Iodides to Arenes Are Facilitated by Oxidative Rearomatization with Dioxygen Dennis P. Curran and Adam I. Keller pp 13706–13707 DOI: 10.1021/ja066077q Supporting Info

Expanding Dendrons. The Photoisomerism of Folded Azobenzene Dendrons Christopher J. Gabriel and Jon R. Parquette pp 13708–13709 DOI: 10.1021/ja066126z Supporting Info

Controlling Gold Atom Penetration through Alkanethiolate Self-Assembled Monolayers on Au{111} by Adjusting Terminal Group Intermolecular Interactions Zihua Zhu, Thomas A. Daniel, Masato Maitani, Orlando M. Cabarcos, David L. Allara, and Nicholas Winograd pp 13710–13719 DOI: 10.1021/ja060084x Supporting Info

Fabrication of Steady Junctions Consisting of α,ω-Bis(thioacetate) Oligo(p-phenylene vinylene)s in Nanogap Electrodes Tien-Tzu Liang, Yasuhisa Naitoh, Masayo Horikawa, Takao Ishida, and Wataru Mizutani pp 13720–13726 DOI: 10.1021/ja062561h Supporting Info

Facile Synthesis of Monomeric Alumatranes Weiping Su, Youngjo Kim, Arkady Ellern, Ilia A. Guzei, and John G. Verkade pp 13727–13735 DOI: 10.1021/ja0626786 Supporting Info

Remote Control of Diastereoselectivity in Intramolecular Reactions of Chiral Allylsilanes Weston R. Judd, Sooho Ban, and Jeffrey Aubé pp 13736–13741 DOI: 10.1021/ja063411+ Supporting Info

Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex Wai Yiu Hung, Jun Zhu, Ting Bin Wen, Ka Po Yu, Herman H. Y. Sung, Ian D. Williams, Zhenyang Lin, and Guochen Jia pp 13742–13752 DOI: 10.1021/ja064570w Supporting Info

Lithium Diisopropylamide-Mediated Ortholithiation and Anionic Fries Rearrangement of Aryl Carbamates:  Role of Aggregates and Mixed Aggregates Kanwal Jit Singh and David B. Collum pp 13753–13760 DOI: 10.1021/ja064655x Supporting Info

Building Functionalized Peptidomimetics:  Use of Electroauxiliaries for Introducing N-Acyliminium Ions into Peptides Haizhou Sun, Connor Martin, David Kesselring, Rebecca Keller, and Kevin D. Moeller pp 13761–13771 DOI: 10.1021/ja064737l Supporting Info

Reaction Intermediates in the Photoreduction of Oxygen Molecules at the (101) TiO2 (Anatase) Surface Giuseppe Mattioli, Francesco Filippone, and Aldo Amore Bonapasta pp 13772–13780 DOI: 10.1021/ja062145x Supporting Info

Homogeneous Decomposition of Aryl- and Alkylimido Precursors for the Chemical Vapor Deposition of Tungsten Nitride:  A Combined Density Functional Theory and Experimental Study Yong Sun Won, Young Seok Kim, Timothy J. Anderson, Laurel L. Reitfort, Ion Ghiviriga, and Lisa McElwee-White pp 13781–13788 DOI: 10.1021/ja0621804 Supporting Info

Direct UV Raman Monitoring of 310-Helix and π-Bulge Premelting during α-Helix Unfolding Aleksandr V. Mikhonin and Sanford A. Asher pp 13789–13795 DOI: 10.1021/ja062269+

Tautomerism in the Guanyl Radical Chryssostomos Chatgilialoglu, Clara Caminal, Alessio Altieri, Georgios C. Vougioukalakis, Quinto G. Mulazzani, Thanasis Gimisis, and Maurizio Guerra pp 13796–13805 DOI: 10.1021/ja062636h Supporting Info

The Conformation of cyclo(−d-Pro−Ala4−) as a Model for Cyclic Pentapeptides of the dL4 Type Markus Heller, Martin Sukopp, Natia Tsomaia, Michael John, Dale F. Mierke, Bernd Reif, and Horst Kessler pp 13806–13814 DOI: 10.1021/ja063174a Supporting Info

Glycine at the Pyrite−Water Interface:  The Role of Surface Defects Nisanth N. Nair, Eduard Schreiner, and Dominik Marx pp 13815–13826 DOI: 10.1021/ja063295a Supporting Info

Redox Non-innocence of Thioether Macrocycles:  Elucidation of the Electronic Structures of Mononuclear Complexes of Gold(II) and Silver(II) Jennifer L. Shaw, Joanna Wolowska, David Collison, Judith A. K. Howard, Eric J. L. McInnes, Jonathan McMaster, Alexander J. Blake, Claire Wilson, and Martin Schröder pp 13827–13839 DOI: 10.1021/ja0636439 Supporting Info

The Lipidated Membrane Anchor of Full Length N-Ras Protein Shows an Extensive Dynamics as Revealed by Solid-State NMR Spectroscopy Guido Reuther, Kui-Thong Tan, Alexander Vogel, Christine Nowak, Klaus Arnold, Jürgen Kuhlmann, Herbert Waldmann, and Daniel Huster pp 13840–13846 DOI: 10.1021/ja063635s

Fine Tuning the Production of Nanosized β-Carotene Particles Using Spinning Disk Processing Natthinee Anantachoke, Mohamed Makha, Colin L. Raston, Vichai Reutrakul, Nigel C. Smith, and Martin Saunders pp 13847–13853 DOI: 10.1021/ja063545n Supporting Info

Reorganization Free Energies for Long-Range Electron Transfer in a Porphyrin-Binding Four-Helix Bundle Protein Jochen Blumberger and Michael L. Klein pp 13854–13867 DOI: 10.1021/ja063852t Supporting Info

Competition as a Design Concept:  Polymorphism in Self-Assembled Monolayers of Biphenyl-Based Thiols Piotr Cyganik, Manfred Buck, Thomas Strunskus, Andrei Shaporenko, James D. E. T. Wilton-Ely, Michael Zharnikov, and Christof Wöll pp 13868–13878 DOI: 10.1021/ja0640647 Supporting Info

A Conformational Study of Phospha(III)- and Phospha(V)-guanidine Compounds Natalie E. Mansfield, Joanna Grundy, Martyn P. Coles, Anthony G. Avent, and Peter B. Hitchcock pp 13879–13893 DOI: 10.1021/ja064212t Supporting Info

A General RNA-Capping Ribozyme Retains Stereochemistry during Cap Exchange Hani S. Zaher and Peter J. Unrau pp 13894–13900 DOI: 10.1021/ja0639822 Supporting Info

Electronic Structure of Bis(imino)pyridine Iron Dichloride, Monochloride, and Neutral Ligand Complexes:  A Combined Structural, Spectroscopic, and Computational Study Suzanne C. Bart, Krzysztof Chłopek, Eckhard Bill, Marco W. Bouwkamp, Emil Lobkovsky, Frank Neese, Karl Wieghardt, and Paul J. Chirik pp 13901–13912 DOI: 10.1021/ja064557b Supporting Info

A Biocompatible Surfactant with Folded Hydrophilic Head Group:  Enhancing the Stability of Self-Inclusion Complexes of Ferrocenyl in a β-Cyclodextrin Unit by Bond Rigidity Yongbin Han, Kejun Cheng, Karen A. Simon, Yanmei Lan, Preeti Sejwal, and Yan-Yeung Luk pp 13913–13920 DOI: 10.1021/ja064591q Supporting Info

Extension of the Experimental Electron Density Analysis to Metastable States:  A Case Example of the Spin Crossover Complex Fe(btr)2(NCS)2·H2O Vincent Legrand, Sébastien Pillet, Mohamed Souhassou, Noël Lugan, and Claude Lecomte pp 13921–13931 DOI: 10.1021/ja064355f Supporting Info

Charge Penetration and the Origin of Large O−H Vibrational Red-Shifts in Hydrated-Electron Clusters, (H2O)n- John M. Herbert and Martin Head-Gordon pp 13932–13939 DOI: 10.1021/ja064949i Supporting Info

An Efficient Proton-Coupled Electron-Transfer Process during Oxidation of Ferulic Acid by Horseradish Peroxidase:  Coming Full Cycle Etienne Derat and Sason Shaik pp 13940–13949 DOI: 10.1021/ja065058d Supporting Info

Cluster−Support Interactions and Morphology of MoS2 Nanoclusters in a Graphite-Supported Hydrotreating Model Catalyst Jakob Kibsgaard, Jeppe V. Lauritsen, Erik Lægsgaard, Bjerne S. Clausen, Henrik Topsøe, and Flemming Besenbacher pp 13950–13958 DOI: 10.1021/ja0651106

Two-Dimensional Ordered β-Sheet Lipopeptide Monolayers Silvia Cavalli, Jan-Willem Handgraaf, Emily E. Tellers, Daniela C. Popescu, Mark Overhand, Kristian Kjaer, Vladimir Vaiser, Nico A. J. M. Sommerdijk, Hanna Rapaport, and Alexander Kros pp 13959–13966 DOI: 10.1021/ja065479v Supporting Info

Intermolecular Interactions:  Physical Picture, Computational Methods and Model Potentials Edited by Ilya G. Kaplan (Universidad Nacional Autónomo de México, Mexico). John Wiley & Sons, Ltd.:  Chichester. 2006. xii + 368 pp. $160. ISBN 0-470-86332-3. David C. Easter p 13967 DOI: 10.1021/ja069785k

Surface-Initiated Polymerization I and II. Advances in Polymer Science, 197 and 198 Edited by Rainer Jordan (TU München, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xii + 202. $199. ISBN 3-540-30247-6 (Volume I) and xii + 214 pp. $209. ISBN 3-540-30251-4 (Volume II). Scott M. Husson pp 13967–13968 DOI: 10.1021/ja069751c

Nanoscale Devices − Fundamental and Applications Edited by Rudolf Gross (Bayerische Akademie der Wissenschaften, Garching, Germany), Anatolie Sidorenko (Institute of Electronic Engineering and Industrial Technologies ASM, Kishinev, Moldova), and Lenar Tagirov (Kazan State University, Kazan, Russia). Springer:  Dordrecht. 2006. xxii + 400 pp. $89.95. ISBN 1-4020-5105-0. p 13968 DOI: 10.1021/ja0697929

The Organic Chemistry of Sugars Edited by Daniel E. Levy (Scios, Inc., Fremont, CA) and Péter Fügedi (Hungarian Academy of Sciences, Budapest). CRC Press and Taylor and Francis Group:  Boca Raton, FL. 2005. xxiv + 880 pp. $199.95. ISBN 0-827-5355-0. David C. Baker pp 13968–13969 DOI: 10.1021/ja059892z

Boronic Acids:  Preparation, Applications in Organic Synthesis and Medicine Edited by Dennis G. Hall (University of Alberta). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2005. xxvi + 550 pp. $170.00. ISBN 3-527-30991-8. John J. Lavigne pp 13969–13970 DOI: 10.1021/ja059840+

Polyelectrolytes and Polyzwitterions:  Synthesis, Properties, and Applications Edited by Andrew B. Lowe and Charles L. McCormick (University of Southern Mississippi). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2006. xii + 186 pp. $149.00. ISBN 0-8412-3958-4. p 13970 DOI: 10.1021/ja069794t

Issue 43

Building Symmetric Two-Dimensional Two-Photon Materials Ajit Bhaskar, Ramakrishna Guda, Michael M. Haley, and Theodore Goodson III pp 13972–13973 DOI: 10.1021/ja062709x Supporting Info

Observation of Non-Förster-Type Energy-Transfer Behavior in Quantum Dot−Phthalocyanine Conjugates Smita Dayal, Yongbing Lou, Anna Cristina S. Samia, Jeffrey C. Berlin, Malcolm E. Kenney, and Clemens Burda pp 13974–13975 DOI: 10.1021/ja063415e Supporting Info

Template Ordered Open-Grid Arrays of Paired Endohedral Fullerenes David S. Deak, Fabien Silly, Kyriakos Porfyrakis, and Martin R. Castell pp 13976–13977 DOI: 10.1021/ja0634369

High-Affinity Binding and Direct Electron Transfer to Solid Metals by the Shewanella oneidensis MR-1 Outer Membrane c-type Cytochrome OmcA Yijia Xiong, Liang Shi, Baowei Chen, M. Uljana Mayer, Brian H. Lower, Yuri Londer, Saumyaditya Bose, Michael F. Hochella, James K. Fredrickson, and Thomas C. Squier pp 13978–13979 DOI: 10.1021/ja063526d Supporting Info

A Three-Coordinate and Quadruply Bonded Mo−Mo Complex Yi-Chou Tsai, Yang-Miin Lin, Jen-Shiang K. Yu, and Jenn-Kang Hwang pp 13980–13981 DOI: 10.1021/ja0635884 Supporting Info

Molecular Basis for Dimethylsulfoxide (DMSO) Action on Lipid Membranes Rebecca Notman, Massimo Noro, Brendan O'Malley, and Jamshed Anwar pp 13982–13983 DOI: 10.1021/ja063363t Supporting Info

A Genetically Encoded Infrared Probe Kathryn C. Schultz, Lubica Supekova, Youngha Ryu, Jianming Xie, Roshan Perera, and Peter G. Schultz pp 13984–13985 DOI: 10.1021/ja0636690 Supporting Info

A Supramolecular Multi-Block Copolymer with a High Propensity for Alternation Taiho Park and Steven C. Zimmerman pp 13986–13987 DOI: 10.1021/ja064116s Supporting Info

Enhancing the Thermal Stability of Polythiophene:Fullerene Solar Cells by Decreasing Effective Polymer Regioregularity Kevin Sivula, Christine K. Luscombe, Barry C. Thompson, and Jean M. J. Fréchet pp 13988–13989 DOI: 10.1021/ja064434r Supporting Info

Formation of Solvent Cages around Organometallic Complexes in Thin Films of Supported Ionic Liquid Carsten Sievers, Oriol Jimenez, Thomas E. Müller, Stefan Steuernagel, and Johannes A. Lercher pp 13990–13991 DOI: 10.1021/ja064204c Supporting Info

Ammonia Triborane:  A Promising New Candidate for Amineborane-Based Chemical Hydrogen Storage Chang Won Yoon and Larry G. Sneddon pp 13992–13993 DOI: 10.1021/ja064526g Supporting Info

A Genetic Toolbox for Creating Reversible Ca2+-Sensitive Materials Shana Topp, V. Prasad, Gianguido C. Cianci, Eric R. Weeks, and Justin P. Gallivan pp 13994–13995 DOI: 10.1021/ja064546i Supporting Info

Sulfated and Phosphated Mesoporous Nb Oxide in the Benzylation of Anisole and Toluene by Benzyl Alcohol Yuxiang Rao, Michel Trudeau, and David Antonelli pp 13996–13997 DOI: 10.1021/ja0647147 Supporting Info

Liquid-Crystalline Polymers from Cationic Dendronized Polymer−Anionic Lipid Complexes Nadia Canilho, Edis Kasëmi, Raffaele Mezzenga, and A. Dieter Schlüter pp 13998–13999 DOI: 10.1021/ja065113i Supporting Info

Prediction of Tetraoxygen Formation on Rutile TiO2(110) Devina Pillay, Yun Wang, and Gyeong S. Hwang pp 14000–14001 DOI: 10.1021/ja063453y

Reactions of P-Donor Ligands with N-Silyl(halogeno)organophosphoranimines:  Formation of Cations with P−P Coordination Bonds and Poly(alkyl/aryl)phosphazenes at Ambient Temperature Keith Huynh, Alan J. Lough, and Ian Manners pp 14002–14003 DOI: 10.1021/ja063979i Supporting Info

Delineation of a Fundamental α-Ketoheterocycle Substituent Effect for Use in the Design of Enzyme Inhibitors F. Anthony Romero, Inkyu Hwang, and Dale L. Boger pp 14004–14005 DOI: 10.1021/ja064522b Supporting Info

Asymmetric Epoxidation of Terminal Alkenes with Hydrogen Peroxide Catalyzed by Pentafluorophenyl PtII Complexes Marco Colladon, Alessandro Scarso, Paolo Sgarbossa, Rino A. Michelin, and Giorgio Strukul pp 14006–14007 DOI: 10.1021/ja0647607 Supporting Info

Strong Ferromagnetic Exchange Couplings in Copper(II) and Nickel(II) Complexes with a Paramagnetic Tridentate Chelate Ligand, 2,2‘-Bipyridin-6-yl tert-Butyl Nitroxide Keita Osanai, Atsushi Okazawa, Takashi Nogami, and Takayuki Ishida pp 14008–14009 DOI: 10.1021/ja065623c Supporting Info

Pd(II)-Catalyzed Asymmetric Addition of Malonates to Dihydroisoquinolines Naoki Sasamoto, Christian Dubs, Yoshitaka Hamashima, and Mikiko Sodeoka pp 14010–14011 DOI: 10.1021/ja065646r Supporting Info

Degradation and Reconstruction of Moenomycin A and Derivatives:  Dissecting the Function of the Isoprenoid Chain Masaatsu Adachi, Yi Zhang, Catherine Leimkuhler, Binyuan Sun, John V. LaTour, and Daniel E. Kahne pp 14012–14013 DOI: 10.1021/ja065905c Supporting Info

“Kinetic NMR Titration”:  Including Chemical Shift Information in the Kinetic Analysis of Supramolecular Reaction Systems such as Organic Replicators Insa Stahl and Günter von Kiedrowski pp 14014–14015 DOI: 10.1021/ja065894n Supporting Info

Light-Regulated Sampling of Protein Tyrosine Kinase Activity Qunzhao Wang, Zhaohua Dai, Sean M. Cahill, Michael Blumenstein, and David S. Lawrence pp 14016–14017 DOI: 10.1021/ja065852z Supporting Info

Excimer-Based Peptide Beacons:  A Convenient Experimental Approach for Monitoring Polypeptide−Protein and Polypeptide−Oligonucleotide Interactions Kenneth J. Oh, Kevin J. Cash, and Kevin W. Plaxco pp 14018–14019 DOI: 10.1021/ja0651310 Supporting Info

A Simple Method for Kinetic Control of DNA-Induced Nanoparticle Assembly Mathew M. Maye, Dmytro Nykypanchuk, Daniel van der Lelie, and Oleg Gang pp 14020–14021 DOI: 10.1021/ja0654229 Supporting Info

Nanorings from the Self-Assembly of Amphiphilic Molecular Dumbbells Jung-Keun Kim, Eunji Lee, Zhegang Huang, and Myongsoo Lee pp 14022–14023 DOI: 10.1021/ja065487b Supporting Info

Anhydrous Photochemical Uranyl(VI) Reduction:  Unprecedented Retention of Equatorial Coordination Accompanying Reversible Axial Oxo/Alkoxide Exchange Shanmugaperumal Kannan, Anthony E. Vaughn, Eric M. Weis, Charles L. Barnes, and Paul B. Duval pp 14024–14025 DOI: 10.1021/ja065822w Supporting Info

Synthesis and Characterization of Ge2Sb2Te5 Nanowires with Memory Switching Effect Yeonwoong Jung, Se-Ho Lee, Dong-Kyun Ko, and Ritesh Agarwal pp 14026–14027 DOI: 10.1021/ja065938s Supporting Info

Total Synthesis of (±)-Chartelline C Phil S. Baran and Ryan A. Shenvi pp 14028–14029 DOI: 10.1021/ja0659673 Supporting Info

Catalytic Intermolecular Enal−Alkyne [3 + 2] Reductive Cycloadditions Ananda Herath and John Montgomery pp 14030–14031 DOI: 10.1021/ja0660249 Supporting Info

A PARACEST MRI Contrast Agent To Detect Enzyme Activity Byunghee Yoo and Marty D. Pagel pp 14032–14033 DOI: 10.1021/ja063874f Supporting Info

Sodium Ion Internalized within Phospholipid Membranes Fredric M. Menger, Ashley L. Galloway, Mary E. Chlebowski, and Shaoxing Wu pp 14034–14035 DOI: 10.1021/ja065702o Supporting Info

A Cycle for Organic Nitrile Synthesis via Dinitrogen Cleavage John J. Curley, Emma L. Sceats, and Christopher C. Cummins pp 14036–14037 DOI: 10.1021/ja066090a Supporting Info

The Total Synthesis of (+)-Tedanolide Gunnar Ehrlich, Jorma Hassfeld, Ulrike Eggert, and Markus Kalesse pp 14038–14039 DOI: 10.1021/ja0659572 Supporting Info

Assembly of Three-Dimensional Polymeric Constructs Containing Cells/Biomolecules Using Carbon Dioxide Yong Yang, Yubing Xie, Xihai Kang, L. James Lee, and Douglas A. Kniss pp 14040–14041 DOI: 10.1021/ja066157u Supporting Info

Highly Convergent Three Component Benzyne Coupling:  The Total Synthesis of ent-Clavilactone B Igor Larrosa, Marianne I. Da Silva, Patricio M. Gómez, Peter Hannen, Eunjung Ko, Steven R. Lenger, Simon R. Linke, Andrew J. P. White, Donna Wilton, and Anthony G. M. Barrett pp 14042–14043 DOI: 10.1021/ja0662671 Supporting Info

Attomole Microarray Detection of MicroRNAs by Nanoparticle-Amplified SPR Imaging Measurements of Surface Polyadenylation Reactions Shiping Fang, Hye Jin Lee, Alastair W. Wark, and Robert M. Corn pp 14044–14046 DOI: 10.1021/ja065223p Supporting Info

Highly Regioselective Catalytic Oxidative Coupling Reactions:  Synthetic and Mechanistic Investigations Kami L. Hull, Erica L. Lanni, and Melanie S. Sanford pp 14047–14049 DOI: 10.1021/ja065718e Supporting Info

Total Synthesis of Antheliolide A Chandra Sekhar Mushti, Jae-Hun Kim, and E. J. Corey pp 14050–14052 DOI: 10.1021/ja066336b Supporting Info

α-Secondary Isotope Effects as Probes of “Tunneling-Ready” Configurations in Enzymatic H-Tunneling:  Insight from Environmentally Coupled Tunneling Models Christopher R. Pudney, Sam Hay, Michael J. Sutcliffe, and Nigel S. Scrutton pp 14053–14058 DOI: 10.1021/ja0614619 Supporting Info

Fungus-Mediated Biotransformation of Amorphous Silica in Rice Husk to Nanocrystalline Silica Vipul Bansal, Absar Ahmad, and Murali Sastry pp 14059–14066 DOI: 10.1021/ja062113+ Supporting Info

Surface and Interface Control on Photochemically Initiated Immobilization Li Liu, Mark H. Engelhard, and Mingdi Yan pp 14067–14072 DOI: 10.1021/ja062802l

Conformational Flexibility, Internal Hydrogen Bonding, and Passive Membrane Permeability:  Successful in Silico Prediction of the Relative Permeabilities of Cyclic Peptides Taha Rezai, Jonathan E. Bock, Mai V. Zhou, Chakrapani Kalyanaraman, R. Scott Lokey, and Matthew P. Jacobson pp 14073–14080 DOI: 10.1021/ja063076p Supporting Info

An Organic White Light-Emitting Fluorophore Youjun Yang, Mark Lowry, Corin M. Schowalter, Sayo O. Fakayode, Jorge O. Escobedo, Xiangyang Xu, Huating Zhang, Timothy J. Jensen, Frank R. Fronczek, Isiah M. Warner, and Robert M. Strongin pp 14081–14092 DOI: 10.1021/ja0632207 Supporting Info

High Fidelity Kinetic Self-Sorting in Multi-Component Systems Based on Guests with Multiple Binding Epitopes Pritam Mukhopadhyay, Peter Y. Zavalij, and Lyle Isaacs pp 14093–14102 DOI: 10.1021/ja063390j Supporting Info

Surface Chirality of CuO Thin Films Roland Widmer, Franz-Josef Haug, Pascal Ruffieux, Oliver Gröning, Michael Bielmann, Pierangelo Gröning, and Roman Fasel pp 14103–14108 DOI: 10.1021/ja0640703

Probing the Intrachain and Interchain Effects on the Fluorescence Behavior of Pentiptycene-Derived Oligo(p-phenyleneethynylene)s Jye-Shane Yang, Jyu-Lun Yan, Chung-Yu Hwang, Shih-Yi Chiou, Kang-Ling Liau, Hui-Hsu Gavin Tsai, Gene-Hsiang Lee, and Shie-Ming Peng pp 14109–14119 DOI: 10.1021/ja0640389 Supporting Info

Solvent Effects in Thermodynamically Controlled Multicomponent Nanocage Syntheses Xuejun Liu and Ralf Warmuth pp 14120–14127 DOI: 10.1021/ja0644733 Supporting Info

Nonlinear Optical Properties and Excited-State Dynamics of Highly Symmetric Expanded Porphyrins Zin Seok Yoon, Jung Ho Kwon, Min-Chul Yoon, Mi Kyoung Koh, Su Bum Noh, Jonathan L. Sessler, Jeong Tae Lee, Daniel Seidel, Apolonio Aguilar, Soji Shimizu, Masaaki Suzuki, Atsuhiro Osuka, and Dongho Kim pp 14128–14134 DOI: 10.1021/ja064773k Supporting Info

Spatially Controlled Suzuki and Heck Catalytic Molecular Coupling Jason J. Davis, Claire B. Bagshaw, Katerina L. Busuttil, Yuki Hanyu, and Karl S. Coleman pp 14135–14141 DOI: 10.1021/ja064840a Supporting Info

Peptide-Directed Microstructure Formation of Polymers in Organic Media Jens Hentschel and Hans G. Börner pp 14142–14149 DOI: 10.1021/ja0649872 Supporting Info

In Vivo Monitoring of Mercury Ions Using a Rhodamine-Based Molecular Probe Sung-Kyun Ko, Young-Keun Yang, Jinsung Tae, and Injae Shin pp 14150–14155 DOI: 10.1021/ja065114a Supporting Info

Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C Virgil Percec, Tamaz Guliashvili, Janine S. Ladislaw, Anna Wistrand, Anna Stjerndahl, Monika J. Sienkowska, Michael J. Monteiro, and Sangrama Sahoo pp 14156–14165 DOI: 10.1021/ja065484z Supporting Info

Wetting Properties of Passivated Metal Nanocrystals at Liquid−Vapor Interfaces: A Computer Simulation Study Kafui A. Tay and Fernando Bresme pp 14166–14175 DOI: 10.1021/ja061901w

Trivalent [(C5Me5)2(THF)Ln]2(μ-η2:η2-N2) Complexes as Reducing Agents Including the Reductive Homologation of CO to a Ketene Carboxylate, (μ-η4-O2CCCO)2- William J. Evans, David S. Lee, Joseph W. Ziller, and Nikolas Kaltsoyannis pp 14176–14184 DOI: 10.1021/ja0640851 Supporting Info

A Total Synthesis of Xestodecalactone A and Proof of Its Absolute Stereochemistry:  Interesting Observations on Dienophilic Control with 1,3-Disubstituted Nonequivalent Allenes Toshiharu Yoshino, Fay Ng, and Samuel J. Danishefsky pp 14185–14191 DOI: 10.1021/ja064270e Supporting Info

Insights into the Distribution of Water in a Self-Humidifying H2/O2 Proton-Exchange Membrane Fuel Cell Using 1H NMR Microscopy Kirk W. Feindel, Steven H. Bergens, and Roderick E. Wasylishen pp 14192–14199 DOI: 10.1021/ja064389n Supporting Info

Structure Assignment of Lagunapyrone B by Fluorous Mixture Synthesis of Four Candidate Stereoisomers Fanglong Yang, Jeffery J. Newsome, and Dennis P. Curran pp 14200–14205 DOI: 10.1021/ja064812s Supporting Info

A Ni2+ (S = 1) Kagome Compound Templated by 1,8-Diazacubane [J. Am. Chem. Soc. 2006, 128, 9934−9935]. J. N. Behera and C. N. R. Rao p 14206 DOI: 10.1021/ja0699743

Encyclopedia of Electrochemistry, Volume 7a:  Inorganic Electrochemistry Edited by Fritz Scholz (Universität Greifswald, Germany) and Christopher J. Pickett (John Innes Centre, Norwich, UK). Series Edited by Allen J. Bard and Martin Stratmann. Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. x + 564 pp. $320. ISBN 3-527-30399-5. Andrew Bocarsly p 14207 DOI: 10.1021/ja069755h

Carbon-Rich Compounds:  From Molecules to Materials Edited by Michael M. Haley (University of Oregon) and Rik R. Tykwinski (University of Alberta). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xx + 644 pp. $190.00. ISBN 3-527-31224-2. W. E. Billups pp 14207–14208 DOI: 10.1021/ja069739k

Organic Reactions, Volume 67 Editor-in-Chief: Larry E. Overman (University of California, Irvine). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. viii + 686 pp. $125. ISBN 0-470-04145-5. p 14208 DOI: 10.1021/ja069774r

Issue 44

Formation of FePt Nanoparticles Having High Coercivity Ryan D. Rutledge, William H. Morris, III, Matthew S. Wellons, Zheng Gai, Jian Shen, James Bentley, James E. Wittig, and Charles M. Lukehart pp 14210–14211 DOI: 10.1021/ja0633868 Supporting Info

Hydrogen Bonding Makes a Difference in the Rhodium-Catalyzed Enantioselective Hydrogenation Using Monodentate Phosphoramidites Yan Liu, Christian A. Sandoval, Yoshiki Yamaguchi, Xue Zhang, Zheng Wang, Koichi Kato, and Kuiling Ding pp 14212–14213 DOI: 10.1021/ja063350f Supporting Info

Modified Pyrimidines Specifically Bind the Purine Riboswitch Sunny D. Gilbert, Sarah J. Mediatore, and Robert T. Batey pp 14214–14215 DOI: 10.1021/ja063645t Supporting Info

Electron-Transfer Reduction of Cup-Stacked Carbon Nanotubes Affording Cup-Shaped Carbons with Controlled Diameter and Size Kenji Saito, Masataka Ohtani, and Shunichi Fukuzumi pp 14216–14217 DOI: 10.1021/ja064300d Supporting Info

A Heterotetranuclear [NiIIReIV3] Single-Molecule Magnet José Martínez-Lillo, Donatella Armentano, Giovanni De Munno, Wolfgang Wernsdorfer, Miguel Julve, Francesc Lloret, and Juan Faus pp 14218–14219 DOI: 10.1021/ja0643873 Supporting Info

sp3 C−H Bond Arylation Directed by Amidine Protecting Group:  α-Arylation of Pyrrolidines and Piperidines Stefan J. Pastine, Denis V. Gribkov, and Dalibor Sames pp 14220–14221 DOI: 10.1021/ja064481j Supporting Info

A Low-Spin Alkylperoxo−Iron(III) Complex with Weak Fe−O and O−O Bonds:  Implications for the Mechanism of Superoxide Reductase Divya Krishnamurthy, Gary D. Kasper, Frances Namuswe, William D. Kerber, Amy A. Narducci Sarjeant, Pierre Moënne-Loccoz, and David P. Goldberg pp 14222–14223 DOI: 10.1021/ja064525o Supporting Info

Colchicine Glycorandomization Influences Cytotoxicity and Mechanism of Action Aqeel Ahmed, Noël R. Peters, Megan K. Fitzgerald, James A. Watson, Jr., F. Michael Hoffmann, and Jon S. Thorson pp 14224–14225 DOI: 10.1021/ja064686s Supporting Info

Spectrally-Resolved Atomic-Scale Length Variations of Gold Nanorods Kosei Ueno, Saulius Juodkazis, Vygantas Mizeikis, Keiji Sasaki, and Hiroaki Misawa pp 14226–14227 DOI: 10.1021/ja0645786 Supporting Info

La@C72 Having a Non-IPR Carbon Cage Takatsugu Wakahara, Hidefumi Nikawa, Takashi Kikuchi, Tsukasa Nakahodo, G. M. Aminur Rahman, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Kazunori Yamamoto, Naomi Mizorogi, Zdenek Slanina, and Shigeru Nagase pp 14228–14229 DOI: 10.1021/ja064751y Supporting Info

Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O2)]+ Matthew T. Kieber-Emmons, Jamespandi Annaraj, Mi Sook Seo, Katherine M. Van Heuvelen, Takehiko Tosha, Teizo Kitagawa, Thomas C. Brunold, Wonwoo Nam, and Charles G. Riordan pp 14230–14231 DOI: 10.1021/ja0644879 Supporting Info

Direct and High Resolution Characterization of Cytochrome c Equilibrium Folding Laura B. Sagle, Jörg Zimmermann, Philip E. Dawson, and Floyd E. Romesberg pp 14232–14233 DOI: 10.1021/ja065179d Supporting Info

Mesoscale Chiroptics of Rhythmic Precipitates Erica Gunn, Ryan Sours, Jason B. Benedict, Werner Kaminsky, and Bart Kahr pp 14234–14235 DOI: 10.1021/ja065139+ Supporting Info

Interplay of Fidelity, Binding Strength, and Structure in Supramolecular Polymers Taiho Park and Steven C. Zimmerman pp 14236–14237 DOI: 10.1021/ja065469u Supporting Info

Design of Open-Framework Germanates by Combining Different Building Units Kirsten E. Christensen, Lei Shi, Tony Conradsson, Tie-zhen Ren, Mike S. Dadachov, and Xiaodong Zou pp 14238–14239 DOI: 10.1021/ja065403z Supporting Info

Channel-Selective Independent Sorption and Collection of Hydrophilic and Hydrophobic Molecules by Cs2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] Ionic Crystal Chunjie Jiang, Aldes Lesbani, Ryosuke Kawamoto, Sayaka Uchida, and Noritaka Mizuno pp 14240–14241 DOI: 10.1021/ja065732r Supporting Info

Control of Absolute Helicity in Single-Stranded Abiotic Metallofoldamers Zhenzhen Dong, Richard J. Karpowicz, Jr., Shi Bai, Glenn P. A. Yap, and Joseph M. Fox pp 14242–14243 DOI: 10.1021/ja065721y Supporting Info

Effect of Nanoscale Geometry on Molecular Conformation:  Vibrational Sum-Frequency Generation of Alkanethiols on Gold Nanoparticles Champika Weeraman, Achani K. Yatawara, Andrey N. Bordenyuk, and Alexander V. Benderskii pp 14244–14245 DOI: 10.1021/ja065756y Supporting Info

Heme−Heme Interactions in the Cytochrome b6f Complex:  EPR Spectroscopy and Correlation with Structure Anna I. Zatsman, Huamin Zhang, William A. Gunderson, William A. Cramer, and Michael P. Hendrich pp 14246–14247 DOI: 10.1021/ja065798m Supporting Info

Fluoride Ion Capture from Water with a Cationic Borane Ching-Wen Chiu and François P. Gabbaï pp 14248–14249 DOI: 10.1021/ja0658463 Supporting Info

Photodeformable Spherical Hybrid Nanoparticles Lihua Zhao, Douglas A. Loy, and Kenneth J. Shea pp 14250–14251 DOI: 10.1021/ja066047n Supporting Info

Antimicrobial Leucocin Analogues with a Disulfide Bridge Replaced by a Carbocycle or by Noncovalent Interactions of Allyl Glycine Residues Darren J. Derksen, Jake L. Stymiest, and John C. Vederas pp 14252–14253 DOI: 10.1021/ja066203q Supporting Info

Single-Step Synthesis of Pyrimidine Derivatives Mohammad Movassaghi and Matthew D. Hill pp 14254–14255 DOI: 10.1021/ja066405m Supporting Info

Alkyl-Functionalized Organic Dyes for Efficient Molecular Photovoltaics Nagatoshi Koumura, Zhong-Sheng Wang, Shogo Mori, Masanori Miyashita, Eiji Suzuki, and Kohjiro Hara pp 14256–14257 DOI: 10.1021/ja0645640 Supporting Info

Freestanding Mesoporous Quasi-Single-Crystalline Co3O4 Nanowire Arrays Yanguang Li, Bing Tan, and Yiying Wu pp 14258–14259 DOI: 10.1021/ja065308q Supporting Info

Control of Pyramidal Inversion Rates by Redox Switching Mark W. Davies, Michael Shipman, James H. R. Tucker, and Tiffany R. Walsh pp 14260–14261 DOI: 10.1021/ja065325f Supporting Info

Characterization of SpnQ from the Spinosyn Biosynthetic Pathway of Saccharopolyspora spinosa:  Mechanistic and Evolutionary Implications for C-3 Deoxygenation in Deoxysugar Biosynthesis Lin Hong, Zongbao Zhao, and Hung-wen Liu pp 14262–14263 DOI: 10.1021/ja0649670 Supporting Info

Kinetic Resolutions of Indolines by a Nonenzymatic Acylation Catalyst Forrest O. Arp and Gregory C. Fu pp 14264–14265 DOI: 10.1021/ja0657859 Supporting Info

Surface-Mediated NH and N Addition to Styrene on Ag(110) Xiaoying Liu, Robert J. Madix, and Cynthia M. Friend pp 14266–14267 DOI: 10.1021/ja065344p Supporting Info

Stereoselective Preparation of 1-Siloxy-1-alkenylcopper Species by 1,2-Csp2-to-O Silyl Migration of Acylsilanes Akira Tsubouchi, Kotaro Onishi, and Takeshi Takeda pp 14268–14269 DOI: 10.1021/ja0658822 Supporting Info

Organolutetium Vinyl and Tuck-Over Complexes via C−H Bond Activation William J. Evans, Timothy M. Champagne, and Joseph W. Ziller pp 14270–14271 DOI: 10.1021/ja065788l Supporting Info

Dramatic Solvent and Hydration Effects on the Transition State of Soybean Peroxidase Anne L. Serdakowski, Inmar Z. Munir, and Jonathan S. Dordick pp 14272–14273 DOI: 10.1021/ja0660150 Supporting Info

A Gold-Catalyzed Unique Cycloisomerization of 1,5-Enynes:  Efficient Formation of 1-Carboxycyclohexa-1,4-dienes and Carboxyarenes Shaozhong Wang and Liming Zhang pp 14274–14275 DOI: 10.1021/ja066220f Supporting Info

Directed Biosynthesis of Alkaloid Analogs in the Medicinal Plant Catharanthus roseus Elizabeth McCoy and Sarah E. O'Connor pp 14276–14277 DOI: 10.1021/ja066787w Supporting Info

A General Synthetic Strategy for Oxide-Supported Metal Nanoparticle Catalysts Nanfeng Zheng and Galen D. Stucky pp 14278–14280 DOI: 10.1021/ja0659929 Supporting Info

Mechanistic Borderline between One-Step Hydrogen Transfer and Sequential Transfers of Electron and Proton in Reactions of NADH Analogues with Triplet Excited States of Tetrazines and Ru(bpy)32+* Junpei Yuasa and Shunichi Fukuzumi pp 14281–14292 DOI: 10.1021/ja0604562 Supporting Info

Mechanistic Study of Hydrogen Transfer to Imines from a Hydroxycyclopentadienyl Ruthenium Hydride. Experimental Support for a Mechanism Involving Coordination of Imine to Ruthenium Prior to Hydrogen Transfer Joseph S. M. Samec, Alida H. Éll, Jenny B. Åberg, Timofei Privalov, Lars Eriksson, and Jan-E. Bäckvall pp 14293–14305 DOI: 10.1021/ja061494o Supporting Info

DFT Study on the Palladium-Catalyzed Allylation of Primary Amines by Allylic Alcohol Olivier Piechaczyk, Claire Thoumazet, Yves Jean, and Pascal le Floch pp 14306–14317 DOI: 10.1021/ja0621997 Supporting Info

Picosecond Isomerization in Photochromic Ruthenium−Dimethyl Sulfoxide Complexes Aaron A. Rachford and Jeffrey J. Rack pp 14318–14324 DOI: 10.1021/ja0641305 Supporting Info

On the Biosynthetic Origin of Methoxymalonyl-Acyl Carrier Protein, the Substrate for Incorporation of “Glycolate” Units into Ansamitocin and Soraphen A Silke C. Wenzel, Rachel M. Williamson, Christian Grünanger, Jun Xu, Klaus Gerth, Rodolfo A. Martinez, Steven J. Moss, Brian J. Carroll, Stephanie Grond, Clifford J. Unkefer, Rolf Müller, and Heinz G. Floss pp 14325–14336 DOI: 10.1021/ja064408t

Stabilization of a Kinetically Favored Nanostructure:  Surface ROMP of Self-Assembled Conductive Nanocoils from a Norbornene-Appended Hexa-peri-hexabenzocoronene Takuya Yamamoto, Takanori Fukushima, Yohei Yamamoto, Atsuko Kosaka, Wusong Jin, Noriyuki Ishii, and Takuzo Aida, pp 14337–14340 DOI: 10.1021/ja064461h Supporting Info

Ion Permeability of SAMs on Nanoparticle Surfaces Timo Laaksonen, Outi Pelliniemi, and Bernadette M. Quinn pp 14341–14346 DOI: 10.1021/ja064701t Supporting Info

Nanostructures versus Solid Solutions:  Low Lattice Thermal Conductivity and Enhanced Thermoelectric Figure of Merit in Pb9.6Sb0.2Te10-xSex Bulk Materials Pierre F. P. Poudeu, Jonathan D'Angelo, Huijun Kong, Adam Downey, Jarrod L. Short, Robert Pcionek, Timothy P. Hogan, Ctirad Uher, and Mercouri G. Kanatzidis pp 14347–14355 DOI: 10.1021/ja0647811 Supporting Info

A Minimalist Approach toward Protein Recognition by Epitope Transfer from Functionally Evolved β-Sheet Surfaces Srivats Rajagopal, Scott C. Meyer, Aaron Goldman, Min Zhou, and Indraneel Ghosh pp 14356–14363 DOI: 10.1021/ja064885b Supporting Info

Direct Nitric Oxide Detection in Aqueous Solution by Copper(II) Fluorescein Complexes Mi Hee Lim, Brian A. Wong, William H. Pitcock, Jr., Deepa Mokshagundam, Mu-Hyun Baik, and Stephen J. Lippard pp 14364–14373 DOI: 10.1021/ja064955e Supporting Info

Synthesis of Nonspherical Colloidal Particles with Anisotropic Properties Jin-Woong Kim, Ryan J. Larsen, and David A. Weitz pp 14374–14377 DOI: 10.1021/ja065032m Supporting Info

Tuning Peptoid Secondary Structure with Pentafluoroaromatic Functionality:  A New Design Paradigm for the Construction of Discretely Folded Peptoid Structures Benjamin C. Gorske and Helen E. Blackwell pp 14378–14387 DOI: 10.1021/ja065248o Supporting Info

Carbene vs Olefin Products of C−H Activation on Ruthenium via Competing α- and β-H Elimination Vladimir F. Kuznetsov, Kamaluddin Abdur-Rashid, Alan J. Lough, and Dmitry G. Gusev pp 14388–14396 DOI: 10.1021/ja065249g Supporting Info

Rotational Reorganization of Doped Cholesteric Liquid Crystalline Films Rienk Eelkema, Michael M. Pollard, Nathalie Katsonis, Javier Vicario, Dirk J. Broer, and Ben L. Feringa pp 14397–14407 DOI: 10.1021/ja065334o Supporting Info

Temperature-Programmed Microwave-Assisted Synthesis of SBA-15 Ordered Mesoporous Silica Ewa B. Celer and Mietek Jaroniec pp 14408–14414 DOI: 10.1021/ja065345h Supporting Info

New Carbon Based Materials for Electrochemical Energy Storage Systems Edited by Igor V. Barsukov (Superior Graphite Co., Chicago, IL), Christopher S. Johnson (Argonne National Lab., Argonne, IL), Joseph E. Doniger (Dontech Global, Inc., Lake Forest, IL) Vyacheslav Z. Barsukov (Kiev National University of Technology and Design, Kiev, Ukraine). Springer:  Dordrecht. 2006. xxiv + 524 pp. $89.95. ISBN 1-4020-4810-6. p 14415 DOI: 10.1021/ja0697931

Advances in Chemical Physics, Volume 133. Fractals, Diffusion, and Relaxation in Disordered Complex Systems, Parts A−B Edited by Yuri P. Kalmykov (Université de Perpignan, France) and William T. Coffey (Trinity College, Dublin, Ireland). Series Edited by Stuart A. Rice. J. Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xxii + 570 pp (for A) and xxii + 728 pp (for B). $295 for set. ISBN 0-470-04607-4 for set. p 14415 DOI: 10.1021/ja069796d

Handbook of Laser-Induced Breakdown Spectrscopy By David A. Cremers (Applied Research Associates, Inc., Albuquerque, NM) and Leon J. Radziemski (Research Corporation, Tucson, AZ). John Wiley & Sons, Ltd.:  Chichester. 2006. xviii + 284 pp. $145.00. ISBN 0-470-09299-8. p 14415 DOI: 10.1021/ja069799q

Microwave-Assisted Synthesis of Heterocycles. Topics in Heterocyclic Chemistry, 01 Edited by Erik Van der Eycken (K. U. Leuven, Heverlee, Belgium) and C. Oliver Kappe (Karl-Franzens University, Graz, Austria). Series Edited by R. R. Gupta. Springer:  Berlin, Heidelberg, New York. 2006. xiv + 310 pp. $149. ISBN:  3-540-30983-7. Daniel M. Ketcha pp 14415–14416 DOI: 10.1021/ja0697626

Issue 45

Spin-Site Exchange System Constructed from Endohedral Metallofullerenes and Organic Donors Takahiro Tsuchiya, Kumiko Sato, Hiroki Kurihara, Takatsugu Wakahara, Yutaka Maeda, Takeshi Akasaka, Kei Ohkubo, Shunichi Fukuzumi, Tatsuhisa Kato, and Shigeru Nagase pp 14418–14419 DOI: 10.1021/ja062634x Supporting Info

A Catalytic Nanomaterial-Based Optical Chemo-Sensor Array Na Na, Sichun Zhang, Shuai Wang, and Xinrong Zhang pp 14420–14421 DOI: 10.1021/ja063632f Supporting Info

Control of Cationic Conjugated Polymer Performance in Light Emitting Diodes by Choice of Counterion Renqiang Yang, Hongbin Wu, Yong Cao, and Guillermo C. Bazan pp 14422–14423 DOI: 10.1021/ja063723c Supporting Info

From Macro- to Nanoscopic Templating with Nanographenes Wojciech Pisula, Marcel Kastler, Daniel Wasserfallen, Richard J. Davies, Mari-Cruz García-Gutiérrez, and Klaus Müllen pp 14424–14425 DOI: 10.1021/ja0641960 Supporting Info

Synthesis of 7-Azaserotonin:  Its Photophysical Properties Associated with Excited State Proton Transfer Reaction Pei-Wen Wu, Wan-Ting Hsieh, Yi-Ming Cheng, Ching-Yen Wei, and Pi-Tai Chou pp 14426–14427 DOI: 10.1021/ja064310e Supporting Info

DNA-Directed Assembly of Polyanilines:  Modified Cytosine Nucleotides Transfer Sequence Programmability to a Conjoined Polymer Bhaskar Datta, Gary B. Schuster, Amanda McCook, Stephen C. Harvey, and Krystyna Zakrzewska pp 14428–14429 DOI: 10.1021/ja0648413 Supporting Info

Membrane Activation:  Selective Vesicle Fusion via Small Molecule Recognition Yun Gong, Yumei Luo, and Dennis Bong pp 14430–14431 DOI: 10.1021/ja0644576 Supporting Info

Top-Down ESI-ECD-FT-ICR Mass Spectrometry Localizes Noncovalent Protein-Ligand Binding Sites Yongming Xie, Jennifer Zhang, Sheng Yin, and Joseph A. Loo pp 14432–14433 DOI: 10.1021/ja063197p Supporting Info

Occlusion of Grubbs' Catalysts in Active Membranes of Polydimethylsiloxane:  Catalysis in Water and New Functional Group Selectivities Martin T. Mwangi, M. Brett Runge, and Ned B. Bowden pp 14434–14435 DOI: 10.1021/ja0642212 Supporting Info

Synthesis of Polycyclic Benzonitriles via a One-Pot Aryl Alkylation/Cyanation Reaction Brian Mariampillai, Dino Alberico, Valérie Bidau, and Mark Lautens pp 14436–14437 DOI: 10.1021/ja064742p Supporting Info

Nickel-Catalyzed Addition of Alkynylboranes to Alkynes Michinori Suginome, Masamichi Shirakura, and Akihiko Yamamoto pp 14438–14439 DOI: 10.1021/ja064970j Supporting Info

Dramatic Ligand Effect in Catalytic Asymmetric Reductive Aldol Reaction of Allenic Esters to Ketones Dongbo Zhao, Kounosuke Oisaki, Motomu Kanai, and Masakatsu Shibasaki pp 14440–14441 DOI: 10.1021/ja0652565 Supporting Info

Diphenylsilylene Andrey G. Moiseev and William J. Leigh pp 14442–14443 DOI: 10.1021/ja0653223 Supporting Info

Extended Squaraine Dyes with Large Two-Photon Absorption Cross-Sections Sung-Jae Chung, Shijun Zheng, Toru Odani, Luca Beverina, Jie Fu, Lazaro A. Padilha, Arianna Biesso, Joel M. Hales, Xiaowei Zhan, Karin Schmidt, Aijun Ye, Egbert Zojer, Stephen Barlow, David J. Hagan, Eric W. Van Stryland, Yuanping Yi, Zhigang Shuai, Giorgio A. Pagani, Jean-Luc Brédas, Joseph W. Perry, and Seth R. Marder pp 14444–14445 DOI: 10.1021/ja065556m Supporting Info

Electric Field-Induced Isomerization of Azobenzene by STM Micol Alemani, Maike V. Peters, Stefan Hecht, Karl-Heinz Rieder, Francesca Moresco, and Leonhard Grill pp 14446–14447 DOI: 10.1021/ja065449s Supporting Info

A Functional Model for the Cysteinate-Ligated Non-Heme Iron Enzyme Superoxide Reductase (SOR) Terutaka Kitagawa, Abhishek Dey, Priscilla Lugo-Mas, Jason B. Benedict, Werner Kaminsky, Edward Solomon, and Julie A. Kovacs pp 14448–14449 DOI: 10.1021/ja064870d Supporting Info

Nativelike Structure in Designed Four α-Helix Bundles Driven by Buried Polar Interactions Ronald L. Koder, Kathleen G. Valentine, Jose Cerda, Dror Noy, Kevin M. Smith, A. Joshua Wand, and P. Leslie Dutton pp 14450–14451 DOI: 10.1021/ja064883r Supporting Info

Spontaneous Membrane Fusion Induced by Chemical Formation of Ceramides in a Lipid Bilayer Munetaka Kunishima, Masafumi Tokaji, Keisuke Matsuoka, Jin Nishida, Masanori Kanamori, Kazuhito Hioki, and Shohei Tani pp 14452–14453 DOI: 10.1021/ja0652969 Supporting Info

Selective Synthesis of TbMn2O5 Nanorods and TbMnO3 Micron Crystals Jian-Tao Han, Yun-Hui Huang, Wei Huang, and John B. Goodenough pp 14454–14455 DOI: 10.1021/ja065520u Supporting Info

Inhibition of β-Amyloid Fibrillization by Directed Evolution of a β-Sheet Presenting Miniature Protein Thaddeus J. Smith, Cliff I. Stains, Scott C. Meyer, and Indraneel Ghosh pp 14456–14457 DOI: 10.1021/ja065557e Supporting Info

Photoreversibly Switchable Superhydrophobic Surface with Erasable and Rewritable Pattern Ho Sun Lim, Joong Tark Han, Donghoon Kwak, Meihua Jin, and Kilwon Cho pp 14458–14459 DOI: 10.1021/ja0655901 Supporting Info

Non-Nanogold Catalysis of Carbon Monoxide Oxidative Amination Bolin Zhu and Robert J. Angelici pp 14460–14461 DOI: 10.1021/ja065706t Supporting Info

The Effect of Receptor Clustering on Vesicle−Vesicle Adhesion Robert J. Mart, Kwan Ping Liem, Xi Wang, and Simon J. Webb pp 14462–14463 DOI: 10.1021/ja0657612 Supporting Info

Molecular Recognition and Stabilization of Iminium Ions in Water Vy M. Dong, Dorothea Fiedler, Barbara Carl, Robert G. Bergman, and Kenneth N. Raymond pp 14464–14465 DOI: 10.1021/ja0657915 Supporting Info

Prediction and Observation of Isostructurality Induced by Solvent Incorporation in Multicomponent Crystals Aurora J. Cruz Cabeza, Graeme M. Day, W. D. Samuel Motherwell, and William Jones pp 14466–14467 DOI: 10.1021/ja065845a Supporting Info

Activity-Based Protein Profiling Reagents for Protein Arginine Deiminase 4 (PAD4):  Synthesis and in vitro Evaluation of a Fluorescently Labeled Probe Yuan Luo, Bryan Knuckley, Monica Bhatia, Perry J. Pellechia, and Paul R. Thompson pp 14468–14469 DOI: 10.1021/ja0656907 Supporting Info

Terthiophene Radical Cations End-Capped by Bicyclo[2.2.2]octene Units:  Formation of Bent π-Dimers Mutually Attracted at the Central Position Daisuke Yamazaki, Tohru Nishinaga, Nobuhide Tanino, and Koichi Komatsu pp 14470–14471 DOI: 10.1021/ja065995l Supporting Info

Solid-State 29Si NMR Study of RSiSiR:  A Tool for Analyzing the Nature of the Si−Si Bond Victoria Kravchenko, Rei Kinjo, Akira Sekiguchi, Masaaki Ichinohe, Robert West, Yael S. Balazs, Asher Schmidt, Miriam Karni, and Yitzhak Apeloig pp 14472–14473 DOI: 10.1021/ja065817s Supporting Info

Signal Ratio Amplification via Modulation of Resonance Energy Transfer:  Proof of Principle in an Emission Ratiometric Hg(II) Sensor Ali Coskun and Engin U. Akkaya pp 14474–14475 DOI: 10.1021/ja066144g Supporting Info

Linkage Effects on Binding Affinity and Activation of GPR30 and Estrogen Receptors ERα/β with Tridentate Pyridin-2-yl Hydrazine Tricarbonyl−Re/99mTc(I) Chelates Chinnasamy Ramesh, Bj Bryant, Tapan Nayak, Chetana M. Revankar, Tamara Anderson, Kathryn E. Carlson, John A. Katzenellenbogen, Larry A. Sklar, Jeffrey P. Norenberg, Eric R. Prossnitz, and Jeffrey B. Arterburn pp 14476–14477 DOI: 10.1021/ja066360p Supporting Info

Mechanical Control of Enantioselectivity of Amino Acid Recognition by Cholesterol-Armed Cyclen Monolayer at the Air-Water Interface Tsuyoshi Michinobu, Satoshi Shinoda, Takashi Nakanishi, Jonathan P. Hill, Kazuko Fujii, Tomoko N. Player, Hiroshi Tsukube, and Katsuhiko Ariga pp 14478–14479 DOI: 10.1021/ja066429t Supporting Info

Synthesis of Benzonorcaradienes by Gold(I)-Catalyzed [4+3] Annulation David J. Gorin, Pascal Dubé, and F. Dean Toste pp 14480–14481 DOI: 10.1021/ja066694e Supporting Info

Direction Specific Interactions of 1,4-Dicarboxylic Acid with Calcite Surfaces H. Henry Teng, Yang Chen, and Elli Pauli pp 14482–14484 DOI: 10.1021/ja063167m

Solid-State NMR, Crystallographic, and Computational Investigation of Bisphosphonates and Farnesyl Diphosphate Synthase−Bisphosphonate Complexes Junhong Mao, Sujoy Mukherjee, Yong Zhang, Rong Cao, John M. Sanders, Yongcheng Song, Yonghui Zhang, Gary A. Meints, Yi Gui Gao, Dushyant Mukkamala, Michael P. Hudock, and Eric Oldfield pp 14485–14497 DOI: 10.1021/ja061737c Supporting Info

Optical Characterization of Eu-Doped and Undoped Gd2O3 Nanoparticles Synthesized by the Hydrogen Flame Pyrolysis Method Ewa M. Goldys, Krystyna Drozdowicz-Tomsia, Sun Jinjun, Dosi Dosev, Ian M. Kennedy, Sergiey Yatsunenko, and Marek Godlewski pp 14498–14505 DOI: 10.1021/ja0621602

Electrostatic, Steric, and Hydration Interactions Favor Na+ Condensation around DNA Compared with K+ Alexey Savelyev and Garegin A. Papoian pp 14506–14518 DOI: 10.1021/ja0629460 Supporting Info

Spectroscopic Studies of Solvated Hydrogen and Hydroxide Ions at Aqueous Surfaces Teresa L. Tarbuck, Stephanie T. Ota, and Geraldine L. Richmond pp 14519–14527 DOI: 10.1021/ja063184b Supporting Info

DNA Condensation and Cell Transfection Properties of Guanidinium Calixarenes:  Dependence on Macrocycle Lipophilicity, Size, and Conformation Francesco Sansone, Miroslav Dudi, Gaetano Donofrio, Claudio Rivetti, Laura Baldini, Alessandro Casnati, Sara Cellai, and Rocco Ungaro pp 14528–14536 DOI: 10.1021/ja0634425 Supporting Info

Controlled Modulation of Conductance in Silicon Devices by Molecular Monolayers Tao He, Jianli He, Meng Lu, Bo Chen, Harry Pang, William F. Reus, Whitney M. Nolte, David P. Nackashi, Paul D. Franzon, and James M. Tour pp 14537–14541 DOI: 10.1021/ja063571l Supporting Info

Photochromic Switching of Excited-State Intramolecular Proton-Transfer (ESIPT) Fluorescence:  A Unique Route to High-Contrast Memory Switching and Nondestructive Readout Seon-Jeong Lim, Jangwon Seo, and Soo Young Park pp 14542–14547 DOI: 10.1021/ja0637604

Prediction of Folding Preference of 10 kDa Silk-like Proteins Using a Lego Approach and ab Initio Calculations Gábor Pohl, Tamás Beke, János Borbély, and András Perczel pp 14548–14559 DOI: 10.1021/ja063933p Supporting Info

Characterization of the Phenoxyl Radical in Model Complexes for the CuB Site of Cytochrome c Oxidase:  Steady-State and Transient Absorption Measurements, UV Resonance Raman Spectroscopy, EPR Spectroscopy, and DFT Calculations for M-BIAIP Yasutomo Nagano, Jin-Gang Liu, Yoshinori Naruta, Tadaaki Ikoma, Shozo Tero-Kubota, and Teizo Kitagawa pp 14560–14570 DOI: 10.1021/ja061507y Supporting Info

A Critical Analysis of the Cyclic and Open Alternatives of the Transmetalation Step in the Stille Cross-Coupling Reaction Ainara Nova, Gregori Ujaque, Feliu Maseras, Agustí Lledós, and Pablo Espinet pp 14571–14578 DOI: 10.1021/ja0635736 Supporting Info

Spectroscopic Characterization of a High-Potential Lipo-Cupredoxin Found in Streptomyces coelicolor Jonathan A. R. Worrall, Michael C. Machczynski, Bart J. F. Keijser, Giulia di Rocco, Stefano Ceola, Marcellus Ubbink, Erik Vijgenboom, and Gerard W. Canters pp 14579–14589 DOI: 10.1021/ja064112n Supporting Info

Very Small and Soft Scorpionates:  Water Stable Technetium Tricarbonyl Complexes Combining a Bis-agostic (k3-H, H, S) Binding Motif with Pendant and Integrated Bioactive Molecules Leonor Maria, António Paulo, Isabel C. Santos, Isabel Santos, Philipp Kurz, Bernhard Spingler, and Roger Alberto pp 14590–14598 DOI: 10.1021/ja0644226 Supporting Info

Self-Assembled Nanocages for Hydrophilic Guest Molecules Marie-Christine Jones, Pankaj Tewari, Claudia Blei, Kelly Hales, Darrin J. Pochan, and Jean-Christophe Leroux pp 14599–14605 DOI: 10.1021/ja065462c Supporting Info

Synthesis, DNA Polymerase Incorporation, and Enzymatic Phosphate Hydrolysis of Formamidopyrimidine Nucleoside Triphosphates Shuhei Imoto, Jennifer N. Patro, Yu Lin Jiang, Natsuhisa Oka, and Marc M. Greenberg pp 14606–14611 DOI: 10.1021/ja065525r Supporting Info

Modulation of the Catalytic Behavior of α-Chymotrypsin at Monolayer-Protected Nanoparticle Surfaces Chang-Cheng You, Sarit S. Agasti, Mrinmoy De, Michael J. Knapp, and Vincent M. Rotello pp 14612–14618 DOI: 10.1021/ja064433z Supporting Info

The Boat-Shaped Polyketide Resistoflavin Results from Re-Facial Central Hydroxylation of the Discoid Metabolite Resistomycin Keishi Ishida, Katja Maksimenka, Kathrin Fritzsche, Kirstin Scherlach, Gerhard Bringmann, and Christian Hertweck pp 14619–14624 DOI: 10.1021/ja064550u Supporting Info

Persistent Electron-Transfer State of a π-Complex of Acridinium Ion Inserted between Porphyrin Rings of Cofacial Bisporphyrins Makiko Tanaka, Kei Ohkubo, Claude P. Gros, Roger Guilard, and Shunichi Fukuzumi pp 14625–14633 DOI: 10.1021/ja064678b Supporting Info

High-Performance Air-Stable n-Type Transistors with an Asymmetrical Device Configuration Based on Organic Single-Crystalline Submicrometer/Nanometer Ribbons Qingxin Tang, Hongxiang Li, Yaling Liu, and Wenping Hu pp 14634–14639 DOI: 10.1021/ja064476f Supporting Info

New Insights into α-GalNAc−Ser Motif:  Influence of Hydrogen Bonding versus Solvent Interactions on the Preferred Conformation Francisco Corzana, Jesús H. Busto, Gonzalo Jiménez-Osés, Juan L. Asensio, Jesús Jiménez-Barbero, Jesús M. Peregrina, and Alberto Avenoza pp 14640–14648 DOI: 10.1021/ja064539u Supporting Info

Order−Disorder Transition Coupled with Magnetic Bistability in the Ferricinium Salt of a Radical Nickel Dithiolene Complex Olivier Jeannin, Rodolphe Clérac, and Marc Fourmigué pp 14649–14656 DOI: 10.1021/ja064842v Supporting Info

12/10- and 11/13-Mixed Helices in α/γ- and β/γ-Hybrid Peptides Containing C-Linked Carbo-γ-amino Acids with Alternating α- and β-Amino Acids Gangavaram V. M. Sharma, Vivekanand B. Jadhav, Kallaganti V. S. Ramakrishna, Pagadala Jayaprakash, Kongari Narsimulu, Velaparthi Subash, and Ajit C. Kunwar pp 14657–14668 DOI: 10.1021/ja064875a Supporting Info

Oxidation of Nitrite by a trans-Dioxoruthenium(VI) Complex:  Direct Evidence for Reversible Oxygen Atom Transfer Wai-Lun Man, William W. Y. Lam, Wai-Yeung Wong, and Tai-Chu Lau pp 14669–14675 DOI: 10.1021/ja064975g Supporting Info

Synthesis, Structure, and Reactivity of a Stabilized Calcium Carbene:  R2CCa Lars Orzechowski, Georg Jansen, and Sjoerd Harder pp 14676–14684 DOI: 10.1021/ja065000z Supporting Info

Photooxidation of Olefins under Oxygen in Platinum(II) Complex-Loaded Mesoporous Molecular Sieves Ke Feng, Ren-Yuan Zhang, Li-Zhu Wu, Bo Tu, Ming-Li Peng, Li-Ping Zhang, Dongyuan Zhao, and Chen-Ho Tung pp 14685–14690 DOI: 10.1021/ja0648256 Supporting Info

Transition-State Structure of Human 5‘-Methylthioadenosine Phosphorylase Vipender Singh and Vern L. Schramm pp 14691–14696 DOI: 10.1021/ja065419p Supporting Info

The “Azido Gauche Effect”Implications for the Conformation of Azidoprolines Louis-Sebastian Sonntag, Sabine Schweizer, Christian Ochsenfeld, and Helma Wennemers pp 14697–14703 DOI: 10.1021/ja0654938 Supporting Info

Toward a Designed, Functioning Genetic System with Expanded-Size Base Pairs:  Solution Structure of the Eight-Base xDNA Double Helix Stephen R. Lynch, Haibo Liu, Jianmin Gao, and Eric T. Kool pp 14704–14711 DOI: 10.1021/ja065606n Supporting Info

Rates of Oxygen Exchange between the [HxNb6O19]8-x(aq) Lindqvist Ion and Aqueous Solutions Jay R. Black, May Nyman, and William H. Casey pp 14712–14720 DOI: 10.1021/ja065529w Supporting Info

Toward Raman Fingerprints of Single Dye Molecules at Atomically Smooth Au(111) Katrin F. Domke, Dai Zhang, and Bruno Pettinger pp 14721–14727 DOI: 10.1021/ja065820b

Atoms-in-Molecules Study of Intra- and Intermolecular Bonding in the Pentaerythritol Tetranitrate Crystal Elizabeth A. Zhurova, Adam I. Stash, Vladimir G. Tsirelson, Vladimir V. Zhurov, Ekaterina V. Bartashevich, Vladimir A. Potemkin, and A. Alan Pinkerton pp 14728–14734 DOI: 10.1021/ja0658620 Supporting Info

Issue 46

Induction of a Heterochiral Helix through the Covalent Chiral Domino Effect Originating in the “Schellman Motif” Naoki Ousaka and Yoshihito Inai pp 14736–14737 DOI: 10.1021/ja063873n Supporting Info

Synthesis of Oligosubstituted Bullvalones:  Shapeshifting Molecules Under Basic Conditions Alex R. Lippert, Juthanat Kaeobamrung, and Jeffrey W. Bode pp 14738–14739 DOI: 10.1021/ja063900+ Supporting Info

The Formation of Nematic Liquid Crystal Phases by Hen Lysozyme Amyloid Fibrils Adam M. Corrigan, Christian Müller, and Mark R. H. Krebs pp 14740–14741 DOI: 10.1021/ja064455l Supporting Info

A Mo(VI) Alkylidyne Complex with Polyhedral Oligomeric Silsesquioxane Ligands:  Homogeneous Analogue of a Silica-Supported Alkyne Metathesis Catalyst Hyeon Mo Cho, Haim Weissman, Scott R. Wilson, and Jeffrey S. Moore pp 14742–14743 DOI: 10.1021/ja065101x Supporting Info

Nor-Seco-Cucurbit[10]uril Exhibits Homotropic Allosterism Wei-Hao Huang, Simin Liu, Peter Y. Zavalij, and Lyle Isaacs pp 14744–14745 DOI: 10.1021/ja064776x Supporting Info

Optical Rotation of Achiral Pentaerythritol Kacey Claborn, Javier Herreros Cedres, Christine Isborn, Alexey Zozulya, Edgar Weckert, Werner Kaminsky, and Bart Kahr pp 14746–14747 DOI: 10.1021/ja064631q Supporting Info

Study of Molecular Junctions with a Combined Surface-Enhanced Raman and Mechanically Controllable Break Junction Method Jing-Hua Tian, Bo Liu, Xiulan Li, Zhi-Lin Yang, Bin Ren, Sun-Tao Wu, Nongjian Tao, and Zhong-Qun Tian pp 14748–14749 DOI: 10.1021/ja0648615 Supporting Info

Harnessing the Energy of Molecular Recognition in a Nanomachine Having a Photochemical On/Off Switch Roger J. Coulston, Hideki Onagi, Stephen F. Lincoln, and Christopher J. Easton pp 14750–14751 DOI: 10.1021/ja0651761 Supporting Info

Nuclear Relaxation of H2 and H2@C60 in Organic Solvents Elena Sartori, Marco Ruzzi, Nicholas J. Turro, John D. Decatur, David C. Doetschman, Ronald G. Lawler, Anatoly L. Buchachenko, Yasujiro Murata, and Koichi Komatsu pp 14752–14753 DOI: 10.1021/ja065172w

Type III Polyketide Synthase β-Ketoacyl-ACP Starter Unit and Ethylmalonyl-CoA Extender Unit Selectivity Discovered by Streptomyces coelicolor Genome Mining Lijiang Song, Francisco Barona-Gomez, Christophe Corre, Longkuan Xiang, Daniel W. Udwary, Michael B. Austin, Joseph P. Noel, Bradley S. Moore, and Gregory L. Challis pp 14754–14755 DOI: 10.1021/ja065247w Supporting Info

Simple Conjugation and Purification of Quantum Dot−Antibody Complexes Using a Thermally Responsive Elastin-Protein L Scaffold As Immunofluorescent Agents U Loi Lao, Ashok Mulchandani, and Wilfred Chen pp 14756–14757 DOI: 10.1021/ja065343x Supporting Info

Proton-Selective 17O−1H Distance Measurements in Fast Magic-Angle-Spinning Solid-State NMR Spectroscopy for the Determination of Hydrogen Bond Lengths Andreas Brinkmann and Arno P. M. Kentgens pp 14758–14759 DOI: 10.1021/ja065415k Supporting Info

Self-Assembly of Facially Amphiphilic Dendrimers on Surfaces Yangbin Chen, Ashootosh V. Ambade, Dharma Rao Vutukuri, and S. Thayumanavan pp 14760–14761 DOI: 10.1021/ja065625x Supporting Info

Concurrent N−H and α-C−H Bond Activations of Pyrrolidine and Piperidine under Ambient Conditions by 18e Tungsten Allyl Nitrosyl Complexes Jenkins Y. K. Tsang, Chikako Fujita-Takayama, Miriam S. A. Buschhaus, Brian O. Patrick, and Peter Legzdins pp 14762–14763 DOI: 10.1021/ja065663g Supporting Info

Functionalization of Single-Wall Carbon Nanotubes by Tandem High-Pressure/Cr(CO)6 Activation of Diels−Alder Cycloaddition Cécilia Ménard-Moyon, Françoise Dumas, Eric Doris, and Charles Mioskowski pp 14764–14765 DOI: 10.1021/ja065698g Supporting Info

An Oligomer-Based Approach to Skeletal Diversity in Small-Molecule Synthesis David A. Spiegel, Frank C. Schroeder, Jeremy R. Duvall, and Stuart L. Schreiber pp 14766–14767 DOI: 10.1021/ja065724a Supporting Info

A Cellular FRET-Based Sensor for β-O-GlcNAc, A Dynamic Carbohydrate Modification Involved in Signaling Luz D. Carrillo, Lakshmipriya Krishnamoorthy, and Lara K. Mahal pp 14768–14769 DOI: 10.1021/ja065835+ Supporting Info

Conversion of Methanol into Hydrocarbons over Zeolite H-ZSM-5:  Ethene Formation Is Mechanistically Separated from the Formation of Higher Alkenes Stian Svelle, Finn Joensen, Jesper Nerlov, Unni Olsbye, Karl-Petter Lillerud, Stein Kolboe, and Morten Bjørgen pp 14770–14771 DOI: 10.1021/ja065810a Supporting Info

Readily Available Unprotected Amino Aldehydes Ryan Hili and Andrei K. Yudin pp 14772–14773 DOI: 10.1021/ja065898s Supporting Info

Resolving Radial Composition Gradients in Polarized Confocal Raman Spectra of Individual 3C-SiC Nanowires Joëlle Fréchette and Carlo Carraro pp 14774–14775 DOI: 10.1021/ja0656346 Supporting Info

Facile Synthesis of Gold−Silver Nanocages with Controllable Pores on the Surface Jingyi Chen, Joseph M. McLellan, Andrew Siekkinen, Yujie Xiong, Zhi-Yuan Li, and Younan Xia pp 14776–14777 DOI: 10.1021/ja066023g Supporting Info

Molecular Dynamics Calculation of the Activation Volume for Water Exchange on Li+ James R. Rustad and Andrew G. Stack pp 14778–14779 DOI: 10.1021/ja066022o

Phase-Controlled One-Dimensional Shape Evolution of InSe Nanocrystals Kang Hyun Park, Kwonho Jang, Soyoung Kim, Hae Jin Kim, and Seung Uk Son pp 14780–14781 DOI: 10.1021/ja0660711 Supporting Info

NMR Spectroscopy Can Characterize Proteins Encapsulated in a Sol-Gel Matrix Korin E. Wheeler, Judith M. Nocek, and Brian M. Hoffman pp 14782–14783 DOI: 10.1021/ja066244m Supporting Info

Methylaminated Potassium Fulleride, (CH3NH2)K3C60:  Towards Hyperexpanded Fulleride Lattices Alexey Yu. Ganin, Yasuhiro Takabayashi, Craig A. Bridges, Yaroslav Z. Khimyak, Serena Margadonna, Kosmas Prassides, and Matthew J. Rosseinsky pp 14784–14785 DOI: 10.1021/ja066295j Supporting Info

Stable Single-Layer Light-Emitting Electrochemical Cell Using 4,7-Diphenyl-1,10-phenanthroline-bis(2-phenylpyridine)iridium(III) Hexafluorophosphate Henk J. Bolink, Luca Cappelli, Eugenio Coronado, Michael Grätzel, Enrique Ortí, Rubén D. Costa, Pedro M. Viruela, and Md. K. Nazeeruddin pp 14786–14787 DOI: 10.1021/ja066416f Supporting Info

Rigid Oligonaphthalenediimide Rods as Transmembrane Anion−π Slides Virginie Gorteau, Guillaume Bollot, Jiri Mareda, Alejandro Perez-Velasco, and Stefan Matile pp 14788–14789 DOI: 10.1021/ja0665747 Supporting Info

Total Synthesis of the Diazobenzofluorene Antibiotic (−)-Kinamycin C1 Xiaoguang Lei and John A. Porco, Jr. pp 14790–14791 DOI: 10.1021/ja066621v Supporting Info

Effect of Surface Functionalization of MCM-41-Type Mesoporous Silica Nanoparticles on the Endocytosis by Human Cancer Cells Igor Slowing, Brian G. Trewyn, and Victor S.-Y. Lin pp 14792–14793 DOI: 10.1021/ja0645943 Supporting Info

Photoinduced Signal Amplification through Controlled Externally Sensitized Fragmentation in Masked Sensitizers Rudresha Kottani, Janaki R. R. Majjigapu, Alexei Kurchan, Kavitha Majjigapu, Tiffany P. Gustafson, and Andrei G. Kutateladze pp 14794–14795 DOI: 10.1021/ja066692u Supporting Info

Oxidative Amide Synthesis and N-Terminal α-Amino Group Ligation of Peptides in Aqueous Medium Wing-Kei Chan, Chi-Ming Ho, Man-Kin Wong, and Chi-Ming Che pp 14796–14797 DOI: 10.1021/ja064479s Supporting Info

Near-UV Induced Interstrand Cross-Links in Anthraquinone−DNA Duplexes François Bergeron, Vandana K. Nair, and J. Richard Wagner pp 14798–14799 DOI: 10.1021/ja064625u Supporting Info

Palladium-Catalyzed Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Anion Equivalent Akihiro Takemiya and John F. Hartwig pp 14800–14801 DOI: 10.1021/ja064782t Supporting Info

Highly Enantioselective Organocatalytic Biginelli Reaction Xiao-Hua Chen, Xiao-Ying Xu, Hua Liu, Lin-Feng Cun, and Liu-Zhu Gong pp 14802–14803 DOI: 10.1021/ja065267y Supporting Info

Solution Phase Isomerization of Vibrationally Excited Singlet Nitrenes to Vibrationally Excited 1,2-Didehydroazepine Gotard T. Burdzinski, Chris T. Middleton, Terry L. Gustafson, and Matthew S. Platz pp 14804–14805 DOI: 10.1021/ja065783o

An Efficient Mammalian Transfer RNA Target for Bleomycin Zhi-Fu Tao, Kazuhide Konishi, Gérard Keith, and Sidney M. Hecht pp 14806–14807 DOI: 10.1021/ja066187x Supporting Info

Remarkably Efficient Enantioselective Titanium(IV)−(R)-H8-BINOLate Catalyst for Arylations to Aldehydes by Triaryl(tetrahydrofuran)aluminum Reagents Kuo-Hui Wu and Han-Mou Gau pp 14808–14809 DOI: 10.1021/ja062080y Supporting Info

Cyclic C-Amino Phosphorus Ylides as a Source of Bidentate Heteroditopic Ligands (Phosphine/Aminocarbene) for Transition Metals Joan Vignolle, Bruno Donnadieu, Didier Bourissou, Michèle Soleilhavoup, and Guy Bertrand pp 14810–14811 DOI: 10.1021/ja0662725 Supporting Info

Beckmann Rearrangement of 15N-Cyclohexanone Oxime on Zeolites Silicalite-1, H-ZSM-5, and H-[B]ZSM-5 Studied by Solid-State NMR Spectroscopy V. R. Reddy Marthala, Yijiao Jiang, Jun Huang, Wei Wang, Roger Gläser, and Michael Hunger pp 14812–14813 DOI: 10.1021/ja066392c Supporting Info

Cyclopentadienone Synthesis by Rhodium(I)-Catalyzed [3 + 2] Cycloaddition Reactions of Cyclopropenones and Alkynes Paul A. Wender, Thomas J. Paxton, and Travis J. Williams pp 14814–14815 DOI: 10.1021/ja065868p Supporting Info

Ruthenium-catalyzed [2 + 2 + 1] Cocyclization of Isocyanates, Alkynes, and CO Enables the Rapid Synthesis of Polysubstituted Maleimides Teruyuki Kondo, Masato Nomura, Yasuyuki Ura, Kenji Wada, and Take-aki Mitsudo pp 14816–14817 DOI: 10.1021/ja066305g Supporting Info

Tandem Cyclization of Alkynes via Rhodium Alkynyl and Alkenylidene Catalysis Jung Min Joo, Yu Yuan, and Chulbom Lee pp 14818–14819 DOI: 10.1021/ja066374v Supporting Info

High Frequency Dielectric Response in a Branched Phthalocyanine Meng Guo, Xingzhong Yan, Young Kwon, Teruaki Hayakawa, Masa-aki Kakimoto, and Theodore Goodson III pp 14820–14821 DOI: 10.1021/ja063796w Supporting Info

Cationic Zinc Enolates as Highly Active Catalysts for Acrylate Polymerization Logan E. Garner, Hongping Zhu, Mark L. Hlavinka, John R. Hagadorn, and Eugene Y.-X. Chen pp 14822–14823 DOI: 10.1021/ja066401h Supporting Info

Uncatalyzed Zirconium-Mediated Biphenylation of o-Dihalobenzenes To Form Triphenylenes Cameron L. Hilton, Christopher R. Jamison, and Benjamin T. King p 14824 DOI: 10.1021/ja065602i Supporting Info

Enantioselective Synthesis of N1999A2 Nan Ji, Hardwin O'Dowd, Brad M. Rosen, and Andrew G. Myers pp 14825–14827 DOI: 10.1021/ja0662467 Supporting Info

Electrochemical Origin of Voltage-Controlled Molecular Conductance Switching Jin He, Qiang Fu, Stuart Lindsay, Jacob W. Ciszek, and James M. Tour pp 14828–14835 DOI: 10.1021/ja0635433 Supporting Info

Generation and Reactivity of Simple Chloro(aryl)carbenes within the Cavities of Nonacidic Zeolites Reinaldo Moya-Barrios and Frances L. Cozens pp 14836–14844 DOI: 10.1021/ja064779+

Carbenoid Chain Reactions:  Substitutions by Organolithium Compounds at Unactivated 1-Chloro-1-alkenes Rudolf Knorr, Claudio Pires, Claudia Behringer, Thomas Menke, Johannes Freudenreich, Eva C. Rossmann, and Petra Böhrer pp 14845–14853 DOI: 10.1021/ja0649116 Supporting Info

Thermal [1,5] Hydrogen Sigmatropic Shifts in cis,cis-1,3-Cyclononadienes Probed by Gas-Phase Kinetic Studies and Density Functional Theory Calculations John E. Baldwin, Anuradha S. Raghavan, B. Andes Hess, Jr., and Lidia Smentek pp 14854–14862 DOI: 10.1021/ja065656s Supporting Info

Polyhedral Gold Nanocrystals with Oh Symmetry:  From Octahedra to Cubes Daeha Seo, Ji Chan Park, and Hyunjoon Song pp 14863–14870 DOI: 10.1021/ja062892u Supporting Info

Chiral Recognition in Cucurbituril Cavities Mikhail V. Rekharsky, Hatsuo Yamamura, Chika Inoue, Masao Kawai, Issey Osaka, Ryuichi Arakawa, Kouhei Shiba, Akihiro Sato, Young Ho Ko, Narayanan Selvapalam, Kimoon Kim, and Yoshihisa Inoue pp 14871–14880 DOI: 10.1021/ja063323p Supporting Info

Catalytically Induced Electrokinetics for Motors and Micropumps Walter F. Paxton, Paul T. Baker, Timothy R. Kline, Yang Wang, Thomas E. Mallouk, and Ayusman Sen pp 14881–14888 DOI: 10.1021/ja0643164 Supporting Info

Synthesis of MIL-102, a Chromium Carboxylate Metal−Organic Framework, with Gas Sorption Analysis Suzy Surblé, Franck Millange, Christian Serre, Tina Düren, Michel Latroche, Sandrine Bourrelly, Philip L. Llewellyn, and Gérard Férey pp 14889–14896 DOI: 10.1021/ja064343u

In Vivo and in Vitro Lipid Peroxidation of Arachidonate Esters:  The Effect of Fish Oil ω-3 Lipids on Product Distribution Todd A. Davis, Ling Gao, Huiyong Yin, Jason D. Morrow, and Ned A. Porter pp 14897–14904 DOI: 10.1021/ja064399o Supporting Info

Base Pair Recognition of the Stereochemically α-Substituted γ-Turn of Pyrrole/Imidazole Hairpin Polyamides Wen Zhang, Masafumi Minoshima, and Hiroshi Sugiyama pp 14905–14912 DOI: 10.1021/ja064369l Supporting Info

The Dynamics of Self-Trapped Beams of Incoherent White Light in a Free-Radical Photopolymerizable Medium Jihua Zhang and Kalaichelvi Saravanamuttu pp 14913–14923 DOI: 10.1021/ja0645335 Supporting Info

Chiral Translation and Cooperative Self-Assembly of Discrete Helical Structures Using Molecular Recognition Dyads Hiroshi Nakade, Brian J. Jordan, Hao Xu, Gang Han, Sudhanshu Srivastava, Rochelle R. Arvizo, Graeme Cooke, and Vincent M. Rotello pp 14924–14929 DOI: 10.1021/ja064554z Supporting Info

Thin Film Voltammetry of Spinach Photosystem II. Proton-Gated Electron Transfer Involving the Mn4 Cluster Khrisna Alcantara, Bernard Munge, Zeus Pendon, Harry A. Frank, and James F. Rusling pp 14930–14937 DOI: 10.1021/ja0645537 Supporting Info

A Mechanistic Dichotomy in Scandium Ion-Promoted Hydride Transfer of an NADH Analogue:  Delicate Balance between One-Step Hydride-Transfer and Electron-Transfer Pathways Junpei Yuasa, Shunsuke Yamada, and Shunichi Fukuzumi pp 14938–14948 DOI: 10.1021/ja064708a Supporting Info

Synthesis, Structure, and Chemistry of New, Mixed Group 14 and 16 Heterocycles:  Nucleophile-Induced Ring Contraction of Mesocyclic Dications Eric Block, Evgeny V. Dikarev, Richard S. Glass, Jin Jin, Bo Li, Xiaojie Li, and Shao-Zhong Zhang pp 14949–14961 DOI: 10.1021/ja065037j Supporting Info

A Synthetic Cycle for the Ruthenium-Promoted Formation of 1H-Phosphindoles from Phosphaalkynes Joseph G. Cordaro, Daniel Stein, and Hansjörg Grützmacher pp 14962–14971 DOI: 10.1021/ja0651198 Supporting Info

Direct Visualization of Enzymatic Cleavage and Oxidative Damage by Hydroxyl Radicals of Single-Stranded DNA with a Cationic Polythiophene Derivative Yanli Tang, Fude Feng, Fang He, Shu Wang, Yuliang Li, and Daoben Zhu pp 14972–14976 DOI: 10.1021/ja065159b

Catalytic Asymmetric Synthesis of Acyclic Arrays by Tandem 1,4-Addition-Aldol Reactions Gareth P. Howell, Stephen P. Fletcher, Koen Geurts, Bjorn ter Horst, and Ben L. Feringa pp 14977–14985 DOI: 10.1021/ja0651862 Supporting Info

Asymmetric Synthesis of Highly Functionalized Tetrahydrothiophenes by Organocatalytic Domino Reactions Sven Brandau, Eddy Maerten, and Karl Anker Jørgensen pp 14986–14991 DOI: 10.1021/ja065507+ Supporting Info

Assembly of Triangular Trimetallic Complexes by Triamidophosphine Ligands:  Spin-Frustrated Mn2+ Plaquettes and Diamagnetic Mg2+ Analogues with a Combined Through-Space, Through-Bond Pathway for 31P-31P Spin−Spin Coupling Jillian A. Hatnean, Ritu Raturi, Julie Lefebvre, Daniel B. Leznoff, Gavin Lawes, and Samuel A. Johnson pp 14992–14999 DOI: 10.1021/ja065597i Supporting Info

A Well-Defined Hydrocarbon-Soluble Calcium Hydroxide:  Synthesis, Structure, and Reactivity Christian Ruspic, Sharanappa Nembenna, Anja Hofmeister, Jörg Magull, Sjoerd Harder, and Herbert W. Roesky pp 15000–15004 DOI: 10.1021/ja065631t Supporting Info

AlMe3 and ZnMe2 Adducts of a Titanium Imido Methyl Cation:  A Combined Crystallographic, Spectroscopic, and DFT Study Paul D. Bolton, Eric Clot, Andrew R. Cowley, and Philip Mountford pp 15005–15018 DOI: 10.1021/ja065638a Supporting Info

Shuttling Mechanism of Ion Transfer at the Interface between Two Immiscible Liquids François O. Laforge, Peng Sun, and Michael V. Mirkin pp 15019–15025 DOI: 10.1021/ja0656090 Supporting Info

Sugar-Assisted Ligation of N-Linked Glycopeptides with Broad Sequence Tolerance at the Ligation Junction Ashraf Brik, Simon Ficht, Yu-Ying Yang, Clay S. Bennett, and Chi-Huey Wong pp 15026–15033 DOI: 10.1021/ja065601q Supporting Info

Modulating Rhodopsin Receptor Activation by Altering the pKa of the Retinal Schiff Base  [J. Am. Chem. Soc. 2006, 128, 10503−10512].  Reiner Vogel, Friedrich Siebert, Elsa C. Y. Yan, Thomas P. Sakmar, Amiram Hirshfeld, and Mordechai Sheves p 15034 DOI: 10.1021/ja069975v

Issue 47

Preparation of Hierarchically Porous Nickel from Macroporous Silicon Xi Zhang and King-Ning Tu pp 15036–15037 DOI: 10.1021/ja062562+

Coiled Molecules in Spring Loaded Devices Dariush Ajami and Julius Rebek, Jr pp 15038–15039 DOI: 10.1021/ja064233n

Compaction Dynamics of Single DNA Molecules under Tension Wen-Bo Fu, Xiao-Ling Wang, Xing-Hua Zhang, Shi-Yong Ran, Jie Yan, and Ming Li pp 15040–15041 DOI: 10.1021/ja064305a Supporting Info

13C Direct Detected NMR Increases the Detectability of Residual Dipolar Couplings Stéphane Balayssac, Ivano Bertini, Claudio Luchinat, Giacomo Parigi, and Mario Piccioli pp 15042–15043 DOI: 10.1021/ja0645436 Supporting Info

Symmetrical Gas-Phase Dissociation of Noncovalent Protein Complexes via Surface Collisions Christopher M. Jones, Richard L. Beardsley, Asiri S. Galhena, Shai Dagan, Guilong Cheng, and Vicki H. Wysocki pp 15044–15045 DOI: 10.1021/ja064586m Supporting Info

Ionic-like Behavior of Oppositely Charged Nanoparticles Alexander M. Kalsin, Bartlomiej Kowalczyk, Stoyan K. Smoukov, Rafal Klajn, and Bartosz A. Grzybowski pp 15046–15047 DOI: 10.1021/ja0642966 Supporting Info

Oxidative Cross-Coupling through Double Transmetallation:  Surprisingly High Selectivity for Palladium-Catalyzed Cross-Coupling of Alkylzinc and Alkynylstannanes Yingsheng Zhao, Haibo Wang, Xiaohui Hou, Yanhe Hu, Aiwen Lei, Heng Zhang, and Lizheng Zhu pp 15048–15049 DOI: 10.1021/ja0647351 Supporting Info

Iron-Catalyzed Carbometalation of Propargylic and Homopropargylic Alcohols Donghui Zhang and Joseph M. Ready pp 15050–15051 DOI: 10.1021/ja0647708 Supporting Info

Thickness-Dependent Structural Transitions in Fluorinated Copper-phthalocyanine (F16CuPc) Films Dimas G. de Oteyza, Esther Barrena, J. Oriol Ossó, Stefan Sellner, and Helmut Dosch pp 15052–15053 DOI: 10.1021/ja064641r Supporting Info

One-Step Microwave Preparation of Well-Defined and Functionalized Polymeric Nanoparticles Zesheng An, Wei Tang, Craig J. Hawker, and Galen D. Stucky pp 15054–15055 DOI: 10.1021/ja065250f Supporting Info

Transient Terminal Cu−Nitrene Intermediates from Discrete Dicopper Nitrenes Yosra M. Badiei, Ammani Krishnaswamy, Marie M. Melzer, and Timothy H. Warren pp 15056–15057 DOI: 10.1021/ja065299l Supporting Info

Increased Alignment of Electronic Polymers in Liquid Crystals via Hydrogen Bonding Extension Johan Hoogboom and Timothy M. Swager pp 15058–15059 DOI: 10.1021/ja065662o Supporting Info

Frustrated Organic Solids Display Unexpected Gas Sorption Praveen K. Thallapally, Scott J. Dalgarno, and Jerry L. Atwood pp 15060–15061 DOI: 10.1021/ja065499x Supporting Info

Self-Organized Interconnect Method for Molecular Devices Masateru Taniguchi, Yoshihiro Nojima, Kazumichi Yokota, Jun Terao, Kimihiko Sato, Nobuaki Kambe, and Tomoji Kawai pp 15062–15063 DOI: 10.1021/ja065806z Supporting Info

A Controlled-Release Strategy for the Generation of Cross-Linked Hydrogel Microstructures Giovanni Talei Franzesi, Bin Ni, Yibo Ling, and Ali Khademhosseini pp 15064–15065 DOI: 10.1021/ja065867x Supporting Info

Light-Induced Flipping of a Conserved Glutamine Sidechain and Its Orientation in the AppA BLUF Domain Jeffrey S. Grinstead, Marcela Avila-Perez, Klaas J. Hellingwerf, Rolf Boelens, and Robert Kaptein pp 15066–15067 DOI: 10.1021/ja0660103 Supporting Info

Synthesis, Structural Characterization, and Spectroscopy of the Cadmium−Cadmium Bonded Molecular Species Ar‘CdCdAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) Zhongliang Zhu, Roland C. Fischer, James C. Fettinger, Eric Rivard, Marcin Brynda, and Philip P. Power pp 15068–15069 DOI: 10.1021/ja066108h Supporting Info

Very High Third-Order Nonlinear Optical Activities of Intrazeolite PbS Quantum Dots Hyun Sung Kim, Myoung Hee Lee, Nak Cheon Jeong, Seung Mook Lee, Bum Ku Rhee, and Kyung Byung Yoon pp 15070–15071 DOI: 10.1021/ja0661966 Supporting Info

Multimodal Image-Guided Enzyme/Prodrug Cancer Therapy Cong Li, Paul T. Winnard, Jr., Tomoyo Takagi, Dmitri Artemov, and Zaver M. Bhujwalla pp 15072–15073 DOI: 10.1021/ja066199i Supporting Info

Ferroelectric Porous Molecular Crystal, [Mn3(HCOO)6](C2H5OH), Exhibiting Ferrimagnetic Transition HengBo Cui, Zheming Wang, Kazuyuki Takahashi, Yoshinori Okano, Hayao Kobayashi, and Akiko Kobayashi pp 15074–15075 DOI: 10.1021/ja0665390 Supporting Info

Sequential Hydrocarbon Functionalization:  Allylic C−H Oxidation/Vinylic C−H Arylation Jared H. Delcamp and M. Christina White pp 15076–15077 DOI: 10.1021/ja066563d Supporting Info

Templated Synthesis of Single-Walled Carbon Nanotube and Metal Nanoparticle Assemblies in Solution Dan Wang, Zi-Chen Li, and Liwei Chen pp 15078–15079 DOI: 10.1021/ja066617j Supporting Info

Resonance Stabilized Bisdiselenazolyls as Neutral Radical Conductors Jaclyn L. Brusso, Kristina Cvrkalj, Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, and Craig M. Robertson pp 15080–15081 DOI: 10.1021/ja0666856 Supporting Info

Structure and Catalytic Function of Re-Oxo Species Grafted onto H-MFI Zeolite by Sublimation of Re2O7 Howard S. Lacheen, Paul J. Cordeiro, and Enrique Iglesia pp 15082–15083 DOI: 10.1021/ja065832x Supporting Info

The Total Synthesis of Moenomycin A James G. Taylor, Xuechen Li, Markus Oberthür, Wenjiang Zhu, and Daniel E. Kahne pp 15084–15085 DOI: 10.1021/ja065907x Supporting Info

Measurement of the α-Secondary Kinetic Isotope Effect for the Reaction Catalyzed by Mammalian Protein Farnesyltransferase June E. Pais, Katherine E. Bowers, and Carol A. Fierke pp 15086–15087 DOI: 10.1021/ja065838m Supporting Info

Chiral N-Heterocyclic Carbene Catalyzed, Enantioselective Oxodiene Diels−Alder Reactions with Low Catalyst Loadings Ming He, Gerson J. Uc, and Jeffrey W. Bode pp 15088–15089 DOI: 10.1021/ja066380r Supporting Info

Gadolinium-Based Hybrid Nanoparticles as a Positive MR Contrast Agent Hiroki Hifumi, Seiichi Yamaoka, Akihiro Tanimoto, Daniel Citterio, and Koji Suzuki pp 15090–15091 DOI: 10.1021/ja066442d Supporting Info

Simple and Versatile Method for Tagging Phenyldiazirine Photophores Hiroyuki Nakashima, Makoto Hashimoto, Yutaka Sadakane, Takenori Tomohiro, and Yasumaru Hatanaka pp 15092–15093 DOI: 10.1021/ja066479y Supporting Info

Efficient Intermolecular [2 + 2 + 2] Alkyne Cyclotrimerization in Aqueous Medium Using a Ruthenium(IV) Precatalyst Victorio Cadierno, Sergio E. García-Garrido, and José Gimeno pp 15094–15095 DOI: 10.1021/ja066552k Supporting Info

“Click to Chelate”:  Synthesis and Installation of Metal Chelates into Biomolecules in a Single Step Thomas L. Mindt, Harriet Struthers, Luc Brans, Todor Anguelov, Christian Schweinsberg, Veronique Maes, Dirk Tourwé, and Roger Schibli pp 15096–15097 DOI: 10.1021/ja066779f Supporting Info

Amphiphilicity-Driven Organization of Nanoparticles into Discrete Assemblies Eugene R. Zubarev, Jun Xu, Arshad Sayyad, and Jacob D. Gibson pp 15098–15099 DOI: 10.1021/ja066708g Supporting Info

Simultaneous Determination of Protein Backbone Structure and Dynamics from Residual Dipolar Couplings Guillaume Bouvignies, Phineus Markwick, Rafael Brüschweiler, and Martin Blackledge pp 15100–15101 DOI: 10.1021/ja066704b Supporting Info

Synthesis of Methane in Nanotube Channels by a Flash Deng-Zhu Guo, Zeng-Quan Xue, Qi Chen, Geng-Min Zhang, Zhao-Xiang Zhang, and Zhen-Nan Gu pp 15102–15103 DOI: 10.1021/ja066909k Supporting Info

Insights into the Molecular Mechanism Underlying Polymorph Selection Caroline Desgranges and Jerome Delhommelle pp 15104–15105 DOI: 10.1021/ja0670310 Supporting Info

Highly Convergent Total Synthesis of (+)-Acutiphycin Ryan M. Moslin and Timothy F. Jamison pp 15106–15107 DOI: 10.1021/ja0670660 Supporting Info

X-ray Crystal Structures of Manganese(II)-Reconstituted and Native Toluene/o-Xylene Monooxygenase Hydroxylase Reveal Rotamer Shifts in Conserved Residues and an Enhanced View of the Protein Interior Michael S. McCormick, Matthew H. Sazinsky, Karen L. Condon, and Stephen J. Lippard pp 15108–15110 DOI: 10.1021/ja064837r Supporting Info

Low Polydispersity Star Polymers via Cross-Linking Macromonomers by ATRP Haifeng Gao, Shigeki Ohno, and Krzysztof Matyjaszewski pp 15111–15113 DOI: 10.1021/ja066964t Supporting Info

Antibodies with Broad Specificity to Azaspiracids by Use of Synthetic Haptens Craig J. Forsyth, Jianyan Xu, Son T. Nguyen, Ingunn A. Samdal, Lyn R. Briggs, Thomas Rundberget, Morten Sandvik, and Christopher O. Miles pp 15114–15116 DOI: 10.1021/ja066971h Supporting Info

Origin of the Linear Relationship between CH2/NH/O−SWNT Reaction Energies and Sidewall Curvature: Armchair Nanotubes Guishan Zheng, Zhi Wang, Stephan Irle, and Keiji Morokuma pp 15117–15126 DOI: 10.1021/ja061306u Supporting Info

Geometry, Energetics, and Dynamics of Hydrogen Bonds in Proteins:  Structural Information Derived from NMR Scalar Couplings Joerg Gsponer, Harri Hopearuoho, Andrea Cavalli, Christopher M. Dobson, and Michele Vendruscolo pp 15127–15135 DOI: 10.1021/ja0614722 Supporting Info

Neutron Diffraction and Simulation Studies of CsNO3 and Cs2CO3 Solutions Philip E. Mason, George W. Neilson, Christopher E. Dempsey, and John W. Brady pp 15136–15144 DOI: 10.1021/ja0613207 Supporting Info

Supramolecular Bis(rutheniumphthalocyanine)−Perylenediimide Ensembles:  Simple Complexation as a Powerful Tool toward Long-Lived Radical Ion Pair States M. Salomé Rodríguez-Morgade, Tomás Torres, Carmen Atienza-Castellanos, and Dirk M. Guldi pp 15145–15154 DOI: 10.1021/ja0622195 Supporting Info

Hydration of Mononucleotides Dengfeng Liu, Thomas Wyttenbach, and Michael T. Bowers pp 15155–15163 DOI: 10.1021/ja062418o Supporting Info

N-Methylated Cyclic Pentaalanine Peptides as Template Structures Jayanta Chatterjee, Dale Mierke, and Horst Kessler pp 15164–15172 DOI: 10.1021/ja063123d Supporting Info

Conformationally Constrained 2‘-N,4‘-C-Ethylene-Bridged Thymidine (Aza-ENA-T):  Synthesis, Structure, Physical, and Biochemical Studies of Aza-ENA-T-Modified Oligonucleotides Oommen P. Varghese, Jharna Barman, Wimal Pathmasiri, Oleksandr Plashkevych, Dmytro Honcharenko, and Jyoti Chattopadhyaya pp 15173–15187 DOI: 10.1021/ja0634977 Supporting Info

Unraveling the Aflatoxin−FAPY Conundrum:  Structural Basis for Differential Replicative Processing of Isomeric Forms of the Formamidopyrimidine-Type DNA Adduct of Aflatoxin B1 Kyle L. Brown, James Z. Deng, Rajkumar S. Iyer, Lalitha G. Iyer, Markus W. Voehler, Michael P. Stone, Constance M. Harris, and Thomas M. Harris pp 15188–15199 DOI: 10.1021/ja063781y Supporting Info

15N Solid-State NMR Provides a Sensitive Probe of Oxidized Flavin Reactive Sites Ronald L. Koder, Jr., Joseph D. Walsh, Maxim S. Pometun, P. Leslie Dutton, Richard J. Wittebort, and Anne-Frances Miller pp 15200–15208 DOI: 10.1021/ja0648817 Supporting Info

Direct Observation of Substrate−Enzyme Complexation by Surface Forces Measurement1 Takehiro Suzuki, Yuan-Wei Zhang, Tanetoshi Koyama, Darryl Y. Sasaki, and Kazue Kurihara pp 15209–15214 DOI: 10.1021/ja061822k

Enantioselective Synthesis of Diversely Substituted Quaternary 1,4-Benzodiazepin-2-ones and 1,4-Benzodiazepine-2,5-diones Paul R. Carlier, Hongwu Zhao, Stephanie L. MacQuarrie-Hunter, Joseph C. DeGuzman, and Danny C. Hsu pp 15215–15220 DOI: 10.1021/ja0640142 Supporting Info

Lipid Lateral Mobility and Membrane Phase Structure Modulation by Protein Binding Martin B. Forstner, Chanel K. Yee, Atul N. Parikh, and Jay T. Groves pp 15221–15227 DOI: 10.1021/ja064093h Supporting Info

Chemistry of Periodate-Mediated Cross-Linking of 3,4-Dihydroxylphenylalanine-Containing Molecules to Proteins Bo Liu, Lyle Burdine, and Thomas Kodadek pp 15228–15235 DOI: 10.1021/ja065794h Supporting Info

Intramolecular Sulfur Transfer in N-Enoyl Oxazolidine-2-thiones Promoted by Brønsted Acids. Practical Asymmetric Synthesis of β-Mercapto Carboxylic Acids and Mechanistic Insights Claudio Palomo, Mikel Oiarbide, Rosa López, Pedro B. González, Enrique Gómez-Bengoa, José M. Saá, and Anthony Linden pp 15236–15247 DOI: 10.1021/ja0654027 Supporting Info

Dissection of Aminoglycoside−Enzyme Interactions:  A Calorimetric and NMR Study of Neomycin B Binding to the Aminoglycoside Phosphotransferase(3‘)-IIIa Can Özen, Joseph M. Malek, and Engin H. Serpersu pp 15248–15254 DOI: 10.1021/ja0643220 Supporting Info

Topological Control in Heterometallic Metal−Organic Frameworks by Anion Templating and Metalloligand Design Sara R. Halper, Loi Do, Jay R. Stork, and Seth M. Cohen pp 15255–15268 DOI: 10.1021/ja0645483 Supporting Info

Cation Exchange in Lipophilic G-Quadruplexes:  Not All Ion Binding Sites Are Equal Ling Ma, Maura Iezzi, Mark S. Kaucher, Yiu-Fai Lam, and Jeffery T. Davis pp 15269–15277 DOI: 10.1021/ja064878n Supporting Info

A Rational Approach to Minimal High-Resolution Cross-Reactive Arrays Eric Green, Mark J. Olah, Tatiana Abramova, Lance R. Williams, Darko Stefanovic, Tilla Worgall, and Milan N. Stojanovic pp 15278–15282 DOI: 10.1021/ja0642663 Supporting Info

Simulating Self-Assembly of ZnS Nanoparticles into Mesoporous Materials Dean C. Sayle, Benoît C. Mangili, Jacek Klinowski, and Thi. X. T. Sayle pp 15283–15291 DOI: 10.1021/ja0650697 Supporting Info

FAST-NMR:  Functional Annotation Screening Technology Using NMR Spectroscopy Kelly A. Mercier, Michael Baran, Viswanathan Ramanathan, Peter Revesz, Rong Xiao, Gaetano T. Montelione, and Robert Powers pp 15292–15299 DOI: 10.1021/ja0651759

Determination of the Adsorption Isotherm of Methanol on the Surface of Ice. An Experimental and Grand Canonical Monte Carlo Simulation Study Pál Jedlovszky, Lívia Pártay, Paul N. M. Hoang, Sylvain Picaud, Philipp von Hessberg, and John N. Crowley pp 15300–15309 DOI: 10.1021/ja065553+ Supporting Info

On the Mechanism of Hydrolysis of Phosphate Monoesters Dianions in Solutions and Proteins Marco Klähn, Edina Rosta, and Arieh Warshel pp 15310–15323 DOI: 10.1021/ja065470t Supporting Info

Solution-Phase Single Quantum Dot Fluorescence Resonance Energy Transfer Thomas Pons, Igor L. Medintz, Xiang Wang, Douglas S. English, and Hedi Mattoussi pp 15324–15331 DOI: 10.1021/ja0657253 Supporting Info

Temperature-Responsive Protein Pores Yuni Jung, Hagan Bayley, and Liviu Movileanu pp 15332–15340 DOI: 10.1021/ja065827t Supporting Info

Distinct Kinetic Pathways Generate Organogel Networks with Contrasting Fractality and Thixotropic Properties Xiao Huang, Srinivasa R. Raghavan, Pierre Terech, and Richard G. Weiss pp 15341–15352 DOI: 10.1021/ja0657206 Supporting Info

Issue 48

Control of Antigen Presentation with a Photoreleasable Agonist Peptide Andrew L. DeMond, Toby Starr, Michael L. Dustin, and Jay T. Groves pp 15354–15355 DOI: 10.1021/ja065304l Supporting Info

Activity-Based Substrate Profiling for Gcn5-Related N-Acetyltransferases:  The Use of Chloroacetyl-Coenzyme A To Identify Protein Substrates Michael Yu, Luiz Pedro Sorio de Carvalho, Guangxing Sun, and John S. Blanchard pp 15356–15357 DOI: 10.1021/ja066298w Supporting Info

Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET Hongyi Hou, Ken C.-F. Leung, Daniela Lanari, Alshakim Nelson, J. Fraser Stoddart, and Robert H. Grubbs pp 15358–15359 DOI: 10.1021/ja065572j Supporting Info

Critical Guest Concentration and Complete Tuning Pattern Appearing in the Binary Clathrate Hydrates Do-Youn Kim, Jeasung Park, Jong-won Lee, John A. Ripmeester, and Huen Lee pp 15360–15361 DOI: 10.1021/ja0655791 Supporting Info

Hybrid Gold/Silica/Nanocrystal-Quantum-Dot Superstructures:  Synthesis and Analysis of Semiconductor−Metal Interactions Nanguo Liu, Bradley S. Prall, and Victor I. Klimov pp 15362–15363 DOI: 10.1021/ja0660296 Supporting Info

Unexpected Acetylcholinesterase Activity of Cocaine Esterases Claude J. Rogers, Lisa M. Eubanks, Tobin J. Dickerson, and Kim D. Janda pp 15364–15365 DOI: 10.1021/ja066241+ Supporting Info

A Synthetic Mimic of Protein Inner Space:  Buried Polar Interactions in a Deep Water-Soluble Host Sara M. Butterfield and Julius Rebek, Jr. pp 15366–15367 DOI: 10.1021/ja0663374 Supporting Info

Azotolane Liquid-Crystalline Polymers:  Huge Change in Birefringence by Photoinduced Alignment Change Kunihiko Okano, Osamu Tsutsumi, Atsushi Shishido, and Tomiki Ikeda pp 15368–15369 DOI: 10.1021/ja0664382 Supporting Info

Self-Assembly of Coordination Polymers:  Evidence for Dynamic Exchange between Oligomers in Solution and the Isolation of a Homochiral Decagold(I) Oligomer Craig A. Wheaton, Michael C. Jennings, and Richard J. Puddephatt pp 15370–15371 DOI: 10.1021/ja066450u Supporting Info

FEP-Guided Selection of Bicyclic Heterocycles in Lead Optimization for Non-Nucleoside Inhibitors of HIV-1 Reverse Transcriptase Joseph T. Kim, Andrew D. Hamilton, Christopher M. Bailey, Robert A. Domoal, Ligong Wang, Karen S. Anderson, and William L. Jorgensen pp 15372–15373 DOI: 10.1021/ja066472g Supporting Info

Homo- and Hetero-[3]Rotaxanes with Two π-Systems Clasped in a Single Macrocycle Eric J. F. Klotz, Tim D. W. Claridge, and Harry L. Anderson pp 15374–15375 DOI: 10.1021/ja0665139 Supporting Info

Probing Biocatalytic Transformations with CdSe−ZnS QDs Ron Gill, Ronit Freeman, Jian-Ping Xu, Itamar Willner, Shira Winograd, Itzik Shweky, and Uri Banin pp 15376–15377 DOI: 10.1021/ja066636t Supporting Info

Asymmetric Modular Synthesis of Highly Functionalized Medium-Sized Carbocycles and Lactones via Ring-Closing Metathesis of Sulfoximine-Substituted Trienes Michal Lejkowski, Hans-Joachim Gais, Prabal Banerjee, and Cornelia Vermeeren pp 15378–15379 DOI: 10.1021/ja0651658 Supporting Info

Ethidium and Proflavine Binding to a 2‘,5‘-Linked RNA Duplex Eric D. Horowitz and Nicholas V. Hud pp 15380–15381 DOI: 10.1021/ja065339l Supporting Info

Stereoselective Lewis Acid-Catalyzed α-Acylvinyl Additions Troy E. Reynolds, Ashwin R. Bharadwaj, and Karl A. Scheidt pp 15382–15383 DOI: 10.1021/ja0653674 Supporting Info

Extraordinary Atomic Mobility of Au{111} at 80 Kelvin: Effect of Styrene Adsorption Ashleigh E. Baber, Stephen C. Jensen, Erin V. Iski, and E. Charles H. Sykes pp 15384–15385 DOI: 10.1021/ja065904k Supporting Info

Enhanced Oxide Ion Conductivity in Stabilized δ-Bi2O3 Rita Punn, Antonio M. Feteira, Derek C. Sinclair, and Colin Greaves pp 15386–15387 DOI: 10.1021/ja065961d Supporting Info

Unambiguous Determination of the Ionization State of a Glycoside Hydrolase Active Site Lysine by 1H−15N Heteronuclear Correlation Spectroscopy David K. Y. Poon, Mario Schubert, Jason Au, Mark Okon, Stephen G. Withers, and Lawrence P. McIntosh pp 15388–15389 DOI: 10.1021/ja065766z Supporting Info

Metal−Ligand Cooperation in C−H and H2 Activation by an Electron-Rich PNP Ir(I) System:  Facile Ligand Dearomatization−Aromatization as Key Steps Eyal Ben-Ari, Gregory Leitus, Linda J. W. Shimon, and David Milstein pp 15390–15391 DOI: 10.1021/ja066411i Supporting Info

Solid-Phase Total Synthesis and Structure Proof of Callipeltin B Ravi Krishnamoorthy, Leslie D. Vazquez-Serrano, Jeffrey A. Turk, Jennifer A. Kowalski, Alan G. Benson, Nneka T. Breaux, and Mark A. Lipton pp 15392–15393 DOI: 10.1021/ja0666250 Supporting Info

Stereochemical Diversity in Asymmetric Cyclization via Memory of Chirality Takeo Kawabata, Seiji Matsuda, Shimpei Kawakami, Daiki Monguchi, and Katsuhiko Moriyama pp 15394–15395 DOI: 10.1021/ja0670761 Supporting Info

Controlling Regiochemistry in Negishi Carboaluminations. Fine Tuning the Ligand on Zirconium Bruce H. Lipshutz, Tom Butler, and Asher Lower pp 15396–15398 DOI: 10.1021/ja065769b Supporting Info

Lithium Diisopropylamide Solvated by Hexamethylphosphoramide:  Substrate-Dependent Mechanisms for Dehydrobrominations Yun Ma, Antonio Ramirez, Kanwal Jit Singh, Ivan Keresztes, and David B. Collum pp 15399–15404 DOI: 10.1021/ja060964b Supporting Info

Particle−Wire−Tube Mechanism for Carbon Nanotube Evolution Guixiang Du, Shouai Feng, Jianghong Zhao, Chang Song, Shuli Bai, and Zhenping Zhu pp 15405–15414 DOI: 10.1021/ja064151z

Synthesis and Reactivity of Azapalladacyclobutanes Joshua E. Ney and John P. Wolfe pp 15415–15422 DOI: 10.1021/ja0660756 Supporting Info

Radical/Ion Pair Formation in the Electrochemical Reduction of Arene Sulfenyl Chlorides Chang Ji, Mohamed Ahmida, M'hamed Chahma, and Abdelaziz Houmam pp 15423–15431 DOI: 10.1021/ja062796t Supporting Info

An Efficient Computational Method for Predicting Rotational Diffusion Tensors of Globular Proteins Using an Ellipsoid Representation Yaroslav E. Ryabov, Charles Geraghty, Amitabh Varshney, and David Fushman pp 15432–15444 DOI: 10.1021/ja062715t Supporting Info

A General Polymer-Based Process To Prepare Mixed Metal Oxides:  The Case of Zn1-xMgxO Nanoparticles Guangqiang Lu, Ingo Lieberwirth, and Gerhard Wegner pp 15445–15450 DOI: 10.1021/ja0638096

Characterization of Manganese(V)−Oxo Polyoxometalate Intermediates and Their Properties in Oxygen-Transfer Reactions Alex M. Khenkin, Devesh Kumar, Sason Shaik, and Ronny Neumann pp 15451–15460 DOI: 10.1021/ja0638455 Supporting Info

Characterization of Structure and Stability of Long Telomeric DNA G-Quadruplexes Hai-Qing Yu, Daisuke Miyoshi, and Naoki Sugimoto pp 15461–15468 DOI: 10.1021/ja064536h Supporting Info

Crystal Structure and Magnetic Properties of FeTe2O5X (X = Cl, Br):  A Frustrated Spin Cluster Compound with a New Te(IV) Coordination Polyhedron Richard Becker, Mats Johnsson, Reinhard K. Kremer, Hans-Henning Klauss, and Peter Lemmens pp 15469–15475 DOI: 10.1021/ja064738d Supporting Info

A Modular Approach toward Regulating the Secondary Coordination Sphere of Metal Ions:  Differential Dioxygen Activation Assisted by Intramolecular Hydrogen Bonds Robie L. Lucas, Matthew K. Zart, Jhumpa Murkerjee, Thomas N. Sorrell, Douglas R. Powell, and A. S. Borovik pp 15476–15489 DOI: 10.1021/ja063935+ Supporting Info

Short-Lived Quinonoid Species from 5,6-Dihydroxyindole Dimers en Route to Eumelanin Polymers:  Integrated Chemical, Pulse Radiolytic, and Quantum Mechanical Investigation Alessandro Pezzella, Lucia Panzella, Orlando Crescenzi, Alessandra Napolitano, Suppiah Navaratman, Ruth Edge, Edward J. Land, Vincenzo Barone, and Marco d'Ischia pp 15490–15498 DOI: 10.1021/ja0650246 Supporting Info

Energetic Determinants of Oligomeric State Specificity in Coiled Coils Jorge Ramos and Themis Lazaridis pp 15499–15510 DOI: 10.1021/ja0655284 Supporting Info

(n,m) Abundance Evaluation of Single-Walled Carbon Nanotubes by Fluorescence and Absorption Spectroscopy Zhengtang Luo, Lisa D. Pfefferle, Gary L. Haller, and Fotios Papadimitrakopoulos pp 15511–15516 DOI: 10.1021/ja0657096 Supporting Info

Zinspy Sensors with Enhanced Dynamic Range for Imaging Neuronal Cell Zinc Uptake and Mobilization Elizabeth M. Nolan, Jubin W. Ryu, Jacek Jaworski, Rodney P. Feazell, Morgan Sheng, and Stephen J. Lippard pp 15517–15528 DOI: 10.1021/ja065759a Supporting Info

Novobiocin:  Redesigning a DNA Gyrase Inhibitor for Selective Inhibition of Hsp90 Joseph A. Burlison, Len Neckers, Andrew B. Smith, Anthony Maxwell, and Brian S. J. Blagg pp 15529–15536 DOI: 10.1021/ja065793p Supporting Info

Self-Organized Monolayer of meso-Tetradodecylporphyrin Coordinated to Au(111) Nathalie Katsonis, Javier Vicario, Tibor Kudernac, Johan Visser, Michael M. Pollard, and Ben L. Feringa pp 15537–15541 DOI: 10.1021/ja065823o Supporting Info

Immobilization of Ligands with Precise Control of Density to Electroactive Surfaces Eugene W. L. Chan and Muhammad N. Yousaf pp 15542–15546 DOI: 10.1021/ja065828l Supporting Info

Dispersion and Separation of Small-Diameter Single-Walled Carbon Nanotubes [J. Am. Chem. Soc. 2006, 128, 12239−12242]. Yutaka Maeda, Makoto Kanda, Masahiro Hashimoto, Tadashi Hasegawa, Shin-ichi Kimura, Yongfu Lian, Takatsugu Wakahara, Takeshi Akasaka, Said Kazaoui, Nobutsugu Minami, Toshiya Okazaki, Yuhei Hayamizu, Kenji Hata, Jing Lu, and Shigeru Nagase p 15547 DOI: 10.1021/ja067137v

Molded, High Surface Area Polymer Electrolyte Membranes from Cured Liquid Precursors [J. Am. Chem. Soc. 2006, 128, 12963−12972]. Zhilian Zhou, Raymond N. Dominey, Jason P. Rolland, Benjamin W. Maynor, Ashish A. Pandya, and Joseph M. DeSimone p 15547 DOI: 10.1021/ja069976n

Isolation, Structure, and Absolute Stereochemistry of Platensimycin, A Broad Spectrum Antibiotic Discovered Using an Antisense Differential Sensitivity Strategy [J. Am. Chem. Soc. 2006, 128, 11916−11920]. Sheo B. Singh, Hiranthi Jayasuriya, John G. Ondeyka, Kithsiri B. Herath, Chaowei Zhang, Deborah L. Zink, Nancy N. Tsou, Richard G. Ball, Angela Basilio, Olga Genilloud, Maria Teresa Diez, Francisca Vicente, Fernando Pelaez, Katherine Young, and Jun Wang p 15547 DOI: 10.1021/ja069977f

Modern Aspects of Electrochemistry, No. 39 Edited by C. G. Vayenas (University of Patras, Greece), Ralph E. White (University of South Carolina), and Maria E. Gamboa-Adelco (Superior, CO). Springer Science + Business Media, LLC:  New York. 2006. xxii + 280 pp. $139.00. ISBN 0-387-23371-7. Andrew A. Gewirth p 15548 DOI: 10.1021/ja069763y

Radioionidation Reactions for Pharmaceuticals:  Compendium for Effective Synthesis Strategies By Heinz H. Coenen (Institute of Nuclear Chemistry, Jülich, Germany), John Mertens (BEFY/NUGE, Bruxelles, Belgium), and Bernard Mazière (CEA/DRIPP, Orsay France). Springer:  Dordrecht. 2006. xii + 102 pp. $99.00 ISBN 1-4020-4560-3. Walter Loveland p 15548 DOI: 10.1021/ja069779o

Handbook of Practical X-Ray Fluorescence Analy-sis Edited by Burkhard Beckhoff (Physikalisch-Technische Bundesanstalt, Berlin, Germany), Birgit Kanngiesser (Technische Universität Berlin), Norbert Langhoff (IfG-Inst. for Scientific Instruments GmbH, Berlin), Reiner Wedell, and Helmut Wolff (Institut für Angewandte Photonik e.V., Berlin). Springer:  Berlin, Heidelberg, New York. 2006. xxiv + 864 pp. $459.00. ISBN 3-540-28603-9. p 15548 DOI: 10.1021/ja069803y

Issue 49

Structure of the Oxidized Active Site of Galactose Oxidase from Realistic In Silico Models Dalia Rokhsana, David M. Dooley, and Robert K. Szilagyi pp 15550–15551 DOI: 10.1021/ja062702f Supporting Info

Ir-Catalyzed Functionalization of 2-Substituted Indoles at the 7-Position:  Nitrogen-Directed Aromatic Borylation Sulagna Paul, Ghayoor A. Chotana, Daniel Holmes, Rebecca C. Reichle, Robert E. Maleczka, Jr., and Milton R. Smith, III pp 15552–15553 DOI: 10.1021/ja0631652 Supporting Info

Structure−Reactivity Correlations for Solid-State Enantioselective Photochemical Reactions Established Directly from Powder X-ray Diffraction Eugene Y. Cheung, Kenneth D.M. Harris, Ting Kang, John R. Scheffer, and James Trotter pp 15554–15555 DOI: 10.1021/ja063706n Supporting Info

Helix Propensity of Highly Fluorinated Amino Acids Hsien-Po Chiu, Yuta Suzuki, Donald Gullickson, Raheel Ahmad, Bashkim Kokona, Robert Fairman, and Richard P. Cheng pp 15556–15557 DOI: 10.1021/ja0640445 Supporting Info

Modification of Aniline Containing Proteins Using an Oxidative Coupling Strategy Jacob M. Hooker, Aaron P. Esser-Kahn, and Matthew B. Francis pp 15558–15559 DOI: 10.1021/ja064088d Supporting Info

Oxidized Gold as an Ultrathin Etch Resist Applied in Microcontact Printing Ruben B. A. Sharpe, Dirk Burdinski, Jurriaan Huskens, Harold J. W. Zandvliet, David N. Reinhoudt, and Bene Poelsema pp 15560–15561 DOI: 10.1021/ja065291b Supporting Info

Intermolecular Arene C−H Activation by Nickel(II) Lan-Chang Liang, Pin-Shu Chien, and Yu-Lun Huang pp 15562–15563 DOI: 10.1021/ja065505p Supporting Info

Enhanced Covariance Spectroscopy from Minimal Datasets Yanbin Chen, Fengli Zhang, Wolfgang Bermel, and Rafael Brüschweiler pp 15564–15565 DOI: 10.1021/ja065522e Supporting Info

Synthesis of Tertiary β-Hydroxy Amides by Enolate Additions to Acylsilanes Robert B. Lettan II, Troy E. Reynolds, Chris V. Galliford, and Karl A. Scheidt pp 15566–15567 DOI: 10.1021/ja065605v Supporting Info

Light-Emitting Electrochemical Cells with Millimeter-Sized Interelectrode Gap:  Low-Voltage Operation at Room Temperature Joon-Ho Shin and Ludvig Edman pp 15568–15569 DOI: 10.1021/ja0657051

Base Pairing within the ψ32,ψ39-Modified Anticodon Arm of Escherichia coli tRNAPhe Izabela Tworowska and Edward P. Nikonowicz pp 15570–15571 DOI: 10.1021/ja0659368 Supporting Info

Copper Catalyzed Asymmetric Synthesis of Chiral Allylic Esters Koen Geurts, Stephen P. Fletcher, and Ben L. Feringa pp 15572–15573 DOI: 10.1021/ja065780b Supporting Info

Singlet Oxygen Photogeneration at Surface Modified Titanium Dioxide Agnieszka Jańczyk, Elżbieta Krakowska, Grażyna Stochel, and Wojciech Macyk pp 15574–15575 DOI: 10.1021/ja065970m

Hexathiapentacene:  Structure, Molecular Packing, and Thin-Film Transistors Alejandro L. Briseno, Qian Miao, Mang-Mang Ling, Colin Reese, Hong Meng, Zhenan Bao, and Fred Wudl pp 15576–15577 DOI: 10.1021/ja066088j Supporting Info

Neutron Powder Diffraction Study of D2 Sorption in Cu3(1,3,5-benzenetricarboxylate)2 Vanessa K. Peterson, Yun Liu, Craig M. Brown, and Cameron J. Kepert pp 15578–15579 DOI: 10.1021/ja0660857 Supporting Info

Surface-Enhanced Raman Spectroscopy (SERS) for Sub-Micromolar Detection of DNA/RNA Mononucleotides Steven E. J. Bell and Narayana M. S. Sirimuthu pp 15580–15581 DOI: 10.1021/ja066263w Supporting Info

Development of High Magnetization Fe3O4/Polystyrene/Silica Nanospheres via Combined Miniemulsion/Emulsion Polymerization Hong Xu, Longlan Cui, Naihu Tong, and Hongchen Gu pp 15582–15583 DOI: 10.1021/ja066165a Supporting Info

Aptamer-Capped Nanocrystal Quantum Dots:  A New Method for Label-Free Protein Detection Jong Hyun Choi, Kok Hao Chen, and Michael S. Strano pp 15584–15585 DOI: 10.1021/ja066506k Supporting Info

Microcapsule Enabled Multicatalyst System Sarah L. Poe, Muris Kobašlija, and D. Tyler McQuade pp 15586–15587 DOI: 10.1021/ja066476l Supporting Info

Unusual Crystalline and Polycrystalline Structures in Methane Hydrates Jenel Vatamanu and Peter G. Kusalik pp 15588–15589 DOI: 10.1021/ja066515t Supporting Info

Crystalline Graphite from an Organometallic Solution-Phase Reaction Erich C. Walter, Tobias Beetz, Matthew Y. Sfeir, Louis E. Brus, and Michael L. Steigerwald pp 15590–15591 DOI: 10.1021/ja0666203 Supporting Info

Magnetic Ordering (Tc = 90 K) Observed for Layered [FeII(TCNE•-)(NCMe)2]+[FeIIICl4]- (TCNE = Tetracyanoethylene) Konstantin I. Pokhodnya, Michael Bonner, Jae-Hyuk Her, Peter W. Stephens, and Joel S. Miller pp 15592–15593 DOI: 10.1021/ja066744f Supporting Info

Effect of Protonation on the Conformation of Cinchonidine Ryan A. Olsen, Dan Borchardt, Larry Mink, Arun Agarwal, Leonard J. Mueller, and Francisco Zaera pp 15594–15595 DOI: 10.1021/ja066989s Supporting Info

DNA-Catalyzed Transfer of a Reporter Group Tom N. Grossmann and Oliver Seitz pp 15596–15597 DOI: 10.1021/ja0670097 Supporting Info

Rhodium-Catalyzed Arylative and Alkenylative Cyclization of 1,5-Enynes Induced by Geminal Carbometalation of Alkynes Yiyun Chen and Chulbom Lee pp 15598–15599 DOI: 10.1021/ja067125+ Supporting Info

Unravelling the Origin of the High-Catalytic Activity of Supported Au:  A Density-Functional Theory-Based Interpretation Norge Cruz Hernández, Javier Fdez. Sanz, and José A. Rodriguez pp 15600–15601 DOI: 10.1021/ja0670153 Supporting Info

Nucleophilic Catalysis of Hydrazone Formation and Transimination:  Implications for Dynamic Covalent Chemistry Anouk Dirksen, Sjoerd Dirksen, Tilman M. Hackeng, and Philip E. Dawson pp 15602–15603 DOI: 10.1021/ja067189k Supporting Info

Lewis Base Activation of Grignard Reagents with N-Heterocyclic Carbenes. Cu-Free Catalytic Enantioselective Additions to γ-Chloro-α,β-Unsaturated Esters Yunmi Lee and Amir H. Hoveyda pp 15604–15605 DOI: 10.1021/ja067456m Supporting Info

Preparation of Multilayered Trimodal Colloid Crystals and Binary Inverse Opals Jianjun Wang, Qin Li, Wolfgang Knoll, and Ulrich Jonas pp 15606–15607 DOI: 10.1021/ja067221a Supporting Info

Reduction Potential Tuning of the Blue Copper Center in Pseudomonas aeruginosa Azurin by the Axial Methionine as Probed by Unnatural Amino Acids Dewain K. Garner, Mark D. Vaughan, Hee Jung Hwang, Masha G. Savelieff, Steven M. Berry, John F. Honek, and Yi Lu pp 15608–15617 DOI: 10.1021/ja062732i Supporting Info

Reactions Involving Di-trans-[12]Annulenes Matthew K. Kiesewetter, Matthew N. Gard, Richard C. Reiter, and Cheryl D. Stevenson pp 15618–15624 DOI: 10.1021/ja062846u

Total Synthesis of (+)-Rishirilide B:  Development and Application of General Processes for Enantioselective Oxidative Dearomatization of Resorcinol Derivatives Lupe H. Mejorado and Thomas R. R. Pettus pp 15625–15631 DOI: 10.1021/ja062987w Supporting Info

Tandem Enyne Metathesis and Claisen Rearrangement:  A Versatile Approach to Conjugated Dienes of Variable Substitution Patterns Daniel A. Clark, Amol A. Kulkarni, Kyle Kalbarczyk, Bryan Schertzer, and Steven T. Diver pp 15632–15636 DOI: 10.1021/ja063132m Supporting Info

Density Functional Theory Studies on the Mechanism of the Reduction of CO2 to CO Catalyzed by Copper(I) Boryl Complexes Haitao Zhao, Zhenyang Lin, and Todd B. Marder pp 15637–15643 DOI: 10.1021/ja063671r Supporting Info

2D Supramolecular Assemblies of Benzene-1,3,5-triyl-tribenzoic Acid:  Temperature-Induced Phase Transformations and Hierarchical Organization with Macrocyclic Molecules Mario Ruben, Dietmar Payer, Aitor Landa, Alessio Comisso, Chiara Gattinoni, Nian Lin, Jean-Paul Collin, Jean-Pierre Sauvage, Alessandro De Vita, and Klaus Kern pp 15644–15651 DOI: 10.1021/ja063601k Supporting Info

Ultrafast Deactivation Processes in Aminopyridine Clusters:  Excitation Energy Dependence and Isotope Effects E. Samoylova, V.R. Smith, H.-H. Ritze, W. Radloff, M. Kabelac, and T. Schultz pp 15652–15656 DOI: 10.1021/ja0638612

Crystal Structures of Thermoelectric n- and p-type Ba8Ga16Ge30 Studied by Single Crystal, Multitemperature, Neutron Diffraction, Conventional X-ray Diffraction and Resonant Synchrotron X-ray Diffraction Mogens Christensen, Nina Lock, Jacob Overgaard, and Bo B. Iversen pp 15657–15665 DOI: 10.1021/ja063695y Supporting Info

Origin of Photoactivity of Nitrogen-Doped Titanium Dioxide under Visible Light Stefano Livraghi, Maria Cristina Paganini, Elio Giamello, Annabella Selloni, Cristiana Di Valentin, and Gianfranco Pacchioni pp 15666–15671 DOI: 10.1021/ja064164c Supporting Info

Intramolecular Charge-Transfer Mechanism in Quinolidines:  The Role of the Amino Twist Angle Christof Hättig, Arnim Hellweg, and Andreas Köhn pp 15672–15682 DOI: 10.1021/ja0642010 Supporting Info

Asymmetric Total Synthesis of (+)- and ent-(−)-Yatakemycin and Duocarmycin SA:  Evaluation of Yatakemycin Key Partial Structures and Its Unnatural Enantiomer Mark S. Tichenor, John D. Trzupek, David B. Kastrinsky, Futoshi Shiga, Inkyu Hwang, and Dale L. Boger pp 15683–15696 DOI: 10.1021/ja064228j Supporting Info

An Example of Lipophiloselectivity:  The Preferred Oxidation, in Water, of Hydrophobic 2-Alkanols Catalyzed by a Cross-Linked Polyethyleneimine−Polyoxometalate Catalyst Assembly Adina Haimov and Ronny Neumann pp 15697–15700 DOI: 10.1021/ja064294l Supporting Info

Binding of Muscimol-Conjugated Quantum Dots to GABAC Receptors Hélène A. Gussin, Ian D. Tomlinson, Deborah M. Little, Michael R. Warnement, Haohua Qian, Sandra J. Rosenthal, and David R. Pepperberg pp 15701–15713 DOI: 10.1021/ja064324k Supporting Info

New Benchmark for Water Photooxidation by Nanostructured α-Fe2O3 Films Andreas Kay, Ilkay Cesar, and Michael Grätzel pp 15714–15721 DOI: 10.1021/ja064380l

Magnetostructural Correlations in Polynuclear Complexes:  The Fe4 Butterflies Thomas Cauchy, Eliseo Ruiz, and Santiago Alvarez pp 15722–15727 DOI: 10.1021/ja0641498 Supporting Info

Direct Measurements of Rate Constants and Activation Volumes for the Binding of H2, D2, N2, C2H4, and CH3CN to W(CO)3(PCy3)2:  Theoretical and Experimental Studies with Time-Resolved Step-Scan FTIR and UV−Vis Spectroscopy David C. Grills, Rudi van Eldik, James T. Muckerman, and Etsuko Fujita pp 15728–15741 DOI: 10.1021/ja064627e Supporting Info

Charge Instability in Quadrupolar Chromophores:  Symmetry Breaking and Solvatochromism Francesca Terenziani, Anna Painelli, Claudine Katan, Marina Charlot, and Mireille Blanchard-Desce pp 15742–15755 DOI: 10.1021/ja064521j Supporting Info

Toward Monodispersed Silver Nanoparticles with Unusual Thermal Stability Junming Sun, Ding Ma, He Zhang, Xiumei Liu, Xiuwen Han, Xinhe Bao, Gisela Weinberg, Norbert Pfänder, and Dangsheng Su pp 15756–15764 DOI: 10.1021/ja064884j Supporting Info

Helical Metallohost−Guest Complexes via Site-Selective Transmetalation of Homotrinuclear Complexes Shigehisa Akine, Takanori Taniguchi, and Tatsuya Nabeshima pp 15765–15774 DOI: 10.1021/ja0646702 Supporting Info

Disproportionation of Pyrazine in NH+···N Hydrogen-Bonded Complexes:  New Materials of Exceptional Dielectric Response Andrzej Katrusiak and Marek Szafrański pp 15775–15785 DOI: 10.1021/ja0650192 Supporting Info

Aggregation-Mediated Optical Properties of pH-Responsive Anionic Conjugated Polyelectrolytes Fuke Wang and Guillermo C. Bazan pp 15786–15792 DOI: 10.1021/ja065061x Supporting Info

Trifluoromethyl Derivatives of Insoluble Small-HOMO−LUMO-Gap Hollow Higher Fullerenes. NMR and DFT Structure Elucidation of C2-(C74-D3h)(CF3)12, Cs-(C76-Td(2))(CF3)12, C2-(C78-D3h(5))(CF3)12, Cs-(C80-C2v(5))(CF3)12, and C2-(C82-C2(5))(CF3)12 Natalia B. Shustova, Igor V. Kuvychko, Robert D. Bolskar, Konrad Seppelt, Steven H. Strauss, Alexey A. Popov, and Olga V. Boltalina pp 15793–15798 DOI: 10.1021/ja065178l Supporting Info

Chemical Reaction-Inspired Crystal Growth of a Coordination Polymer toward Morphology Design and Control Shigeyuki Masaoka, Daisuke Tanaka, Hiroyuki Kitahata, Sumiko Araki, Ryotaro Matsuda, Kenichi Yoshikawa, Kenichi Kato, Masaki Takata, and Susumu Kitagawa pp 15799–15808 DOI: 10.1021/ja065254k Supporting Info

What Factors Influence the Ratio of CH Hydroxylation versus CC Epoxidation by a Nonheme Cytochrome P450 Biomimetic? Sam P. de Visser pp 15809–15818 DOI: 10.1021/ja065365j Supporting Info

Farnesyl Diphosphate Synthase:  The Art of Compromise between Substrate Selectivity and Stereoselectivity Hirekodathakallu V. Thulasiram and C. Dale Poulter pp 15819–15823 DOI: 10.1021/ja065573b Supporting Info

Single Wall Carbon Nanotube Amplification:  En Route to a Type-Specific Growth Mechanism Richard E. Smalley, Yubao Li, Valerie C. Moore, B. Katherine Price, Ramon Colorado, Jr., Howard K. Schmidt, Robert H. Hauge, Andrew R. Barron, and James M. Tour pp 15824–15829 DOI: 10.1021/ja065767r

Solution Chemistry of a Water-Soluble η2-H2 Ruthenium Complex:  Evidence for Coordinated H2 Acting as a Hydrogen Bond Donor Nathaniel K. Szymczak, Lev N. Zakharov, and David R. Tyler pp 15830–15835 DOI: 10.1021/ja065532f Supporting Info

Nanosecond Folding Dynamics of a Three-Stranded β-Sheet Yao Xu, Pradipta Purkayastha, and Feng Gai pp 15836–15842 DOI: 10.1021/ja064865+

The Nature and Extent of π-Stabilization within Foiled Carbenes Jean-Luc Mieusset and Udo H. Brinker pp 15843–15850 DOI: 10.1021/ja065595y Supporting Info

A General Strategy for Synthesis of Both (6Z)- and (6E)-Cladiellin Diterpenes:  Total Syntheses of (−)-Cladiella-6,11-dien-3-ol, (+)-Polyanthellin A, (−)-Cladiell-11-ene-3,6,7-triol, and (−)-Deacetoxyalcyonin Acetate Hyoungsu Kim, Hyunjoo Lee, Jayoung Kim, Sanghee Kim, and Deukjoon Kim pp 15851–15855 DOI: 10.1021/ja065782w Supporting Info

Accelerating Unimolecular Decarboxylation by Preassociated Acid Catalysis in Thiamin-Derived Intermediates:  Implicating Brønsted Acids as Carbanion Traps in Enzymes Ronald Kluger, Glenn Ikeda, Qingyan Hu, Pengpeng Cao, and Joel Drewry pp 15856–15864 DOI: 10.1021/ja066249j

Development and Validation of an Integrated Computational Approach for the Modeling of cw-ESR Spectra of Free Radicals in Solution:  p-(Methylthio)phenyl Nitronylnitroxide in Toluene as a Case Study Vincenzo Barone, Marina Brustolon, Paola Cimino, Antonino Polimeno, Mirco Zerbetto, and Alfonso Zoleo pp 15865–15873 DOI: 10.1021/ja065475q Supporting Info

Effect of Anchoring Groups on Single-Molecule Conductance:  Comparative Study of Thiol-, Amine-, and Carboxylic-Acid-Terminated Molecules Fang Chen, Xiulan Li, Joshua Hihath, Zhifeng Huang, and Nongjian Tao pp 15874–15881 DOI: 10.1021/ja065864k

Predicting Substrates by Docking High-Energy Intermediates to Enzyme Structures Johannes C. Hermann, Eman Ghanem, Yingchun Li, Frank M. Raushel, John J. Irwin, and Brian K. Shoichet pp 15882–15891 DOI: 10.1021/ja065860f Supporting Info

Resolution of Chiral Phosphate, Phosphonate, and Phosphinate Esters by an Enantioselective Enzyme Library Charity Nowlan, Yingchun Li, Johannes C. Hermann, Timothy Evans, Joseph Carpenter, Eman Ghanem, Brian K. Shoichet, and Frank M. Raushel pp 15892–15902 DOI: 10.1021/ja0658618 Supporting Info

Calix[4]arene-Linked Bisporphyrin Hosts for Fullerenes:  Binding Strength, Solvation Effects, and Porphyrin−Fullerene Charge Transfer Bands Ali Hosseini, Steven Taylor, Gianluca Accorsi, Nicola Armaroli, Christopher A. Reed, and Peter D. W. Boyd pp 15903–15913 DOI: 10.1021/ja066031x Supporting Info

Deprotonations and Charges of Well-Defined {Mo72Fe30} Nanoacids Simply Stepwise Tuned by pH Allow Control/Variation of Related Self-Assembly Processes Tianbo Liu, Brandon Imber, Ekkehard Diemann, Guang Liu, Katrina Cokleski, Huilin Li, Zhiqiang Chen, and Achim Müller pp 15914–15920 DOI: 10.1021/ja066133n

Grafting and Patterned Grafting of Block Copolymer Nanotubes onto Inorganic Substrates Kyoungmoo Koh, Guojun Liu, and C. Grant Willson pp 15921–15927 DOI: 10.1021/ja066684d Supporting Info

Characterization of the FKBP·Rapamycin·FRB Ternary Complex  [J. Am. Chem. Soc. 2005, 127, 4715−4721]. Laura A. Banaszynski, Corey W. Liu, and Thomas J. Wandless p 15928 DOI: 10.1021/ja0699788 Supporting Info

Issue 50

Magnetic Susceptibility-Induced Alignment of Proteins in Reverse Micelles Kathleen G. Valentine, Maxim S. Pometun, Joseph M. Kielec, Robert E. Baigelman, Jayme K. Staub, Kristy L. Owens, and A. Joshua Wand pp 15930–15931 DOI: 10.1021/ja061438n Supporting Info

Stabilizing and Destabilizing Effects of Phenylalanine → F5-Phenylalanine Mutations on the Folding of a Small Protein Matthew G. Woll, Erik B. Hadley, Sandro Mecozzi, and Samuel H. Gellman pp 15932–15933 DOI: 10.1021/ja0634573 Supporting Info

Highly Emissive Organic Solids Containing 2,5-Diboryl-1,4-phenylene Unit Cui-Hua Zhao, Atsushi Wakamiya, Yuko Inukai, and Shigehiro Yamaguchi pp 15934–15935 DOI: 10.1021/ja0637550 Supporting Info

Ribozyme-Mediated Signal Augmentation on a Mass-Sensitive Biosensor Scott M. Knudsen, Joonhyung Lee, Andrew D. Ellington, and Cagri A. Savran pp 15936–15937 DOI: 10.1021/ja064137m Supporting Info

Photochemically Driven Shape Changes of Crystalline Organic Nanorods Rabih O. Al-Kaysi, Astrid M. Müller, and Christopher J. Bardeen pp 15938–15939 DOI: 10.1021/ja064535p Supporting Info

A Cyclic Triphenylamine Dimer for Organic Field-Effect Transistors with High Performance Yabin Song, Chong'an Di, Xiaodi Yang, Shouping Li, Wei Xu, Yunqi Liu, Lianming Yang, Zhigang Shuai, Deqing Zhang, and Daoben Zhu pp 15940–15941 DOI: 10.1021/ja064726s Supporting Info

A Smart Magnetic Resonance Contrast Agent for Selective Copper Sensing Emily L. Que and Christopher J. Chang pp 15942–15943 DOI: 10.1021/ja065264l Supporting Info

In Situ and Ex Situ Observations of the Growth Dynamics of Single Perylene Nanocrystals in Water Takashi Tachikawa, Hae-Ryong Chung, Akito Masuhara, Hitoshi Kasai, Hidetoshi Oikawa, Hachiro Nakanishi, Mamoru Fujitsuka, and Tetsuro Majima pp 15944–15945 DOI: 10.1021/ja0654276 Supporting Info

Design and Synthesis of an Enzyme Activity-Based Labeling Molecule with Fluorescence Spectral Change Toru Komatsu, Kazuya Kikuchi, Hideo Takakusa, Kenjiro Hanaoka, Tasuku Ueno, Mako Kamiya, Yasuteru Urano, and Tetsuo Nagano pp 15946–15947 DOI: 10.1021/ja0657307 Supporting Info

Amide-to-E-Olefin versus Amide-to-Ester Backbone H-Bond Perturbations:  Evaluating the O−O Repulsion for Extracting H-Bond Energies Yanwen Fu, Jianmin Gao, Jan Bieschke, Maria A. Dendle, and Jeffery W. Kelly pp 15948–15949 DOI: 10.1021/ja065303t Supporting Info

Properties of Cu(thd)2 as a Precursor to Prepare Cu/SiO2 Catalyst Using the Atomic Layer Epitaxy Technique Ching S. Chen, Jarrn H. Lin, Jainn H. You, and Chi R. Chen pp 15950–15951 DOI: 10.1021/ja063083d

Influence of Base Dynamics on the Conformational Properties of DNA:  Observation of Static Conformational States in Rigid Duplexes at 77 K Robert K. Neely and Anita C. Jones pp 15952–15953 DOI: 10.1021/ja064390m Supporting Info

Template Synthesized Molecularly Imprinted Polymer Nanotube Membranes for Chemical Separations Hai-Juan Wang, Wen-Hui Zhou, Xiao-Fei Yin, Zhi-Xia Zhuang, Huang-Hao Yang, and Xiao-Ru Wang pp 15954–15955 DOI: 10.1021/ja065116v Supporting Info

Collagen Fibers as a Chiral Agent:  A Demonstration of Stereochemistry Effects Uzi Eliav and Gil Navon pp 15956–15957 DOI: 10.1021/ja065047k

Stereospecific Palladium-Catalyzed Cross-Coupling of (E)- and (Z)-Alkenylsilanolates with Aryl Chlorides Scott E. Denmark and Jeffrey M. Kallemeyn pp 15958–15959 DOI: 10.1021/ja065988x Supporting Info

Total Synthesis of Amphidinolide E Porino Va and William R. Roush pp 15960–15961 DOI: 10.1021/ja066663j Supporting Info

C-H Bond Activation of Arenes by a Transient η2-Cyclopropene Niobium Complex Pascal Oulié, Cédric Boulho, Laure Vendier, Yannick Coppel, and Michel Etienne pp 15962–15963 DOI: 10.1021/ja066985n Supporting Info

Catalytic C−C Bond Formation Accomplished by Selective C−F Activation of Perfluorinated Arenes Thomas Schaub, Marc Backes, and Udo Radius pp 15964–15965 DOI: 10.1021/ja064068b Supporting Info

Cytosine-Gated Hole Creation and Transfer in DNA in Aqueous Solution Robert F. Anderson, Sujata S. Shinde, and Andrej Maroz pp 15966–15967 DOI: 10.1021/ja0658416 Supporting Info

Inhibition of Energy Transfer between Conjugated Polymer Chains in Host/Guest Nanocomposites Generates White Photo- and Electroluminescence Eyal Aharon, Michael Kalina, and Gitti L. Frey pp 15968–15969 DOI: 10.1021/ja066290m Supporting Info

Contrasting Views of the Internal Dynamics of the HhaI Methyltransferase Target DNA Reported by Solution and Solid-State NMR Spectroscopy Paul A. Miller, Zahra Shajani, Gary A. Meints, Dorothy Caplow, Gil Goobes, Gabriele Varani, and Gary P. Drobny pp 15970–15971 DOI: 10.1021/ja066329n Supporting Info

Stabilization of G-Quadruplex DNA by Highly Selective Ligands via Click Chemistry Adam D. Moorhouse, Ana Mafalda Santos, Mekala Gunaratnam, Michael Moore, Stephen Neidle, and John E. Moses pp 15972–15973 DOI: 10.1021/ja0661919 Supporting Info

Controlled Gold Nanoparticle Diffusion in Nanotubes:  Platfom of Partial Functionalization and Gold Capping Sang Jun Son and Sang Bok Lee pp 15974–15975 DOI: 10.1021/ja0663632 Supporting Info

An OFF−OFF−ON Fluorescence Sensor for Metal Ions in Stepwise Complex Formation of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine with Metal Ions Junpei Yuasa and Shunichi Fukuzumi pp 15976–15977 DOI: 10.1021/ja066381j Supporting Info

Highly Connected Two-Dimensional Crystals of DNA Six-Point-Stars Yu He, Ye Tian, Alexander E. Ribbe, and Chengde Mao pp 15978–15979 DOI: 10.1021/ja0665141 Supporting Info

Facile Photochemical Synthesis of Unprotected Aqueous Gold Nanoparticles Katherine L. McGilvray, Matthew R. Decan, Dashan Wang, and Juan C. Scaiano pp 15980–15981 DOI: 10.1021/ja066522h

Biocompatible Heterostructured Nanoparticles for Multimodal Biological Detection Jin-sil Choi, Young-wook Jun, Soo-In Yeon, Hyoung Chan Kim, Jeon-Soo Shin, and Jinwoo Cheon pp 15982–15983 DOI: 10.1021/ja066547g Supporting Info

Coulombic Dragging of Molecules on Surfaces Induced by Separately Flowing Liquids Boyang Wang and Petr Král pp 15984–15985 DOI: 10.1021/ja066431k Supporting Info

Electron Donor Solvent Effects Provide Biosensing with Quantum Dots Baikuntha P. Aryal and David E. Benson pp 15986–15987 DOI: 10.1021/ja066658f Supporting Info

Evidence for Spontaneous Resolution of Icosahedral Proline Sunnie Myung, K. Patrick Lorton, Samuel I. Merenbloom, Marco Fioroni, Stormy L. Koeniger, Ryan R. Julian, Mu-Hyun Baik, and David E. Clemmer pp 15988–15989 DOI: 10.1021/ja066278u Supporting Info

Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands Armelle Ouali, Régis Laurent, Anne-Marie Caminade, Jean-Pierre Majoral, and Marc Taillefer pp 15990–15991 DOI: 10.1021/ja066505s Supporting Info

Supra-Assembly of Siliceous Vesicles Hongning Wang, Xufeng Zhou, Meihua Yu, Yunhua Wang, Lu Han, Jun Zhang, Pei Yuan, Graeme Auchterlonie, Jin Zou, and Chengzhong Yu pp 15992–15993 DOI: 10.1021/ja066707o Supporting Info

Instantaneous Carbon−Carbon Bond Formation Using a Microchannel Reactor with a Catalytic Membrane Yasuhiro Uozumi, Yoichi M. A. Yamada, Tomohiko Beppu, Naoshi Fukuyama, Masaharu Ueno, and Takehiko Kitamori pp 15994–15995 DOI: 10.1021/ja066697r Supporting Info

Amino Acids Labeled with [99mTc(CO)3]+ and Recognized by the l-type Amino Acid Transporter LAT1 Yu Liu, Jae Kyoung Pak, Paul Schmutz, Matthias Bauwens, John Mertens, Hector Knight, and Roger Alberto pp 15996–15997 DOI: 10.1021/ja066002m Supporting Info

Diphosphiranium (P2C) or Diphosphetanium (P2C2) Cyclic Cations:  Different Fates for the Electrophile-Initiated Cyclodimerization of a Phosphaalkene Joshua I. Bates and Derek P. Gates pp 15998–15999 DOI: 10.1021/ja0667662 Supporting Info

Adhesive π-Clamping within Synthetic Multifunctional Pores Hiroyuki Tanaka, Svetlana Litvinchuk, Duy-Hien Tran, Guillaume Bollot, Jiri Mareda, Naomi Sakai, and Stefan Matile pp 16000–16001 DOI: 10.1021/ja066886+ Supporting Info

High-Performance Organic Semiconductors:  Asymmetric Linear Acenes Containing Sulphur Ming L. Tang, Toshihiro Okamoto, and Zhenan Bao pp 16002–16003 DOI: 10.1021/ja066824j Supporting Info

In Search of Radical Intermediates in the Reactions Catalyzed by Lysine 2,3-Aminomutase and Lysine 5,6-Aminomutase Gregory M. Sandala, David M. Smith, and Leo Radom pp 16004–16005 DOI: 10.1021/ja0668421 Supporting Info

Oxygen Isotope Effects upon Reversible O2-Binding Reactions:  Characterizing Mononuclear Superoxide and Peroxide Structures Michael P. Lanci and Justine P. Roth pp 16006–16007 DOI: 10.1021/ja0669326 Supporting Info

Highly Enantioselective Recognition of Dicarboxylic Acid Substrates by the Control of Nonlinear Responses Tomohiro Ikeda, Osamu Hirata, Masayuki Takeuchi, and Seiji Shinkai pp 16008–16009 DOI: 10.1021/ja067001x Supporting Info

Relative Rates for the Amination of η3-Allyl and η3-Benzyl Complexes of Palladium Adam M. Johns, Jesse W. Tye, and John F. Hartwig pp 16010–16011 DOI: 10.1021/ja067084h Supporting Info

Catalyst-Transfer Polycondensation for the Synthesis of Poly(p-phenylene) with Controlled Molecular Weight and Low Polydispersity Ryo Miyakoshi, Kyohei Shimono, Akihiro Yokoyama, and Tsutomu Yokozawa pp 16012–16013 DOI: 10.1021/ja067107s Supporting Info

Ultrafast Solid-State 2D NMR Experiments via Orientational Encoding Rangeet Bhattacharyya and Lucio Frydman pp 16014–16015 DOI: 10.1021/ja067170h

Sum Frequency Generation Imaging Microscopy of CO on Platinum Katherine Cimatu and Steven Baldelli pp 16016–16017 DOI: 10.1021/ja067063n

The Total Synthesis of Tubulysin D Hillary M. Peltier, Jeffrey P. McMahon, Andrew W. Patterson, and Jonathan A. Ellman pp 16018–16019 DOI: 10.1021/ja067177z Supporting Info

Building Addressable Libraries:  The Use of a Mass Spectrometry Cleavable Linker for Monitoring Reactions on a Microelectrode Array Ceng Chen, Gabriella Nagy, Amy V. Walker, Karl Maurer, Andy McShea, and Kevin D. Moeller pp 16020–16021 DOI: 10.1021/ja067194o Supporting Info

A Nanocatalyst-Based Assay for Proteins:  DNA-Free Ultrasensitive Electrochemical Detection Using Catalytic Reduction of p-Nitrophenol by Gold-Nanoparticle Labels Jagotamoy Das, Md. Abdul Aziz, and Haesik Yang pp 16022–16023 DOI: 10.1021/ja0672167 Supporting Info

A Stable Schrock-Type Hafnium−Silylene Complex Norio Nakata, Toshiyuki Fujita, and Akira Sekiguchi pp 16024–16025 DOI: 10.1021/ja067251d Supporting Info

Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities Yu Miura, Takuya Shibata, Kotaro Satoh, Masami Kamigaito, and Yoshio Okamoto pp 16026–16027 DOI: 10.1021/ja067587n Supporting Info

Combined Redox Couples for Catalytic Oxidation of Methane by Dioxygen at Low Temperatures Zengjian An, Xiulian Pan, Xiumei Liu, Xiuwen Han, and Xinhe Bao pp 16028–16029 DOI: 10.1021/ja0647912 Supporting Info

Chemical Rescue of α3-Galactosyltransferase. Implications in the Mechanism of Retaining Glycosyltransferases Ana Monegal and Antoni Planas pp 16030–16031 DOI: 10.1021/ja0659931 Supporting Info

Driving Parts of Krebs Cycle in Reverse through Mineral Photochemistry Xiang V. Zhang and Scot T. Martin pp 16032–16033 DOI: 10.1021/ja066103k

Mechanisms of Photocatalytic Remote Oxidation Wakana Kubo and Tetsu Tatsuma pp 16034–16035 DOI: 10.1021/ja066041y

Exciplex−Exciplex Energy Transfer and Annihilation in Solid Films of Porphyrin−Fullerene Dyads Heli Lehtivuori, Helge Lemmetyinen, and Nikolai V. Tkachenko pp 16036–16037 DOI: 10.1021/ja0662366 Supporting Info

Vinyldiazolactone as a Vinylcarbene Precursor:  Highly Selective C−H Insertion and Cyclopropanation Reactions Darren Bykowski, Kou-Hui Wu, and Michael P. Doyle pp 16038–16039 DOI: 10.1021/ja066452e Supporting Info

Catalytic Carbonyl Z-Dienylation via Multicomponent Reductive Coupling of Acetylene to Aldehydes and α-Ketoesters Mediated by Hydrogen:  Carbonyl Insertion into Cationic Rhodacyclopentadienes Jong Rock Kong and Michael J. Krische pp 16040–16041 DOI: 10.1021/ja0664786 Supporting Info

Embedding an Allylmetal Dimer in a Chiral Cavity:  The Unprecedented Stereoselectivity of a Twofold Wittig [1,2]-Rearrangement Manfred Schlosser and Frédéric Bailly pp 16042–16043 DOI: 10.1021/ja066462f Supporting Info

Axially Chiral Guanidine as Highly Active and Enantioselective Catalyst for Electrophilic Amination of Unsymmetrically Substituted 1,3-Dicarbonyl Compounds Masahiro Terada, Megumi Nakano, and Hitoshi Ube pp 16044–16045 DOI: 10.1021/ja066808m Supporting Info

Exiguamine A, an Indoleamine-2,3-dioxygenase (IDO) Inhibitor Isolated from the Marine Sponge Neopetrosia exigua Harry C. Brastianos, Eduardo Vottero, Brian O. Patrick, Rob Van Soest, Teatulohi Matainaho, A. Grant Mauk, and Raymond J. Andersen pp 16046–16047 DOI: 10.1021/ja067211+ Supporting Info

Ruthenium Metallacycles Derived from 14-Electron Complexes. New Insights into Olefin Metathesis Intermediates Anna G. Wenzel and Robert H. Grubbs pp 16048–16049 DOI: 10.1021/ja0666598 Supporting Info

Enantioselective Arylation of 2-Methylacetoacetates Catalyzed by CuI/trans-4-Hydroxy-l-proline at Low Reaction Temperatures Xiaoan Xie, Yu Chen, and Dawei Ma pp 16050–16051 DOI: 10.1021/ja066991j Supporting Info

High-Oxidation-State Neutral and Cationic Tantalum(IV) Alkyl Complexes That Are Stable toward β-Hydrogen and β-Methyl Eliminations Albert Epshteyn, Peter Y. Zavalij, and Lawrence R. Sita pp 16052–16053 DOI: 10.1021/ja067011y Supporting Info

Copper-Catalyzed Rearrangement of Vinyl Oxiranes Lindsay A. Batory, Christine E. McInnis, and Jon T. Njardarson pp 16054–16055 DOI: 10.1021/ja067073o Supporting Info

Mechanism of Benzylsuccinate Synthase Probed by Substrate and Isotope Exchange Lei Li and E. Neil G. Marsh pp 16056–16057 DOI: 10.1021/ja067329q Supporting Info

A Tetraphosphorus Ligand for Highly Regioselective Isomerization−Hydroformylation of Internal Olefins Yongjun Yan, Xiaowei Zhang, and Xumu Zhang pp 16058–16061 DOI: 10.1021/ja0622249 Supporting Info

Nonlithographic Fabrication of Microfluidic Devices Valentine I. Vullev, Jiandi Wan, Volkmar Heinrich, Pavel Landsman, Paul E. Bower, Bing Xia, Brent Millare, and Guilford Jones, II pp 16062–16072 DOI: 10.1021/ja061776o Supporting Info

Nature and Energies of Electrons and Holes in a Conjugated Polymer, Polyfluorene Norihiko Takeda, Sadayuki Asaoka, and John R. Miller pp 16073–16082 DOI: 10.1021/ja062596h Supporting Info

22π Smaragdyrin Molecular Conjugates with Aromatic Phenylacetylenes and Ferrocenes:  Syntheses, Electrochemical, and Photonic Properties Rajneesh Misra, Rajeev Kumar, Tavarekere K. Chandrashekar, C. H. Suresh, Amit Nag, and Debabrata Goswami pp 16083–16091 DOI: 10.1021/ja0628295 Supporting Info

A Third Mode of DNA Binding:  Phosphate Clamps by a Polynuclear Platinum Complex Seiji Komeda, Tinoush Moulaei, Kristen Kruger Woods, Masahiko Chikuma, Nicholas P. Farrell, and Loren Dean Williams pp 16092–16103 DOI: 10.1021/ja062851y Supporting Info

Cell-Permeable Peptide Nucleic Acid Designed to Bind to the 5‘-Untranslated Region of E-cadherin Transcript Induces Potent and Sequence-Specific Antisense Effects Anca Dragulescu-Andrasi, Srinivas Rapireddy, Gaofei He, Birendra Bhattacharya, Jens J. Hyldig-Nielsen, Gerald Zon, and Danith H. Ly pp 16104–16112 DOI: 10.1021/ja063383v Supporting Info

Chiral Alignment of OPV Chromophores:  Exploitation of the Ureidophthalimide-Based Foldamer Renatus W. Sinkeldam, Freek J. M. Hoeben, Maarten J. Pouderoijen, Inge De Cat, Jian Zhang, Shuhei Furukawa, Steven De Feyter, Jef A. J. M. Vekemans, and E. W. Meijer pp 16113–16121 DOI: 10.1021/ja063405d Supporting Info

Hydrogen-Bonded Porous Coordination Polymers:  Structural Transformation, Sorption Properties, and Particle Size from Kinetic Studies Kazuhiro Uemura, Kazuya Saito, Susumu Kitagawa, and Hidetoshi Kita pp 16122–16130 DOI: 10.1021/ja064152r Supporting Info

Generating New Specific RNA Interaction Interfaces Using C-Loops Kirill A. Afonin and Neocles B. Leontis pp 16131–16137 DOI: 10.1021/ja064289h

Potential of Mean Force for Tetramethylammonium Binding to Cagelike Oligosilicates in Aqueous Solution S. Caratzoulas, D. G. Vlachos, and M. Tsapatsis pp 16138–16147 DOI: 10.1021/ja064597f

Proton-Shuffle Mechanism of O−O Activation for Formation of a High-Valent Oxo−Iron Species of Bleomycin Devesh Kumar, Hajime Hirao, Sason Shaik, and Pawel M. Kozlowski pp 16148–16158 DOI: 10.1021/ja064611o Supporting Info

Dynamics of Asp23−Lys28 Salt-Bridge Formation in Aβ10-35 Monomers Bogdan Tarus, John E. Straub, and D. Thirumalai pp 16159–16168 DOI: 10.1021/ja064872y Supporting Info

Iridium−Iron−Monocarborane Clusters from Oxidative Insertion Reactions of [IrCl(CO)(PPh3)2] with Ferracarborane Anions Andreas Franken, Thomas D. McGrath, and F. Gordon A. Stone pp 16169–16177 DOI: 10.1021/ja065042n Supporting Info

Planar Trimethylenemethane Dianion Chemistry of Lanthanide Metallocenes:  Synthesis, Structure, Density Functional Theory Analysis, and Reactivity of [(C5Me5)2Ln]2[μ-η3:η3-C(CH2)3] Complexes William J. Evans, Timothy M. Champagne, Joseph W. Ziller, and Nikolas Kaltsoyannis pp 16178–16189 DOI: 10.1021/ja0645988 Supporting Info

Structure-Based Secondary Structure-Independent Approach To Design Protein Ligands:  Application to the Design of Kv1.2 Potassium Channel Blockers C. Magis, D. Gasparini, A. Lecoq, M. H. Le Du, E. Stura, J. B. Charbonnier, G. Mourier, J.-C. Boulain, L. Pardo, A. Caruana, A. Joly, M. Lefranc, M. Masella, A. Menez, and P. Cuniasse pp 16190–16205 DOI: 10.1021/ja0646491 Supporting Info

Design, Synthesis, and Computational Studies of Inhibitors of Bcl-XL Cheol-Min Park, Tetsuro Oie, Andrew M. Petros, Haichao Zhang, Paul M. Nimmer, Rodger F. Henry, and Steven W. Elmore pp 16206–16212 DOI: 10.1021/ja0650347 Supporting Info

Self-Organized Ureido Substituted Diacetylenic Organogel. Photopolymerization of One-Dimensional Supramolecular Assemblies to Give Conjugated Nanofibers Olivier J. Dautel, Mike Robitzer, Jean-Pierre Lère-Porte, Françoise Serein-Spirau, and Joël J. E. Moreau pp 16213–16223 DOI: 10.1021/ja065434u Supporting Info

Supramolecular Assemblies from Amphiphilic Homopolymers:  Testing the Scope Elamprakash N. Savariar, Sivakumar V. Aathimanikandan, and S. Thayumanavan pp 16224–16230 DOI: 10.1021/ja065213o Supporting Info

Surface Tension and Fluid Flow Driven Self-Assembly of Ordered ZnO Nanorod Films for High-Performance Field Effect Transistors Baoquan Sun and Henning Sirringhaus pp 16231–16237 DOI: 10.1021/ja065242z Supporting Info

Creation of a Pair of Stereochemically Complementary Biocatalysts Gavin J. Williams, Thomas Woodhall, Lorna M. Farnsworth, Adam Nelson, and Alan Berry pp 16238–16247 DOI: 10.1021/ja065233q

Electrochemically Controlled Self-Assembly of an Organometallic Block Copolymer Hany B. Eitouni and Nitash P. Balsara pp 16248–16252 DOI: 10.1021/ja065389q

Multicomponent Polymer Brushes Feng Zhou, Zijian Zheng, Bo Yu, Weimin Liu, and Wilhelm T. S. Huck pp 16253–16258 DOI: 10.1021/ja0654377

All-Photonic Molecular Half-Adder Joakim Andréasson, Stephen D. Straight, Gerdenis Kodis, Choong-Do Park, Michael Hambourger, Miguel Gervaldo, Bo Albinsson, Thomas A. Moore, Ana L. Moore, and Devens Gust pp 16259–16265 DOI: 10.1021/ja0654579 Supporting Info

Advanced Surface Functionalization of Periodic Mesoporous Silica:  Kinetic Control by Trisilazane Reagents Clemens Zapilko, Markus Widenmeyer, Iris Nagl, Frank Estler, Reiner Anwander, Gabriele Raudaschl-Sieber, Olaf Groeger, and Günter Engelhardt pp 16266–16276 DOI: 10.1021/ja065444v Supporting Info

Highly Active Copper-Based Catalyst for Atom Transfer Radical Polymerization Huadong Tang, Navamoney Arulsamy, Maciej Radosz, Youqing Shen, Nicolay V. Tsarevsky, Wade A. Braunecker, Wei Tang, and Krzysztof Matyjaszewski pp 16277–16285 DOI: 10.1021/ja0653369 Supporting Info

Supramolecular Allosteric Cofacial Porphyrin Complexes Christopher G. Oliveri, Nathan C. Gianneschi, SonBinh T. Nguyen, Chad A. Mirkin, Charlotte L. Stern, Zdzislaw Wawrzak, and Maren Pink pp 16286–16296 DOI: 10.1021/ja0661010 Supporting Info

Photosensitized Reduction of Water to Hydrogen Using Human Serum Albumin Complexed with Zinc−Protoporphyrin IX Teruyuki Komatsu, Rong-Min Wang, Patricia A. Zunszain, Stephen Curry, and Eishun Tsuchida pp 16297–16301 DOI: 10.1021/ja0656806 Supporting Info

“Proton Holes” in Long-Range Proton Transfer Reactions in Solution and Enzymes:  A Theoretical Analysis Demian Riccardi, Peter König, Xavier Prat-Resina, Haibo Yu, Marcus Elstner, Thomas Frauenheim, and Qiang Cui pp 16302–16311 DOI: 10.1021/ja065451j Supporting Info

Solvent Effect on the Singlet Excited-State Lifetimes of Nucleic Acid Bases:  A Computational Study of 5-Fluorouracil and Uracil in Acetonitrile and Water Fabrizio Santoro, Vincenzo Barone, Thomas Gustavsson, and Roberto Improta pp 16312–16322 DOI: 10.1021/ja0657861 Supporting Info

Quantitative Real-Time Measurements of DNA Hybridization with Alkylated Nonoxidized Silicon Nanowires in Electrolyte Solution Yuri L. Bunimovich, Young Shik Shin, Woon-Seok Yeo, Michael Amori, Gabriel Kwong, and James R. Heath pp 16323–16331 DOI: 10.1021/ja065923u Supporting Info

Allylic Nitro Compounds as Nitrite Donors Harinath Chakrapani, Michael J. Gorczynski, and S. Bruce King pp 16332–16337 DOI: 10.1021/ja066011v Supporting Info

Conformational Preference of Polyglycine in Solution to Elongated Structure Satoshi Ohnishi, Hironari Kamikubo, Masayoshi Onitsuka, Mikio Kataoka, and David Shortle pp 16338–16344 DOI: 10.1021/ja066008b Supporting Info

A Combined Quantum Mechanical and Molecular Mechanical Study of the Reaction Mechanism and α-Amino Acidity in Alanine Racemase Dan Thomas Major and Jiali Gao pp 16345–16357 DOI: 10.1021/ja066334r Supporting Info

p-tert-Butylcalix[4]arene Complexes of Molybdenum and Tungsten:  Reactivity of the Calixarene Methylene CH Bond and the Facile Migration of the Metal around the Phenolic Rim of the Calixarene Daniela Buccella and Gerard Parkin pp 16358–16364 DOI: 10.1021/ja066457b Supporting Info

Steric Communication of Chiral Information Observed in Dendronized Polyacetylenes Virgil Percec, Emad Aqad, Mihai Peterca, Jonathan G. Rudick, Lance Lemon, Juan C. Ronda, Binod B. De, Paul A. Heiney, and E. W. Meijer pp 16365–16372 DOI: 10.1021/ja0665848 Supporting Info

Dipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts A. S. Hock, Richard R. Schrock, and Amir H. Hoveyda pp 16373–16375 DOI: 10.1021/ja0665904 Supporting Info

Alkyl Chain Barriers for Kinetic Optimization in Dye-Sensitized Solar Cells Jessica E. Kroeze, Narukuni Hirata, Sara Koops, Md. K. Nazeeruddin, Lukas Schmidt-Mende, Michael Grätzel, and James R. Durrant pp 16376–16383 DOI: 10.1021/ja065653f Supporting Info

Oxidative Palladium(II) Catalysis:  A Highly Efficient and Chemoselective Cross-Coupling Method for Carbon−Carbon Bond Formation under Base-Free and Nitrogenous-Ligand Conditions Kyung Soo Yoo, Cheol Hwan Yoon, and Kyung Woon Jung pp 16384–16393 DOI: 10.1021/ja063710z Supporting Info

A New Class of SN2 Reactions Catalyzed by Protic Solvents:  Facile Fluorination for Isotopic Labeling of Diagnostic Molecules Dong Wook Kim, Doo-Sik Ahn, Young-Ho Oh, Sungyul Lee, Hee Seup Kil, Seung Jun Oh, Sang Ju Lee, Jae Seung Kim, Jin Sook Ryu, Dae Hyuk Moon, and Dae Yoon Chi pp 16394–16397 DOI: 10.1021/ja0646895 Supporting Info

Combination of a Dinuclear Zn2+ Complex and a Medium Effect Exerts a 1012-Fold Rate Enhancement of Cleavage of an RNA and DNA Model System Alexei A. Neverov, Zhong-Lin Lu, Christopher I. Maxwell, Mark F. Mohamed, Christopher J. White, Josephine S. W. Tsang, and R. Stan Brown pp 16398–16405 DOI: 10.1021/ja0651714

Efficient Transamidation of Primary Carboxamides by in Situ Activation with N,N-Dialkylformamide Dimethyl Acetals Thomas A. Dineen, Matthew A. Zajac, and Andrew G. Myers pp 16406–16409 DOI: 10.1021/ja066728i Supporting Info

Marinomycins A−D, Antitumor-Antibiotics of a New Structure Class from a Marine Actinomycete of the Recently Discovered Genus “Marinispora” [J. Am. Chem. Soc. 2006, 128, 1622−1632]. Hak Cheol Kwon, Christopher A. Kauffman, Paul R. Jensen, and William Fenical p 16410 DOI: 10.1021/ja0666497

Surface-Enhanced Vibrational Spectroscopy By Ricardo Aroca (University of Windsor, Canada). John Wiley & Sons, Ltd:  Chichester. 2006. xxvi + 234 pp. $130. ISBN 0-471-60731-2. Candace M. Coyle p 16411 DOI: 10.1021/ja069770m

Bioorganometallic Chemistry, Topics in Organometallic Chemistry, 17 Edited by Gerard Simonneaux (DR CNRS, Rennes, France). Springer:  Berlin, Heidelberg, New York. 2006. x + 222 pp. $199.00. ISBN 3-540-33047-X. Heinz-Bernhard Kraatz pp 16411–16412 DOI: 10.1021/ja069791g

Light-Associated Reactions of Synthetic Polymers By A. Ravve (Consultant, Niles, IL). Springer Science + Business Media, LLC:  New York. 2006. x + 370 pp. $99.00. ISBN 0-387-31803-8. Pradip K. Bhowmik p 16412 DOI: 10.1021/ja069776b

Annual Review of Materials Research, Volume 36, 2006 Edited by Venkatraman Gopalan (Pennsylvania State University), Gerhard Wegner (Max-Planck Institute, Mainz), David R. Clarke (University of California, Santa Barbara), Manfred Rühle (Max-Planck Institute, Stuttgart), and John C. Bravman (Stanford University). Annual Reviews:  Palo Alto, CA. 2006. xii + 636 pp. $85.00. ISBN 0-8243-1736-X. p 16412 DOI: 10.1021/ja069809n

Issue 51

Competitive Chemisorption between Pairs of Cinchona Alkaloids and Related Compounds from Solution onto Platinum Surfaces Zhen Ma and Francisco Zaera pp 16414–16415 DOI: 10.1021/ja0659323 Supporting Info

TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion Satoru Shimomura, Ryotaro Matsuda, Takashi Tsujino, Takashi Kawamura, and Susumu Kitagawa pp 16416–16417 DOI: 10.1021/ja0660047 Supporting Info

High-Performance Low-Cost Organic Field-Effect Transistors with Chemically Modified Bottom Electrodes Chong-an Di, Gui Yu, Yunqi Liu, Xinjun Xu, Dacheng Wei, Yabin Song, Yanming Sun, Ying Wang, Daoben Zhu, Jian Liu, Xinyu Liu, and Dexin Wu pp 16418–16419 DOI: 10.1021/ja066092v Supporting Info

The in Vitro Characterization of the Iterative Avermectin Glycosyltransferase AveBI Reveals Reaction Reversibility and Sugar Nucleotide Flexibility Changsheng Zhang, Christoph Albermann, Xun Fu, and Jon S. Thorson pp 16420–16421 DOI: 10.1021/ja065950k Supporting Info

Enantioselective Synthesis of an All-syn Four Vicinal Fluorine Motif Luke Hunter, David O'Hagan, and Alexandra M. Z. Slawin pp 16422–16423 DOI: 10.1021/ja066188p Supporting Info

Mechanisms of Electron Transfer in Catalysis by Copper Zinc Superoxide Dismutase Valeriy V. Smirnov and Justine P. Roth pp 16424–16425 DOI: 10.1021/ja066369r Supporting Info

Stepwise Synthesis and Magnetic Control of Trimetallic Magnets [Co2Ln(L)2(H2O)4][Cr(CN)6]·nH2O (Ln = La, Gd; H2L = 2,6-Di(acetoacetyl)pyridine) with 3-D Pillared-Layer Structure Takuya Shiga, Hisashi Ōkawa, Susumu Kitagawa, and Masaaki Ohba pp 16426–16427 DOI: 10.1021/ja066434x Supporting Info

Coexistence of Magnetization Relaxation and Dielectric Relaxation in a Single-Chain Magnet Yue-Ling Bai, Jun Tao, Wolfgang Wernsdorfer, Osamu Sato, Rong-Bin Huang, and Lan-Sun Zheng pp 16428–16429 DOI: 10.1021/ja066679+ Supporting Info

Single-Molecule Detection of Airborne Singlet Oxygen Kazuya Naito, Takashi Tachikawa, Shi-Cong Cui, Akira Sugimoto, Mamoru Fujitsuka, and Tetsuro Majima pp 16430–16431 DOI: 10.1021/ja066739b Supporting Info

Radically Different Antioxidants:  Thermally Generated Carbon-Centered Radicals as Chain-Breaking Antioxidants Mathieu Frenette, Patricia D. MacLean, L. Ross C. Barclay, and Juan C. Scaiano pp 16432–16433 DOI: 10.1021/ja066870j Supporting Info

A “Molecular Pivot-Hinge” Based on the pH-Regulated Intramolecular Switching of Pt−Pt and π−π Interactions Chi-Kin Koo, Benny Lam, Sze-Kar Leung, Michael Hon-Wah Lam, and Wai-Yeung Wong pp 16434–16435 DOI: 10.1021/ja066914o Supporting Info

Cooperative Jahn-Teller Distortion, Phase Transitions, and Weak Ferromagnetism in the KCrF3 Perovskite Serena Margadonna and Georgios Karotsis pp 16436–16437 DOI: 10.1021/ja0669272 Supporting Info

Key Role of the Lewis Base Position in Asymmetric Bifunctional Catalysis:  Design and Evaluation of a New Ligand for Chiral Polymetallic Catalysts Ikuo Fujimori, Tsuyoshi Mita, Keisuke Maki, Motoo Shiro, Akihiro Sato, Sanae Furusho, Motomu Kanai, and Masakatsu Shibasaki pp 16438–16439 DOI: 10.1021/ja067003h Supporting Info

The Total Synthesis of (±)-11-O-Debenzoyltashironin Silas P. Cook, Alessandra Polara, and Samuel J. Danishefsky pp 16440–16441 DOI: 10.1021/ja0670254 Supporting Info

An Activated Equivalent of Lactide toward Organocatalytic Ring-Opening Polymerization Olivier Thillaye du Boullay, Emmanuel Marchal, Blanca Martin-Vaca, Fernando P. Cossío, and Didier Bourissou pp 16442–16443 DOI: 10.1021/ja067046y Supporting Info

An Antiparallel α-Helical Coiled-Coil Model System for Rapid Assessment of Side-Chain Recognition at the Hydrophobic Interface Erik B. Hadley and Samuel H. Gellman pp 16444–16445 DOI: 10.1021/ja067178r Supporting Info

Ultrafast Spectroscopic Study of the Photochemistry and Photophysics of Arylhalodiazirines:  Direct Observation of Carbene and Zwitterion Formation Jin Wang, Gotard Burdzinski, Jacek Kubicki, Matthew S. Platz, Robert A. Moss, Xiaolin Fu, Piotr Piotrowiak, and Mykhaylo Myahkostupov pp 16446–16447 DOI: 10.1021/ja067205d Supporting Info

Enantioselective Reductive Coupling of 1,3-Enynes to Heterocyclic Aromatic Aldehydes and Ketones via Rhodium-Catalyzed Asymmetric Hydrogenation:  Mechanistic Insight into the Role of Brønsted Acid Additives Venukrishnan Komanduri and Michael J. Krische pp 16448–16449 DOI: 10.1021/ja0673027 Supporting Info

Synthesis and Reactivity of the Methylene Arenium Form of a Benzyl Cation, Stabilized by Complexation Elena Poverenov, Gregory Leitus, and David Milstein pp 16450–16451 DOI: 10.1021/ja067298z Supporting Info

The Two-State Issue in the Mixed-Valence Binuclear CuA Center in Cytochrome c Oxidase and N2O Reductase Serge I. Gorelsky, Xiangjin Xie, Ying Chen, James A. Fee, and Edward I. Solomon pp 16452–16453 DOI: 10.1021/ja067583i Supporting Info

Remote Desymmetrization at Near-Nanometer Group Separation Catalyzed by a Miniaturized Enzyme Mimic Chad A. Lewis, Anna Chiu, Michele Kubryk, Jaume Balsells, David Pollard, Craig K. Esser, Jerry Murry, Robert A. Reamer, Karl B. Hansen, and Scott J. Miller pp 16454–16455 DOI: 10.1021/ja067840j Supporting Info

PNA−DNA Duplexes, Triplexes, and Quadruplexes Are Stabilized with trans-Cyclopentane Units Ethan A. Englund, Qun Xu, Mark A. Witschi, and Daniel H. Appella pp 16456–16457 DOI: 10.1021/ja064317w Supporting Info

The Sodium Salt of Diethyl 1H-pyrazole-3,5-dicarboxylate as an Efficient Amphiphilic Receptor for Dopamine and Amphetamines. Crystal Structure and Solution Studies Felipe Reviriego, Maria Isabel Rodríguez-Franco, Pilar Navarro, Enrique García-España, Malva Liu-González, Begoña Verdejo, and Antonio Domènech pp 16458–16459 DOI: 10.1021/ja064657h Supporting Info

Encapsulation and NMR on an Aggregating Peptide before Fibrillogenesis Kristi L. Lazar, Josh W. Kurutz, Robert Tycko, and Stephen C. Meredith pp 16460–16461 DOI: 10.1021/ja064999n Supporting Info

A Renewable Nanosensor Based on a Glass Nanopipette Joe D. Piper, Richard W. Clarke, Yuri E. Korchev, Liming Ying, and David Klenerman pp 16462–16463 DOI: 10.1021/ja0650899 Supporting Info

Synthesis and Biological Activity of PTEN-Resistant Analogues of Phosphatidylinositol 3,4,5-Trisphosphate Honglu Zhang, Nicolas Markadieu, Renaud Beauwens, Christophe Erneux, and Glenn D. Prestwich pp 16464–16465 DOI: 10.1021/ja065002j Supporting Info

Self-Assembling Poly(dioxaborole)s as Blue-Emissive Materials Weijun Niu, Mark D. Smith, and John J. Lavigne pp 16466–16467 DOI: 10.1021/ja065986c Supporting Info

Engineered Growth of Organic Crystalline Films Using Liquid Crystal Solvents F. Scott Wilkinson, Ronald F. Norwood, Joseph M. McLellan, L. Rhys Lawson, and David L. Patrick pp 16468–16469 DOI: 10.1021/ja066153p Supporting Info

Inorganic−Organic Hybrid Membranes with Anhydrous Proton Conduction Prepared from 3-Aminopropyltriethoxysilane and Sulfuric Acid by the Sol−Gel Method Teruaki Tezuka, Kiyoharu Tadanaga, Akitoshi Hayashi, and Masahiro Tatsumisago pp 16470–16471 DOI: 10.1021/ja066345k Supporting Info

Chiral Photocages Based on Phthalimide Photochemistry Alberto Soldevilla and Axel G. Griesbeck pp 16472–16473 DOI: 10.1021/ja066582n Supporting Info

A Mesoporous Metal−Organic Framework with Permanent Porosity Xi-Sen Wang, Shengqian Ma, Daofeng Sun, Sean Parkin, and Hong-Cai Zhou pp 16474–16475 DOI: 10.1021/ja066616r Supporting Info

Optical Imaging of Bacterial Infection in Living Mice Using a Fluorescent Near-Infrared Molecular Probe W. Matthew Leevy, Seth T. Gammon, Hua Jiang, James R. Johnson, Dustin J. Maxwell, Erin N. Jackson, Manuel Marquez, David Piwnica-Worms, and Bradley D. Smith pp 16476–16477 DOI: 10.1021/ja0665592 Supporting Info

Peptide Macrocyclization:  The Reductase of the Nostocyclopeptide Synthetase Triggers the Self-Assembly of a Macrocyclic Imine Florian Kopp, Christoph Mahlert, Jan Grünewald, and Mohamed A. Marahiel pp 16478–16479 DOI: 10.1021/ja0667458 Supporting Info

A Sakurai−Prins−Ritter Sequence for the Three-Component Diastereoselective Synthesis of 4-Amino Tetrahydropyrans Oleg L. Epstein and Tomislav Rovis pp 16480–16481 DOI: 10.1021/ja066794k Supporting Info

Catalytic Enantioselective Hetero-Diels−Alder Reactions of an Azo Compound Masanori Kawasaki and Hisashi Yamamoto pp 16482–16483 DOI: 10.1021/ja066726y Supporting Info

GlcNAcstatin:  a Picomolar, Selective O-GlcNAcase Inhibitor That Modulates Intracellular O-GlcNAcylation Levels Helge C. Dorfmueller, Vladimir S. Borodkin, Marianne Schimpl, Sharon M. Shepherd, Natalia A. Shpiro, and Daan M. F. van Aalten pp 16484–16485 DOI: 10.1021/ja066743n Supporting Info

Using Triethynylphosphine Ligands Bearing Bulky End Caps To Create a Holey Catalytic Environment:  Application to Gold(I)-Catalyzed Alkyne Cyclizations Atsuko Ochida, Hideto Ito, and Masaya Sawamura pp 16486–16487 DOI: 10.1021/ja066800c Supporting Info

Lewis Acid-Catalyzed Enantioselective Hydroxylation Reactions of Oxindoles and β-Keto Esters Using DBFOX Ligand Takehisa Ishimaru, Norio Shibata, Jun Nagai, Shuichi Nakamura, Takeshi Toru, and Shuji Kanemasa pp 16488–16489 DOI: 10.1021/ja0668825 Supporting Info

Hydrothermal Synthesis of Single-Crystalline Antimony Telluride Nanobelts Weidong Shi, Jiangbo Yu, Haishui Wang, and Hongjie Zhang pp 16490–16491 DOI: 10.1021/ja066944r Supporting Info

Denatured State Effects and the Origin of Nonclassical Values in Protein Folding Jae-Hyun Cho and Daniel P. Raleigh pp 16492–16493 DOI: 10.1021/ja0669878

Highly Oxidizing Excited States of Re and Tc Complexes Andrew S. Del Negro, Carl J. Seliskar, William R. Heineman, Sean E. Hightower, Samuel A. Bryan, and B. Patrick Sullivan pp 16494–16495 DOI: 10.1021/ja067114g Supporting Info

Palladium-Catalyzed Benzene Arylation:  Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design Marc Lafrance and Keith Fagnou pp 16496–16497 DOI: 10.1021/ja067144j Supporting Info

Templated Assembly of Water-Soluble Nano-Capsules:  Inter-Phase Sequestration, Storage, and Separation of Hydrocarbon Gases Corinne L. D. Gibb and Bruce C. Gibb pp 16498–16499 DOI: 10.1021/ja0670916 Supporting Info

W(CO)5(L)-Catalyzed Tandem Intramolecular Cyclopropanation/Cope Rearrangement for the Stereoselective Construction of Bicyclo[5.3.0]decane Framework Hiroyuki Kusama, Yuji Onizawa, and Nobuharu Iwasawa pp 16500–16501 DOI: 10.1021/ja0671924 Supporting Info

Retinal Counterion Switch Mechanism in Vision Evaluated by Molecular Simulations Karina Martínez-Mayorga, Michael C. Pitman, Alan Grossfield, Scott E. Feller, and Michael F. Brown pp 16502–16503 DOI: 10.1021/ja0671971 Supporting Info

Cationic Palladium Complex Catalyzed Highly Enantioselective Intramolecular Addition of Arylboronic Acids to Ketones. A Convenient Synthesis of Optically Active Cycloalkanols Guixia Liu and Xiyan Lu pp 16504–16505 DOI: 10.1021/ja0672425 Supporting Info

Encodable Activators of Src Family Kinases Crystal D. Zellefrow, Jennifer S. Griffiths, Sarmistha Saha, Abby M. Hodges, Jessica L. Goodman, Joshiawa Paulk, Joshua A. Kritzer, and Alanna Schepartz pp 16506–16507 DOI: 10.1021/ja0672977 Supporting Info

Photoreaction of a 2,11-Diaza[3.3]paracyclophane Derivative:  Formation of Octahedrane by Photochemical Dimerization of Benzene Hideki Okamoto, Kyosuke Satake, Hiroyuki Ishida, and Masaru Kimura pp 16508–16509 DOI: 10.1021/ja067350r Supporting Info

Growth of Ultrathin Films of Amorphous Ruthenium−Phosphorus Alloys Using a Single Source CVD Precursor Jinhong Shin, Abdul Waheed, Kyriacos Agapiou, Wyatt A. Winkenwerder, Hyun-Wu Kim, Richard A. Jones, Gyeong S. Hwang, and John G. Ekerdt pp 16510–16511 DOI: 10.1021/ja0673938

Isolation of a Tetrameric Cation−Cation Complex of Pentavalent Uranyl Fabien Burdet, Jacques Pécaut, and Marinella Mazzanti pp 16512–16513 DOI: 10.1021/ja067445t Supporting Info

Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry Matthew D. Sanderson, Justin W. Kamplain, and Christopher W. Bielawski pp 16514–16515 DOI: 10.1021/ja067475w Supporting Info

Direct Observation of the Oxidative Addition of the Aryl Carbon−Oxygen Bond to a Ruthenium Complex and Consideration of the Relative Reactivity between Aryl Carbon−Oxygen and Aryl Carbon−Hydrogen Bonds Satoshi Ueno, Eiichiro Mizushima, Naoto Chatani, and Fumitoshi Kakiuchi pp 16516–16517 DOI: 10.1021/ja067612p Supporting Info

Diindolylquinoxalines:  Effective Indole-Based Receptors for Phosphate Anion Jonathan L. Sessler, Dong-Gyu Cho, and Vincent Lynch pp 16518–16519 DOI: 10.1021/ja067720b Supporting Info

Water Penetration into Protein Secondary Structure Revealed by Hydrogen−Deuterium Exchange Two-Dimensional Infrared Spectroscopy Lauren P. DeFlores and Andrei Tokmakoff pp 16520–16521 DOI: 10.1021/ja067723o Supporting Info

Synthesis of Colloidal Uranium−Dioxide Nanocrystals Huimeng Wu, Yongan Yang, and Y. Charles Cao pp 16522–16523 DOI: 10.1021/ja067940p Supporting Info

Excited-State Mixed-Valence Distortions in a Diisopropyl Diphenyl Hydrazine Cation Jenny V. Lockard, Jeffrey I. Zink, Yun Luo, Michael N. Weaver, Asgeir E. Konradsson, Joseph W. Fowble, and Stephen F. Nelsen pp 16524–16531 DOI: 10.1021/ja0609093

Control of Interchain Contacts, Solid-State Fluorescence Quantum Yield, and Charge Transport of Cationic Conjugated Polyelectrolytes by Choice of Anion Renqiang Yang, Andres Garcia, Dmitry Korystov, Alexander Mikhailovsky, Guillermo C. Bazan, and Thuc-Quyen Nguyen pp 16532–16539 DOI: 10.1021/ja0611341 Supporting Info

Active Site Labeling of G8 in the Hairpin Ribozyme:  Implications for Structure and Mechanism Jason M. Thomas and David M. Perrin pp 16540–16545 DOI: 10.1021/ja063942y Supporting Info

Singlet Fission for Dye-Sensitized Solar Cells:  Can a Suitable Sensitizer Be Found? Irina Paci, Justin C. Johnson, Xudong Chen, Geeta Rana, Duška Popović, Donald E. David, Arthur J. Nozik, Mark A. Ratner, and Josef Michl pp 16546–16553 DOI: 10.1021/ja063980h Supporting Info

Electronic Communication and Negative Binding Cooperativity in Diborylated Bithiophenes Anand Sundararaman, Krishnan Venkatasubbaiah, Maria Victor, Lev N. Zakharov, Arnold L. Rheingold, and Frieder Jäkle pp 16554–16565 DOI: 10.1021/ja064396b Supporting Info

Comparing the Electronic Properties of the Low-Spin Cyano−Ferric [Fe(N4)(Cys)] Active Sites of Superoxide Reductase and P450cam Using ENDOR Spectroscopy and DFT Calculations Tran-Chin Yang, Rebecca L. McNaughton, Michael D. Clay, Francis E. Jenney, Jr., Rangan Krishnan, Donald M. Kurtz, Jr., Michael W. W. Adams, Michael K. Johnson, and Brian M. Hoffman pp 16566–16578 DOI: 10.1021/ja064656p Supporting Info

Thickness Dependence of Microstructure in Semiconducting Films of an Oligofluorene Derivative Dean M. DeLongchamp, Mang Mang Ling, Youngsuk Jung, Daniel A. Fischer, Mark E. Roberts, Eric K. Lin, and Zhenan Bao pp 16579–16586 DOI: 10.1021/ja064384q Supporting Info

Electrochemical Oxidation of CoCp(CO)2:  Radical−Substrate Reaction of a 17 e-/18 e- Pair and Production of a Unique Dimer Radical Ayman Nafady, Paulo Jorge Costa, Maria José Calhorda, and William E. Geiger pp 16587–16599 DOI: 10.1021/ja0653775 Supporting Info

Carbon−Oxygen Bond Cleavage with η9,η5-Bis(indenyl)zirconium Sandwich Complexes Christopher A. Bradley, Luis F. Veiros, Doris Pun, Emil Lobkovsky, Ivan Keresztes, and Paul J. Chirik pp 16600–16612 DOI: 10.1021/ja065456g Supporting Info

Two-Dimensional Porous Molecular Networks of Dehydrobenzo[12]annulene Derivatives via Alkyl Chain Interdigitation Kazukuni Tahara, Shuhei Furukawa, Hiroshi Uji-i, Tsutomu Uchino, Tomoyuki Ichikawa, Jian Zhang, Wael Mamdouh, Motohiro Sonoda, Frans C. De Schryver, Steven De Feyter, and Yoshito Tobe pp 16613–16625 DOI: 10.1021/ja0655441 Supporting Info

Targeting of Cancer Cells with Ferrimagnetic Ferritin Cage Nanoparticles Masaki Uchida, Michelle L. Flenniken, Mark Allen, Deborah A. Willits, Bridgid E. Crowley, Susan Brumfield, Ann F. Willis, Larissa Jackiw, Mark Jutila, Mark J. Young, and Trevor Douglas pp 16626–16633 DOI: 10.1021/ja0655690 Supporting Info

Anodic Electrodeposition of Highly Oriented Zirconium Phosphate and Polyaniline-Intercalated Zirconium Phosphate Films Takahiro Takei, Yoji Kobayashi, Hideo Hata, Yoshinori Yonesaki, Nobuhiro Kumada, Nobukazu Kinomura, and Thomas E. Mallouk pp 16634–16640 DOI: 10.1021/ja065677m

Dark-Field Oxidative Addition-Based Chemosensing:  New Bis-cyclometalated Pt(II) Complexes and Phosphorescent Detection of Cyanogen Halides Samuel W. Thomas III, Koushik Venkatesan, Peter Müller, and Timothy M. Swager pp 16641–16648 DOI: 10.1021/ja065645z Supporting Info

Stereospecificity in Metallocene Catalyzed Acrylate Polymerizations:  The Chiral Orientation of the Growing Chain Selects Its Own Chain End Enantioface Lucia Caporaso, Josè Gracia-Budrìa, and Luigi Cavallo pp 16649–16654 DOI: 10.1021/ja065703g Supporting Info

Calculation of Vibronic Couplings for Phenoxyl/Phenol and Benzyl/Toluene Self-Exchange Reactions:  Implications for Proton-Coupled Electron Transfer Mechanisms Jonathan H. Skone, Alexander V. Soudackov, and Sharon Hammes-Schiffer pp 16655–16663 DOI: 10.1021/ja0656548 Supporting Info

Synthesis of Oligoenes that Contain up to 15 Double Bonds from 1,6-Heptadiynes Constantin Czekelius, Jillian Hafer, Zachary J. Tonzetich, Richard R. Schrock, Ronald L. Christensen, and Peter Müller pp 16664–16675 DOI: 10.1021/ja0656705 Supporting Info

Ab Initio Calculations of the Potential Surface for Rearrangement of 2,2,3,3-Tetrafluoromethylenecyclopropane to 1-(Difluoromethylene)-2,2-difluorocyclopropane Haiyan Wei, David A. Hrovat, and Weston Thatcher Borden pp 16676–16683 DOI: 10.1021/ja065963y Supporting Info

Synthetic Seleno-Glutaredoxin 3 Analogues Are Highly Reducing Oxidoreductases with Enhanced Catalytic Efficiency Norman Metanis, Ehud Keinan, and Philip E. Dawson pp 16684–16691 DOI: 10.1021/ja0661414 Supporting Info

Dynamic Processes in [16]Annulene:  Möbius Bond-Shifting Routes to Configuration Change Ryan P. Pemberton, Colleen M. McShane, Claire Castro, and William L. Karney pp 16692–16700 DOI: 10.1021/ja066152x Supporting Info

Molecular Engineering of Organic Sensitizers for Solar Cell Applications Sanghoon Kim, Jae Kwan Lee, Sang Ook Kang, Jaejung Ko, J.-H. Yum, Simona Fantacci, Filippo De Angelis, D. Di Censo, Md. K. Nazeeruddin, and Michael Grätzel pp 16701–16707 DOI: 10.1021/ja066376f Supporting Info

Quinones as Electron Acceptors. X-Ray Structures, Spectral (EPR, UV−vis) Characteristics and Electron-Transfer Reactivities of Their Reduced Anion Radicals as Separated vs Contact Ion Pairs Jian-Ming Lü, Sergiy V. Rosokha, Ivan S. Neretin, and Jay K. Kochi pp 16708–16719 DOI: 10.1021/ja066471o Supporting Info

Total Synthesis and Evaluation of Cytostatin, Its C10−C11 Diastereomers, and Additional Key Analogues:  Impact on PP2A Inhibition Brian G. Lawhorn, Sobhana B. Boga, Scott E. Wolkenberg, David A. Colby, Carla-Maria Gauss, Mark R. Swingle, Lauren Amable, Richard E. Honkanen, and Dale L. Boger pp 16720–16732 DOI: 10.1021/ja066477d Supporting Info

Deviation from the Planaritya Large Dy3N Cluster Encapsulated in an Ih-C80 Cage:  An X-ray Crystallographic and Vibrational Spectroscopic Study Shangfeng Yang, Sergey I. Troyanov, Alexey A. Popov, Matthias Krause, and Lothar Dunsch pp 16733–16739 DOI: 10.1021/ja066814i Supporting Info

Giant Macrocycles Composed of Thiophene, Acetylene, and Ethylene Building Blocks Kazumi Nakao, Masayuki Nishimura, Tomoya Tamachi, Yoshiyuki Kuwatani, Hitoshi Miyasaka, Tohru Nishinaga, and Masahiko Iyoda pp 16740–16747 DOI: 10.1021/ja067077t Supporting Info

Driven Evolution of a Constitutional Dynamic Library of Molecular Helices Toward the Selective Generation of [2 × 2] Gridlike Arrays under the Pressure of Metal Ion Coordination Nicolas Giuseppone, Jean-Louis Schmitt, and Jean-Marie Lehn pp 16748–16763 DOI: 10.1021/ja0666452 Supporting Info

Coordination Environment of a Site-Bound Metal Ion in the Hammerhead Ribozyme Determined by 15N and 2H ESEEM Spectroscopy Matthew Vogt, Simanti Lahiri, Charles G. Hoogstraten, R. David Britt, and Victoria J. DeRose pp 16764–16770 DOI: 10.1021/ja057035p

Carbohydrate Amino Acids:  The Intrinsic Conformational Preference for a β-Turn-Type Structure in a Carbopeptoid Building Block Rebecca A. Jockusch, Francis O. Talbot, Paul S. Rogers, Michela I. Simone, George W. J. Fleet, and John P. Simons pp 16771–16777 DOI: 10.1021/ja0607133 Supporting Info

Model for Proton Transport Coupled to Protein Conformational Change:  Application to Proton Pumping in the Bacteriorhodopsin Photocycle Antonio M. Ferreira and Donald Bashford pp 16778–16790 DOI: 10.1021/ja060742d

Electronic Switching of Single Silicon Atoms by Molecular Field Effects Krishnan R. Harikumar, John C. Polanyi, Peter A. Sloan, Serge Ayissi, and Werner A. Hofer pp 16791–16797 DOI: 10.1021/ja062874c Supporting Info

Hsc70 ATPase:  An Insight into Water Dissociation and Joint Catalytic Role of K+ and Mg2+ Metal Cations in the Hydrolysis Reaction Mauro Boero, Takashi Ikeda, Etsuro Ito, and Kiyoyuki Terakura pp 16798–16807 DOI: 10.1021/ja064117k

Electrochemical Investigations of the Interconversions between Catalytic and Inhibited States of the [FeFe]-Hydrogenase from Desulfovibrio desulfuricans Alison Parkin, Christine Cavazza, Juan C. Fontecilla-Camps, and Fraser A. Armstrong pp 16808–16815 DOI: 10.1021/ja064425i Supporting Info

Methyaluminoxane (MAO) Polymerization Mechanism and Kinetic Model from Ab Initio Molecular Dynamics and Electronic Structure Calculations Lacramioara Negureanu, Randall W. Hall, Leslie G. Butler, and Larry A. Simeral pp 16816–16826 DOI: 10.1021/ja064545q Supporting Info

Influence of Single-Walled Carbon Nanotubes Induced Crystallinity Enhancement and Morphology Change on Polymer Photovoltaic Devices Jianxin Geng and Tingying Zeng pp 16827–16833 DOI: 10.1021/ja065035z Supporting Info

Differential Sensing of Protein Influences by NO and CO Vibrations in Heme Adducts Mohammed Ibrahim, Changliang Xu, and Thomas G. Spiro pp 16834–16845 DOI: 10.1021/ja064859d Supporting Info

Adsorption of Molecular Hydrogen on Coordinatively Unsaturated Ni(II) Sites in a Nanoporous Hybrid Material Paul M. Forster, Juergen Eckert, Brandon D. Heiken, John B. Parise, Ji Woong Yoon, Sung Hwa Jhung, Jong-San Chang, and Anthony K. Cheetham pp 16846–16850 DOI: 10.1021/ja0649217 Supporting Info

A Theoretical Analysis of Rate Constants and Kinetic Isotope Effects Corresponding to Different Reactant Valleys in Lactate Dehydrogenase Silvia Ferrer, Iñaki Tuñón, Sergio Martí, Vicente Moliner, Mireia Garcia-Viloca, Àngels González-Lafont, and José M. Lluch pp 16851–16863 DOI: 10.1021/ja0653977 Supporting Info

Dissecting and Reducing the Heterogeneity of Excited-State Energy Transport in DNA-Based Photonic Wires Mike Heilemann, Robert Kasper, Philip Tinnefeld, and Markus Sauer pp 16864–16875 DOI: 10.1021/ja065585x

Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn2+ Coordination Sites Mircea Dinc, Anne Dailly, Yun Liu, Craig M. Brown, Dan. A. Neumann, and Jeffrey R. Long pp 16876–16883 DOI: 10.1021/ja0656853 Supporting Info

Chemical Grafting of Biphenyl Self-Assembled Monolayers on Ultrananocrystalline Diamond Simon Q. Lud, Marin Steenackers, Rainer Jordan, Paola Bruno, Dieter M. Gruen, Peter Feulner, Jose A. Garrido, and Martin Stutzmann pp 16884–16891 DOI: 10.1021/ja0657049

Coupling Molecular Beacons to Barcoded Metal Nanowires for Multiplexed, Sealed Chamber DNA Bioassays Rebecca L. Stoermer, Kristin B. Cederquist, Sean K. McFarland, Michael Y. Sha, Sharron G. Penn, and Christine D. Keating pp 16892–16903 DOI: 10.1021/ja0658261 Supporting Info

Elucidation of Hydrolysis Mechanisms for Fatty Acid Amide Hydrolase and Its Lys142Ala Variant via QM/MM Simulations Ivan Tubert-Brohman, Orlando Acevedo, and William L. Jorgensen pp 16904–16913 DOI: 10.1021/ja065863s

Synthesis, Properties, and Reactions of a Series of Stable Dialkyl-Substituted Silicon−Chalcogen Doubly Bonded Compounds Takeaki Iwamoto, Katsuhiro Sato, Shintaro Ishida, Chizuko Kabuto, and Mitsuo Kira pp 16914–16920 DOI: 10.1021/ja065774f Supporting Info

Catalytic Mechanism of Glycosyltransferases:  Hybrid Quantum Mechanical/Molecular Mechanical Study of the Inverting N-Acetylglucosaminyltransferase I Stanislav Kozmon and Igor Tvaroška pp 16921–16927 DOI: 10.1021/ja065944o Supporting Info

Self-Organization of Polybases Neutralized with Mesogenic Wedge-Shaped Sulfonic Acid Molecules:  An Approach toward Supramolecular Cylinders Xiaomin Zhu, Uwe Beginn, Martin Möller, Raluca I. Gearba, Denis V. Anokhin, and Dimitri A. Ivanov pp 16928–16937 DOI: 10.1021/ja065968v Supporting Info

Microsolvation Effects on the Excited-State Dynamics of Protonated Tryptophan Sébastien R. Mercier, Oleg V. Boyarkin, Anthi Kamariotis, Matteo Guglielmi, Ivano Tavernelli, Michele Cascella, Ursula Rothlisberger, and Thomas R. Rizzo pp 16938–16943 DOI: 10.1021/ja065980n Supporting Info

Efficient Intramolecular General Acid Catalysis of Nucleophilic Attack on a Phosphodiester Anthony J. Kirby, Marcelo F. Lima, Davi da Silva, Christo D. Roussev, and Faruk Nome pp 16944–16952 DOI: 10.1021/ja066439u Supporting Info

Seeded Growth of Asymmetric Binary Nanocrystals Made of a Semiconductor TiO2 Rodlike Section and a Magnetic γ-Fe2O3 Spherical Domain Raffaella Buonsanti, Vincenzo Grillo, Elvio Carlino, Cinzia Giannini, Maria Lucia Curri, Claudia Innocenti, Claudio Sangregorio, Klaus Achterhold, Fritz Günter Parak, Angela Agostiano, and Pantaleo Davide Cozzoli pp 16953–16970 DOI: 10.1021/ja066557h Supporting Info

Mechanism of Catalytic Aziridination with Manganese Corrole:  The Often Postulated High-Valent Mn(V) Imido Is Not the Group Transfer Reagent Michael J. Zdilla and Mahdi M. Abu-Omar pp 16971–16979 DOI: 10.1021/ja0665489 Supporting Info

Diastereomeric Xe Chemical Shifts in Tethered Cryptophane Cages E. Janette Ruiz, Devin N. Sears, Alexander Pines, and Cynthia J. Jameson pp 16980–16988 DOI: 10.1021/ja066661z

Total Synthesis, Structure Revision, and Absolute Configuration of (−)-Brevenal Haruhiko Fuwa, Makoto Ebine, Andrea J. Bourdelais, Daniel G. Baden, and Makoto Sasaki pp 16989–16999 DOI: 10.1021/ja066772y Supporting Info

Exploring the Actinide−Actinide Bond:  Theoretical Studies of the Chemical Bond in Ac2, Th2, Pa2, and U2 Björn O. Roos, Per-Åke Malmqvist, and Laura Gagliardi pp 17000–17006 DOI: 10.1021/ja066615z

High-Resolution Electronic Spectra of Ethylenedioxythiophene Oligomers Dorothee Wasserberg, Stefan C. J. Meskers, René A. J. Janssen, Elena Mena-Osteritz, and Peter Bäuerle pp 17007–17017 DOI: 10.1021/ja066920k Supporting Info

Glyoxalase I-type Hemithioacetal Isomerization Reactivity of a Mononuclear Ni(II) Deprotonated Amide Complex Katarzyna Rudzka, Atta M. Arif, and Lisa M. Berreau pp 17018–17023 DOI: 10.1021/ja0601336 Supporting Info

Expression of a Supramolecular Complex at a Multivalent Interface Olga Crespo-Biel, Choon Woo Lim, Bart Jan Ravoo, David N. Reinhoudt, and Jurriaan Huskens pp 17024–17032 DOI: 10.1021/ja0637705 Supporting Info

Reduction of O2 to Superoxide Anion (O2•-) in Water by Heteropolytungstate Cluster-Anions Yurii V. Geletii, Craig L. Hill, Rajai H. Atalla, and Ira A. Weinstock pp 17033–17042 DOI: 10.1021/ja064244g Supporting Info

Synthesis, Structure, and Resolution of Exceptionally Twisted Pentacenes Jun Lu, Douglas M. Ho, Nancy J. Vogelaar, Christina M. Kraml, Stefan Bernhard, Neal Byrne, Laura R. Kim, and Robert A. Pascal, Jr. pp 17043–17050 DOI: 10.1021/ja065935f Supporting Info

Asymmetric Induction in Hydrogen-Mediated Reductive Aldol Additions to α-Amino Aldehydes Catalyzed by Rhodium:  Selective Formation of syn-Stereotriads Directed by Intramolecular Hydrogen-Bonding Cheol-Kyu Jung and Michael J. Krische pp 17051–17056 DOI: 10.1021/ja066198q Supporting Info

Total Synthesis of (−)-Heptemerone B and (−)-Guanacastepene E Aubry K. Miller, Chambers C. Hughes, Joshua J. Kennedy-Smith, Stefan N. Gradl, and Dirk Trauner pp 17057–17062 DOI: 10.1021/ja0660507 Supporting Info

On the Mechanism of an Asymmetric α,β-Unsaturated Carboxylic Acid Hydrogenation:  Application to the Synthesis of a PGD2 Receptor Antagonist David M. Tellers, J. Christopher McWilliams, Guy Humphrey, Michel Journet, Lisa DiMichele, Joseph Hinksmon, Arlene E. McKeown, Thorsten Rosner, Yongkui Sun, and Richard D. Tillyer pp 17063–17073 DOI: 10.1021/ja0623358 Supporting Info

Thermal Formation of Homochiral Serine Clusters and Implications for the Origin of Homochirality Pengxiang Yang, Ruifeng Xu, Sergio C. Nanita, and R. Graham Cooks pp 17074–17086 DOI: 10.1021/ja064617d Supporting Info

Cycloalkane and Cycloalkene C−H Bond Dissociation Energies Zhixin Tian, Alireza Fattahi, Lev Lis, and Steven R. Kass pp 17087–17092 DOI: 10.1021/ja065348u Supporting Info

Chemistry of the Silica Surface:  Liquid−Solid Reactions of Silica Gel with Trimethylaluminum Jianhua Li, Joseph A. DiVerdi, and Gary E. Maciel pp 17093–17101 DOI: 10.1021/ja065497c Supporting Info

Population Balance Models and Monte Carlo Simulation for Nanoparticle Formation in Water-in-Oil Microemulsions:  Implications for CdS Synthesis Mani Ethayaraja and Rajdip Bandyopadhyaya pp 17102–17113 DOI: 10.1021/ja0652621 Supporting Info

Temperature- and Solvent-Dependent Binding of Dihydrogen in Iridium Pincer Complexes Inigo Göttker-Schnetmann, D. Michael Heinekey, and Maurice Brookhart pp 17114–17119 DOI: 10.1021/ja065854j

Metal-Catalyzed Phosphodiester Cleavage:  Secondary 18O Isotope Effects as an Indicator of Mechanism Jill Rawlings, W. Wallace Cleland, and Alvan C. Hengge pp 17120–17125 DOI: 10.1021/ja065931a

Chiral Self-Recognition:  Direct Spectroscopic Detection of the Homochiral and Heterochiral Dimers of Propylene Oxide in the Gas Phase Zheng Su, Nicole Borho, and Yunjie Xu pp 17126–17131 DOI: 10.1021/ja066128j Supporting Info

Mechanism of Electrochemical Charge Transport in Individual Transition Metal Complexes Tim Albrecht, Adrian Guckian, Alexander M. Kuznetsov, Johannes G. Vos, and Jens Ulstrup pp 17132–17138 DOI: 10.1021/ja066213r Supporting Info

When Does an Intermediate Become a Transition State? Degenerate Isomerization without Competing Racemization during Solvolysis of (S)-1-(3-Nitrophenyl)ethyl Tosylate Yutaka Tsuji and John P. Richard pp 17139–17145 DOI: 10.1021/ja066235d

Changeover during in Situ Compositional Modulation of Hexacyanoferrate (Prussian Blue) Material Paulo Roberto Bueno, David Giménez-Romero, Claude Gabrielli, José Juan García-Jareño, Hubert Perrot, and Francisco Vicente pp 17146–17152 DOI: 10.1021/ja066982a

Microporous Metal−Organic Frameworks Incorporating 1,4-Benzeneditetrazolate:  Syntheses, Structures, and Hydrogen Storage Properties [J. Am. Chem. Soc. 2006, 128, 8904−8913]. Mircea Dinc, Anta F. Yu, and Jeffrey R. Long p 17153 DOI: 10.1021/ja068019a Supporting Info

Organocatalytic Direct Michael Reaction of Ketones and Aldehydes with β-Nitrostyrene in Brine  [J. Am. Chem. Soc. 2006, 128, 4966−4967]. Nobuyuki Mase, Kaori Watanabe, Hidemi Yoda, Kunihiko Takabe, Fujie Tanaka, and Carlos F. Barbas III p 17153 DOI: 10.1021/ja069980z

Dramatic Increases in the Lifetime of the Er3+ Ion in a Molecular Complex Using a Perfluorinated Imidodiphosphonate Sensitizing Ligand  [J. Am. Chem. Soc. 2005, 127, 524−525].  Gaetano Mancino, Andrew J. Ferguson, Andrew Beeby, Nicholas J. Long, and Tim S. Jones p 17153 DOI: 10.1021/ja069982j

Propargyl Glycosides as Stable Glycosyl Donors:  Anomeric Activation and Glycoside Syntheses [J. Am. Chem. Soc. 2006, 128, 9620−9621]. Srinivas Hotha and Sudhir Kashyap pp 17153–17154 DOI: 10.1021/ja067885k

An OFF−OFF−ON Fluorescence Sensor for Metal Ions in Stepwise Complex Formation of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine with Metal Ions  [J. Am. Chem. Soc. 2006, 128, 15976−15977]. Junpei Yuasa and Shunichi Fukuzumi p 17154 DOI: 10.1021/ja069981r Supporting Info

Review of Scanning Auger Electron Microscopy Edited by Martin Prutton and Mohamed M. El Gomati (University of York, UK). John Wiley & Sons, Ltd:  Chichester. 2006. xviii + 368 pp. $200.00. ISBN 0-470-86677-2. Joseph A. Gardella, Jr. p 17155 DOI: 10.1021/ja0697673

Radicals in Synthesis I:  Methods and Mechanisms. Topics in Current Chemistry, 263 Edited by Andreas Gansäuer (Universität Bonn, Germany) Springer:  Berlin, Heidelberg, New York. 2006. xii + 204 pp. $ 209. ISBN 3-540-31329-X. T. V. RajanBabu pp 17155–17156 DOI: 10.1021/ja069768v

Organofluorine Chemistry By Kenji Uneyama (Okayama University, Japan). Blackwell Publishing, Ltd.:  Oxford. 2006. x + 340 pp. $179.99. ISBN 1-4051-2561-6. Markus Etzkorn p 17156 DOI: 10.1021/ja0697976

Chemical Dynamics in the Condensed Phases:  Relaxation, Transfer, and Reactions in Condensed Molecular Systems By Abraham Nitzan (Tel Aviv University). Oxford University Press:  Oxford, New York. 2006. xxii + 720 pp. $89.50. ISBN 0-19-852979-1. Eric R. Bittner pp 17156–17157 DOI: 10.1021/ja069771e

Exploiting Chemical Diversity for Drug Discovery Edited by Paul A. Bartlett (University of California, Berkeley) and Michael Entzeroth (S*Bio Pte Ltd, Singapore). Royal Society of Chemistry:  Cambridge. 2006. xxiv + 420 pp. $219. ISBN 0-85404-842-1. Terence A. Kelly p 17157 DOI: 10.1021/ja069758u